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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/80268完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 康敦彥(Dun-Yen Kang) | |
| dc.contributor.author | Yi-Jui Hsieh | en |
| dc.contributor.author | 謝宜芮 | zh_TW |
| dc.date.accessioned | 2022-11-24T03:03:34Z | - |
| dc.date.available | 2021-07-23 | |
| dc.date.available | 2022-11-24T03:03:34Z | - |
| dc.date.copyright | 2021-07-23 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-07-05 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/80268 | - |
| dc.description.abstract | "金屬有機骨架(Metal-organic frameworks, MOFs)是一種結晶性多孔材料，具有高表面積、多樣性、結構彈性、孔徑大小也能藉由分子設計來調控。因此被廣泛應用在薄膜分離、觸媒反應、吸附等。因大多金屬有機骨架薄膜在液態中存在穩定性問題或是在合成薄膜過程中會產生薄膜缺陷問題，所以在滲透蒸發領域中並沒有太多成功利用純金屬有機骨架薄膜進行醇類(乙醇或異丙醇)和水分離的相關文獻。大多是採用沸石薄膜、高分子薄膜或是有機/無機複合膜來進行滲透蒸發的研究。因此本研究著重在使用純金屬有機骨架薄膜(Zn-aip-azpy)來探討薄膜對於醇類和水的分離能力，同時我們也發現薄膜的沉積步驟對於形成高質量緻密膜有著非常大的影響。此外我們也探討了在薄膜表面塗佈一層poly(vinyl alcohol)(PVA)是否能提高薄膜在滲透蒸發實驗中的穩定性。而在薄膜滲透蒸發效能的探討中，我們分別將薄膜針對結構穩定性、化學穩定性及熱穩定性來進行討論，並比較as-synthesized Zn-aip-azpy薄膜和PVA/Zn-aip-azpy薄膜在不同條件下的滲透蒸發效能。本研究藉由二次生長法來製備Zn-aip-azpy薄膜，並輔以XRD、SEM、FT-IR、接觸角儀等儀器檢測薄膜的結構及性質，接著比較Zn-aip-azpy薄膜和PVA/Zn-aip-azpy薄膜在不同條件下滲透蒸發的表現。我們發現薄膜在90 wt.%異丙醇水溶液中的表現最佳且最穩定，對於Zn-aip-azpy薄膜而言，水對異丙醇的分離係數約450，而PVA/Zn-aip-azpy薄膜則可以達到接近2000。本研究同時也利用薄膜空氣滲透實驗來驗證及說明滲透蒸發表現和薄膜缺陷間的關係。" | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-24T03:03:34Z (GMT). No. of bitstreams: 1 U0001-0307202117230100.pdf: 6248321 bytes, checksum: b2dcd83d111ee07d015ff17d825db7d6 (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 口試委員會審定書 I 誌謝 II 摘要 III Abstract IV 目錄 V 圖目錄 VIII 表目錄 XI 第1章、 緒論 1 1.1 研究動機 1 1.2 研究目的 3 第2章、 文獻回顧 4 2.1 薄膜分離程序 4 2.1.1 薄膜分離程序簡介 4 2.1.2 滲透蒸發薄膜應用 7 2.1.3 薄膜分離機制 9 2.2 金屬有機骨架薄膜 13 2.2.1 金屬有機骨架簡介 13 2.2.2 金屬有機骨架薄膜合成 17 2.2.3 金屬有機骨架應用於滲透蒸發之文獻回顧 19 第3章、 實驗步驟與方法 22 3.1 實驗藥品 22 3.2 薄膜製程步驟 23 3.2.1 Zn-aip-azpy粉體合成 23 3.2.2 Zn-aip-azpy 晶種層(Seed layer)合成 24 3.2.3 Zn-aip-azpy 薄膜二次生長 25 3.2.4 旋轉塗佈PVA於薄膜表層 26 3.3 材料檢測儀器 27 3.3.1 X光繞射 (XRD) 27 3.3.2 場發射掃描式電子顯微鏡 (FE-SEM) 28 3.3.3 接觸角量測儀 28 3.3.4 傅立葉轉換紅外光譜儀 (FT-IR) 29 3.3.5 氣相層析儀 (GC) 29 3.4 Rietveld Refinement 結構精修 31 3.5 薄膜滲透蒸發實驗 31 3.6 薄膜空氣滲透實驗 33 第4章、 結果與討論 35 4.1 金屬有機骨架薄膜結構鑑定與分析結果 35 4.1.1 Zn-aip-azpy粉體合成 35 4.1.2 Zn-aip-azpy晶種層沉積 36 4.1.3 Zn-aip-azpy薄膜合成 37 4.1.4 Zn-aip-azpy之晶體結構擬合 42 4.2 Zn-aip-azpy薄膜滲透蒸發效能 45 4.2.1 Zn-aip-azpy薄膜於異丙醇-水滲透蒸發之結果 45 4.2.2 Zn-aip-azpy薄膜之熱穩定性 52 4.2.3 Zn-aip-azpy薄膜於乙醇-水滲透蒸發之結果 55 4.2.4 Zn-aip-azpy薄膜滲透蒸發效能與相關文獻比較 58 4.3 薄膜空氣滲透率結果討論 61 4.3.1 薄膜操作時間長短對空氣滲透率的影響 61 4.3.2 不同溫度滲透蒸發後之空氣滲透率檢測結果 63 4.3.3 不同醇類滲透蒸發後之空氣滲透率檢測結果 65 4.3.4 統整空氣滲透率實驗結果 67 第5章、 結論與未來展望 69 參考文獻 70 | |
| dc.language.iso | zh-TW | |
| dc.subject | 醇類除水 | zh_TW |
| dc.subject | 金屬有機骨架 | zh_TW |
| dc.subject | 金屬有機骨架薄膜 | zh_TW |
| dc.subject | 滲透蒸發 | zh_TW |
| dc.subject | 異丙醇 | zh_TW |
| dc.subject | Metal-organic framework | en |
| dc.subject | alcohol dehydration | en |
| dc.subject | isopropanol | en |
| dc.subject | pervaporation | en |
| dc.subject | metal-organic framework membrane | en |
| dc.title | 層狀金屬有機骨架薄膜於滲透蒸發之應用 | zh_TW |
| dc.title | Layered Metal-Organic Framework Membrane for Pervaporation | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 王大銘(Hsin-Tsai Liu),羅世強(Chih-Yang Tseng),林立強 | |
| dc.subject.keyword | 金屬有機骨架,金屬有機骨架薄膜,滲透蒸發,異丙醇,醇類除水, | zh_TW |
| dc.subject.keyword | Metal-organic framework,metal-organic framework membrane,pervaporation,isopropanol,alcohol dehydration, | en |
| dc.relation.page | 84 | |
| dc.identifier.doi | 10.6342/NTU202101252 | |
| dc.rights.note | 同意授權(限校園內公開) | |
| dc.date.accepted | 2021-07-05 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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