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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 吳乃立 | |
dc.contributor.author | Jen-Hao Chien | en |
dc.contributor.author | 錢人豪 | zh_TW |
dc.date.accessioned | 2021-07-11T14:43:50Z | - |
dc.date.available | 2021-10-14 | |
dc.date.copyright | 2016-10-14 | |
dc.date.issued | 2016 | |
dc.date.submitted | 2016-08-09 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/78149 | - |
dc.description.abstract | An increasing number of metal oxides exhibiting pseudocapacitive behaviors have been investigated in recent years. We have discovered a nanocrystalline oxide material having the formula of MnFe2O4 that have so far been the only oxide electrode showing pseudocapacitance in both aqueous and organic Li-ion electrolytes. The discovery of this material has opened up the possibility of setting up a high voltage pseudocapacitors of substantially enhanced energy density over the state-of-the-art organic supercapacitors.
In the first part of the thesis, MnFe2O4/CB composite materials have been synthesized via coprecipitation method and followed with a thermal calcination. The electrodes of that composite were tested for the capacitive behaviors in aqueous NaCl solution. For different calcination temperatures, the electrode using MnFe2O4/CB which calcined at 350°C exhibits 63.1 F/g-composite under 10 mV/s scan rate and possesses the largest capacitance compared to the others. Second, we have explored the spinel-based nanocrystalline ferrite electrodes with various transition metal compositions in organic Li-ion electrolyte. The results indicated that an increment in specific capacitance could be observed with increased concentration of manganese ion. Moreover, an enhanced energy density of MnFe2O4/CB supercapacitor could be obtained by applying the organic Li-ion electrolyte. It displays a substantially higher energy density of 59.6 Wh/kg at a power density of 413 W/kg. Even at a high power density of 16809 W/kg, it still delivers an energy density of 24.3 Wh/kg. The relationship between capacitance and potential window had also been examined and it was found out that more lithium ions could react with the inner surface of manganese ferrite with broader voltage window and thus resulted in a relatively larger pseudocapacitance. Enhanced rate performance was derived by diluting the concentration of transition metals. The capacitance retentions of MnFe2O4/carbon electrodes are found to be above 60% under 100 mV/s. The superior capability of delivering rather high capacitance under high-power conditions is attributed to the spinel structure formed after lower temperature calcination. Based on our previous study, the pseudocapacitance is predominantly arising from the charge-transfer reaction at the tetrahedral sites of the spinel, balanced by the insertion of cations from the electrolyte. Besides, the operation voltage window was carefully determined in view of leakage current for the upper voltage limit. On the other hand, the lower voltage limit was selected to maximize the energy density of the spinel oxide electrode. | en |
dc.description.provenance | Made available in DSpace on 2021-07-11T14:43:50Z (GMT). No. of bitstreams: 1 ntu-105-R03524039-1.pdf: 15232919 bytes, checksum: 16cb2440a208ec0543e7470f45a50fce (MD5) Previous issue date: 2016 | en |
dc.description.tableofcontents | 致謝.................................................II
摘要.................................................IV Abstract.............................................VI Table of Contents..................................VIII List of Tables......................................XII List of Figures....................................XIII Chapter 1 Introduction..........................1 1.1 Background....................................1 1.2 Motivations and Objectives....................2 Chapter 2 Theory and Literature Review..........3 2.1 Introduction to Electrochemical Capacitors....3 2.1.1 Introduction to Energy Storage Devices........3 2.1.2 Classifications of Electrochemical Capacitors.6 2.1.3 Models and Theory for Electric Double Layer...8 2.1.4 Electrochemical Characteristics of Capacitors12 2.2 Development of Electrochemical Capacitors....14 2.2.1 Electrode Materials..........................14 2.2.2 Electrolyte..................................17 2.3 Introduction to Manganese Ferrite, MnFe2O4...19 2.3.1 Structure and Characteristics................19 2.3.2 Synthesis and Development on Supercapacitors.23 Chapter 3 Experimental.........................25 3.1 Synthesis of Electrode Materials.............25 3.1.1 MnFe2O4/Carbon Black Composite Materials.....26 3.1.2 MnFe2O4/Carbon Nanotube Composite Materials..27 3.1.3 MnFe2O4/Carbon Composite Materials Fabricated by Diluted Concentration of Transition Metals...........27 3.2 Analysis and Characterization................31 3.2.1 Phase Identification.........................31 3.2.2 Microstructure Characterizations.............33 3.2.3 Surface Area Analysis........................33 3.2.4 Resistivity of Powder-like Mixture...........34 3.3 Electrochemical Characterizations............35 3.3.1 Preparation of Electrodes....................35 3.3.2 Cyclic Voltammetry...........................36 3.3.3 Chronopotentiometry..........................37 Chapter 4 Investigation on Capacitive Performance of Ferrite Supercapacitors...........................39 4.1 Introduction.................................39 4.2 Material Characterizations...................41 4.3 Operating Characteristics of Manganese Ferrite/ Carbon Black Supercapacitors in Aqueous Electrolyte..47 4.3.1 Investigation on MnFe2O4/CB Composite Materials47 4.3.2 Investigation on Mn1-xFe2+xO4/CB Composite Materials............................................49 4.4 Investigation on Electrochemical Behaviors of Mn1-xFe2+xO4/Carbon Black Supercapacitors in Organic Li-ion Electrolyte......................................54 4.4.1 Effect on rate performance by replacing NaOH(aq) with LiOH(aq) in the coprecipitation process.........54 4.4.2 Rate performance of Mn1-xFe2+xO4/CB electrode under high potential.......................55 4.4.3 Rate performance of Mn1-xFe2+xO4/CB electrode over wider potential window..........................56 4.4.4 Enhanced Energy Density of MnFe2O4/Carbon Black Supercapacitors......................................57 4.4.5 Cycling Stability of MnFe2O4/Carbon Black in Organic Li-ion Electrolyte...........................57 4.4.6 Relationship between Capacitance and Potential Window of MnFe2O4/Carbon Composite Materials.........58 4.5 Electrochemical Performance of MnFe2O4/Carbon Nanotube Synthesized by Impregnation Method..........71 4.5.1 Physical Analysis of MnFe2O4/CNT Composite Materials............................................71 4.5.2 Electrochemical Properties of MnFe2O4/CNT Composite Materials..................................72 4.6 Enhanced Rate Capability of MnFe2O4/Carbon Composite Materials Fabricated by Diluted Concentration of Transition Metals.................................76 4.6.1 Physical Analysis of MnFe2O4/Carbon Composite Materials............................................76 4.6.2 Crystallinity Effect on Electrochemical Property .....................................................84 4.6.3 Electrochemical Characterization of MnFe2O4/Carbon Composite Materials...................84 4.7 A precise way to determine the operation voltage window...............................................94 Chapter 5 Conclusions and Outlook..............98 References..........................................100 | |
dc.language.iso | en | |
dc.title | 探討錳鐵氧化物超高電容器在有機系電解液中的速率表現 | zh_TW |
dc.title | Study on Rate Performance of MnFe2O4 with Organic Li-Ion Electrolyte | en |
dc.type | Thesis | |
dc.date.schoolyear | 104-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 吳弘俊,方家振 | |
dc.subject.keyword | 超高電容器,MnFe2O4,有機系電解液,速率表現,能量密度,稀釋, | zh_TW |
dc.subject.keyword | Supercapacitor,MnFe2O4,Organic Li-ion electrolyte,Rate performance,Energy density,Diluted concentration, | en |
dc.relation.page | 110 | |
dc.identifier.doi | 10.6342/NTU201602172 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2016-08-09 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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