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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢(Sheng-Hsien Chiu) | |
| dc.contributor.author | Ting-Jia Gu | en |
| dc.contributor.author | 顧庭嘉 | zh_TW |
| dc.date.accessioned | 2021-07-11T14:42:34Z | - |
| dc.date.available | 2021-11-02 | |
| dc.date.copyright | 2016-11-02 | |
| dc.date.issued | 2016 | |
| dc.date.submitted | 2016-08-17 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/78111 | - |
| dc.description.abstract | 本研究中，我們利用實驗室先前所發表的系統，以鈉離子為模版，對一個具有尿素單元的分子進行辨識合成車輪烷。此尿素分子在未接上保護基的情況下可溶於水中並形成水凝膠，但在經由夾鎖法鎖上大環分子，形成車輪烷的結構後便可抑制其凝膠化作用。希望能將此系統做延伸，設計上一個可受光刺激斷裂的大環，讓此車輪烷分子可在接受光照後產生水凝膠。 | zh_TW |
| dc.description.abstract | We reported a single urea functionality in a hydrogelator that could be“clipped”by a macrocycle generated from a diamine and a dialdehyde through the templating effect of a Na + ion. The interlocked macrocycle on the hydrogelator would restrained the solution from hydrogelizing. In addition, the ability to hydrogelize could be recovered by utilizing irradiation. | en |
| dc.description.provenance | Made available in DSpace on 2021-07-11T14:42:34Z (GMT). No. of bitstreams: 1 ntu-105-R03223202-1.pdf: 4125337 bytes, checksum: 2b2e4f7f8b9d26445f29ccc3ccc5b9b0 (MD5) Previous issue date: 2016 | en |
| dc.description.tableofcontents | 第一章、導論 1
1.1 前言 1 1.2 內鎖型分子：車輪烷 2 1.3 車輪烷分子的合成策略 3 1.3.1 早期車輪烷分子的合成 3 1.3.2 模版導引法 4 第二章、結果與討論 7 2.1 研究動機 7 2.2 車輪烷分子的設計 12 2.3 車輪烷分子合成測試 15 2.4 結論 22 第三章、實驗部分 23 第四章、參考文獻 33 附錄 37 | |
| dc.language.iso | zh-TW | |
| dc.title | 以車輪烷為架構之光致水凝膠研究 | zh_TW |
| dc.title | A Photo-Triggerable Rotaxane-Based Hydrogel | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 104-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 李文山(Wen-Shan Li),賴建成(Chien-Chen Lai),徐秀福(Hsiu-Fu Hsu),陳平(Richard Cheng) | |
| dc.subject.keyword | 車輪烷,水凝膠, | zh_TW |
| dc.subject.keyword | rotaxane,hydrogel, | en |
| dc.relation.page | 51 | |
| dc.identifier.doi | 10.6342/NTU201602952 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2016-08-18 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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