請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/78345
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 陳誠亮(Cheng-Liang Chen) | |
dc.contributor.author | Tsung-Shi You | en |
dc.contributor.author | 游悰熺 | zh_TW |
dc.date.accessioned | 2021-07-11T14:52:16Z | - |
dc.date.available | 2021-07-31 | |
dc.date.copyright | 2020-08-11 | |
dc.date.issued | 2020 | |
dc.date.submitted | 2020-08-05 | |
dc.identifier.citation | 1. World Bioenergy Association, Global bioenergy statistics. 2019. 2. Dalena, F.; Senatore, A.; Basile, M.; Marino, D.; Basile, A., From sugars to ethanol—from agricultural wastes to algal sources: An overview. In Second and Third Generation of Feedstocks, 2019; pp 3-34. 3. Renewable Fuels Association, World fuel ethanol production. Report of the Renwable Fuels Association (RFA), Washington, DC. 2018. 4. Tashiro, Y.; Yoshida, T.; Noguchi, T.; Sonomoto, K., Recent advances and future prospects for increased butanol production by acetone-butanol-ethanol fermentation. Engineering in Life Sciences 2013, 13 (5), 432-445. 5. Singh, l.; Chaudhary, D. G.; Kataria, R., Production of reducing sugars from lignocellulosic biomass for fuel ethanol production. 2011. 6. Patraşcu, I.; Bîldea, C. S.; Kiss, A. A., Eco-efficient butanol separation in the ABE fermentation process. Separation and Purification Technology 2017, 177, 49-61. 7. Kiss, A. A.; Luo, H.; Bildea, C. S., Energy efficient bioethanol purification by heat pump assisted extractive distillation. In 12th International Symposium on Process Systems Engineering and 25th European Symposium on Computer Aided Process Engineering, 2015; pp 1307-1312. References 8. Kolesinska, B.; Fraczyk, J.; Binczarski, M.; Modelska, M.; Berlowska, J.; Dziugan, P.; Antolak, H.; Kaminski, Z. J.; Witonska, I. A.; Kregiel, D., Butanol synthesis routes for biofuel production: Trends and perspectives. Materials (Basel) 2019, 12 (3). 9. Dublin, N-Butanol report 2018-2022: global $5.58 Bn market driven by growing construction industry in emerging economies, https://www.prnewswire.com/news-releases/n-butanol-report-2018-2022-global-5-58-bn-market-driven-by-growing-construction-industry-in-emerging-economies-300652807.html. 2018. 10. Jiang, Y.; Liu, J.; Jiang, W.; Yang, Y.; Yang, S., Current status and prospects of industrial bio-production of n-butanol in China. Biotechnology advances 2015, 33 (7), 1493-1501. 11. Rosales-Calderon, O.; Arantes, V., A review on commercial-scale high-value products that can be produced alongside cellulosic ethanol. Biotechnology for Biofuels 2019, 12 (1), 240. 12. Bio-butanol market - growth, trends, and forecast (2020 - 2025), https://www.mordorintelligence.com/industry-reports/bio-butanol-market. 2019. 13. Dublin, Global bio-butanol market growth, trends and forecasts (2019-2024): demand from biofuel to rise at the fastest rate, https://www.businesswire.com/news/home/20190328005800/en/Global-Bio-Butanol-Market-Growth-Trends-Forecasts-2019-2024. 2019. 14. Karimi, K.; Tabatabaei, M.; Sárvári Horváth, I.; Kumar, R., Recent trends in acetone, butanol, and ethanol (ABE) production. Biofuel Research Journal 2015, 2 (4), 301-308. 15. Abdehagh, N.; Tezel, F. H.; Thibault, J., Separation techniques in butanol production: Challenges and developments. Biomass and Bioenergy 2014, 60, 222-246. 16. Renon, H.; Prausnitz, J. M., Local compositions in thermodynamic excess functions for liquid mixtures. Aiche J 1968, 14 (1), 135-144. 17. Kiss, A. A., Advanced distillation technologies: design, control and applications. John Wiley Sons: 2013. 18. Ku, H. C.; Tu, C. H., Isobaric vapor-liquid equilibria for mixtures of acetone, ethanol, and 2,2,4-trimethylpentane at 101.3 kPa. Fluid Phase Equilib. 2005, 231 (1), 99-108. 19. Polednova, J.; Wichterle, I., Vapor liquid equilibrium in the acetone water-system at 101.325 kpa. Fluid Phase Equilib. 1984, 17 (1), 115-121. 20. Ling, T.; Van Winkle, M., Properties of binary mixtures as a function of composition. Industrial Engineering Chemistry Chemical Engineering Data Series 1958, 3 (1), 88-95. 21. Lee, H.-Y.; Yen, L.-T.; Chien, I. L.; Huang, H.-P., Reactive distillation for esterification of an alcohol mixture containing n-Butanol and n-Amyl Alcohol. Industrial Engineering Chemistry Research 2009, 48 (15), 7186-7204. 22. Cripwell, J. T.; Schwarz, C. E.; Burger, A. J., Vapor–liquid equilibria measurements for the nine n-Alkane/Ketone pairs comprising 2-, 3-, and 4-Heptanone with n-Octane, n-Nonane, and n-Decane. Journal of Chemical Engineering Data 2015, 60 (3), 602-611. 23. Iwakabe, K.; Kosuge, H., Isobaric vapor–liquid–liquid equilibria with a newly developed still. Fluid Phase Equilib. 2001, 192, 171-186. 24. Stabnikov, V. M.; Metyushev, B. D.; Protsyuk, T. B.; Yushchenko, N. M., Equilibrium in the ethyl alcohol + water system at atmospheric pressure. Pishch. Prom-st. (Kiev). 1972. 15, 49-56. 25. Lai, H.-S.; Lin, Y.-F.; Tu, C.-H., Isobaric (vapor+ liquid) equilibria for the ternary system of (ethanol+ water+ 1, 3-propanediol) and three constituent binary systems at P= 101.3 kPa. The Journal of Chemical Thermodynamics 2014, 68, 13-19. 26. Sørensen, J. M., Liquid-liquid equilibrium data collection / J.M. Sørensen, W. Arlt. DECHEMA, Deutsche Gesellschaft für Chemisches Apparatewesen: Frankfurt/Main, 1979. 27. Kaymak, D. B., Design and control of an alternative process for biobutanol purification from ABE fermentation. Industrial Engineering Chemistry Research 2019, 58 (5), 1957-1965. 28. Chang, J. W.; Yu, C. C. The relative gains for non-square multivariable system. Chemical Engineering Science. 1990, 45, 1309-1323. 29. Luyben, W. L., Comparison of extractive distillation and pressure-swing distillation for acetone/chloroform separation. Computers Chemical Engineering 2013, 50, 1-7. 30. Dai, S.-B.; Lee, H.-Y.; Chen, C.-L., Design and economic evaluation for the production of ethyl lactate via reactive distillation combined with various separation configurations. Industrial Engineering Chemistry Research 2018, 58 (15), 6121-6132. 31. Luyben, W. L., Control of a column/pervaporation process for separating the ethanol/water azeotrope. Industrial Engineering Chemistry Research 2009, 48 (7), 3484-3495. 32. Delgado, P.; Sanz, M. T.; Beltrán, S., Pervaporation of the quaternary mixture present during the esterification of lactic acid with ethanol. J Membrane Sci 2009, 332 (1), 113-120. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/78345 | - |
dc.description.abstract | 丁醇普遍做溶劑、有機合成等用途,甚至有潛力作為交通運輸燃料使用,能量密度比乙醇高,更接近天然氣,此外,丁醇不親水特性能大幅減少對車輛的腐蝕性。在現今社會中,生質能源開始受到重視,因此生物丁醇有取代石油丁醇的高度潛力。生物丁醇的生產主要來自由微生物與小分子葡萄糖進行ABE發酵,此一程序會同時產出大量的乙醇和丙酮,但是酒精對於微生物有害,故需要操作在非常稀釋環境下發酵,因此丁醇純度相對非常低,必需耗費相當多的能源用於分離高純度的丁醇,本研究根據Patraşcu 等人文獻進行改良,透過製程改善,有效降低能耗。又為了讓副產品乙醇純度高於99.5 wt% (高於乙醇/水沸點組成),安裝商業化薄膜-PERVAP○R2201打破共沸點使殘餘水分離。後續一系列的熱整合探討,並且進階探討塔堆積(column stacking)策略,最終結果,比起Patraşcu文獻設計,能耗減少達57%,每年費用則減少將近52%,不僅提升了產物純度,也大幅下降能源浪費問題。另外此研究也進行動態模擬,共分為無熱整合、有熱整合、有用塔堆積程序等三部分,皆以溫控方式取代組成控制,並且添加一些經驗公式改變控制器的設定點來改善操控結果,模擬擾動±10%進料和進料組成情況,結果得出以上三種純度偏差皆能小於0.05%,即使為較複雜的熱整合,溫度控制皆相當理想。 | zh_TW |
dc.description.abstract | Butanol is generally used as a solvent, organic synthesis, etc., and even has the potential as a transportation fuel. Butanol is more energy density than ethanol and close to gasoline. However, biobutanol gradually replaces petro butanol since biobutanol can cut down energy crisis and environmental pollution problems. Acetone-Butanol-Ethanol fermentation is the main product of biobutanol method and also produces ethanol and acetone. Fermentation is essential to be operated in diluted surroundings since products are toxic to microorganisms. Thus, high product purity is required enormous energy consumption. This paper aim is to propose a modified process design that uses distillations, the decanter, a membrane and also applies heat integration to intensify efficiency usage. Besides, the column stacking strategy is considered in this process. According to Patraşcu et al. reference, this work not only makes energy consumption decrease by 57% and TAC decreases by 52%, but also can obtain high purity all butanol, acetone and ethanol 99.5 wt%. Besides, this study carries on dynamic simulations for the processes with/without heat integration and with column stacking. Throughput change and feed composition are changed by ±10%. The results that all products can return to the desired points. Temperature control is suitable for these two cases. | en |
dc.description.provenance | Made available in DSpace on 2021-07-11T14:52:16Z (GMT). No. of bitstreams: 1 U0001-3007202001373200.pdf: 8097965 bytes, checksum: 95c0947887b622ada9c5c7c7804926d7 (MD5) Previous issue date: 2020 | en |
dc.description.tableofcontents | 口試委員會審定書.............................................................. i 誌謝......................................................................... ii 中文摘要...................................................................... iii Abstract..................................................................... iv Contents .................................................................... v Figure Index................................................................. viii Table Index.................................................................. xi 1. Introduction ............................................................. 1 2. Basic Design for Separating ABE Fermentation.............................. 9 2.1 Patraşcu’s Design for Separating ABE Fermentation........................ 9 2.2. Basic Design – Update of the Patraşcu’s Design.......................... 14 3. Proposed Novel Designs for Separating ABE Fermentation.................... 17 3.1. Proposed Design-1 – Removing Acetone First ............................ 17 3.2. Proposed Design-2 – Membrane Recovery of Ethanol ....................... 22 3.3. Proposed Design-3 – Heat Integration.................................... 25 3.4. Proposed Design-4 – Column Stacking .................................... 32 4. Plant-wide Control System Design.......................................... 38 4.1. Plant-wide Control for Proposed Design-2 – Membrane Recovery of Ethanol. 39 4.1.1. Control Scheme........................................................ 39 4.1.2. Control performance................................................... 44 4.1.3. Intensified Control Scheme ........................................... 47 4.1.4. Intensified Control Performance....................................... 48 4.2. Plant-wide Control for Proposed Design-3 – Heat integration............. 51 4.2.1. Control Scheme ....................................................... 51 4.2.2. Control Performance .................................................. 57 4.3. Plant-wide Control for Proposed Design-4 – Column stacking ............. 61 4.3.1. Control Scheme ....................................................... 61 4.3.2. Control Performance................................................... 69 4.4. Discussions ............................................................ 73 5. Conclusions .............................................................. 76 References................................................................... 79 Appendix .................................................................... 84 | |
dc.language.iso | en | |
dc.title | ABE發酵生物丁醇高能效純化程序之設計 | zh_TW |
dc.title | Energy efficient design of biobutanol purification process from acetone/butanol/ethanol fermentation | en |
dc.type | Thesis | |
dc.date.schoolyear | 108-2 | |
dc.description.degree | 碩士 | |
dc.contributor.author-orcid | 0000-0003-2042-9747 | |
dc.contributor.oralexamcommittee | 錢義隆(I-Lung Chien),吳哲夫(Jeffery D. Ward),李豪業(Hao-Yeh Lee),李瑞元(Jui-Yuan Lee) | |
dc.subject.keyword | 丁醇,ABE發酵,薄膜,熱整合,塔堆積,動態模擬, | zh_TW |
dc.subject.keyword | ABE fermentation,Biobutanol,Process design,Membrane,Column stacking,Dynamics simulation, | en |
dc.relation.page | 86 | |
dc.identifier.doi | 10.6342/NTU202002072 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2020-08-05 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
U0001-3007202001373200.pdf 目前未授權公開取用 | 7.91 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。