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  1. NTU Theses and Dissertations Repository
  2. 電機資訊學院
  3. 光電工程學研究所
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/73575
完整後設資料紀錄
DC 欄位值語言
dc.contributor.advisor王倫
dc.contributor.authorChien-Lin Wuen
dc.contributor.author吳建霖zh_TW
dc.date.accessioned2021-06-17T08:06:16Z-
dc.date.available2021-08-21
dc.date.copyright2019-08-21
dc.date.issued2019
dc.date.submitted2019-08-19
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[3]. Sanders, Mollye, et al. 'An enhanced LSPR fiber-optic nanoprobe for ultrasensitive detection of protein biomarkers.' Biosensors and Bioelectronics 61 (2014): 95-101.
[4]. Satija, Jitendra, et al. 'Optimal design for U-bent fiber-optic LSPR sensor probes.' Plasmonics 9.2 (2014): 251-260.
[5]. Eidelloth, W., and R. L. Sandstrom. 'Wet etching of gold films compatible with high T c superconducting thin films.' Applied physics letters 59.13 (1991): 1632-1634.
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[7]. Barbillon, G., et al. 'Gold nanoparticles by soft UV nanoimprint lithography coupled to a lift-off process for plasmonic sensing of antibodies.' Microelectronic Engineering 87.5-8 (2010): 1001-1004.
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[9]. Jia, Peipei, and Jun Yang. 'Integration of large-area metallic nanohole arrays with multimode optical fibers for surface plasmon resonance sensing.' Applied Physics Letters 102.24 (2013): 243107.
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[16]. C.H.Chiang, “Fabrication of subwavelength dual structures on silicon substrates with anti-reflection and low sliding angles,” in Graduate Institute of Photonics and Optoelectronics (2010), National Taiwan University: Taipei.
[17]. Y. P. Chen, “Stitching submicron periodic patterns over a planar substrate and a roller by utilizing step-and-align interference lithography,” in Graduate Institute of Photonics and Optoelectronics (2011), National Taiwan University: Taipei.
[18]. Hatzakis, M., B. J. Canavello, and J. M. Shaw. 'Single-step optical lift-off process.' IBM Journal of Research and Development 24.4 (1980): 452-460.
[19]. Lee, Seung-Woo, et al. 'Highly sensitive biosensing using arrays of plasmonic Au nanodisks realized by nanoimprint lithography.' ACS nano 5.2 (2011): 897-904.
[20]. Chang, Yun-Chorng, et al. 'A large-scale sub-100 nm Au nanodisk array fabricated using nanospherical-lens lithography: a low-cost localized surface plasmon resonance sensor.' Nanotechnology 24.9 (2013): 095302.
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[22]. Kim, Keun Soo, et al. 'Large-scale pattern growth of graphene films for stretchable transparent electrodes.' nature 457.7230 (2009): 706.
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[27]. D. R. Lide, CRC handbook of chemistry and physics, CRC Press (2005).
[28]. J. P. Berenger, “A perfectly matched layer for the absorption of electromagnetic waves,” Journal of Computational Physics 144(2) (1994): 185-200.
[29]. Rodríguez-Cantó, Pedro Javier, et al. 'Demonstration of near infrared gas sensing using gold nanodisks on functionalized silicon.' Optics express 19.8 (2011): 7664-7672.
[30]. Lirtsman, V., M. Golosovsky, and D. Davidov. 'Infrared surface plasmon resonance technique for biological studies.' Journal of Applied Physics 103.1 (2008): 014702.
[31]. Neubrech, Frank, et al. 'Resonant plasmonic and vibrational coupling in a tailored nanoantenna for infrared detection.' Physical review letters 101.15 (2008): 157403.
[32]. W. H. Jheng, “Method of mass production of surface plasmon resonance fiber probes for lable-free biosensing and preliminary test of efficiency,” in Graduate Institute of Photonics and Optoelectronics (2016), National Taiwan University: Taipei.
[33]. C. F. Lo, “Fabrication improvement of surface plasmon resonance type optical fiber probes and their optical characteristics,” in Graduate Institute of Photonics and Optoelectronics (2017), National Taiwan University: Taipei.
[34]. C. L. Wu, ' Novel fabrication of surface plasmon resonance fiber probes using water-assisted peel-off and scoop-up method.' 2018 50th International conference on solid state devices and materials (SSDM)
[35]. Brown, Lisa V., et al. 'Fan-shaped gold nanoantennas above reflective substrates for surface-enhanced infrared absorption (SEIRA).' Nano letters 15.2 (2015): 1272-1280.
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[38]. Raichlin, Yosef, and Abraham Katzir. 'Fiber-optic evanescent wave spectroscopy in the middle infrared.' Applied spectroscopy62.2 (2008): 55A-72A.
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dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/73575-
dc.description.abstract近來,製作奈米金屬粒子結構並應用於侷限型表面電漿共振感測十分受到矚目,到目前為止已經發展了許多應用。我們實驗室先前已有利用奈米轉印的方法製作表面電漿共振元件的經驗,但應用皆只有在可見光波段,往中紅外等長波長的應用顯得較為新穎。
在此論文中,我們致力於週期性奈米金屬粒子的製作。透過創新的製程將奈米金粒子製作在矽基板上以及D型矽核光纖上。此外我們也使用了FDTD Solutions此商業用軟體來研究侷限型表面電漿共振元件的光學特性,模擬結果預測了穿透頻譜,同時侷限型表面電漿共振的位置與特性也被探討與證實。在折射率量測上,我們感測不同濃度的葡萄糖水溶液,且我們的元件也隨改變濃度有波長飄移的現象。在中紅外的指紋訊號也發現有被侷限型表面電漿共振所增強的現象。
zh_TW
dc.description.abstractRecently the fabrication of metallic nano-structures and subsequent applications to sensing based on localized surface plasmon resonance (LSPR) has drawn a lot of attentions. By nanotransfer printing (nTP) method, fabrication of quality SPR sensors was realized in our lab. However, the applications were limited in the visible range, so extension to mid-infrared is attractive.
In this thesis, we study how to fabricate metallic nanodisks. Through a novel fabrication process, the periodic metallic nanodisks were made onto silicon chip and D shaped silicon core fiber. To simulate the optical characteristics of the LSPR sensors, a commercial software, FDTD Solutions was used in this study. The simulated results revealed the trends of the measured transmission spectra and the characteristics of LSPR were also confirmed and discussed. In refractive index sensing, various concentrations of glucose solution were under test, and the resonant wavelengths of the spectra shifted as the concentration changed. The fingerprint signal in mid infrared range was enhanced by LSPR.
en
dc.description.provenanceMade available in DSpace on 2021-06-17T08:06:16Z (GMT). No. of bitstreams: 1
ntu-108-R04941109-1.pdf: 5270202 bytes, checksum: b929be095122d6e3728c45073b8a1c30 (MD5)
Previous issue date: 2019
en
dc.description.tableofcontents中文摘要………………………………………………………………..ii
ABSTRACT …………………………………………………………….iii
Statement of Contributions iv
LIST OF FIGURES viii
LIST OF TABLES xii
LIST OF SYMBOLS AND ABBREVIATIONS xiii
Chapter 1 Introduction 1
1.1 Motivation 1
1.2 Organization of thesis 5
Chapter 2 Fabrication of Localized Surface Plasmon Resonance Sensors 7
2.1 Two-beam interference lithography 7
2.2 Fabrication of LSPR chip with 2D metallic nanodisks arrays 9
2.2.1 Undercut structure created by lift-off resist 9
2.2.2 Undercut structure created by O2 plasma etching 10
Chapter 3 Novel Fabrication of Localized Surface Plasmon Resonance Using Water-Assisted Peel-off and Scoop-up Method 16
3.1 Water-assisted peel-off and scoop-up method 16
3.1.1 Fabrication of metal mesh film 18
3.1.2 The reliability of peel-off solution 19
3.1.3 The reliability of etching mask material: chromium versus gold 20
3.2 Optimization of process parameter 21
3.2.1 Gold mesh film thickness 21
3.2.2 Soaking time in acetone 23
3.3 Fabrication of gold nanodisks 28
3.3.1 Fabrication of gold nanodisks on silicon wafer 28
3.3.2 Fabrication of gold nanodisks on D shaped fiber 31
Chapter 4 Characteristics of Localized Surface Plasmon Resonance Sensors in MIR Range……………….…………………..33
4.1 Localized surface plasmon resonance 33
4.1.1 The finite-difference time-domain simulation model 33
4.1.2 Comparison of simulation and experiment results 36
4.1.3 Tunable LSPR signal 39
4.1.4 Comparison of electrical field between near-infrared and mid-infrared LSPR sensors …………………………………………………………….40
4.2 Optical characteristics of the LSPR silicon chips fabricated by two methods…………………………………………………………………....43
4.3 Optical characteristics of the D shaped LSPR fiber sensor 46
4.4 Surface enhanced infrared absorption (SEIRA) 50
Chapter 5 Conclusion and Future Work 52
5.1 Conclusions 52
5.2 Future work 55
5.2.1 Improvement the efficiency of enhancement 55
5.2.2 Advantages of the mid-infrared devices for sensing applications 57
References……………...……………………………………………….58
Publication……………………………………………………………...59
dc.language.isoen
dc.subject干涉微影zh_TW
dc.subject侷限型表面電漿zh_TW
dc.subject中紅外波段zh_TW
dc.subject掀離製程zh_TW
dc.subjectmid infrared rangeen
dc.subjectlift-off processen
dc.subjectinterference lithographyen
dc.subjectlocalized surface plasmon resonanceen
dc.title應用於中紅外波段感測的侷限型表面電漿共振型元件之製作與特性zh_TW
dc.titleFabrication and Characterization of Localized Surface Plasmon Resonance Sensors for Mid-Infrared Range Applicationsen
dc.typeThesis
dc.date.schoolyear107-2
dc.description.degree碩士
dc.contributor.oralexamcommittee蔡五湖,黃念祖,徐世祥
dc.subject.keyword干涉微影,掀離製程,中紅外波段,侷限型表面電漿,zh_TW
dc.subject.keywordinterference lithography,lift-off process,mid infrared range,localized surface plasmon resonance,en
dc.relation.page64
dc.identifier.doi10.6342/NTU201903943
dc.rights.note有償授權
dc.date.accepted2019-08-20
dc.contributor.author-college電機資訊學院zh_TW
dc.contributor.author-dept光電工程學研究所zh_TW
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