Skip navigation

DSpace

機構典藏 DSpace 系統致力於保存各式數位資料(如:文字、圖片、PDF)並使其易於取用。

點此認識 DSpace
DSpace logo
English
中文
  • 瀏覽論文
    • 校院系所
    • 出版年
    • 作者
    • 標題
    • 關鍵字
    • 指導教授
  • 搜尋 TDR
  • 授權 Q&A
    • 我的頁面
    • 接受 E-mail 通知
    • 編輯個人資料
  1. NTU Theses and Dissertations Repository
  2. 工學院
  3. 機械工程學系
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/76992
完整後設資料紀錄
DC 欄位值語言
dc.contributor.advisor廖洺漢(Ming-Han Liao)
dc.contributor.authorTzu-Hsien Chanen
dc.contributor.author詹子賢zh_TW
dc.date.accessioned2021-07-10T21:42:43Z-
dc.date.available2021-07-10T21:42:43Z-
dc.date.copyright2020-08-07
dc.date.issued2020
dc.date.submitted2020-07-30
dc.identifier.citation[1] M. Golio J. Golio, “RF and Microwave Passive and Active Technologies,” pp. 18-1 ,2007
[2] “MOSFET,” (https://en.wikipedia.org/wiki/MOSFET), 2020/06/20
[3] G. E. Moore, “Cramming More Components Onto Integrated Circuits,” Electronics, Vol. 38, No. 8, 1965
[4] S. M. Sze K. K. Ng, “Physics of Semiconductor Devices.3rd ed,” pp.333, 2008
[5] A. Leather, “Intel claims Moore's Law is alive and well,” (https://bit-tech.net/others/ tech/intel-claims-moore-s-law-isn-t-dead-but-ali/1/), 2020/06/20
[6] A. B. Sachid, M. C. Chen, C. Hu, “FinFET with high-κ spacers for improved drive current,” IEEE Electron Device Lett, vol. 37, no. 7, pp. 835-838, 2016
[7] A. Mishra, M. Pattanaik, V. Sharma, “Double gate vertical tunnel FET for hybrid CMOS-TFET based low standby power logic circuits,” International Conference on Microelectronics, pp. 1-4, India, June 2013
[8] T. K. Chiang, “A new threshold voltage model for short-channel junctionless inverted T-shaped gate FETs (JLITFET),” IEEE Trans Nanotechnol, vol. 15, no. 3, pp. 442-447, 2016
[9] Z. Yao, C. L. Kane , C. Dekker, “High-field electrical transport in single-wall carbon nanotubes,” American Physical Society, vol. 84, pp. 2941-2944, 2000
[10] M. S. Fuhrer, B. M. Kim, T. Duerkop, T. Brintlinger, “High-mobility nanotube transistor memory,” Nano letters , vol. 2, pp. 755-759, 2002
[11] E. Pop, D. Mann, Q. Wang, K. Goodson, H. Dai, “Thermal Conductance of an Individual Single-Wall Carbon Nanotube above Room Temperature,” Nano letters, vol. 6, no. 1, pp. 96-100, 2006
[12] S. M. AliZanjani, M. Doustib, M. Dolatshahi, “A new low-power, universal, multi-mode Gm-C filter in CNTFET technology,” SienceDirect, vol. 90, pp. 342-352, 2019
[13] Sumio Iijima, “Helical microtubules of graphitic carbon,” Nature, vol. 354, pp. 56-58, 1991
[14] E. Dervishi , Z. Li , Y. Xu , V. Saini , A. R. Biris , D. Lupu, A. S. Biris, 'Carbon Nanotubes: Synthesis, Properties, and Applications,' Particulate Science and Technology, vol. 27, no. 2, pp. 107-125, 2009
[15] R. Saito, M. Fujita, G. Dresselhaus, M. S Dresselhaus, 'Electronic structure of chiral graphene tubules,' Applied Physics Letters, vol. 60, no. 18, pp. 2204, 1992
[16] T. W. Ebbesen P. M. Ajayan, 'Large-scale synthesis of carbon nanotubes,' Nature, vol. 358, pp. 220-222, 1992
[17] A. Thess, R. Lee, P. Nikolaev, H. Dai, P. Petit, J. Robert, C. Xu, Y. H. Lee, S. G. Kim, A. G. Rinzler, D. T. Colbert, G. E. Scuseria, et al., 'Crystalline Ropes of Metallic Carbon Nanotubes,' AAAS Science, vol. 273, no. 5274, pp. 483-487, 1996
[18] M. Terrones, N. Grobert, J. Olivares, J. P. Zhang, H. Terrones, K. Kordatos, W. K. Hsu, J. P. Hare, P. D. Townsend, K. Prassides, A. K. Cheetham, H. W. Kroto , D. R. M. Walton, 'Controlled production of aligned-nanotube bundles,' Nature, vol. 388, pp. 52-55, 1997
[19] 黃建盛,“奈米碳管簡介,”科學新天地, vol. 13, pp. 4-9, 2006
[20] M. Kumar Y. Ando, 'Chemical Vapor Deposition of Carbon Nanotubes: A Review on Growth Mechanism and Mass Production,' American Scientific Publishers, vol. 10, pp. 3739-3758, 2010
[21] M. A. Azam, N. S. A. Manaf, E. Talib, M. S. A. Bistamam, 'Aligned carbon nanotube from catalytic chemical vapor deposition technique for energy storage device: a review,' Springer Ionics, vol. 19, pp. 1455-1476, 2013
[22] R.T.K.Baker, M.A.Barber, P.S.Harris, F.S.Feates, R.J.Waite, 'Nucleation and growth of carbon deposits from the nickel catalyzed decomposition of acetylene,' ScienceDirect, vol. 26, no. 1, pp. 51-62, 1972
[23] R.T.K.Baker R.J.Waite, 'Formation of carbonaceous deposits from the platinum-iron catalyzed decomposition of acetylene,' Atomic Energy Research Establishment, ScienceDirect, vol. 37, no. 1, pp. 101-105, 1975
[24] K. Hernadi, A. Fonseca, J. B. Nagy, D. Bernaerts, A. A. Lucas, 'Fe-catalyzed carbon nanotube formation,' ScienceDirect, vol. 34, no. 10, pp. 1249-1257, 1996
[25] S. Fan, M. G. Chapline, N. R. Franklin, T. W. Tombler, A. M. Cassell, H. Dai, 'Self-oriented Regular Arrays of Carbon Nanotubes and Their Field Emission Properties,' AAAS Science, vol. 283, no. 5401, pp. 512-514, 1999
[26] W. Z. Li , S. S. Xie, L. X. Qian, B. H. Chang, B. S. Zou, W. Y. Zhou, R. A. Zhao, G. Wang, 'Large-Scale Synthesis of Aligned Carbon Nanotubes,' AAAS Science, Vol. 274, No. 5293, pp. 1701-1703, 1996
[27] O. A. Nerushev, S. Dittmar, R.-E. Morjan, F. Rohmund, E. E. B. Campbell , 'Particle size dependence and model for iron-catalyzed growth of carbon nanotubes by thermal chemical vapor deposition,' AIP Journal of Applied Physics, vol. 93, pp. 4185-4190, 2003
[28] R. E. Morjan, O. A. Nerushev, M. Sveningsson, F. Rohmund, L. K. L. Falk, E. E. B. Campbell, 'Growth of carbon nanotubes from C60,' Applied Physics A, vol. 78, pp. 253-261, 2004
[29] F. Ding, P. Larsson, J. A. Larsson, R. Ahuja, H. Duan, A. Rosén, K. Bolton, 'The Importance of Strong Carbon−Metal Adhesion for Catalytic Nucleation of Single-Walled Carbon Nanotubes,' American Chemical Society, vol. 8, no. 2, pp. 463-468, 2007
[30] K. Hata, D. N. Futaba, K. Mizuno, T. Namai, M. Yumura, S. Iijima, 'Water-Assisted Highly Efficient Synthesis of Impurity-Free Single-Walled Carbon Nanotubes,' AAAS Science, vol. 306, no. 5700, pp. 1362-1364, 2004
[31] B. Kitiyanan, W. E. Alvarez, J. H. Harwell, D. E. Resasco, 'Controlled production of single-wall carbon nanotubes by catalytic decomposition of CO on bimetallic Co–Mo catalysts,' ScienceDirect , vol. 317, no. 3-5, pp. 497-503, 2000
[32] R. Andrews, D. Jacques, A. M. Rao, F. Derbyshire, D. Qian, X. Fan, E. C. Dickey, J. Chen, 'Continuous production of aligned carbon nanotubes: a step closer to commercial realization,' ScienceDirect, vol. 303, no. 5-6, pp. 467-474, 1999
[33] C. L. Cheung, A. Kurtz, H. Park, C. M. Lieber, 'Diameter-Controlled Synthesis of Carbon Nanotubes,' American Chemical Society, vol. 106, pp. 2429-2433, 2002
[34] N. Nagaraju, A. Fonseca, Z. Konya, J. B. Nagy, 'Alumina and silica supported metal catalysts for the production of carbon nanotubes,' ScienceDirect, vol. 181, no. 1-2, pp. 57-62, 2002
[35] S. M. Huang, M. Woodson, R. Smalley, J. Liu, 'Growth Mechanism of Oriented Long Single Walled Carbon Nanotubes Using “Fast-Heating” Chemical Vapor Deposition Process,' American Chemical Society, vol. 4, no. 6, pp. 1025-1028, 2004
[36] N. Nagaraju, Y. Zhang, A. Chang, J. Cao, Q. Wang, W. Kim, Y. Li, N. Morris, E. Yenilmez, J. Kong, H. Dai, 'Electric-field-directed growth of aligned single-walled carbon nanotubes,' Applied Physics Letters, vol. 79, no. 19, pp. 3155-3157, 2001
[37] S. M. Huang, X. Y. Cai, C. S. Du, J. Liu, 'Oriented Long Single Walled Carbon Nanotubes on Substrates from Floating Catalysts,' American Chemical Society, vol. 107, no. 48, pp. 13251-13254, 2003
[38] R. Zhang, Y. y. Zhang, F. Wei, 'Horizontally aligned carbon nanotube arrays: growth mechanism, controlled synthesis, characterization, properties and applications,' The Royal Society of Chemistry, vol. 46, no. 12, pp. 3661-3715, 2017
[39] R. Zhang, Y. y. Zhang, F. Wei, 'Ultralow Feeding Gas Flow Guiding Growth of Large-Scale Horizontally Aligned Single-Walled Carbon Nanotube Arrays,' American Chemical Society, vol. 7, no. 7, pp. 2073-2079, 2007
[40] S. Han, X. L. Liu, C. W. Zhou, 'Template-Free Directional Growth of Single-Walled Carbon Nanotubes on a- and r-Plane Sapphire,' American Chemical Society, vol. 127, no. 15, pp. 5294-5295, 2005
[41] H. Ago, N. Ishigami, N. Yoshihara, K. Imamoto, S. Akita, K.-i. Ikeda, M. Tsuji, T. Ikuta, K. Takahashi, 'Visualization of Horizontally-Aligned Single-Walled Carbon Nanotube Growth with 13C/12C Isotopes,' American Chemical Society, vol. 112, no. 6, pp. 1735-1738, 2007
[42] C. Kocabas, S. H. Hur, A. Gaur, M. A. Meitl, M. Shim, J. A. Rogers, 'Guided Growth of Large-Scale, Horizontally Aligned Arrays of Single-Walled Carbon Nanotubes and Their Use in Thin-Film Transistors,' Small, vol. 1, no. 7, pp. 1110-1116, 2005
[43] S. J. Kang, C. Kocabas, T. Ozel, M. Shim, N. Pimparkar, M. A. Alam, S. V. Rotkin, J. A. Rogers, 'High-performance electronics using dense, perfectly aligned arrays of single-walled carbon nanotubes,' Nature, vol. 2, pp. 230-236, 2007
[44] K. Ryu, A. Badmaev, C. Wang, A.Lin, N. Patil, L. Gomez, A. Kumar, S. Mitra, H. S. P. Wong, C. Zhou, 'CMOS-Analogous Wafer-Scale Nanotube-on-Insulator Approach for Submicrometer Devices and Integrated Circuits Using Aligned Nanotubes,' American Chemical Society, vol. 9, pp. 189-197, 2008
[45] N. Patil, A.Lin, E. R. Myers, K. Ryu, A. Badmaev, C. Zhou, H. S. P. Wong, S. Mitra, 'Wafer-Scale Growth and Transfer of Aligned Single-Walled Carbon Nanotubes,' IEEE Transactions on Nanotechnology, vol. 8, no. 4, pp. 498-504, 2009
[46] P. G. Collins, M. S. Arnold, P. Avouris, 'Engineering Carbon Nanotubes and Nanotube Circuits Using Electrical Breakdown,' AAAS Science, vol. 292, no. 5517, pp. 706-709, 2009
[47] A. Lin, N. Patil, K. Ryu, A. Badmaev, L. G. D. Arco, C. Zhou, S. Mitra, H. S. P. Wong, 'Threshold Voltage and On–Off Ratio Tuning for Multiple-Tube Carbon Nanotube FETs,' IEEE Transactions on Nanotechnology, vol. 8, no. 1, pp. 4-9, 2009
[48] D. Brambley, B. Martin, P. D. Prewett, 'Microlithography: An overview,' Advanced Materials for Optics and Electronics, vol. 4, pp. 55-74, 1994
[49] 'Electron Beam Source for Electron Beam Deposition,' (https://www.jeol.co.jp/en/
science/eb.html), 2020/06/18
[50] C. Kocabas, S. J. Kang, T. Ozel, M. Shim, 'Improved Synthesis of Aligned Arrays of Single-Walled Carbon Nanotubes and Their Implementation in Thin Film Type Transistors,' American Chemical Society, vol. 111, no. 48, pp. 17879-17886, 2007
[51] '掃描式電子顯微鏡 (SEM),' (https://eaglabs.com.tw/sem.html), 2020/06/18
[52] '場發射掃描式電子顯微鏡Field-emission scanning electron micros,' (http://web.nchu.edu.tw/~pinlin/diagram.jpg), 2020/06/18
[53] 'Raman Imaging and Spectroscopy,' (https://www.horiba.com/en_en/raman-imaging-and-spectroscopy/), 2020/06/18
[54] 孫玫蘭, '拉曼實驗裝置及原理,' 2002
[55] 'Single Crystal Quartz Wafer,' (http://www.semiwafer.com/single-crystal-quartz-wafer.html), 2020/06/25
[56] P. Lia J. Zhang, 'Sorting out semiconducting single-walled carbon nanotube arrays by preferential destruction of metallic tubes using water,' Journal of Materials Chemistry, vol. 21, pp. 11815-11821, 2011
dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/76992-
dc.description.abstract本論文主要是透過化學氣相沉積法在石英基板上成長出水平奈米碳管陣列,并藉由改變成長水平奈米碳管製程所需要的製程參數,找到最適合成長出水平奈米碳管的參數。首先,使用高溫爐管將石英基板表面進行退火製程,接著透過曝光顯影製程以及電子束蒸鍍系統,在石英基板表面上蒸鍍一層鐵催化劑薄膜,再使用真空高溫爐管系統嘗試在石英基板上成長出水平奈米碳管陣列。最後利用掃描式電子顯微鏡以及拉曼光譜測量系統對於水平奈米碳管進行觀察與量測。
本論文主要觀察到成長水平奈米碳管的製程參數對於水平奈米碳管的影響:(1)使用適當的鐵催化劑薄膜厚度才能夠在石英基板上成長出水平奈米碳管。(2)成長水平奈米碳管的溫度過高與過低都會影響到奈米碳管的生長。(3)成長碳源流量、成長時間以及試片擺放位置影響到是水平奈米碳管陣列的密度。
最後本論文在分析以上的製程參數對於水平奈米碳管影響後,成功的研究出一套屬於本論文的水平奈米碳管製程,如果以後的成長製程有出現偏差,可以藉由這些製程參數分析找到如何改善製程,擁有這套製程便能夠滿足未來實驗室繼續研究奈米碳管場效電晶體的條件。
zh_TW
dc.description.abstractThis thesis focuses on growing horizontal carbon nanotube arrays on a quartz substrate by chemical vapor deposition, we found the most suitable parameters for the growth of horizontal carbon nanotubes by changing the process parameters. First of all, using a high-temperature furnace to anneal the surface of the quartz substrate. Then by using the process of exposure development and electron beam evaporation system, evaporating a layer of iron catalyst film on the quartz base plate, afterwards, using the vacuum high-temperature furnace tube system, attempting to grow up horizontal carbon nanotube array on the quartz substrate. Finally, using scanning electron microscope and Raman spectrograph system to observe and measure the horizontal carbon nanotube.
In this paper, the effects of the production process parameters of the horizontal carbon nanotube were observed:
(1) Only if we use the proper iron catalyst film thickness will the horizontal carbon nanotube grow on the quartz substrate.
(2) The growth of the carbon nanotube will be affected in the condition that the temperature of the manufacturing process is too high or low.
(3) The density of the horizontal carbon nanotube is controlled by the parameters including the carbon growing flux, the growing time and the position of the specimen.
After this paper carries out the analysis of the manufacturing process parameters effects on the horizontal carbon nanotube, we successfully develop a set of horizontal carbon nanotube manufacturing procedures belonging to this paper. If there is any problem caused in the follow-up growth manufacturing process, then we can improve the manufacturing process by the analysis of the manufacturing process parameters. Owning this set of manufacturing processes can make the laboratory be able to research carbon nanotube field-effect transistors in future.
en
dc.description.provenanceMade available in DSpace on 2021-07-10T21:42:43Z (GMT). No. of bitstreams: 1
U0001-2807202023223900.pdf: 4704978 bytes, checksum: 6a7ac1c4d67400aa702c1d05e2a59c9e (MD5)
Previous issue date: 2020
en
dc.description.tableofcontents口試委員審定書 i
致謝 ii
中文摘要 iii
ABSTRACT iv
目錄 v
圖目錄 vii
表目錄 ix
第一章 緒論 1
1.1 前言 1
1.2 研究背景與動機 2
1.3 論文架構 4
第二章 文獻回顧與理論基礎 6
2.1 奈米碳管 6
2.2 奈米碳管的製程 7
2.3 水平奈米碳管 11
2.4 水平奈米碳管製程 12
2.5 國際發展 15
第三章 實驗設備與原理 19
3.1 曝光機 20
3.2 電子束蒸鍍系統 21
3.3 真空高溫爐管系統 22
3.4 場發射掃描電子顯微鏡 23
3.5 拉曼光譜測量系統 24
第四章 實驗流程與製程 26
4.1 實驗流程設計 26
4.2 基板清洗 26
4.3 石英基板退火處理 28
4.4 光阻塗佈 29
4.5 曝光與顯影 31
4.6 鐵催化劑鍍膜 33
4.7 鐵薄膜鍛燒 35
4.8 成長水平奈米碳管 38
第五章 實驗結果與討論 41
5.1 鐵薄膜 41
5.2 成長溫度 44
5.3 成長碳源流量 45
5.4 成長時間 48
5.5 擺放位置 50
5.6 結論 52
第六章 總結與未來研究方向 54
參考文獻 56
dc.language.isozh-TW
dc.subject水平奈米碳管zh_TW
dc.subject石英基板zh_TW
dc.subject低鍍率蒸鍍技術zh_TW
dc.subject鐵薄膜zh_TW
dc.subject化學氣相沉積法zh_TW
dc.subjectquartz substrateen
dc.subjectchemical vapor depositionen
dc.subjectiron filmen
dc.subjectlow evaporation rate evaporation deposition technologyen
dc.subjecthorizontal carbon nanotubeen
dc.title製程參數對水平奈米碳管之結構影響zh_TW
dc.titleEffects of Fabrication Parameters on the Structure of Horizontal Carbon Nanotubeen
dc.typeThesis
dc.date.schoolyear108-2
dc.description.degree碩士
dc.contributor.oralexamcommittee李敏鴻(Min-Hung Lee),劉建豪(Chien-Hao Liu)
dc.subject.keyword石英基板,低鍍率蒸鍍技術,鐵薄膜,化學氣相沉積法,水平奈米碳管,zh_TW
dc.subject.keywordquartz substrate,low evaporation rate evaporation deposition technology,iron film,chemical vapor deposition,horizontal carbon nanotube,en
dc.relation.page62
dc.identifier.doi10.6342/NTU202002005
dc.rights.note未授權
dc.date.accepted2020-07-30
dc.contributor.author-college工學院zh_TW
dc.contributor.author-dept機械工程學研究所zh_TW
顯示於系所單位:機械工程學系

文件中的檔案:
檔案 大小格式 
U0001-2807202023223900.pdf
  未授權公開取用
4.59 MBAdobe PDF
顯示文件簡單紀錄


系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。

社群連結
聯絡資訊
10617臺北市大安區羅斯福路四段1號
No.1 Sec.4, Roosevelt Rd., Taipei, Taiwan, R.O.C. 106
Tel: (02)33662353
Email: ntuetds@ntu.edu.tw
意見箱
相關連結
館藏目錄
國內圖書館整合查詢 MetaCat
臺大學術典藏 NTU Scholars
臺大圖書館數位典藏館
本站聲明
© NTU Library All Rights Reserved