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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/80257完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱靜雯(Ching-Wen Chiu) | |
| dc.contributor.author | Kun-Hao Chen | en |
| dc.contributor.author | 陳崑豪 | zh_TW |
| dc.date.accessioned | 2022-11-24T03:03:22Z | - |
| dc.date.available | 2021-07-23 | |
| dc.date.available | 2022-11-24T03:03:22Z | - |
| dc.date.copyright | 2021-07-23 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-07-05 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/80257 | - |
| dc.description.abstract | 為了研究二價金屬烯的反應性，我們成功地合成了具non-innocent配基之鍺烯與錫烯化合物。具non-innocent配基之鍺化合物可以當作是吡啶環化的N-雜環鍺烯（2）或中性的α-亞氨基吡啶配位的鍺零價化合物（2'）。在2與鹽酸和三氯化硼的反應中觀察到鍺中心與配位基的協同作用，證實在二價鍺原子上存在一個空的p軌域。接著我們發現配位基容易從2轉移到二氯化鍺或二氯化錫之中，並且伴隨著金屬元素鍺沉澱出來，反映了中心零價鍺原子的高電子密度特性。另外也使用兩個當量的四氯-鄰-苯醌進行四個電子的氧化反應，進一步驗證了2具有零價鍺的性質，同時得到了六配位的四價鍺化合物。此外，我們還利用二[二(三甲基甲矽基)氨基] 錫與α-亞氨基吡啶配位基進行轉氨基作用，製備了吡啶配位的二氨基錫烯。接著合成與鑑定含錫基和吡啶基雙牙配位基的釕金屬錯合物，並將其用於酮的氫轉移催化之中。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-24T03:03:22Z (GMT). No. of bitstreams: 1 U0001-0507202117083000.pdf: 6870632 bytes, checksum: 0378c2fed55876b38eb10beae297f2ff (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | "口試委員會審定書 i 謝誌 ii 摘要 iii Abstract iv Contents v List of Figures ix List of Schemes xii List of Tables xiv Chapter 1. Introduction 1 1.1 Metallylenes 1 1.1.1 Germylene 5 1.1.2 Reactivity of Metallylenes 7 1.2 Non-innocent Ligand 10 1.3 Metallylones 15 1.3.1 Carbenes or Metallylenes Stabilized Metallylones 16 1.3.2 Redox Non-innocent Ligand Supported Metallylones 17 1.3.3 Reactivity of Metallylones 18 1.4 Molecular Design 19 1.5 Transfer Hydrogenation of Ketones 21 Chapter 2. Results and Discussion 26 2.1 Non-innocent Ligand Supported Germylenes 26 2.1.1 Synthesis and Characterization 26 2.1.2 Reactivity Study 33 2.2 Non-innocent Ligand Supported Stannylenes 45 2.2.1 Synthesis and Characterization 45 2.2.2 Reactivity Study 47 Chapter 3. Conclusion 59 Chapter 4. Experimental Section 60 General Procedure 60 Germanium(Ⅱ) chloride dioxane complex GeCl2‧C4H8O2 61 Germanium(Ⅱ) bis[bis(trimethylsilyl)amide] Ge[N(SiMe3)2]2 61 Tin(Ⅱ) bis[bis(trimethylsilyl)amide] Sn[N(SiMe3)2]2 62 Synthesis of [(C5H4N)CH2NH(2,4,6-Me3C6H2)] (L) 62 Synthesis of [(C5H4N)CH2N(2,4,6-Me3C6H2)]GeN(SiMe3)2 (1) 63 Synthesis of [C4H4C=CHN(2,4,6-Me3C6H2)]Ge (2) 64 Synthesis of [(C5H4N)CH2N(2,4,6-Me3C6H2)]GeCl (3) 65 Synthesis of [(C5H4N)CH(BCl2)N(2,4,6-Me3C6H2)]GeCl (4) 66 Synthesis of [(C5H4N)HC=N(2,4,6-Me3C6H2)]GeCl[GeCl3-] (5) 67 Synthesis of [(C5H4N)HC=N(2,4,6-Me3C6H2)]SnCl[SnCl3-] (6) 68 Synthesis of [(C5H4N)HC=N(2,4,6-Me3C6H2)]Ge(Ⅳ)(κ2(O,O)-O2C6Cl4)2 (8) 69 Synthesis of [(C5H4N)CH2N(2,4,6-Me3C6H2)]SnN(SiMe3)2 (9) 70 Synthesis of [(C5H4N)CH2N(2,4,6-Me3C6H2)]SnCl[N(SiMe3)2]RuCl(C10H14) (10) 71 Synthesis of [(C5H4N)CH2N(2,4,6-Me3C6H2)]SnN3 (13) 72 Synthesis of [(C5H4N)CH2N(2,4,6-Me3C6H2)]SnCl (14) 73 Synthesis of [(C5H4N)CH2N(2,4,6-Me3C6H2)]SnBr (15) 73 Synthesis of [(C5H4N)CH2N(2,4,6-Me3C6H2)]SnF (16) 74 Synthesis of [(C5H4N)CH2N(2,4,6-Me3C6H2)]BF2 (17) 74 General Procedure for catalytic Transfer Hydrogenation of ketones 75 Characterization of the alcohols 75 1-Phenylethanol (12a) 75 Diphenylmethanol (12b) 76 1-(4-Methoxyphenyl)ethanol (12c) 76 1-(4-Trifluoromethylphenyl)ethanol (12d) 76 1-(Pyridin-3-yl)ethanol (12e) 77 X-ray Crystallography 77 Theoretical Calculations 78 Electron Paramagnetic Resonance 78 Other Reactivity Studies for Germylene 2 79 References 82 Appendix 98 NMR Spectra 98 Crystal Data 138 Optimized structure of 2 in xyz format 175 " | |
| dc.language.iso | en | |
| dc.subject | 鍺烯 | zh_TW |
| dc.subject | 氫轉移催化 | zh_TW |
| dc.subject | 錫基釕金屬錯合物 | zh_TW |
| dc.subject | non-innocent配基 | zh_TW |
| dc.subject | 錫烯 | zh_TW |
| dc.subject | non-innocent ligand | en |
| dc.subject | transfer hydrogenation | en |
| dc.subject | germylene | en |
| dc.subject | germylone | en |
| dc.subject | stannylene | en |
| dc.title | 具Non-innocent配基之鍺烯與錫烯 | zh_TW |
| dc.title | Non-innocent Ligand Supported Germylenes and Stannylenes | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 蔡易州(Hsin-Tsai Liu),劉學儒(Chih-Yang Tseng) | |
| dc.subject.keyword | 鍺烯,錫烯,non-innocent配基,錫基釕金屬錯合物,氫轉移催化, | zh_TW |
| dc.subject.keyword | germylene,germylone,non-innocent ligand,stannylene,transfer hydrogenation, | en |
| dc.relation.page | 176 | |
| dc.identifier.doi | 10.6342/NTU202101278 | |
| dc.rights.note | 同意授權(限校園內公開) | |
| dc.date.accepted | 2021-07-06 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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