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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 李克強 | |
| dc.contributor.author | Tuan Jen Hung | en |
| dc.contributor.author | 段人洪 | zh_TW |
| dc.date.accessioned | 2021-06-17T07:22:32Z | - |
| dc.date.available | 2019-07-11 | |
| dc.date.copyright | 2019-07-11 | |
| dc.date.issued | 2019 | |
| dc.date.submitted | 2019-07-03 | |
| dc.identifier.citation | 1. Masliyah, J.H. and S. Bhattacharjee, Electrokinetic and Colloid Transport Phenomena. Electrokinetic and Colloid Transport Phenomena. 2005: John Wiley & Sons, Inc.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/73208 | - |
| dc.description.abstract | 本研究以具電荷調節多孔球模型為基礎，探討其振盪電泳行為，以提供更趨真實的模擬系統。多孔球模型為模擬聚電解質的重要模型，而聚電解質有很廣泛的應用價值，如許多生物粒子DNA、RNA和蛋白質等，因此在生物醫學領域常見其重要應用，如DNA疫苗、基因轉殖(gene delivery)、藥物釋放…等。因此多孔球粒子的研究為相當重要的課題！
振盪電泳為測量粒子性質的重要工具，因為相較於一般直流電泳，除了待測物不需要稀釋之優勢外，還多了頻率之調控參數，更可避免焦耳熱效應的產生，降低實驗誤差。 具電荷調節多孔球模型相較於粒子帶電量固定的假設更為真實，因為大多數聚電解質都具有可解離之官能基。本研究會討論電荷調節現象對於振盪電泳動度的影響，主要探討的參數為：電解質離子強度、官能基電荷密度、官能基解離常數、多孔球摩擦係數、外加交流電場頻率、pH值等，以提供實驗學者參考。 | zh_TW |
| dc.description.abstract | We use the charge-regulated porous particle model as the basis to investigate the electrokinetic behavior in dynamic electrophoresis of colloid particle. Many bioparticles such as potein, DNA and RNA are belonged to polyelectrolyte which has great application in biomedical field and is well modeled as charged porous spheres. So it is important to know the behavior of these particles.
Dynamic electrophoresis is an important tool for measuring particle properties. Compared with electrophoresis, dynamic electrophoresis can be operated with concentrated sample. Moreover, dynamic electrophoresis is driven by alternating current (AC), which has advantage of convenience of measure and prevention of Joule heating effect. The charge-regulated porous particle model compared with the constant fixed charged porous particle model is more closed to the reality. Since the most polyelectrolytes have dissociable dunctional group on surface, the charge on them are inconstant. In our study, we will discuss the influence of charge-regulation phenomena to the dynamic mobility. Double-layer thickness, functional charge density, friction coefficient, dissociation constant, pH of solution and the electric-field frequency. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T07:22:32Z (GMT). No. of bitstreams: 1 ntu-108-R05524073-1.pdf: 2891510 bytes, checksum: f041897d96d27393731c225cb18ebb2a (MD5) Previous issue date: 2019 | en |
| dc.description.tableofcontents | 摘要 I
Abstract III 目錄 IV 圖目錄 VII 第 1 章 緒論 1 1-1 膠體懸浮液 1 1-2 聚電解質及多孔粒子模型 11 1-3 電動力學現象與文獻回顧 16 1.3.1 電雙層理論 16 1.3.2 電雙層極化效應 17 1.3.3 電泳文獻回顧 18 1.3.4 多孔球電泳文獻回顧 23 1-4 振盪電泳概述 25 1.4.1 振盪電泳理論 25 1.4.2 振盪電泳文獻回顧 28 1-5 電荷調節現象： 31 1-6 研究目的與論文架構 34 第 2 章 理論分析 36 2-1 電動力學方程組 37 2.1.1 電位方程式 37 2.1.2 離子守恆式 39 2.1.3 流場方程式 40 2-2 平衡態與擾動態 45 2.2.1 平衡態 46 2.2.2 擾動態 48 2-3 系統變數無因次化及系統一維化 51 2.3.1 系統參數無因次化 51 2.3.2 擾動狀態變數之線性化 54 2.3.3 系統變數之一維化 57 2-4 粒子受力計算 61 2-5 電泳動度計算 62 2.5.1 靜態電泳動度計算 62 2.5.2 多孔球震盪電泳動度計算 64 第 3 章 數值方法 68 3-1 正交配位法 68 3-2 空間映射 73 3-3 多區聯解問題 75 3-4 牛頓(Newton-Raphson)迭代法 79 3-5 擾動態多變數聯立解 82 第 4 章 多孔球振盪電泳 85 4-1 系統介紹 85 4-2 邊界條件 90 4.2.1 平衡態邊界條件 90 4.2.2 擾動態邊界條件 92 4.2.3 無因次一維化之主控方程式及邊界條件 95 4-3 驗證程式之正確性 102 4.3.1 比對徐瑄珮之單一多孔球 103 4-4 頻率之影響頻率之影響 104 4-5 多孔球摩擦係數之影響 108 4-6 電解質離子強度之影響 112 4-7 官能基密度的影響 121 4-8 官能基解離常數的影響 123 4-9 pH值的影響 127 4-10 結論 131 參考文獻 133 符號說明 144 附錄 148 A-1力積分之推導 148 A-2 球心邊界條件設定 156 A-3 無窮大系統計算方法 159 | |
| dc.language.iso | zh-TW | |
| dc.subject | 電荷調節 | zh_TW |
| dc.subject | 電動力學 | zh_TW |
| dc.subject | 交流電場 | zh_TW |
| dc.subject | 振盪電泳 | zh_TW |
| dc.subject | 電雙層極化效應 | zh_TW |
| dc.subject | 多孔球 | zh_TW |
| dc.subject | porous sphere | en |
| dc.subject | dynamic electrophoresis | en |
| dc.subject | AC electric field | en |
| dc.subject | electrokinetics | en |
| dc.subject | charge-regulation phenomena | en |
| dc.subject | double layer polarization | en |
| dc.title | 具電荷調節多孔球粒子之振盪電泳行為 | zh_TW |
| dc.title | Dynamic Electrophoresis of a Charge-Regulated Porous Sphere | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 107-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 趙玲,游佳欣 | |
| dc.subject.keyword | 振盪電泳,交流電場,電動力學,多孔球,電荷調節,電雙層極化效應, | zh_TW |
| dc.subject.keyword | dynamic electrophoresis,AC electric field,electrokinetics,porous sphere,charge-regulation phenomena,double layer polarization, | en |
| dc.relation.page | 163 | |
| dc.identifier.doi | 10.6342/NTU201801698 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2019-07-03 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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