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DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 席行正 | |
dc.contributor.author | Yu-Chen Chou | en |
dc.contributor.author | 周宥丞 | zh_TW |
dc.date.accessioned | 2021-06-17T08:18:06Z | - |
dc.date.available | 2024-08-18 | |
dc.date.copyright | 2019-08-18 | |
dc.date.issued | 2019 | |
dc.date.submitted | 2019-08-14 | |
dc.identifier.citation | Ahmad, A. A., and Hameed, B. H. (2010). Effect of preparation conditions of activated carbon from bamboo waste for real textile wastewater. Journal of Hazardous Materials, 173(1-3), 487-493.
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/74051 | - |
dc.description.abstract | 本研究以酚醛樹脂球為原料合成出具高比表面積之球狀活性碳(ACS),並應用於超級電容之碳電極材料,以測試球形多孔材料之電容表現。酚醛樹脂球經高溫碳化(500oC,1 小時)後,利用流體化床進行不同條件之二氧化碳物理活化(700–900oC,1–4 小時);本研究同時透過反應曲面法(Response surface methodology)結合中央合成設計實驗(Central composite design)來探討不同活化條件下對於球狀碳孔結構發展之影響。結果顯示在900oC,4 小時的活化條件下,材料比表面積可達3142 m2g-1,孔體積可達1.513 cm3 g-1,孔徑分布則位於微孔與中孔之間。掃描式電子顯微鏡(SEM)觀察結果顯示合成之材料皆具有高度圓球率。超級電容之碳電極由不同活化條件下之球狀碳以及不同比例之黏著劑製備而成,組成二極式系統元件,以比較孔結構對於電容表現之影響。結果顯示,使用具高比表面積(3142 m2 g-1)與具較大之孔徑分布(2–3 nm),並添加5 wt.%的黏著劑,可製備出具最佳電容表現之碳電極,其比電容值於1 M H2SO4 中為143.65 F g-1。在穩定性測試中,經過200 次充放電後,其充放電效率可接近100%,顯示其良好之循環性。整體而言,本研究探討不同條件下以流體化床活化球狀碳之比較以及其產物應用於超級電容之可行性。 | zh_TW |
dc.description.abstract | In this study, activated carbon sphere (ACS) prepared with different activation conditions using a fluidized bed reactor was investigated, and the as–resulted ACSs were fabricated into carbon electrodes to examine the capacitive performance as a supercapacitor. The response surface methodology (RSM) was combined with the central composite design (CCD) to investigate the effects of different activation conditions on pore structure development. The results showed that the ACS activated at 900oC for 4 h possessed the highest specific surface area (3142 m2 g-1) and the greatest pore volume (1.513 cm3 g-1), and the pore size distribution was between micropore and mesopore ranges. Scanning electron microscopy (SEM) analysis revealed good sphericity of ACSs. The carbon electrodes were prepared from ACSs under different activation conditions with different percentage of binder, and their capacitive performance was evaluated through a two–electrode system cell. The results showed that the optimal carbon electrodes could be obtained using ACS with high specific surface area (3142 m2 g-1) and large pore size distribution (2–3 nm) and adding 5 wt.% binder. The specific capacitance was 143.65 F g-1 in 1 M H2SO4. In the cycling stability test, the charge/discharge efficiency could remain near 100% after 200 cycles, showing a good cyclability. Overall, this study explores the comparison of the ACS prepared under different activation conditions using a fluidized bed reactor and the feasibility of resulting ACS for supercapacitors. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T08:18:06Z (GMT). No. of bitstreams: 1 ntu-108-R06541122-1.pdf: 5085572 bytes, checksum: 8ec25b6c460205fb0d52f86d1d44b423 (MD5) Previous issue date: 2019 | en |
dc.description.tableofcontents | 中文摘要 i
ABSTRACT ii CONTENTS iv LIST OF FIGURES vii LIST OF TABLES xii Chapter 1 Introduction 1 1.1 Activated carbon sphere 1 1.2 Supercapacitors 2 1.3 Objectives 2 Chapter 2 Literature Review 4 2.1 Activated Carbon 4 2.1.1 Type of AC 4 2.1.2 Preparation of ACS 6 2.1.3 Characteristics of ACS 14 2.1.4 Application of ACS 16 2.2 Experimental design method 18 2.3 Supercapacitor 21 2.3.1 Definitions of supercapacitors 21 2.3.2 Energy storage mechanisms of supercapacitor 24 2.3.2.1 Pseudocapacitance 24 2.3.2.2 Electric double layer 25 2.3.3 The construction of EDLCs 26 2.3.4 Electrode materials of EDLCs 27 2.4 Electrochemical measurement 28 2.4.1 The measurement of two–electrode and three–electrode systems 28 2.4.2 The capacitance of EDLCs in electrochemical measurements 30 Chapter 3 Materials and Methods 34 3.1 Research Flowchart 34 3.2 Preparation of activated carbon spheres 36 3.2.1 Carbonization and physical activation of PF spheres 36 3.2.2 Experimental design of activation process 37 3.3 Preparation of supercapacitor electrode 39 3.4 Material characterization 40 3.4.1 Surface area, pore volume, and pore size distribution (PSD) 40 3.4.2 Scanning electron microscope (SEM) 41 3.4.3 Transmission electron microscope (TEM) 42 3.4.4 Elemental analysis (EA) 42 3.4.5 X-ray diffractometer (XRD) 43 3.5 Electrochemical measurements 43 3.5.1 Cyclic voltammetry (CV) 44 3.5.2 Galvanostatic charge/discharge (GCD) 45 Chapter 4 Results and Discussion 46 4.1 Physical and chemical properties of ACS 46 4.1.1 Effect of operating factors on the specific surface area 46 4.1.2 Effect of operating factors on pore structure 49 4.1.3 The interaction of factors 53 4.1.4 The optimal condition for preparation of ACS 55 4.1.5 SEM and TEM analysis 55 4.1.6 X-ray diffraction (XRD) analysis 61 4.1.7 Elemental Analysis (EA) 63 4.2 Capacitive performance of fabricated electrodes made from ACS 64 4.2.1 The influence of different samples on electrochemical behavior 64 4.2.2 The influence of different percentage of binder on electrochemical behavior 69 4.2.3 The cycling stability test 71 4.2.4 Literature comparison 73 Chapter 5 Conclusions and Recommendations 75 5.1 Conclusions 75 5.1.1 ACS preparation 75 5.1.2 The capacitive performance of fabricated electrodes made from ACS 76 5.2 Recommendations 77 5.2.1 ACS preparation and applications 77 5.2.2 Supercapacitors 77 REFERENCE ....................................................................................................................... 77 | |
dc.language.iso | en | |
dc.title | 利用流體化床製備活性碳球於超級電容之應用 | zh_TW |
dc.title | Synthesis of Activated Carbon Sphere Using Fluidized
Bed Reactor for Supercapacitor Application | en |
dc.type | Thesis | |
dc.date.schoolyear | 107-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 林坤儀,林進榮,侯嘉洪 | |
dc.subject.keyword | 球狀活性碳,流體化床,反應曲面法,中央合成設計,超級電容,電雙層電容器, | zh_TW |
dc.subject.keyword | activated carbon sphere,fluidized bed,response surface methodology,central composite design,supercapacitors,electric double layer capacitors, | en |
dc.relation.page | 83 | |
dc.identifier.doi | 10.6342/NTU201903402 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2019-08-14 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
顯示於系所單位: | 環境工程學研究所 |
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