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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 段維新 | |
| dc.contributor.author | Ching-Ti Kao | en |
| dc.contributor.author | 高靖棣 | zh_TW |
| dc.date.accessioned | 2021-07-11T15:45:49Z | - |
| dc.date.available | 2023-08-14 | |
| dc.date.copyright | 2018-08-14 | |
| dc.date.issued | 2018 | |
| dc.date.submitted | 2018-08-07 | |
| dc.identifier.citation | [1] A.H. Heuer, L.W. Hobbs, Advances in Ceramics Volume 3 Science and Technology of Zirconia, The American Ceramic Society 1981.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/79123 | - |
| dc.description.abstract | 本研究以微量的氧化鐵作為添加劑，添加進入三莫耳氧化釔穩定氧化鋯(3YSZ)基材中，並探討其相穩定性、電性、硬度、韌性與顏色等性質的影響。藉由添加鐵離子，材料的燒結活性也隨之上升，包括生胚開始收縮的溫度與達最大收縮速率的溫度，都隨著鐵的添加而下降。而由熱分析儀與X光光電子能譜儀的結果得知，鐵在燒結時會產生價數變化，而此現象會對氧化鋯的燒結活性也會有所影響。在燒結過程時，氧化鐵會固溶進入3YSZ內，而鐵離子會與鋯離子會產生取代型缺陷，材料中的氧空缺濃度會因此而改變，結晶相也同時受到影響。包括單斜晶(Monoclinic)的量與晶粒大小都隨著鐵的添加而增加。結果顯示，材料中單斜晶的產生會對材料機械性質產生負面影響。而加入鐵所產生的鐵缺陷會同時影響了晶粒與晶界的導電行為。除此之外，藉由對試片進行不同溫度的熱處理，能更進一步釐清添加鐵缺陷對於氧化鋯的影響。而藉由控制鐵的添加量與燒結環境，材料的微結構特性與顏色都能被調整。 | zh_TW |
| dc.description.abstract | Effect of a small amount of iron oxide addition on the sintering of 3 mol% yttria-stabilized zirconia (3YSZ) has been investigated in the present study. The phase stability, electrical conductivity, hardness, toughness and color of Fe-doped 3YSZ are evaluated. The iron oxide is dissolved into 3YSZ after sintering. Since the presence of iron ions, the concentration of oxygen vacancy is altered. The addition of iron enhances the sintering activity of 3YSZ in terms of the starting temperature for shrinkage and the temperature at maximum densification rate. Through the analysis of thermal and X-ray photoelectron spectrum, the valence transformation of Fe would also affect the sintering activity. However, the phase evolution during sintering is consequently altered. The amount of monoclinic phase and grain size are increased along with the increasing of iron addition. The results from electrical conductivity demonstrate that both the grain and grain boundary conductivities are affected by the iron addition. The formation of m-phase imposes detrimental effect on mechanical property. By treating with the various heat treatments, the influence of iron on the defect in zirconia can be clarified. In addition, the microstructural characteristics and color can be manipulated by controlling the iron addition and sintering condition. | en |
| dc.description.provenance | Made available in DSpace on 2021-07-11T15:45:49Z (GMT). No. of bitstreams: 1 ntu-107-D02527004-1.pdf: 11642487 bytes, checksum: 2985a83d1e941473f1fb6718fa321bbc (MD5) Previous issue date: 2018 | en |
| dc.description.tableofcontents | 口試委員審定書 i
誌謝 ii 摘要 iii ABSTRACT iv CONTENT vi LIST OF TABLES xiv LIST OF FIGURES xvii Chapter 1 Introduction 1 Chapter 2 Literature Review 2 2.1 Yttria-Stabilized Zirconia (YSZ) 2 2.1.1 Phase 2 2.1.2 Phase Stabilized Mechanism 5 2.1.2.1 Concept from the Crystal Chemistry Model 5 2.1.2.2 Concept from the Thermodynamic 6 2.1.3 Grain Size Induced Phase Transformation 8 2.2 Electrical Properties of YSZ 10 2.2.1 Conduction Mechanism of YSZ 10 2.2.2 Measurement Technique for Conductivity 12 2.2.3 Conduction Model for YSZ 15 2.2.4 Influence Factors for Conductivity 17 2.2.4.1 Activation Energy 17 2.2.4.2 Limitation for EIS 24 2.2.5 Electrical Conductivity of Grain 26 2.2.6 Grain Boundary Conductivity 28 2.2.6.1 Glassy Phase 29 2.2.6.2 Grain Size 30 2.2.6.3 Effect of Dopant 31 2.2.6.4 Space Charge Layer 32 2.2.7 Electrode Interface Reaction 36 2.3 Mechanical Property 38 2.3.1 Transformation Toughness 38 2.4 Applications for YSZ 42 2.5 Fe-Doped YSZ System 43 2.5.1 Color for Fe-Doped YSZ 43 2.5.2 Solubility and Phase Diagram for Fe-Doped Zirconia System 46 2.5.3 Lattice Parameter for Fe-Doped Zirconia System 50 2.6 Sintering Activity for Fe-Doped YSZ 53 2.7 Valence Variation of Iron 56 2.8 Electrical Conductivity for Fe-Doped Zirconia System 60 Chapter 3 Experimental Procedures 68 3.1 Materials 68 3.2 Powder Mixture Process 68 3.3 Sintering Process 69 3.4 Characterization of Sintered Specimens 71 3.4.1 Density Measurement 71 3.4.2 Kinetics for Dimension Change 72 3.4.3 Phase and Crystal Structure Identification 72 3.4.4 Microstructure Observation 75 3.4.5 Grain Size Calculation 76 3.4.6 Thermoanalytical Measurement 76 3.5 Electrical Property Measurement 77 3.6 Chromaticity Measurement 80 3.7 Valence State Measurement 81 3.8 Mechanical Property Measurement 82 3.8.1 Young’s Modulus and Poisson’s Ratio 82 3.8.2 Measurement of Flexural Strength 83 3.8.3 Hardness and Fracture Toughness 84 3.9 Composition analysis 87 3.10 Heat Treatments 87 3.11 Sintering Condition Manipulation 88 Chapter 4 Results 89 4.1 Color and Chromatic Analysis 89 4.2 Relative Density 91 4.3 Phase Identification 92 4.4 Phase Transformation Measurement 95 4.5 Sintering Kinetics 98 4.6 Microstructure Observation 102 4.7 Thermoanalytical property 107 4.8 Electrical Property 110 4.8.1 Low Measurement Temperature (300oC - 600oC) 110 4.8.2 High Measurement Temperature (700oC - 900oC) 112 4.9 Valence Identification 114 4.10 Heat Treatments 117 4.10.1 Heat Treatments for 3YSZ 117 4.10.2 Heat Treatments for 1.00Fe-3YSZ 119 4.11 Composition Analysis 121 4.12 Mechanical Property 123 4.12.1 Vickers Hardness and Fracture Toughness 123 4.12.2 Flexural Strength 125 4.13 Atmosphere Manipulation for Sintering 126 4.13.1 Appearance 126 4.13.2 Phase Identification 127 4.13.3 Microstructure Observation and Grain Size Calculation 129 4.13.4 Valence Measurement 131 4.13.5 Electrical Conductivity 133 Chapter 5 Discussion 135 5.1 Solubility of Fe in 3YSZ 135 5.2 Microstructural Characteristic of Fe-3YSZ 137 5.2.1 Grain Size Variation 137 5.2.2 Cracks Formation Mechanism in Fe-3YSZ 139 5.3 Phase Manipulation of 3YSZ and Fe-3YSZ 141 5.3.1 Oxygen Vacancy to Phase Stability 141 5.3.2 Grain Size to Phase Stability 142 5.3.3 Phase Transformation Temperature 145 5.3.4 Summary of the Phase Manipulation for 3YSZ and Fe-3YSZ 150 5.4 Sintering Activity of 3YSZ and Fe-3YSZ 151 5.4.1 Quantitative of Sintering Activity 151 5.4.2 Effect of Liquid Phase to Sintering Activity 151 5.4.3 Influence of Oxygen Vacancy to Sintering Activity 152 5.4.4 Concentration of Oxygen Vacancy 154 5.4.5 Diffusivity of Oxygen Vacancy 154 5.4.6 Effect of Fe valence on sintering 158 5.4.7 Summary of Sintering Activity of Fe-3YSZ 160 5.5 Electrical Property of Fe-3YSZ 161 5.5.1 Electrical Conductivity of Grain 161 5.5.2 Electrical Conductivity of Grain Boundary 163 5.5.2.1 Grain Boundary Conductivity to the Iron Additon 163 5.5.2.2 Grain Boundary Conductivity to Temperature 167 5.5.3 Heat Treatments to Electrical Conductivity 169 5.5.3.1 3YSZ 169 5.5.3.2 Fe-3YSZ 170 5.5.3.3 Segregation to Blocking Factor 173 5.5.4 High Measurement Temperature (Interface Reaction) 173 5.5.4.1 Conductivity of the Oxygen Ion Transfer Reaction 174 5.5.4.2 Conductivity of the Mass Transfer Reaction 175 5.5.5 Summary of the Electrical Conductivity 177 5.6 Valence Transformation of Fe to Temperature 178 5.7 Color of 3YSZ and Fe-3YSZ 180 5.8 Mechanical Property of 3YSZ and Fe-3YSZ 181 Chapter 6 Conclusions 184 Chapter 7 Future Works 187 7.1 Color Manipulation 187 7.2 Applications in Dental Material 187 7.3 Sintering Behavior for Various Atmospheres 187 7.4 Valence Verification for Fe 188 References 189 | |
| dc.language.iso | en | |
| dc.subject | 電化學阻抗頻譜儀 | zh_TW |
| dc.subject | 顏色 | zh_TW |
| dc.subject | X光光電子頻譜儀 | zh_TW |
| dc.subject | 機械性質 | zh_TW |
| dc.subject | 氧化釔穩定氧化鋯 | zh_TW |
| dc.subject | 氧化鐵 | zh_TW |
| dc.subject | 燒結活性 | zh_TW |
| dc.subject | 相轉變機制 | zh_TW |
| dc.subject | color | en |
| dc.subject | phase transformation | en |
| dc.subject | sintering activity | en |
| dc.subject | iron oxide | en |
| dc.subject | Yttria-stabilized zirconia | en |
| dc.subject | electrochemical impedance spectroscopy | en |
| dc.subject | mechanical property | en |
| dc.subject | X-ray photoelectron spectroscopy | en |
| dc.title | 添加微量氧化鐵對氧化釔安定氧化鋯之燒結行為與電性之影響 | zh_TW |
| dc.title | Effect of a Small Amount of Iron Addition on Sintering Behavior and Electrical Property of Yttria-Stabilized Zirconia | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 106-2 | |
| dc.description.degree | 博士 | |
| dc.contributor.oralexamcommittee | 郭錦龍,劉哲原,周振嘉,施劭儒,許沛衣 | |
| dc.subject.keyword | 氧化釔穩定氧化鋯,氧化鐵,燒結活性,相轉變機制,電化學阻抗頻譜儀,機械性質,X光光電子頻譜儀,顏色, | zh_TW |
| dc.subject.keyword | Yttria-stabilized zirconia,iron oxide,sintering activity,phase transformation,electrochemical impedance spectroscopy,mechanical property,X-ray photoelectron spectroscopy,color, | en |
| dc.relation.page | 207 | |
| dc.identifier.doi | 10.6342/NTU201802632 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2018-08-07 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| dc.date.embargo-lift | 2023-08-14 | - |
| 顯示於系所單位： | 材料科學與工程學系 | |
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