請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/79841完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢(Sheng-Hsien Chiu) | |
| dc.contributor.author | Hung-Te Cheng | en |
| dc.contributor.author | 鄭閎德 | zh_TW |
| dc.contributor.author | f04223174 | |
| dc.date.accessioned | 2022-11-23T09:13:27Z | - |
| dc.date.available | 2021-11-08 | |
| dc.date.available | 2022-11-23T09:13:27Z | - |
| dc.date.copyright | 2021-11-08 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-08-16 | |
| dc.identifier.citation | [1] (a) C. J. Pedersen, J. Am. Chem. Soc., 1967, 89, 7017-7036; (b) C. J. Pedersen, Angew. Chem. Int. Ed. Engl., 1988, 27, 1021; (c) G. W. Gokel Crown Ether Cambridge, Royal Society of Chemistry, 1990. [2] G. G. Ferenczy, G. Naray-Szabo, Chem. Rev. 1995, 95, 829-847. [3] (a) D. Dougherty, Science 1996, 271, 163-168; (b) J. C. Ma, D. A. Dougherty, Chem. Rev. 1997, 97, 1303-1324; (c) G. W. Gokel, S. L. De Wall, E. S. Meadows, Eur. J. Org. Chem. 2000, 17, 1967-1978; (d) G. W. Gokel, L. J. Barbour, R. Ferdani, J. Hu, Acc. Chem. Res. 2002, 35, 878-886. [4] (a) C. A. Hunter, J. K. M. Sanders, J. Am. Chem. Soc. 1990, 112, 5525-5534; (b) D. G. Hamilton, J. E. Davies, L. Prodi, J. K. M. Sanders, Chem. Eur. J. 1998, 4, 608-620. [5] G. M. Whitesides, E. E. Simanek, J. P. Mathias, C. T. Seto, D. N. Chin, M. Mammen, D. M. Gordon, Acc. Chem. Res. 1995, 28, 37-44. [6] A.-M. Albrecht-Gary, C. Dietrich-Buchecker, Z. Saad, J.-P. Sauvage, J. Am. Chem. Soc. 1988, 110, 1467-1472. [7] (a) L. R. Pratt, D. J. Chandler, J. Chem. Phys. 1977, 67, 3683-3704; (b) D. Chandler, Nature 2005, 437, 640-647. [8] (a) H. Krause, H. Neusser, Chem. Rev. 1994, 94, 1829-1843; (b) C. Desfrancois, S. Carles, J. P. Schermann, Chem. Rev. 2000, 100, 3943-3962. [9] C. J. Bruns, J. F. Stoddart, The Nature of the Mechanical Bond: From Molecules to Machines, Wiley, New Jersey, 2016. [10] (a) G. W. Gokel, Crown Ethers and Cryptands, Royal Society of Chemistry, 1991; (b) D. J. Cram, J. M. Cram, Container Molecules and Their Guests, Royal Society of Chemistry, 1997; (c) F. Vögtle, E. Weber, Host guest complex chemistry macrocycles: synthesis, structure, application, Springer, 1985. [11] G. M. Whitesides, J. P. Mathias, C. T. Seto, Science 1991, 254, 1312-1319. [12] J. L. Atwood, Inclusion phenomena and molecular recognition, Plenum Press, 1990. [13] Y. Yang, M. W. Urban, Chem. Soc. Rev., 2013, 42, 7446-7467. [14] (a) P. A. Brady, J. K. M. Sanders, Chem. Soc. Rev. 1997, 26, 327-336; (b) J. M. Lehn, A. V. Eliseev, Science 2001, 291, 2331-2332. [15] D. B. Amabilino, P. R. Ashton, J. A. Bravo, F. M. Raymo, J. F. Stoddart, A. J. P. White, D. J. Williams, Eur. J. Org. Chem. 1999, 1295-1302. [16] A. R. Williams, B. H. Northrop, T. Chang, J. F. Stoddart, A. J. P. White, D. J. Williams, Angew. Chem. Int. Ed. 2006, 45, 6665-6669. [17] J. C. Chang, S. H. Tseng, C. Chen. Lai, Y. H. Liu, S. M. Peng, S. H. Chiu, Nat. Chem. 2017, 9, 128-134. [18] Q. Gan, Y. Ferrand, C. Bao, B. Kauffmann, A. Grélard, H. Jiang, I. Huc, Science 2011, 331, 1172-1175. [19] S.-H. Li, H. Y. Zhang, X. Xu, Y. Liu, Nat. Commun. 2015, 6, 7590. [20] S. J. Cantrill , K. S. Chichak , A. J. Peters, J. F. Stoddart, Acc. Chem. Res., 2005, 38 , 1-9. [21] I. T. Harrison, S. Harrison, J. Am. Chem. Soc. 1967, 89, 5723-5724. [22] K. Hiratani, J.-I. Suga, Y. Nagawa, H. Houjou, H. Tokuhisa, M. Numata, K. Watanabe, Tetrahedron Lett. 2002, 43, 5747-5750. [23] V. Aucagne, J. Berná, J. D. Crowley, S. M. Goldup, K. D. Hänni, D. A. Leigh, P. Lusby, V. E. Ronaldson, A. M. Z. Slawin, A. Viterisi, D. B. Walker, J. Am. Chem. Soc. 2007, 129, 11950-11963. [24] D. Pomeranc, D. Jouvenot, J.-C. Chambron, J. P. Collin, V. Heitz, J.-P. Sauvage, Chem. Eur. J. 2003, 9, 4247-4254. [25] (a) M. Asakawa, W. Dehaen, G. L’abbé, S. Menzer, J. Nouwen, F. M. Raymo, J. F. Stoddart, D. J. Williams, J. Org. Chem. 1996, 61, 9591-9595; (b) W. R. Dichtel, O. Š. Miljanić, J. M. Spruell, J. R. Heath, J. F. Stoddart, J. Am. Chem. Soc. 2006, 128, 10388-10390. [26] R. Ahmed, A. Altieri, D. M. D’Souza, D. A. Leigh, K. M. Mullen, M. Papmeyer, A. M. Z. Slawin, J. K. Y. Wong, J. D. Woollins, J. Am. Chem. Soc. 2011, 133, 12304-12310. [27] (a) C. Dietrich-Buchecker, J.-P. Sauvage, Chem. Commun. 1999, 615-616; (b) A.-M. Albrecht-Gary, C. Dietrich-Buchecker, Z. Saad, J.-P. Sauvage, J. Am. Chem. Soc. 1988, 110, 1467-1472; (c) A.-M. Albrecht-Gary, C. Dietrich-Buchecker, Z. Saad, J.-P. Sauvage, J. Chem. Soc. Chem. Commun. 1992, 280-282. [28] Y.-H. Lin, C.-C. Lai, Y.-H. Liu, S.-M. Peng, S.-H. Chiu, Angew. Chem. Int. Ed. 2013, 52, 10231-10236. [29] Y.-H. Lin, C.-C. Lai, S.-H. Chiu, Org. Biomol. Chem. 2014, 12, 2907-2917. [30] L.-Y. Wang, J.-L. Ko, C.-C. Lai, S.-H. Chiu, Chem. Eur. J. 2013, 19, 8850-8860. [31] T. Ogoshi, T. Aoki, R. Shiga, R. Iizuka, S. Ueda, K. Demachi, D. Yamafuji, H. Kayama, T.-a. Yamagishi, J. Am. Chem. Soc. 2012, 134, 20322-20325. [32] T.-H. Ho, C.-C. Lai, Y.-H. Liu, S.-M. Peng, S.-H. Chiu, Chem. Eur. J. 2014, 20, 4563-4567. [33] (a) M. C. T. Fyfe, F. M. Raymo, J. F. Stoddart, Stimul. Concepts Chem. 2005, 211-220; (b) S.-Y. Hsueh, C.-C. Lai, Y.-H. Liu, Y. Wang, S.-M. Peng, S.-H. Chiu, Org. Lett. 2007, 9, 45233-4526; (c) F. M. Raymo, K. N. Houk, J. F. Stoddart, J. Am. Chem. Soc. 1998, 120, 9318-9322. [34] (a) C.-W. Chiu, C.-C. Lai, S.-H. Chiu, J. Am. Chem. Soc. 2007, 129, 3500-3501; (b) S.-H. Ueng, S.-Y. Hsueh, C.-C. Lai, Y.-H. Liu, S.-M. Peng, S.-H. Chiu, Chem. Commun. 2008, 817-819. [35] (a) I. Yoon, M. Narita, T. Shimizu, M. Asakawa, J. Am. Chem. Soc. 2004, 126, 16740-16741; (b) S.-Y. Hsueh, J.-L. Ko, C.-C. Lai, Y.-H. Liu, S.-M. Peng, S.-H. Chiu, Angew. Chem. Int. Ed. 2011, 50, 6643-6646. [36] (a) Molecular Gels (Eds.: R. G. Weiss, P. Terech), Springer, Dordrecht, 2005; (b) Functional Molecular Gels (Eds.: B. Escuder, J. F. Miravet), RSC, Cambridge, 2014. [37] (a) T. H. Kim, M. S. Choi, B.-H. Sohn, S.-Y. Park, W.-S. Lyoo and T. S. Lee, Chem. Commun. 2008, 2364-2366; (b) M. Teng , G. Kuang , X. Jia , M. Gao , Y. Li and Y. Wei, J. Mater. Chem. 2009, 19, 5648-5654. [38] A. Vintiloiu, J.-C. Leroux, J. Control. Release, 2008, 125, 179-192. [39] J.-X. Xiang, L. Shen, Y.-L. Hong, Eur. Polym. J., 2020, 130, 109609. [40] (a) S. Kobayashi, N. Hamasahi, M. Suzuki, M. Kimura, H. Shirai, K. Hanabusa, J. Am. Chem. Soc. 2002, 124, 6550-6551; (b) K. Sada, M. Takeuchi, N. Fujita, M. Numata, S. Shinkai, Chem. Soc. Rev. 2007, 36, 415-435. [41] A. Ajayaghosh, V. K. Praveen, C. Vijayakumar, Chem. Soc. Rev. 2008, 37, 109-122. [42] E. R. Draper, D. J. Adams, Chem. Commun. 2016, 52, 8196-8206. [43] P. Fatás, J. Bachl, S. Oehm, A. I. Jiménez, C. Cativiela and D. Díaz Díaz, Chem. Eur. J. 2013, 19, 8861-8874. [44] S. Miljanić, L. Frkanec, Z. Meić, M. Žinić, Eur. J. Org. Chem. 2006, 1323-1334. [45] S. Matsumoto, S. Yamaguchi, A. Wada, T. Matsui, M. Ikeda, I. Hamachi, Chem. Commun. 2008, 1545-1547. [46] Z. Qiu, H. Yu, J. Li, Y. Wang and Y. Zhang, Chem. Commun. 2009, 3342-3344. [47] Y.-L. Zhao, I. Aprahamain, A. Trabolsi, N. Erina, J. F. Stoddart, J. Am. Chem. Soc. 2008, 130, 6348-6350. [48] (a) S. Tamesue, Y. Takashima, H. Yamaguchi, S. Shinkai, A. Harada, Angew. Chem. Int. Ed. 2010, 49, 7461-7464; (b) K. Iwaso, Y. Takashima, A. Harada, Nat. Chem. 2016, 8, 625. [49] S.-Y. Hsueh, C.-T. Kuo, C.-C. Lai, Y.-H. Liu, H.-F. Hsu, S.-M. Peng, C.-H. Chen, S.-H. Chiu, Angew. Chem. Int. Ed. 2010, 49, 9170-9173; Angew. Chem. 2010, 122, 9356-9359. [50] (a) A.-M. Albrecht-Gary, Z. Saad, C. O. Dietrich-Buchecker, J.-P. Sauvage, J. Am. Chem. Soc. 1985, 107, 3205-3209; (b) K. Uekama, F. Hirayama, T. Irie, Chem. Rev. 1998, 98, 2045-2076; (c) A. H. Parham, B. Windisch, F. Vçgtle, Eur. J. Org. Chem. 1999, 1233-1238; (d) E. Arunkumar, N. Fu, B. D. Smith, Chem. Eur. J. 2006, 12, 4684-4690; (e) A. Fernandes, A. Viterisi, F. Coutrot, S. Potok, D. A. Leigh, V. Aucagne, S. Papot, Angew. Chem. Int. Ed. 2009, 48, 6443-6447; Angew. Chem. 2009, 121, 6565-6569; (f) C. B. Caputo, K. Zhu, V. N. Vukotic, S. J. Loeb, D. W. Stephan, Angew. Chem. Int. Ed. 2013, 52, 960-963; Angew. Chem. 2013, 125, 994-997. [51] (a) S.-T. Tung, C.-C. Lai, Y.-H. Liu, S.-M. Peng, S.-H. Chiu, Angew. Chem. Int. Ed. 2013, 52, 13269-13272; Angew. Chem. 2013, 125, 13511-13514; (b) T.-H. Ho, C.-C. Lai, Y.-H. Liu, S.-M. Peng, S.-H. Chiu, Chem. Eur. J. 2014, 20, 4563-4567. [52] (a) C. G. Bochet, Tetrahedron Lett. 2000, 41, 6341-6346; (b) K. K. Tanabe, C. A. Allen, S. M. Cohen, Angew. Chem. Int. Ed. 2010, 49, 9730-9733; Angew. Chem. 2010, 122, 9924-9927; (c) H. Zhao, E. S. Sterner, E. B. Coughlin, P. Theato, Macromolecules 2012, 45, 1723-1736. [53] (a) S. H. Strauss, Chem. Rev. 1993, 93, 927-942; (b) I. Krossing, I. Raabe, Angew. Chem. Int. Ed. 2004, 43, 2066-2090; Angew. Chem. 2004, 116, 2116-2142; (c) J. Pérez, L. Riera, L. Ion, V. Riera, K. M. Anderson, J. W. Steed, D. Miguel, Dalton Trans. 2008, 878-886; (d) C. Gaeta, F. Troisi, P. Neri, Org. Lett. 2010, 12, 2092-2095; (e) N.-C. Chen, C.-J. Chuang, L.-Y. Wang, C.-C. Lai, S.-H. Chiu, Chem. Eur. J. 2012, 18, 1896-1900; (f) Y.-J. Lee, K.-S. Liu, C.-C. Lai, Y.-H. Liu, S.-M. Peng, R. P. Cheng, S.-H. Chiu, Chem. Eur. J. 2017, 23, 9756-9760. [54] X.-Q. Li, V. Stepanenko, Z. Chen, P. Prins, L. D. A. Siebbeles, F. Wurthner, Chem. Commun. 2006, 3871-3873. [55] (a) D. J. Cornwell, B. O. Okesola, D. K. Smith, Angew. Chem. Int. Ed. 2014, 53, 12461-12465; Angew. Chem. 2014, 126, 12669-12673; (b) D. J. Cornwell, O. J. Daubney, D. K. Smith, J. Am. Chem. Soc. 2015, 137, 15486-15492; (c) E. E. Oseland, Z. J. Ayres, A. Basile, D. M. Haddleton, P. Wilson, P. R. Unwin, Chem. Commun. 2016, 52, 9929-9932; (d) X. He, J. Fan, J. Zou, K. L. Wooley, Chem. Commun. 2016, 52, 8455-8458; (e) J. H. Lee, S. H. Jung, S. S. Lee, K.-Y. Kwon, K. Sakurai, J. Jaworski, J. H. Jung, ACS Nano 2017, 11, 4155-4164. [56] M. Yamanaka, N. Haraya, S. Yamamichi, Chem. Asian J. 2011, 6, 1022-1025. [57] Z.-Q. Yu, X.-M. Xu, C.-Y. Hong, D.-C. Wu, Y.-Z. You, Macromolecules 2014, 47, 4136-4143. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/79841 | - |
| dc.description.abstract | 利用實驗室先前發現的兩種辨識系統，以鈉離子為模板，藉由乙二醇鏈對文獻上已報導具有醯胺或尿素單元的有機和水凝膠體分子進行辨識，便可以夾鎖法合成[2]車輪烷分子。我們在[2]車輪烷之大環分子的苯環上修飾鄰-硝基芐氧基，當使用紫外光照射含有車輪烷分子的溶液時，會使大環分子斷裂，釋放出膠體分子並且使溶液膠化，達到以光觸發溶液膠體化的效果。對內鎖有機膠體分子的[2]車輪烷溶液加上光阻圖像，再照射紫外光，可順利產生光固像化的效果；而內鎖水凝膠分子的[2]車輪烷分子溶液則只需在部分溶液照射紫外光，即可使整個溶液膠體化。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-23T09:13:27Z (GMT). No. of bitstreams: 1 U0001-0408202112530400.pdf: 10412572 bytes, checksum: 1002049a8e55513fc569ddc3bb51a74b (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | 口試委員審定書 I 謝詞 II 中文摘要 III 英文摘要 IV 論文發表 V 圖目錄 VII 流程目錄 IX 第一章、緒論 1 1.1 超分子化學與內鎖分子 1 1.2 內鎖分子-車輪烷的合成 3 第二章、以內鎖方式將一次性光觸發膠化特性導入已知的有機凝膠與水凝膠 11 2-1 研究動機 12 2-2 具有紫外光活性大環之合成與測試 19 2-3 光觸發有機凝膠車輪烷分子的合成及測試 22 2-4 光觸發水凝膠車輪烷分子的合成及測試 26 2-5 結論 31 第三章、實驗部分 32 第四章、參考資料 52 第五章、附錄 58 | |
| dc.language.iso | zh-TW | |
| dc.subject | 模板 | zh_TW |
| dc.subject | 機械互鎖分子 | zh_TW |
| dc.subject | 光裂解 | zh_TW |
| dc.subject | 凝膠 | zh_TW |
| dc.subject | 光致圖像化 | zh_TW |
| dc.subject | 車輪烷 | zh_TW |
| dc.subject | photo-patterning | en |
| dc.subject | templates | en |
| dc.subject | rotaxanes | en |
| dc.subject | MIMs | en |
| dc.subject | photo-cleavage | en |
| dc.subject | gels | en |
| dc.title | 以內鎖方式將一次性光觸發膠化特性導入已知的有機凝膠與水凝膠 | zh_TW |
| dc.title | Interlocked Photo-degradable Macrocycles Allow One-Off Photo-triggerable Gelation of Organo- and Hydrogelators | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 博士 | |
| dc.contributor.advisor-orcid | 邱勝賢(0000-0002-0040-1555) | |
| dc.contributor.oralexamcommittee | 徐秀福(Hsin-Tsai Liu),李文山(Chih-Yang Tseng),賴建成,陳平 | |
| dc.subject.keyword | 機械互鎖分子,光裂解,凝膠,光致圖像化,車輪烷,模板, | zh_TW |
| dc.subject.keyword | MIMs,photo-cleavage,gels,photo-patterning,rotaxanes,templates, | en |
| dc.relation.page | 100 | |
| dc.identifier.doi | 10.6342/NTU202102072 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2021-08-17 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| U0001-0408202112530400.pdf | 10.17 MB | Adobe PDF | 檢視/開啟 |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。