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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 駱尚廉 | |
| dc.contributor.author | Feng-Kuang Chen | en |
| dc.contributor.author | 陳風光 | zh_TW |
| dc.date.accessioned | 2021-07-10T21:46:05Z | - |
| dc.date.available | 2021-07-10T21:46:05Z | - |
| dc.date.copyright | 2020-07-01 | |
| dc.date.issued | 2020 | |
| dc.date.submitted | 2020-06-18 | |
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C., Autoclave meltout of cast explosives, Defense Explosives Safety Board, USA, pp.5-19,1994. 40.U.S. EPA. Inductively coupled plasma - mass spectrometry. Method 6020a, Jan. 1998. 41.行政院環境保護署,以ICP-MS 建立環境中重金屬檢測技術 (Ⅱ),EPA-91-E3S4-02-02,2002。 42. Horlick, G., Spectrochim. Acta 4B, 1555, 1985. 43. Gray. A.L., Spectrochim. Acta 40B, 1525 (1985); 41B, 151, 1986.第12頁,共23頁 44.Tan, S.H.,and Horlick,G., Appl. Spectrosc. 40, 445, 1986. 45.Vaughan, M.A., and Horlick, G., Appl. Spectrosc. 40, 434, 1986. 46.Holden, N.E.,'Table of the Isotopes,' in Lide, D.R., Ed., CRC Handbook of Chemistry and Physics, 74th Ed., CRC Press, Boca Raton, FL, 1993. 47.Lichte, F.E., Anal. Chem.59, 1150, 1987. 48. Evans E.H., and Ebdon, L., J. Anal. At. Spectrom.4, 299, 1989. 49. Beauchemin, D., Spectrochim. Acta 42b, 467, 1987. 50.Houk, R.S., Anal. Chem. 58, 97A, 1986. 51.Thompson, J.J., and Houk, R.S., Appl. Spectrosc. 41,801, 1987. 52.行政院環境保護署,土壤檢測方法總則 NIEA S103.61C,中華民國 98 年。 53.行政院環境保護署,事業廢棄物採樣方法 NIEA R118.02B,中華民國 94 年。 第 15 頁,共 23 頁 54.行政院環境保護署,訂定土壤及地下水污染調查採樣技術指引,EPA-88-H105-03-416,中華民國 88 年。 55.中華民國國家標準,土壤薄管採樣法 CNS 12386 A 3284, 中華民國 86 年。 56.ASTM. Standard test method for standard penetration test (SPT) and split - barrel sampling of soils. ASTM D 1586-11, 2011. 57.ASTM. Standard practice for thin - walled tube sampling of soils for geotechnical sampling of soils. ASTM D 1587-08, 2008. 58.U.S. EPA. Preparation of soil sampling protocols: sampling techniques and strategies. 1992. 59.U.S. EPA. Guidance for choosing a sampling design for environmental data collection. peer review draft, 2000. 60.U.S. EPA. Chapter 2 in subsurface characterization and monitoring techniques: a desk reference guide. Vol.Ⅰ and Ⅱ, 1993. 61.U.S. EPA. Soil Screening Guidance: User’s Guide. 2nd Ed., 1996. 62.Federal Ministry for the Environment, Nature conservation and nuclear safety (German), federal soil protection and contaminated sites ordinance. 1999. 63.U.S. EPA. Test methods for evaluating solid waste Physical/chemical methods. SW-846, Chapter One-Quality Control, Revision 1, 1992. 64.https://kknews.cc/agriculture/6lg28ap.html | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/77086 | - |
| dc.description.abstract | 美國國家環境保護局在2005年文刊中指出,火炸藥類物質為軍事場址特有之污染物,依據國外文獻資料,火炸藥類物質主要出現於兵工廠、彈藥裝填、組裝或包裝廠、軍火庫、彈藥庫、露天炸燬及露天銷燬場、靶場的目標區、廢彈處理場、輕兵器訓練靶場及軍械測試設施。 本篇論文針對上述場址選擇露天銷燬場及靶場來做研究,而土壤的重金屬物質污染種類,則視場址中銷燬及射擊的武器彈藥種類而定;舉例來說,若是用以露天銷燬場,土壤中重金屬源為廢棄彈藥及彈藥整修所拆卸下來的火工零附件,而輕兵器靶場則為輕兵器彈藥射擊後所殘留的彈頭及彈殼。 廢棄彈藥係指不能適用原定用途,或不能作任何有效使用且廢壞及無經濟維修價值之不堪用彈藥。所以彈藥銷燬作業是整體彈藥勤務之一環,彈藥銷燬目的乃為維護安全;因火炸藥具有較高危險性,尤以變質(性)後、敏感性大增,危害性無法估計,須銷燬以策安全。因科技進步,武器汰舊更新頻繁及長期庫儲彈藥變質損壞不堪修復等因素,廢(棄)彈藥將逐漸增多,為確保庫儲安全及避免占用有限儲存空間,彈藥銷燬為一迫切必要工作。 輕兵器靶場射擊是軍方維持戰力及年度戰演訓任務之一,各軍司令部每年均會排定靶場射訓流路並要求國軍所屬各單位進訓實施射擊訓練,於訓練期間依國軍靶場作業規定須於射擊完畢後將彈殼撿拾後繳回彈藥庫,但彈頭的部分卻無明確相關回收規定,所以導致大量累積於靶區,造成環境危害及土壤重金屬超標。 | zh_TW |
| dc.description.abstract | The US Environmental Protection Agency pointed out that explosives are specific pollutants at military sites in 2005. According to foreign literature, explosives mainly appear in arsenals, ammunition loading, assembly or packaging plants, military supply depots, ammunition depots, open detonation, open burning, range impact areas, explosive ordnance disposal sites , training ranges and ordnance test and evaluation sites. This paper selects open destruction sites and shooting ranges for research above the sites. The types of heavy metal pollution in the soil depend on the types of weapons and ammunition destroyed and fired in the sites. For example, if they are used for open destruction sites. The main source of heavy metal contaminants in the soil is the pyrotechnic parts dismantled from waste ammunition and ammunition refurbishment, and the light weapon range is the pollution problem caused by the remaining warheads and shells after the light weapon ammunition is fired. Abandoned ammunition refers to unacceptable ammunition that cannot be used for its original purpose or cannot be used effectively and has no economic maintenance value. Therefore, the destruction of ammunition is a part of the overall ammunition service. The purpose of the destruction of ammunition is to maintain safety. Because of the high danger of fire and explosives, especially after deterioration, the sensitivity is greatly increased and the hazard cannot be estimated. Due to technological advances cause the ammunition unable to use and waste (abandoned) ammunition will gradually increase. To ensure storage safety and avoid occupying limited storage space. The destruction of ammunition is an urgently necessary task. Shooting at training range is one of the main missions to maintain combat effectiveness and annual combat drills. Each military headquarters will schedule the shooting range and require all units affiliated to the national army to conduct shooting training during the training period. The national army's shooting standard process requires that the shell be picked up and returned to the ammunition depot after the shooting is completed, but the warhead part has no clear relevant recycling regulations, so it has caused a large amount of accumulation in the target area, causing environmental hazards and soil heavy metals exceeding the standard. | en |
| dc.description.provenance | Made available in DSpace on 2021-07-10T21:46:05Z (GMT). No. of bitstreams: 1 U0001-1806202009280000.pdf: 10574638 bytes, checksum: e147dd007897493784c48de73e4bfe23 (MD5) Previous issue date: 2020 | en |
| dc.description.tableofcontents | 口試委員會審定書 i 誌謝 ii 中文摘要 iii 英文摘要 iv 目錄 v 圖目錄 viii 表目錄 xi 第一章 前言 1 1.1研究源起 1 1.2研究目的 1 1.3研究內容 2 第二章 文獻回顧 5 2.1火炸藥基本特性 5 2.1.1火炸藥的化學特性 5 2.1.2火炸藥物理及化學安定性 7 2.1.3火炸藥的敏感性 9 2.2火炸藥的分類 10 2.2.1. 用途分類 11 2.2.2組成分類 12 2.2.3敏感性分類 13 2.2.4物理型態分類 13 2.2.5反應速率分類 13 2.3炸藥爆炸性能 13 2.4炸藥爆炸時的特徵 14 2.4.1放熱性 15 2.5火藥鏈介紹及火藥鏈設計考慮因素 15 2.5.1火藥鏈的定義 15 2.5.2火藥鏈的分類 16 2.5.3火藥鏈設計考慮因素 17 2.6低級火藥及發射藥的化學性質及爆炸性質介紹 17 2.6.1黑藥(Black powder) 17 2.6.2發射藥(Propellant):現行廢棄彈藥銷燬場燒最多 18 2.6.3發射藥的化學性質(chemical characteristics): 20 2.6.4發射藥的爆炸性質: 22 2.7高級火藥介紹 24 2.7.1起爆藥 24 2.7.2傳爆藥 26 2.7.3炸裂藥 28 2.7.4爆破藥 32 2.8國軍現行廢彈處理技術簡介 33 第三章 研究方法與材料 35 3.1實驗方法 35 3.1.1先期「資料蒐集審閱」、「人員訪談」及「場址勘查」等三項工作 35 3.1.2土壤採樣方法 40 3.1.3土壤和底泥中元素濃度快速篩選方法-攜帶式X-射線螢光光譜儀分析法 55 3.1.4土壤中重金屬檢測標準作業程序—王水消化法及感應耦合電漿原子發射光譜法 61 第四章 結果與討論 80 4.1輕兵器射擊靶場檢測結果 80 4.1.1武荖坑靶場-北部 80 4.1.2崎頂靶場-中部 90 4.1.3 清泉崗靶場-中部 102 4.1.4 復興靶場-東部 114 4.1.5 太平靶場-東部 126 4.2彈藥銷燬場檢測結果 138 4.2.1明湖彈藥銷燬場-北部 138 4.2.2番社彈藥銷燬場-中部 149 4.2.3田單彈藥銷燬場-南部 160 4.2.4興德彈藥銷燬場-東部 167 4.3靶場及彈藥銷燬場檢測結果討論 179 4.3.1檢測及問卷結果統整 179 4.3.2污染成因分析 180 4.3.3重金屬污染場址對作業人員危害 182 第五章 結論與建議 185 5.1靶場整治及維管方法 185 5.2廢棄彈藥銷燬場整治及維管方法 187 5.3提升作業人員安全防護及改變製程 188 參考文獻 190 | |
| dc.language.iso | zh-TW | |
| dc.subject | 露天銷燬場 | zh_TW |
| dc.subject | 輕兵器靶場 | zh_TW |
| dc.subject | 廢棄彈藥 | zh_TW |
| dc.subject | 輕兵器靶場射擊 | zh_TW |
| dc.subject | 土壤重金屬污染 | zh_TW |
| dc.subject | Open detonation | en |
| dc.subject | Training ranges | en |
| dc.subject | Abandoned ammunition | en |
| dc.subject | Shooting at training range | en |
| dc.subject | Soil heavy metal pollution | en |
| dc.title | 廢棄彈藥銷燬場及射擊靶場土壤重金屬污染探討 | zh_TW |
| dc.title | Investigation of Heavy Metal Pollution in Soil on Abandoned Ammunition Destruction Site and Shooting Range | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 108-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 闕蓓德,鄒倫 | |
| dc.subject.keyword | 露天銷燬場,輕兵器靶場,廢棄彈藥,輕兵器靶場射擊,土壤重金屬污染, | zh_TW |
| dc.subject.keyword | Open detonation,Training ranges,Abandoned ammunition,Shooting at training range,Soil heavy metal pollution, | en |
| dc.relation.page | 193 | |
| dc.identifier.doi | 10.6342/NTU202001025 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2020-06-19 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
| 顯示於系所單位: | 環境工程學研究所 | |
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