請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/78047
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 廖文彬(Wen-Bin Liau) | |
dc.contributor.author | Kai-Ming Tsai | en |
dc.contributor.author | 蔡凱名 | zh_TW |
dc.date.accessioned | 2021-07-11T14:40:38Z | - |
dc.date.available | 2022-02-21 | |
dc.date.copyright | 2017-02-21 | |
dc.date.issued | 2016 | |
dc.date.submitted | 2016-10-19 | |
dc.identifier.citation | 參考文獻
1. 尤浚達,生物可分解性高分子–聚乳酸之應用與發展潛力評估 2. Richard, A. Gross and B. Kalra, Biodegradable Polymers for the Environment. Science, 2002,297,803 3. Erwin, T. H. Vink ; Karl, R. Rabagob ; David, A. Glassnerb ; Patrick R. Gruberb Polymer Degradation and Stability 2003,80,403 4. Auras, R., Poly(lactic acid) : synthesis, structures, properties, processing, and applications 2010 : John Wiley & Sons, Inc. 5. 梅愷,國立台灣大學碩士論文,2009 6. Vasanthakumari, R.; Pennings, AJ. Polymer 1983,24,175 7. Tsuji, H. ; Ikada, Y. Polymer 1995,36,2709 8. Kalb, B.; Pennings, AJ. Polymer 1980,21,607 9. W. C. Lai; W. B. Liau, Polymer 2003,44, 8103 10. Vahik, K.; Darrin, J. P. Macromolecules 2004,37,6480 11. Penju P., Yoshio I., Progress in Polymer Science 34 (2009) 605–640 12. Kobayashi J, Asahi T, Ichiki M, Oikawa A, Suzuki H, Watanabe T, et al. J Appl Phys 1995,77:2957–73. 13. Puiggali J, Ikada Y, Tsuji H, Cartier L, Okihara T, Lotz B. Polymer 2000, 41:8921–30. 14. Cartier L, Okihara T, Ikada Y, Tsuji H, Puiggali J, Lotz B. Polymer 2000,41,8909 15. Hoogsteen W, Postema AR, Pennings AJ, ten Brinke G. , Macromolecules 1990,23:634–42. 16. Abe H, Kikkawa Y, Inoue Y, Doi Y. Biomacromolecules 2001,2:1007–14. 17. Pengju P., Bo Z., Weihua K., Tungalag D., Yoshio I., J. Appl. Polym. Sci. 2008,107, 54–62 18. Vahik K. and Darrin J. P., Macromolecules 2004, 37, 6480-6491 19. M. L. Di Lorenzo, European Polymer Journal 2005,41,569–575 20. Tsuji H, Tezuka Y, Saha SK, Suzuki M, Itsuno S. Polymer 2005,46:4917–27 21. Yasuniwa M, Tsubakihara S, Iura K, Ono Y, Dan Y, Takahashi, K. Crystallization behavior of poly(l-lactic acid). Polymer 2006,47:7554–63 22. Vahik K. and Darrin J. P. Chem. Mater. 2003,15,4317-4324 23. Zhang, J.; Tashiro, K.; Domb, A. J.; Tsuji, H. Macromolecular Symposia 2006,242, 274 24. Kawai T, Rahman N, Matsuba G, Nishida K, Kanaya T and Nakano M., Macromolecules 2007,40:9463–9 25. Jianming, Z.; Kohji ,T ; Hideto, T.; Abraham J. D.; Macromolecules 2008,41,1352 26. M. Itxaso Calafel , Pedro M. Remiro, M. Milagros Cortázar and M. Elena Calahorra, Colloid Polym Sci 2010,288:283–296 27. J. Kalish, S.L. Hsu, American Physical Society, APS March Meeting 2010,15-19 28. Pengju, P.; Zhichao, L.; Bo, Z.; Tungalag D.; Yoshio, I., Macromolecules 2009,42,3374 29. Y. Ikada, K. Jamshidi, H. Tsuji, S.-H. Hyon, Macromolecules 1987, 20, 904 30. H. Tsuji, Macromol. Biosci. 2005, 5, 569. 31. J. Zhang, H. Sato, H. Tsuji, I. Noda, Y. Ozaki, Macromolecules 2005, 38, 1822. 32. T. Okihara, M. Tsuji, A. Kawaguchi, K. Katayama, H. Tsuji, S.-H. Hyon, Y. Ikada, J. Macromol. Sci., -Phys. 1991, B30, 119 33. H. Tsuji, S.H. Hyon, Y. Ikada, Macromolecules 1991, 24, 5651. 34. H. Tsuji, Y. Ikada, Macromolecules 1993, 26, 6918 35. H. Tsuji, Y. Tezuka, Biomacromolecules 2004, 5, 1181. 36. H. Yamane, K. Sasai, Polymer 2003, 44, 2569 37. H. Tsuji, M. Katagiri, J. Narita, Macromol. Mater. Eng. 2011, 296, 887. 38. Portinha D, Bouteiller L, Pensec S, Richez A. Macromolecules 2004, 37, 3401. 39. Shirahama H, Ichimaru A, Tsutsumi C, Nakayama Y, Yasuda H. J Polym Sci, Part A: Polym Chem 2005, 43, 438 40. Ouchi T, Ichimura S, Ohya Y. Polymer 2006, 47, 429. 41. Stevels WM, Ankone MJK, Dijkstra PJ, Feijen J. Macromol Chem Phys 1995, 196, 3687. 42. 黃祖浩,國立台灣大學碩士論文,2013 43. Hideto Tsuji, Michihiko Nakano, Makoto Hashimoto, Kazunori Takashima, Shinji Katsura, Akira Mizuno. Biomacromolecules 2006, 7, 3316. 44. Yamamoto, M. (2011). Stereocomplexation in the Electro-spun PLLA/PDLA Blend Fibers. Master thesis, Kyoto Institute of Technology. 45. Masaki Yamamoto, Goro Nishikawa, Amalina M. Afifi, Isao Wataoka, Jae-chang Lee, Hideki Yamane. American Journal of Macromolecular Science, 2015, 2, 11 46. Bose G M 1745 Recherches sur la cause et sur la veritable theorie del’electricite (Wittenberg) 47. Rayleigh , L. Phil. Mag. 1882, 44 , 184 . 48. Cooley , J.F. US Pattern. (1902),692,631 49. Cooley , J.F. US Pattern. (1903),745,276 . 50. Morton , W.J. US Pattern. (1902),705,691 . 51. Formhals , A. US Pattern. (1934), 1,975,504 . 52. Geoffrey Taylor. Proceedings of the Royal Society A. (1964), 280, 1382, 383. 53. Baumgarten , P.K. J. Colloid Interface Sci. (1971), 36 , 71 . 54. Larrondo, L. , John Manley, R. J. Polym. Sci. Polym. Phys. 1981, 19 , 909. 55. Larrondo, L. , John Manley , R. J. Polym. Sci. Polym. Phys. 1981, 19 ,921 56. Larrondo, L. , John Manley , R. J. Polym. Sci. Polym. Phys. 1981, 19 ,933 57. Nandana Bhardwaj, Subhas C. Kundu. Biotechnology Advances 2010, 28, 325 58. A. Theron, E. Zussman, A. L. Yarin. Nanotechnology 2001, 12, 384 59. Dan Li, Yuliang Wang, Younan Xia. Adv. Mater. 2006, 16, 4, 361 60. D.H. Reneker, A.L. Yarin, Polymer 2008, 49, 2387 61. D.H. Reneker, A.L. Yarin, H. Fong, S. Koombhongse, J. Appl. Phys. 2000, 87, 4531 62. Chi Wang, Huan-Sheng Chien, Kuo-Wei Yan, Chien-Lin Hung, Kan-Lin Hung, Shih-Jung Tsai, Hao-Jhe Jhang. Polymer. 2009, 50, 6100 63. 林哲寬,國立台灣大學碩士論文,2015 64. Fung-Ching Lin, Da-Ming Wang, Juin-Yih Lai. Journal of Membrane Science. 1996, 110, 25 65. L. Zeman, T. Fraser. Journal of Membrane Science. 1993, 84, 93 66. L. Zeman, T. Fraser. Journal of Membrane Science. 1993, 87, 267 67. C. Stropnik, V. Musil, M. Brumen. Polymer. 2000, 41, 9227 68. O. Pitois, B. Francois. Colloid Polym Sci. 1999, 277, 574 69. Mohan Srinivasarao, David Collings, Alan Philips, Sanjay Patel. Science. 2001, 292, 79 70. Pratyush Dayal, Jing Liu, Satish Kumar, Thein Kyu. Macromolecules. 2007, 40, 7689 71. Chia-Ling Pai, Mary C. Boyce, Gregory C. Rutledge. Macromolecules. 2009, 42, 2102 72. Ping Lu, Younan Xia. Langmuir. 2013, 29, 7070 73. Michael Bognitzki, Wolfgang Czado, Thomas Frese. et.al. Adv. Mater. 2001, 13, 70 74. Shengguang Cao, Binghuan Hu, Haiqing Liu. Acta Polymerica Sinica. 2010, 10 75. Lakshmi Natarajan, Jackie New, Aravind Dasari, Suzhu Yub, Munirah Abdul Mananb. RSC Adv., 2014, 4, 44082 76. C. T. Lim, E. P. S. Tan, S. Y. Ng. Applied Physics Letters. 2008, 92, 141908 77. Fischer, E. W.; Sterzel, H. J.; Wegner, G. Kolloid Z. Z. Polym. 1973, 251, 980. 78. Loomis, G. L.; Murdoch, J. R.; Gardner, K. H. Polym. Prepr. 1990, 31, 55. 79. Pengju Pan, Jinjun Yang, Guorong Shan, Yongzhong Bao, Zhixue Weng, Amin Cao, Koji Yazawa, Yoshio Inoue. Macromolecules 2012, 45, 189 80. Brandrup, J. ; Immergut, E. H. ; Grulke, E. A.Hoboken, Polymer handbook. Wiley-Interscience. 1999 81. Polymer Properties Database, from http://polymerdatabase.com/ | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/78047 | - |
dc.description.abstract | 在本研究中,我們探討靜電紡絲纖維的型態與結晶行為。利用摻雜聚右旋乳酸改變聚左旋乳酸的結晶行為,我們發現它們的纖維直徑有些變化。我們也嘗試讓材料形成stereocomplex (SC)晶體,觀察其在靜電紡絲過程中如何影響相分離行為。
我們相信一旦相分離發生且皮層形成後,纖維的尺寸便不再變化。因此,越大的直徑代表著此種材料越早產生相分離。我們發現纖維直徑大的材料,在我們的DSC測試中也具有比較高的結晶度,表示在靜電紡絲過程中,結晶及固-液相分離扮演者重要的角色。 在我們的實驗中,我們發現一種新的晶體,我們稱之為SC΄晶體,其熔點比SC晶體稍微低一些。我們之後做了一些薄膜實驗,推測SC΄晶體的形成,可能與靜電紡絲過程中凝結下來的水氣有關。 | zh_TW |
dc.description.abstract | In this study, we investigate the morphology and crystallization behavior of electrospun fibers. By blending PDLA with PLLA to alter its crystallization behavior, we observed a change in their fiber diameter. We also tried to form stereocomplex (SC) crystal in our materials, to see how it affects the phase separation process during electrospinning.
We believe that once the phase separation occurs and the skin forms, the dimension of the fibers will not change. Thus, larger diameter indicates that the material undergo phase separation earlier. We found that materials with larger diameter also yield higher crystallinity in our DSC test, meaning that crystallization might play a role in solid-liquid phase separation during electrospinning. In our experiment, we also found a new crystal structure, we called it SC΄ crystal, whose melting point is just below that of SC crystal. We then conducted some experiment with membranes and concluded that the forming of SC΄ crystal might be related to water condensed during electrospinning process. | en |
dc.description.provenance | Made available in DSpace on 2021-07-11T14:40:38Z (GMT). No. of bitstreams: 1 ntu-105-R03527030-1.pdf: 3171076 bytes, checksum: 9bc01e52a56c22ccf556cc6d790e5b0a (MD5) Previous issue date: 2016 | en |
dc.description.tableofcontents | 摘要 iv
Abstract v 目錄 vi 圖目錄 viii 表目錄 xi 第一章 緒論 1 第二章 文獻回顧 2 2-1 聚乳酸簡介 2 2-1-1 生物可分解性高分子 2 2-1-2 聚乳酸的合成與應用 4 2-1-3 聚乳酸的結晶結構 6 2-1-3 Stereocomplex簡介 9 2-2 靜電紡絲技術 12 2-2-1 靜電紡絲發展 12 2-2-2 靜電紡絲的裝置與原理 15 2-2-3 靜電紡絲參數 18 2-3 孔洞材料製備與其理論 20 2-3-1 濕式相轉換法製孔洞薄膜 20 2-3-2 靜電紡絲與孔洞纖維 24 第三章 實驗 26 3-1實驗藥品 26 3-2 實驗儀器 26 3-3 實驗方法 29 3-3-1 靜電紡絲製備高分子纖維 29 3-3-2 高分子膜之製備 30 3-3-3 場發掃描式電子顯微鏡 30 3-3-4 熱微差掃瞄分析儀 31 3-3-5 廣角X光繞射儀 31 3-3-6 傅立葉轉換紅外光光譜儀 31 第四章 結果與討論 32 4-1 靜電紡絲下纖維的型態 32 4-2 靜電紡絲下的結晶行為 45 4-3 SC΄晶體結構 61 4-4 相分離界面探討 69 第五章 結論 72 參考文獻 73 | |
dc.language.iso | zh-TW | |
dc.title | 摻雜聚右旋乳酸之聚左旋乳酸靜電紡絲其型態與結晶行為 | zh_TW |
dc.title | Morphology and Crystallization Behavior of Electrospun PLLA blending with PDLA | en |
dc.type | Thesis | |
dc.date.schoolyear | 105-1 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 王大銘,童世煌,羅世強 | |
dc.subject.keyword | 聚乳酸,左右旋聚乳酸摻合物,靜電紡絲,相分離,形態學,結晶, | zh_TW |
dc.subject.keyword | PLA,stereocomplex,electrospinning,phase separation,morphology,crystallization, | en |
dc.relation.page | 77 | |
dc.identifier.doi | 10.6342/NTU201603691 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2016-10-20 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-105-R03527030-1.pdf 目前未授權公開取用 | 3.1 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。