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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/79580完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 林逸彬(Yi-Pin Lin) | |
| dc.contributor.author | Chia-Chun Hsu | en |
| dc.contributor.author | 許佳君 | zh_TW |
| dc.date.accessioned | 2022-11-23T09:04:16Z | - |
| dc.date.available | 2021-11-08 | |
| dc.date.available | 2022-11-23T09:04:16Z | - |
| dc.date.copyright | 2021-11-08 | |
| dc.date.issued | 2021 | |
| dc.date.submitted | 2021-09-16 | |
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An often-overestimated adverse effect of halides in heat/persulfate-based degradation of wastewater contaminants. Environ Int, 130, 104918. Yang, X., Duan, Y., Wang, J., Wang, H., Liu, H. and Sedlak, D. L. (2019b). The Impact of Peroxymonocarbonate (HCO4 (-)) on the Transformation of Organic Contaminants during Hydrogen Peroxide (H2O2) in situ Chemical Oxidation (ISCO). Environ Sci Technol Lett, 6(12), 781-786. Yang, Y., Pignatello, J. J., Ma, J. and Mitch, W. A. (2014). Comparison of halide impacts on the efficiency of contaminant degradation by sulfate and hydroxyl radical-based advanced oxidation processes (AOPs). Environ Sci Technol, 48(4), 2344-2351. Yang, Y., Pignatello, J. J., Ma, J. and Mitch, W. A. (2016). Effect of matrix components on UV/H2O2 and UV/S2O8(2-) advanced oxidation processes for trace organic degradation in reverse osmosis brines from municipal wastewater reuse facilities. Water Res, 89, 192-200. Zhang, T., Chen, Y., Wang, Y., Le Roux, J., Yang, Y. and Croue, J. P. (2014). Efficient peroxydisulfate activation process not relying on sulfate radical generation for water pollutant degradation. Environ Sci Technol, 48(10), 5868-5875. Zhang, W., Zhou, S., Sun, J., Meng, X., Luo, J., Zhou, D. and Crittenden, J. (2018a). Impact of Chloride Ions on UV/H2O2 and UV/Persulfate Advanced Oxidation Processes. Environ Sci Technol, 52(13), 7380-7389. Zhang, Y., Zhang, Q., Dong, Z., Wu, L. and Hong, J. (2018b). Degradation of acetaminophen with ferrous/copperoxide activate persulfate: Synergism of iron and copper. Water Res, 146, 232-243. Zhang, Y., Zhang, Q. and Hong, J. (2017). Sulfate radical degradation of acetaminophen by novel iron–copper bimetallic oxidation catalyzed by persulfate: Mechanism and degradation pathways. Applied Surface Science, 422, 443-451. Zhong, H., Brusseau, M. L., Wang, Y., Yan, N., Quig, L. and Johnson, G. R. (2015). In-situ activation of persulfate by iron filings and degradation of 1,4-dioxane. Water Res, 83, 104-111. Zhou, Y., Xiang, Y., He, Y., Yang, Y., Zhang, J., Luo, L., Peng, H., Dai, C., Zhu, F. and Tang, L. (2018). Applications and factors influencing of the persulfate-based advanced oxidation processes for the remediation of groundwater and soil contaminated with organic compounds. J Hazard Mater, 359, 396-407. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/79580 | - |
| dc.description.abstract | "地下水污染整治一直以來都是維持永續水資源的重要課題，利用現地的方式處理地下水污染是較經濟且對環境較友善的方法。透水性反應牆（permeable reactive barrier, PRB）和現地化學氧化 (In-situ chemical oxidation, ISCO)為現地處理地下水污染的方法。本研究使用氧化銅(CuO)作為透水性反應牆之反應介質，結合過二硫酸鹽作為氧化劑，以現地透水性反應牆化學氧化方式評估在固定流量條件下，2,4-二氯酚、2,4,6-三氯酚及五氯酚的降解效率，並探討不同水質參數包含氯離子、硝酸根、硫酸根、碳酸氫根及腐植酸對五氯酚去除率的影響。追蹤劑實驗結果顯示，架設的實驗系統為重力流，在定流量的條件下（4.8 mL/min），整體水利停留時間為60-75分鐘，而流經CuO透水性反應牆的時間約為10分鐘。三種氯酚類目標污染物在去離子水為基質下的去除率皆可達到99%以上，在含有各種離子的水質條件下，去除效率則有以下的趨勢：2,4,6-三氯酚 > 2,4-二氯酚 > 五氯酚。針對五氯酚在不同水質參數下的降解，實驗結果顯示氯離子和硝酸根對去除效率沒有太大影響，當硫酸根及碳酸氫根濃度分別提高至1.04 mM及10 mM，其去除率仍維持在約90%，較高濃度的腐植酸( 5 mg C/L）則使五氯酚的去除率從96%降至68％，結果顯示腐植酸可能會覆蓋在氧化銅的表面上並有消耗自由基的作用，進而影響五氯酚的降解。" | zh_TW |
| dc.description.provenance | Made available in DSpace on 2022-11-23T09:04:16Z (GMT). No. of bitstreams: 1 U0001-1509202118313800.pdf: 6435215 bytes, checksum: d00bbdf75d71632e0ee62ae1d8cd9c7e (MD5) Previous issue date: 2021 | en |
| dc.description.tableofcontents | Content 摘要 I Abstract II Content IV List of Figures VII List of Tables X Chapter 1 Introduction 1 1.1 Background 1 1.2 Research objectives 3 Chapter 2 Literature Reviews 4 2.1 In situ chemical oxidation (ISCO) 4 2.2 Permeable reactive barrier (PRB) 4 2.3 Persulfate-based advanced oxidation processes 6 2.4 Influences of water matrixes on the performance of persulfate technologies 9 Chapter 3 Materials and Methods 11 3.1 Research framework 11 3.2 Chemicals and reagents 12 3.3 Characterization of copper oxide 12 3.4 Permeable reactive barrier (PRB) module 13 3.5 Chlorophenol degradation experiments 14 3.6 Analytical methods 15 Chapter 4 Results Discussion 17 4.1 Characterization of CuO and hydraulic properties of PRB module 17 4.2 Removal of chlorophenols by PDS activated by CuO-PRB 20 4.2.1 Removal of chlorophenols by PDS activated by CuO-PRB in DI water 20 4.2.2 Removal of chlorophenols by PDS activated by CuO-PRB in water containing various ions 30 4.3 Influences of water matrixes on PCP removal by PDS activated by CuO-PRB 33 4.3.1 Influences of nitrate on PCP removal 33 4.3.2 Influences of chloride on PCP removal 36 4.3.3 Influences of sulfate on PCP removal 39 4.3.4 Influences of bicarbonate on PCP removal 41 4.3.5 Influences of humic acid on PCP removal 43 Chapter 5 Conclusions and Recommendations 46 5.1 Conclusions 46 5.2 Recommendations 47 Reference 49 Appendix 60 | |
| dc.language.iso | en | |
| dc.title | 在不同水質參數下利用氧化銅活化過二硫酸鹽降解氯酚類有機污染物：透水性反應牆模組試驗 | zh_TW |
| dc.title | Degradation of Chlorophenols under Different Water Matrixes by CuO-Activated Peroxydisulfate in Permeable Reactive Barrier Module | en |
| dc.date.schoolyear | 109-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 蔣本基(Hsin-Tsai Liu),潘述元(Chih-Yang Tseng) | |
| dc.subject.keyword | 透水性反應牆,現地化學氧化,氧化銅,過二硫酸鹽,氯酚, | zh_TW |
| dc.subject.keyword | permeable reactive barrier,in-situ chemical oxidation,CuO,peroxydisulfate,chlorophenols, | en |
| dc.relation.page | 66 | |
| dc.identifier.doi | 10.6342/NTU202103198 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2021-09-17 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
| 顯示於系所單位： | 環境工程學研究所 | |
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