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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 韋文誠(Wen-Cheng Wei) | |
dc.contributor.author | Ting-En Li | en |
dc.contributor.author | 李廷恩 | zh_TW |
dc.date.accessioned | 2021-06-17T07:10:04Z | - |
dc.date.available | 2029-07-22 | |
dc.date.copyright | 2019-08-05 | |
dc.date.issued | 2019 | |
dc.date.submitted | 2019-07-22 | |
dc.identifier.citation | [1]http://www.greenpeace.org/taiwan/zh/news/stories/climate_energy/nonuke/2018/JP-new-energy-plan/
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/72911 | - |
dc.description.abstract | 本研究選用三種廢棄玻璃及兩種玻璃配方(G11A5及G17A5),均為四元BaO-SiO2-B2O3-Al2O3成分),加入市售鑄造(或稱澆注)耐火材,或是自行組合之澆注絕熱材料,應用於中溫型燃料電池之熱絕緣。研究中使用SEM+EDS、XRD來分析玻璃成份及晶相,以潤濕角測試及流體化床裝置來進行玻璃融化起始點的研究。在耐火材料製備的實驗規劃以K方(光和耐火材料)及T方(台大材料)為參賽者(player),使用賽局理論,實施一來一往的策略(strategy)及樣品測試,尋求具有最佳性質之耐火澆注料配方。在性質測試中針對其四種性質: 800-1000 oC燒結後收縮率、燒結後三點抗折強度、熱傳導率、耐磨耗率予以改善。性質改善以兩個競爭主體交替提出鑄造熱絕緣之成分修正,進而在此項中溫型耐火材之四種性質上得到回饋(reword)。最後結果顯示,T2-2及T2-3樣品的強度及耐磨耗性質獲得大幅提升,熱處理到1000 o後線性收縮率達2.0 %以內,而800 oC下T2-2含SiC具較高之熱傳導率值0.43±0.05 W/mK,含GW的T2-3樣品為0.28±0.02 W/mK,詳細的性質改善原因在報告中仔細討論。 | zh_TW |
dc.description.abstract | Three waste glasses and two in-house synthesized glasses, G11 glass and G17 glass (quaternary BaO–SiO2–B2O3–Al2O3 composition) are chosen. Those glasses combine with commercial castable refractory powder to meet the need of the thermos-insulation of intermediate-temperature SOFC. The castables perform appropriate four castable properties, shrinkage of 800-1000oC sintering, three-point bending strength of sintered test bars, thermal conductivity, and abrasion resistance. The game is set by two competitive players, and performs one-on-one strategy based on the game theory. The property performance of T2 samples finally gets improved. Three-point bending strength and erosion resistance of T2-2 and T2-3 samples were greatly improved. The linear change was less than 2.0% after heat treatment to 1000 oC, and thermal conductivity value of T2-2 containing SiC shows a higher value of 0.43±0.05 W/mK at 800 °C, and the value of GW-containing T2-3 sample is 0.28±0.02 W/mK. The reasons of the property improvements are discussed in this work. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T07:10:04Z (GMT). No. of bitstreams: 1 ntu-108-R06527048-1.pdf: 3284040 bytes, checksum: d306743456f85210e44043f9ba06f5b9 (MD5) Previous issue date: 2019 | en |
dc.description.tableofcontents | 目錄
摘要 I Abstract II 目錄 III 圖目錄 VI 表目錄 IX 第一章 緒論 1 1.1 研究目標 2 第二章 文獻回顧 3 2.1 玻璃與資源化 3 2.1.1 玻璃熔化和結晶 3 2.1.2 玻璃成分 4 2.1.3 玻璃四元系統(Al2O3-B2O3-SiO2-BaO) 6 2.2 耐火材料 22 2.2.1 不定形耐火材料 22 2.2.2 澆注耐火材料演進 23 2.3 賽局理論 30 2.3.1 賽局理論之起源及演進 30 2.3.2 賽局主導權 31 2.3.3 擴展型賽局與完整訊息 31 第三章 實驗步驟 32 3.1 玻璃合成 32 3.1.1 實驗材料 32 3.1.2 實驗室玻璃合成和成分分析 32 3.1.3 玻璃料大量製作 33 3.2 玻璃性質分析 38 3.2.1 潤濕試驗 38 3.2.2 流體化床裝置 38 3.2.3 DSC測試 38 3.2.4 微結構分析(SEM) 38 3.2.5 XRD晶相分析 39 3.3 賽局之規劃 41 3.4 耐火材性質試驗 42 3.4.1 耐火材收縮率測試 42 3.4.2 耐火材抗折強度測試 43 3.4.3 耐火材熱傳導率測試 43 3.4.4 耐火材耐磨耗率測試[105] 44 3.4.5 沉降試驗 44 第四章 結果與討論 52 4.1 玻璃性質測試結果 52 4.1.1 玻璃基本性質 52 4.1.2 玻璃潤濕測試 53 4.2 賽局起點(K0策略及結果) 69 4.2.1 4.2.1 K0收縮率測試 69 4.2.2 K0抗折強度測試 69 4.2.3 K0熱傳導率測試 70 4.2.4 K0耐磨耗測試 70 4.2.5 K0性質統整 71 4.3 賽局T1實施成果 77 4.3.1 T1收縮率測試 77 4.3.2 T1抗折強度測試 77 4.3.3 T1熱傳導率測試 78 4.3.4 T1耐磨耗測試 79 4.3.5 T1性質統整 79 4.4 賽局K1實施成果 85 4.4.1 K1收縮率測試 85 4.4.2 K1抗折強度測試 86 4.4.3 K1熱傳導率測試 86 4.4.4 K1耐磨耗測試 86 4.4.5 K1性質統整 87 4.5 賽局T2實施成果 95 4.5.1 T2收縮率測試 95 4.5.2 T2抗折強度測試 96 4.5.3 T2熱傳導率測試 97 4.5.4 T2耐磨耗測試 97 4.5.5 T2性質統整 97 第五章 結論 106 References 108 | |
dc.language.iso | zh-TW | |
dc.title | 應用賽局理論於含有廢棄玻璃之中溫型鑄造耐火材料發展 | zh_TW |
dc.title | Waste Glass Application on Intermediate-Temperature Castable Refractory by Game Theory | en |
dc.type | Thesis | |
dc.date.schoolyear | 107-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 薛承輝(Cheng-Hui Hsueh),潘建男,李東陽,王澤 | |
dc.subject.keyword | 賽局理論,廢棄玻璃,澆注料,不定型耐火材,中溫固態燃料電池, | zh_TW |
dc.subject.keyword | Game theory,Waste glass,Castable,Refractory,IT-SOFC, | en |
dc.relation.page | 115 | |
dc.identifier.doi | 10.6342/NTU201901694 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2019-07-22 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
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