請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/72744
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 徐善慧(Shan-hui Hsu) | |
dc.contributor.author | Shu-Ming Liu | en |
dc.contributor.author | 劉書銘 | zh_TW |
dc.date.accessioned | 2021-06-17T07:05:03Z | - |
dc.date.available | 2019-07-31 | |
dc.date.copyright | 2019-07-31 | |
dc.date.issued | 2019 | |
dc.date.submitted | 2019-07-26 | |
dc.identifier.citation | [1] S. K. Deb, A novel electrophotographic system., Applied Optics 8 (S1) (1969) 192-195.
[2] C. G. Granqvist, Electrochromic tungsten oxide films: Review of progress 1993–1998. Sol. Energy Mater. Sol. Cells 60 (2000) 201-262. [3] S. M. Cho, T.-Y. Kim, C. S. Ah, J. Song, S. H. Cheon, H. Ryu, J. Y. Kim, Y.-H. Kim, C.-S. Hwang, Electrochromic device with self-diffusing function for light adaptable displays. Sol. Energy Mater. Sol. Cells 177 (2018) 89-96. [4] Z. Jiao, J. L. Song, X. W. Sun, X. W. Liu, J. M. Wang, L. Ke, H. V. Demir, A fast-switching light-writable and electric-erasable negative photoelectrochromic cell based on Prussian blue films. Sol. Energy Mater. Sol. Cells 98 (2012) 154-160. [5] R. Kharade, S. S. Mali, S. P. Patil, K. R. Patil, M. G. Gang, P. Patil, J. Kim, P. Bhosale, Enhanced electrochromic coloration in Ag nanoparticle decorated WO3 thin films. Electrochim. Acta 102 (2013) 358-368. [6] Y. Watanabe, T. Nagashima, K. Nakamura, N. Kobayashi, Continuous-tone images obtained using three primary-color electrochromic cells containing gel electrolyte. Sol. Energy Mater. Sol. Cells 104 (2012) 140-145. [7] T. Niwa, O. Takai, Electrochemical, Optical and Electronic Properties of Iridium Tin Oxide Thin Film as Counter Electrode of Electrochromic Device. Jpn. J. Appl. Phys. 49 (2010) 105802. [8] P. M. Beaujuge, J. R. Reynolds, Color Control in π-Conjugated Organic Polymers for Use in Electrochromic Devices. Chem. Rev. 110 (2010) 268-320. [9] R. Sydam, A. Ghosh, M. Deepa, Enhanced electrochromic write–erase efficiency of a device with a novel viologen: 1,1′-bis(2-(1H-indol-3-yl)ethyl)-4,4′-bipyridinium diperchlorate. Org. Electron. 17 (2015) 33-43. [10] C. Arbizzani, M. Mastragostino, L. Meneghello, M. Morselli, A. J. J. o. A. E. Zanelli, Poly(3-methylthiophenes) for an all polymer electrochromic device. J. Appl. Electrochem. 26 (1996) 121-123. [11] G. F. Cai, J. P. Tu, D. Zhou, J. H. Zhang, X. L. Wang, C. D. Gu, Dual electrochromic film based on WO3/polyaniline core/shell nanowire array. Sol. Energy Mater. Sol. Cells 122 (2014) 51-58. [12] R. Cinnsealach, G. Boschloo, S. Nagaraja Rao, D. Fitzmaurice, Coloured electrochromic windows based on nanostructured TiO2 films modified by adsorbed redox chromophores. Sol. Energy Mater. Sol. Cells 57 (1999) 107-125. [13] A. Corradini, A. M. Marinangeli, M. Mastragostino, Ito as counter-electrode in a polymer based electrochromic device. Electrochim. Acta 35 (1990) 1757-1760. [14] D. Eric Shen, A. M. Österholm, J. R. Reynolds, Out of sight but not out of mind: the role of counter electrodes in polymer-based solid-state electrochromic devices. J. Mater. Chem. C 3 (2015) 9715-9725. [15] S. Ahmad, M. Deepa, S. A. Agnihotry, Effect of salts on the fumed silica-based composite polymer electrolytes. Sol. Energy Mater. Sol. Cells 92 (2008) 184-189. [16] M. Morita, A. Tanaka, N. Yoshimoto, M. Ishikawa, Polymeric gel electrolytes using a network matrix with carbonyl groups for rechargeable lithium batteries. Solid State Ionics 152-153 (2002) 161-167. [17] P.-Y. Pennarun, P. Jannasch, Electrolytes based on LiClO4 and branched PEG–boronate ester polymers for electrochromics. Solid State Ionics 176 (2005) 1103-1112. [18] S. Ramesh, A. K. Arof, Ionic conductivity studies of plasticized poly(vinyl chloride) polymer electrolytes. Mater. Sci. Eng. B 85 (2001) 11-15. [19] J. Saunier, N. Chaix, F. Alloin, J. P. Belières, J. Y. Sanchez, Electrochemical study of polymethacrylonitrile electrolytes: Conductivity study of polymer/salt complexes and plasticized polymer electrolytes. Part I. Electrochim. Acta 47 (2002) 1321-1326. [20] A. S. Shaplov, R. Marcilla, D. Mecerreyes, Recent Advances in Innovative Polymer Electrolytes based on Poly(ionic liquid)s. Electrochim. Acta 175 (2015) 18-34. [21] P. R. Somani, S. Radhakrishnan, Electrochromic materials and devices: present and future. Mater. Chem. Phys. 77 (2003) 117-133. [22] J. Y. Song, Y. Y. Wang, C. C. Wan, Review of gel-type polymer electrolytes for lithium-ion batteries. J. Power Sources 77 (1999) 183-197. [23] H. W. Heuer, R. Wehrmann, S. Kirchmeyer, Electrochromic Window Based on Conducting Poly(3,4-ethylenedioxythiophene)–Poly(styrene sulfonate). Adv. Funct. Mater. 12 (2002) 89-94. [24] S.-W. Huang, K.-C. Ho, An all-thiophene electrochromic device fabricated with poly(3-methylthiophene) and poly(3,4-ethylenedioxythiophene). Sol. Energy Mater. Sol. Cells 90 (2006) 491-505. [25] G. Leftheriotis, S. Papaefthimiou, P. Yianoulis, Development of multilayer transparent conductive coatings. Solid State Ionics 136-137 (2000) 655-661. [26] S. Liu, L. Xu, F. Li, B. Xu, Z. Sun, Enhanced electrochromic performance of composite films by combination of polyoxometalate with poly(3,4-ethylenedioxythiophene). J. Mater. Chem. 21 (2011) 1946-1952. [27] L. Ma, Y. Li, X. Yu, Q. Yang, C.-H. Noh, Fabricating red–blue-switching dual polymer electrochromic devices using room temperature ionic liquid. Sol. Energy Mater. Sol. Cells 93 (2009) 564-570. [28] A. Guerfi, L. H. Dao, Electrochromic Molybdenum Oxide Thin Films Prepared by Electrodeposition. J. Electrochem. Soc. 136 (1989) 2435-2436. [29] G. A. Niklasson, C. G. Granqvist, Electrochromics for smart windows: thin films of tungsten oxide and nickel oxide, and devices based on these. J. Mater. Chem. 17 (2007) 127-156. [30] A. L. Dyer, E. J. Thompson, J. R. Reynolds, Completing the Color Palette with Spray-Processable Polymer Electrochromics. ACS Appl. Mater. Interfaces 3 (2011) 1787-1795. [31] A. J. C. Silva, S. M. F. Ferreira, D. d. P. Santos, M. Navarro, J. Tonholo, A. S. Ribeiro, A multielectrochromic copolymer based on pyrrole and thiophene derivatives. Sol. Energy Mater. Sol. Cells 103 (2012) 108-113. [32] R. M. Walczak, J. R. Reynolds, Poly(3,4-alkylenedioxypyrroles): The PXDOPs as Versatile Yet Underutilized Electroactive and Conducting Polymers. Adv. Mater. 18 (2006) 1121-1131. [33] L. Groenendaal, F. Jonas, D. Freitag, H. Pielartzik, J. R. Reynolds, Poly(3,4-ethylenedioxythiophene) and Its Derivatives: Past, Present, and Future. Adv. Mater. 12 (2000) 481-494. [34] B. P. Jelle, G. Hagen, Transmission Spectra of an Electrochromic Window Based on Polyaniline, Prussian Blue and Tungsten Oxide. J. Electrochem. Soc. 140 (1993) 3560-3564. [35] R. Sydam, M. Deepa, A. G. Joshi, A novel 1,1′-bis[4-(5,6-dimethyl-1H-benzimidazole-1-yl)butyl]-4,4′-bipyridinium dibromide (viologen) for a high contrast electrochromic device. Org. Electron. 14 (2013) 1027-1036. [36] R. J. Mortimer, Organic electrochromic materials. Electrochim. Acta 44 (1999) 2971-2981. [37] F. S. Han, M. Higuchi, D. G. Kurth, Metallosupramolecular Polyelectrolytes Self-Assembled from Various Pyridine Ring-Substituted Bisterpyridines and Metal Ions: Photophysical, Electrochemical, and Electrochromic Properties. J. Am. Chem. Soc. 130 (2008) 2073-2081. [38] M. Higuchi, Stimuli-responsive metallo-supramolecular polymer films: design, synthesis and device fabrication. J. Mater. Chem. C 2 (2014) 9331-9341. [39] S. Hladysh, D. Václavková, D. Vrbata, D. Bondarev, D. Havlíček, J. Svoboda, J. Zedník, J. Vohlídal, Synthesis and characterization of metallo-supramolecular polymers from thiophene-based unimers bearing pybox ligands. RSC Adv. 7 (2017) 10718-10728. [40] A. Bandyopadhyay, S. Sahu, M. Higuchi, Tuning of Nonvolatile Bipolar Memristive Switching in Co(III) Polymer with an Extended Azo Aromatic Ligand. J. Am. Chem. Soc. 133 (2011) 1168-1171. [41] C.-F. Lin, C.-Y. Hsu, H.-C. Lo, C.-L. Lin, L.-C. Chen, K.-C. Ho, A complementary electrochromic system based on a Prussian blue thin film and a heptyl viologen solution. Sol. Energy Mater. Sol. Cells 95 (2011) 3074-3080. [42] L. M. N. Assis, L. Ponez, A. Januszko, K. Grudzinski, A. Pawlicka, A green-yellow reflective electrochromic device. Electrochim. Acta 111 (2013) 299-304. [43] Y. Alesanco, J. Palenzuela, R. Tena-Zaera, G. Cabañero, H. Grande, B. Herbig, A. Schmitt, M. Schott, U. Posset, A. Guerfi, M. Dontigny, K. Zaghib, A. Viñuales, Plastic electrochromic devices based on viologen-modified TiO2 films prepared at low temperature. Sol. Energy Mater. Sol. Cells 157 (2016) 624-635. [44] A. P. Baioni, M. Vidotti, P. A. Fiorito, E. A. Ponzio, S. I. Córdoba de Torresi, Synthesis and Characterization of Copper Hexacyanoferrate Nanoparticles for Building Up Long-Term Stability Electrochromic Electrodes. Langmuir 23 (2007) 6796-6800. [45] R. Yang, Z. Qian, J. Deng, Electrochemical Deposition of Prussian Blue from a Single Ferricyanide Solution. J. Electrochem. Soc. 145 (1998) 2231-2236. [46] D. Du, M. Wang, Y. Qin, Y. Lin, One-step electrochemical deposition of Prussian Blue–multiwalled carbon nanotube nanocomposite thin-film: preparation, characterization and evaluation for H2O2 sensing. J. Mater. Chem. 20 (2010) 1532-1537. [47] A. A. Karyakin, Prussian Blue and Its Analogues: Electrochemistry and Analytical Applications. Electroanalysis 13 (2001) 813-819. [48] M.-S. Fan, S.-Y. Kao, T.-H. Chang, R. Vittal, K.-C. Ho, A high contrast solid-state electrochromic device based on nano-structural Prussian blue and poly(butyl viologen) thin films. Sol. Energy Mater. Sol. Cells 145 (2016) 35-41. [49] H. Shiozaki, T. Kawamoto, H. Tanaka, S. Hara, M. Tokumoto, A. Gotoh, T. Satoh, M. Ishizaki, M. Kurihara, M. Sakamoto, Electrochromic Thin Film Fabricated Using a Water-Dispersible Ink of Prussian Blue Nanoparticles. Jpn. J. Appl. Phys. 47 (2008) 1242-1244. [50] M. Ishizaki, H. Ando, N. Yamada, K. Tsumoto, K. Ono, H. Sutoh, T. Nakamura, Y. Nakao, M. Kurihara, Redox-coupled alkali-metal ion transport mechanism in binder-free films of Prussian blue nanoparticles. J. Mater. Chem. A 7 (2019) 4777-4787. [51] J. Velevska, M. Pecovska-Gjorgjevich, N. Stojanov, M. Najdoski, Electrochromic Properties of Prussian Blue Thin Films Prepared by Chemical Deposition Method. IJSBAR 25 (2016) 380. [52] T.-H. Chang, C.-W. Hu, R. Vittal, K.-C. Ho, Incorporation of plastic crystal and transparent UV-cured polymeric electrolyte in a complementary electrochromic device. Sol. Energy Mater. Sol. Cells 126 (2014) 213-218. [53] R. Sydam, M. Deepa, S. M. Shivaprasad, A. K. Srivastava, A WO3–poly(butyl viologen) layer-by-layer film/ruthenium purple film based electrochromic device switching by 1 volt application. Sol. Energy Mater. Sol. Cells 132 (2015) 148-161. [54] N. Wang, Z. Lukáacs, B. Gadgil, P. Damlin, C. Janáky, C. Kvarnström, Electrochemical deposition of polyviologen-reduced graphene oxide nanocomposite thin films. Electrochim. Acta 231 (2017) 279-286. [55] D. Dervishogullari, E. Gizzie, G. Kane Jennings, D. Cliffel. Polyviologen as Electron Transport Material in Photosystem I-Based Biophotovoltaic Cells (Vol. 34) (2018) 15658-15664 [56] P. K. Bhowmik, A. H. Molla, H. Han, M. E. Gangoda, R. N. Bose, Lyotropic Liquid Crystalline Main-Chain Viologen Polymers: Homopolymer of 4,4‘-Bipyridyl with the Ditosylate of trans-1,4-Cyclohexanedimethanol and Its Copolymers with the Ditosylate of 1,8-Octanediol. Macromolecules 31 (1998) 621-630. [57] P. K. Bhowmik, H. Han, J. J. Cebe, R. A. Burchett, A. M. Sarker, Main-chain viologen polymers with organic counterions exhibiting thermotropic liquid-crystalline and fluorescent properties., Polym. Chem. 40 (2002) 659-674. [58] I. K. Spiliopoulos, J. A. Mikroyannidis, Poly(pyridinium salt)s with stilbene or distyrylbenzene chromophores. Polym. Chem. 39 (2001) 2454-2462. [59] P. K. Bhowmik, W. Xu, H. Han, Thermotropic liquid crystalline main‐chain viologen polymers: Homopolymer‐of 4,4′‐bipyridyl with ditosylate of trans‐1,4‐cyclohexanedimethanol and its copolymers with ditosylate of 1,8‐octanediol. J. Polym. Sci., Part A: Polym. Chem. 32 (1994) 3205-3209. [60] E. A. Appel, J. d. Barrio, J. Dyson, L. Isaacs, O. A. Scherman, Metastable single-chain polymer nanoparticles prepared by dynamic cross-linking with nor-seco-cucurbit[10]uril. Chemical Science 3 (2012) 2278-2281. [61] E. A. Appel, F. Biedermann, U. Rauwald, S. T. Jones, J. M. Zayed, O. A. Scherman, Supramolecular Cross-Linked Networks via Host−Guest Complexation with Cucurbit[8]uril. J. Am. Chem. Soc. 132 (2010) 14251-14260. [62] L. Voorhaar, R. Hoogenboom, Supramolecular polymer networks: hydrogels and bulk materials. Chem. Soc. Rev. 45 (2016) 4013-4031. [63] M. Soheilmoghaddam, M. U. Wahit, Development of regenerated cellulose/halloysite nanotube bionanocomposite films with ionic liquid. Int. J. Biol. Macromol. 58 (2013) 133-139. [64] S. Li, M. Gao, S. Wang, R. Hu, Z. Zhao, A. Qin, B. Z. Tang, Light up detection of heparin based on aggregation-induced emission and synergistic counter ion displacement. Chem. Commun. 53 (2017) 4795-4798. [65] I. Yamaguchi, N. Mizoguchi, M. Sato, Self-Doped Polyphenylenes Containing Electron-Accepting Viologen Side Group. Macromolecules 42 (2009) 4416-4425. [66] I. Yamaguchi, S. Makishi, Synthesis and chemical properties of electrochromic π-conjugated polyphenylenes with pendant viologen-TCNQ salts. J. Appl. Polym. Sci. 129 (2013) 397-403. [67] I. Yamaguchi, T. Asano, Uncatalyzed synthesis of polypyrrole with viologen side groups and its chemical properties. J. Mater. Sci. 46 (2011) 4582-4587. [68] N. Wang, A. Kähkönen, P. Damlin, T. Ääritalo, J. Kankare, C. Kvarnström, Electrochemical synthesis and characterization of branched viologen derivatives. Electrochim. Acta 154 (2015) 361-369. [69] N. Wang, A. Kähkönen, T. Ääritalo, P. Damlin, J. Kankare, C. Kvarnström, Polyviologen synthesis by self-assembly assisted grafting. RSC Adv. 5 (2015) 101232-101240. [70] T. Sakano, F. Ito, T. Ono, O. Hirata, M. Ozawa, T. Nagamura, Synthesis and electrochromic properties of a highly water-soluble hyperbranched polymer viologen. Thin Solid Films 519 (2010) 1458-1463. [71] H. Inokuchi, Organic semiconductors, conductors and superconductors. Int. Rev. Phys. Chem. 8 (1989) 95-124. [72] M. Mastragostino, Electrochromic devices in: B. Scrosati (Ed.), Applications of Electroactive Polymers., Chapman and Hall, London, (1993) ch. 7 pp. 233–249. [73] J. Roncali, Conjugated poly(thiophenes): synthesis, functionalization, and applications. Chem. Rev. 92 (1992) 711-738. [74] S. J. Higgins, Conjugated polymers incorporating pendant functional groups—synthesis and characterisation. Chem. Soc. Rev. 26 (1997) 247-257. [75] D. J. Walton, Electrically conducting polymers. Materials & Design 11 (1990) 142-152. [76] K. Hyodo, Electrochromism of conducting polymers. Electrochim. Acta 39 (1994) 265-272. [77] T. F. Guarr, Electrochromism: Fundamentals and Applications J. Am. Chem. Soc. 118 (1996) 1816-1816. [78] L. Groenendaal, F. Jonas, D. Freitag, H. Pielartzik, J. R. Reynolds, Poly(3,4-ethylenedioxythiophene) and Its Derivatives: Past, Present, and Future. Adv. Mater. 12 (2000) 481-494. [79] S. A. Sapp, G. A. Sotzing, J. R. Reynolds, High Contrast Ratio and Fast-Switching Dual Polymer Electrochromic Devices. Chem. Mater. 10 (1998) 2101-2108. [80] Y. C. Hsu, K.-C. Ho, The Anionic Effect on the Intercalation and Spectral Properties of Poly(Butyl Viologen) Films. J. New Mater. Electrochem. Syst. 8 (2005) 49-57. [81] T. Saika, T. Iyoda, T. Shimidzu, Electropolymerization of Bis(4-cyano-1-pyridinio) Derivatives for the Preparation of Polyviologen Films on Electrodes. Bull. Chem. Soc. Jpn. 66 (1993) 2054-2060. [82] D. A. Buttry, M. D. Ward, Measurement of interfacial processes at electrode surfaces with the electrochemical quartz crystal microbalance. Chem. Rev. 92 (1992) 1355-1379. [83] V. K. Thakur, G. Ding, J. Ma, P. S. Lee, X. Lu, Hybrid Materials and Polymer Electrolytes for Electrochromic Device Applications. Adv. Mater. 24 (2012) 4071-4096. [84] R. J. Jasinski, The Electrochemistry of Some n‐Heptylviologen Salt Solutions. J. Electrochem. Soc. 124 (1977) 637-641. [85] J. Bruinink, C. G. A. Kregting, J. J. Ponjeé, Modified Viologens with Improved Electrochemical Properties for Display Applications. J. Electrochem. Soc. 124 (1977) 1854-1858. [86] H.-C. Chang, M. Osawa, T. Matsue, I. Uchida, A novel polyviologen electrode fabricated by electrochemical crosslinking. J. Chem. Soc., Chem. Commun. (1991) 611-612. [87] R. N. Dominey, T. J. Lewis, M. S. Wrighton, Synthesis and characterization of a benzylviologen surface-derivatizing reagent. N,N'-Bis(p-(trimethoxysilyl)benzyl)-4,4'-bipyridinium dichloride. J. Phys. Chem. 87 (1983) 5345-5354. [88] K. Kamata, T. Suzuki, T. Kawai, T. Iyoda, Voltammetric anion recognition by a highly cross-linked polyviologen film. J. Electroanal. Chem. 473 (1999) 145-155. [89] G. Bidan, A. Deronzier, J.-C. Moutet, Electrochemical coating of an electrode by a poly(pyrrole) film containing the viologen (4,4′-bipyridinium) system. J. Chem. Soc., Chem. Commun. (1984) 1185-1186. [90] C. F. Shu, M. S. Wrighton, Synthesis and charge-transport properties of polymers derived from the oxidation of 1-hydro-1'-(6-(pyrrol-1-yl)hexyl)-4,4'-bipyridinium bis(hexafluorophosphate) and demonstration of a pH-sensitive microelectrochemical transistor derived from the redox properties of a conventional redox center. J. Phys. Chem. 92 (1988) 5221-5229. [91] H. Akahoshi, S. Toshima, K. Itaya, Electrochemical and spectroelectrochemical properties of polyviologen complex modified electrodes. J. Phys. Chem. 85 (1981) 818-822. [92] J. Stepp, J. B. Schlenoff, Electrochromism and Electrocatalysis in Viologen Polyelectrolyte Multilayers. J. Electrochem. Soc. 144 (1997) 155-158. [93] C.-Y. Hsu, C.-H. Liao, K.-C. Ho, The roles of anion and solvent transport during the redox switching process at a poly(butyl viologen) film studied by an EQCM. Sol. Energy Mater. Sol. Cells 92 (2008) 194-202. [94] M. D. Levi, C. Lopez, E. Vieil, M. A. Vorotyntsev, Influence of ionic size on the mechanism of electrochemical doping of polypyrrole films studied by cyclic voltammetry. Electrochim. Acta 42 (1997) 757-769. [95] H.-C. Lu, S.-Y. Kao, T.-H. Chang, C.-W. Kung, K.-C. Ho, An electrochromic device based on Prussian blue, self-immobilized vinyl benzyl viologen, and ferrocene. Sol. Energy Mater. Sol. Cells 147 (2016) 75-84. [96] Y. Alesanco, A. Viñuales, J. Ugalde, E. Azaceta, G. Cabañero, J. Rodriguez, R. Tena-Zaera, Consecutive anchoring of symmetric viologens: Electrochromic devices providing colorless to neutral-color switching. Sol. Energy Mater. Sol. Cells 177 (2018) 110-119. [97] E. A. Masimov, H. F. J. R. J. o. P. C. A. Abbasov, Hydration numbers of ions in aqueous solutions of KOH, KCl, KI, and KIO3 according to refractometric data. Russ. J. Phys. Chem. A 87 (2013) 1430-1432. [98] P. Sripa, A. Tongraar, T. Kerdcharoen, Characterization of the F−-water and Cl−-water hydrogen bonds in aqueous solution: From “interior” (I) to “surface” (S) states. J. Mol. Liq. 248 (2017) 271-277. [99] R. J. Mortimer, T. S. Varley, In situ spectroelectrochemistry and colour measurement of a complementary electrochromic device based on surface-confined Prussian blue and aqueous solution-phase methyl viologen. Sol. Energy Mater. Sol. Cells 99 (2012) 213-220. [100] J.-Y. Wang, M.-C. Wang, D.-J. Jan, Synthesis of poly(methyl methacrylate)-succinonitrile composite polymer electrolyte and its application for flexible electrochromic devices. Sol. Energy Mater. Sol. Cells 160 (2017) 476-483. [101] F. A. Aguiar, R. Campos, C. Wang, R. Jitchati, A. S. Batsanov, M. R. Bryce, R. Kataky, Comparative electrochemical and impedance studies of self-assembled rigid-rod molecular wires and alkanethiols on gold substrates. Phys. Chem. Chem. Phys. 12 (2010) 14804-14811. [102] M. A. D. Millone, H. Hamoudi, L. Rodríguez, A. Rubert, G. A. Benítez, M. E. Vela, R. C. Salvarezza, J. E. Gayone, E. A. Sánchez, O. Grizzi, C. Dablemont, V. A. Esaulov, Self-Assembly of Alkanedithiols on Au(111) from Solution: Effect of Chain Length and Self-Assembly Conditions. Langmuir 25 (2009) 12945-12953. [103] D. A. Rider, K. D. Harris, D. Wang, J. Bruce, M. D. Fleischauer, R. T. Tucker, M. J. Brett, J. M. Buriak, Thienylsilane-Modified Indium Tin Oxide as an Anodic Interface in Polymer/Fullerene Solar Cells. ACS Appl. Mater. Interfaces 1 (2009) 279-288. [104] D. Kim, A. W. H. Lee, J. I. Eastcott, B. D. Gates, Modifying the Surface Properties of Indium Tin Oxide with Alcohol-Based Monolayers for Use in Organic Electronics. ACS Appl. Nano Mater. 1 (2018) 2237-2248. [105] N. R. Armstrong, C. Carter, C. Donley, A. Simmonds, P. Lee, M. Brumbach, B. Kippelen, B. Domercq, S. Yoo, Interface modification of ITO thin films: organic photovoltaic cells. Thin Solid Films 445 (2003) 342-352. [106] A. Berlin, G. Zotti, G. Schiavon, S. Zecchin, Adsorption of Carboxyl-Terminated Dithiophene and Terthiophene Molecules on ITO Electrodes and Their Electrochemical Coupling to Polymer Layers. The Influence of Molecular Geometry. J. Am. Chem. Soc. 120 (1998) 13453-13460. [107] W. Zhang, G. Zhang, X. Chen, S. Wang, Y. Wang, S. Zhu, Q. Wang, Enhanced performance and stability of electrochromic device based on poly (3-methylthiophene) using 2-thiophenecarboxylic acid as interfacial modifier. Mater. Res. Bull. 107 (2018) 111-117. [108] X. Chen, E. Luais, N. Darwish, S. Ciampi, P. Thordarson, J. J. Gooding, Studies on the Effect of Solvents on Self-Assembled Monolayers Formed from Organophosphonic Acids on Indium Tin Oxide. Langmuir 28 (2012) 9487-9495. [109] P. J. Hotchkiss, S. C. Jones, S. A. Paniagua, A. Sharma, B. Kippelen, N. R. Armstrong, S. R. Marder, The Modification of Indium Tin Oxide with Phosphonic Acids: Mechanism of Binding, Tuning of Surface Properties, and Potential for Use in Organic Electronic Applications. Acc. Chem. Res. 45 (2012) 337-346. [110] K. Pfeiffer, S. Shestaeva, A. Bingel, P. Munzert, L. Ghazaryan, C. van Helvoirt, W. M. M. Kessels, U. T. Sanli, C. Grévent, G. Schütz, M. Putkonen, I. Buchanan, L. Jensen, D. Ristau, A. Tünnermann, A. Szeghalmi, Comparative study of ALD SiO2 thin films for optical applications. Opt. Mater. Express 6 (2016) 660-670. [111] T. J. Gardner, C. D. Frisbie, M. S. Wrighton, Systems for orthogonal self-assembly of electroactive monolayers on Au and ITO: an approach to molecular electronics. J. Am. Chem. Soc. 117 (1995) 6927-6933. [112] B. Vercelli, G. Zotti, G. Schiavon, S. Zecchin, A. Berlin, Adsorption of Hexylferrocene Phosphonic Acid on Indium−Tin Oxide Electrodes. Evidence of Strong Interchain Interactions in Ferrocene Self-Assembled Monolayers. Langmuir 19 (2003) 9351-9356. [113] S. F. J. Appleyard, M. R. Willis, Electroluminescence: enhanced injection using ITO electrodes coated with a self assembled monolayer. Opt. Mater. 9 (1998) 120-124. [114] S. Besbes, A. Ltaief, K. Reybier, L. Ponsonnet, N. Jaffrezic-Renault, J. Davenas, H. Ben Ouada, Injection modifications by ITO functionalization with a self-assembled monolayer in OLEDs. Synth. Met. 138 (2003) 197-200. [115] Z. Z. You, J. Y. Dong, Surface properties of treated ITO anodes for organic light-emitting devices. Appl. Surf. Sci. 249 (2005) 271-276. [116] R. A. Hatton, S. R. Day, M. A. Chesters, M. R. Willis, Organic electroluminescent devices: enhanced carrier injection using an organosilane self assembled monolayer (SAM) derivatized ITO electrode. Thin Solid Films 394 (2001) 291-296. [117] S. E. Koh, K. D. McDonald, D. H. Holt, C. S. Dulcey, J. A. Chaney, P. E. Pehrsson, Phenylphosphonic Acid Functionalization of Indium Tin Oxide: Surface Chemistry and Work Functions. Langmuir 22 (2006) 6249-6255. [118] W. Zhang, W. Ju, X. Wu, Y. Wang, Q. Wang, H. Zhou, S. Wang, C. Hu, Structure, stability and electrochromic properties of polyaniline film covalently bonded to indium tin oxide substrate. Appl. Surf. Sci. 367 (2016) 542-551. [119] M. Brumbach, P. A. Veneman, F. S. Marrikar, T. Schulmeyer, A. Simmonds, W. Xia, P. Lee, N. R. Armstrong, Surface Composition and Electrical and Electrochemical Properties of Freshly Deposited and Acid-Etched Indium Tin Oxide Electrodes. Langmuir 23 (2007) 11089-11099. [120] P. B. Paramonov, S. A. Paniagua, P. J. Hotchkiss, S. C. Jones, N. R. Armstrong, S. R. Marder, J.-L. Brédas, Theoretical Characterization of the Indium Tin Oxide Surface and of Its Binding Sites for Adsorption of Phosphonic Acid Monolayers. Chem. Mater. 20 (2008) 5131-5133. [121] J. Lee, B.-J. Jung, J.-I. Lee, H. Y. Chu, L.-M. Do, H.-K. Shim, Modification of an ITO anode with a hole-transporting SAM for improved OLED device characteristics. J. Mater. Chem. 12 (2002) 3494-3498. [122] S. Yang, J. Zheng, X. Wu, C. Xu, Modification of ITO Surface for High Performance of Electrochromic Polymer Film. Acta Chim. Sin. Chin. Ed. 71 (2013) 1041-1046 [123] H. Zhang, N. Qiu, W. Ni, B. Kan, M. Li, Q. Zhang, X. Wan, Y. Chen, Diketopyrrolopyrrole based small molecules with near infrared absorption for solution processed organic solar cells. Dyes Pigm. 126 (2016) 173-178. [124] G. K. Pande, N. Kim, J. H. Choi, G. Balamurugan, H. C. Moon, J. S. Park, Effects of counter ions on electrochromic behaviors of asymmetrically substituted viologens. Sol. Energy Mater. Sol. Cells 197 (2019) 25-31. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/72744 | - |
dc.description.abstract | 近年來,由於全球變暖問題,節能成為一個重要的課題。 電致變色是電活性材料的氧化還原反應的現象,具有可逆的顏色變化,並且可能引起材料的吸收光譜的顯著變化。
本研究以電變色材料聚丁基紫精(PBV)進行研究。聚丁基紫精(PBV)是具有三種氧化還原狀態的有機聚合物,即二陽離子(PBV2+),自由基陽離子(PBV•+)和二還原態(PBV0)。最穩定的形式是紫色的二陽離子PBV2+。而PBV•+和PBV0分別為無色和棕色。通過對其單體雙(4-氰基-1-吡啶基)丁烷二溴化物(BVBr2)的自由基陽離子狀態施加電位,可以將PBV電聚合到ITO玻璃上。為了改善PBV膜的電化學性質,需要在電解液中添加Fe(CN)64-。 良好的去色/著色的電化學可逆性對於電致變色材料的應用是非常重要的。在第3章中,對電聚合製備含亞鐵氰化物的聚(丁基紫精)(PBV:fc)薄膜,進行研究並且比較添加或不添加亞鐵氰化鉀(K4Fe(CN)6)在電解質中的的氧化還原性質變化。運用循環伏安法(CV)和UV-Vis光譜技術研究PBV:fc薄膜的電化學和電致變色性質。透過電化學石英晶體微天平(EQCM)技術研究了PBV:fc薄膜在氧化還原反應過程中的質量變化,此外,掃描電化學顯微鏡(SECM)可以用來證實Fe(CN)64-陰離子進入/跑出PBV:fc薄膜的穩定性。結果表示,電解質中額外加入K4Fe(CN)6,可以有效地改善PBV:fc薄膜的氧化還原可逆性。我們推測提高PBV:fc薄膜的去色/著色穩定性的原因可能是受到反應過程中Fe(CN)64-電荷平衡的影響。最後,使用PBV:fc薄膜和普魯士藍(PB)薄膜製成互補電致變色器件(ECD),研究亦發現含有K4Fe(CN)6的電解質的ECD比沒有K4Fe(CN)6的電解質有更好的透射率與穩定性。 在第4章中,推測在水溶液中的PBV:fc薄膜吸附性可能是導致收縮的另一個原因,並降低了長期穩定性。此章節的目標是提高PBV:fc薄膜和由PBV:fc薄膜組成的ECD的氧化還原穩定性和長期穩定性,將表面改質的方法運用在修飾ITO玻璃上。首先先將羥基修飾在ITO玻璃上再使用4-氰基苯酚(P-CN)和芐基膦酸(BPO3)修飾基通過縮合反應形成化學鍵結在ITO 玻璃上,製備成P-CN-ITO玻璃和BPO3-ITO玻璃。 PBV:fc薄膜電聚合在P-CN-ITO玻璃和BPO3-ITO玻璃上,分別形成P-CN-PBV:fc薄膜和BPO3-PBV:fc薄膜。此外,PBV:fc薄膜與修飾的ITO玻璃之間形成共價鍵提升吸附力,並且成功的提高電致變色的性質。 在有修飾的PBV:fc薄膜組成的ECD中也增強電性的長期穩定性,其長期維持的穿透度變化亦在修飾的ECD中有效的提升。 | zh_TW |
dc.description.abstract | Energy conservation becomes an important topic owing to the global warming issue. Electrochromism is the phenomena of redox reactions of electroactive materials in company with reversible color changes, and which might cause significant variations in the absorbance spectra of the materials.
Poly(butyl viologen) (PBV) is an organic polymer that has three redox states, namely, di-cation (PBV2+), radical-cation (PBV•+), and di-reduced state (PBV0). The most stable form is the di-cation, PBV2+, which is purple. PBV•+ and PBV0 are colorless and brown, respectively. PBV can be electropolymerized onto the ITO glass by applying a potential to the radical-cation state of its monomer, bis(4-cyano-1-pyridino)butane dibromide (BVBr2). In order to improve the electrochemical properties of the PBV film, addition of Fe(CN)64- in the deposition bath is necessary. High bleaching/coloring electrochemical reversibility is crucial for practical applications of an electrochromic material. In Chapter 3, ferrocyanide-containing poly(butyl viologen) (PBV:fc) thin films were prepared by electropolymerization, and subsequently investigated and compared their redox properties by using the electrolyte with and without the addition of potassium ferrocyanide (K4Fe(CN)6). Electrochemical and electrochromic properties of the PBV:fc thin films were studied by using cyclic voltammetry (CV) and UV-Vis spectroscopy techniques. The mass changes of the PBV:fc thin films during their redox reactions were studied by using electrochemical quartz crystal microbalance (EQCM) technique. In addition, the scanning electrochemical microscope (SECM) studies confirmed the stable anion insertion/extraction of Fe(CN)64- within a PBV:fc thin film. The obtained results indicate that the redox reversibility of the PBV:fc thin film can be effectively improved by the addition of K4Fe(CN)6 in the electrolyte. It is deduced that the enhancement of bleaching/coloring stability of the PBV:fc thin film is affected by Fe(CN)64- charge balance during the reactions. Complementary electrochromic devices (ECDs) using the PBV:fc and Prussian blue (PB) thin films were fabricated. Finally, the ECD with the electrolyte containing K4Fe(CN)6 shows the superior transmittance modulation stability than the one without K4Fe(CN)6. In Chapter 4, the adhesion is supposed that another reason leaded to shrink the PBV:fc thin film in the water solution and decreased the long-term stability. We aim at improving the redox stability and long-term stability of PBV:fc thin film and based ECDs. The surface modification method was introduced into the ITO glass preparation. In the beginning, the hydroxyl group bond on the ITO glass and the chemical bond formed between ITO glass and modifier, 4-cyanophenol (P-CN) and benzyl phosphonic acid (BPO3) by condensation reaction. The P-CN-ITO glass and the BPO3-ITO glass were made. PBV:fc thin film was electropolymerized on the P-CN-ITO glass and the BPO3-ITO glass, forming P-CN-PBV:fc thin film and the BPO3-PBV:fc thin film, respectively. In addition, the formation of covalent bond between PBV:fc thin film and modified ITO glass promoted the adhesion force, and the EC property was successfully enhanced. The ECDs also showed the enhancement on the long-term switching stability based on PBV:fc thin film electrode. The retention of its initial ΔT in modified ECDs are higher than without modified ECD. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T07:05:03Z (GMT). No. of bitstreams: 1 ntu-108-R06549003-1.pdf: 8927876 bytes, checksum: 7997a2c3176f25c3e472d4a7004d7ee4 (MD5) Previous issue date: 2019 | en |
dc.description.tableofcontents | 致謝 I
中文摘要 II Abstract IV Table of Contents VI List of Tables IX List of Figures X Nomenclatures XV Chapter 1 Introduction 1 1.1 Introduction of electrochromism 1 1.2 Introduction of electrochromic materials 4 1.2.1 Prussian blue (PB) 4 1.2.2 Viologens 6 1.2.3 Poly viologens 8 1.2.4 Conducting polymers 12 1.3 Electrochromic devices (ECDs) 15 1.4 Scope of this thesis 19 Chapter 2 Experimental Procedure 21 2.1 General experimental details 21 2.1.1 Materials 21 2.1.2 Apparatus 21 2.2 Experimental detail related to Chapter 3 23 2.2.1 Preparation of PBV:fc thin films 23 2.2.2 Electrochemical analyses using SECM and EQCM 23 2.2.3 Preparation of the ECD 24 2.3 Experimental detail related to Chapter 4 26 2.3.1 Preparation of OH modified ITO glass 26 2.3.2 Preparation of P-CN and BPO3 modified ITO glasses 26 2.3.3 Preparation of P-CN-PBV:fc thin film and BPO3-PBV:fc thin films 27 Chapter 3 Influence of Ferrocyanide on the Long-term Stability of Poly(butyl viologen) Thin Film Based Electrochromic Devices 29 3.1 Introduction 29 3.2 Results and discussion 31 3.2.1 Electrochemical behaviors of the PBV:fc thin films 31 3.2.2 Redox stability of the PBV:fc thin films 33 3.2.3 Mass changes of the PBV:fc thin films during redox reactions 41 3.2.4 Fe(CN)64- transfers at the PBV:fc thin film/electrolyte interface 47 3.2.5 Complementary ECDs using PBV:fc and Prussian blue thin films 51 3.2.6 Electrochemical stability of the ECDs 55 3.3 Conclusions 59 Chapter 4 Influence of the Covalent Bond to Indium Tin Oxide Substrate on the Long -term Stability of the Poly(butyl viologen) Thin Film based Electrochromic Devices 60 4.1. Introduction 60 4.2 Results and discussion 62 4.2.1 XPS spectra of Bare-ITO, OH-ITO, P-CN-ITO, and BPO3-ITO 62 4.2.2 Electrochemical behaviors of the PBV:fc thin films 66 4.2.3 UV-Vis absorption spectra of the PBV:fc thin films 68 4.2.4 Adhesive force of PBV:fc thin films on the ITO substrate 70 4.2.5 Long-term stability of PBV:fc thin films 74 4.2.6 Morphology of PBV:fc thin films 81 4.2.7 Complementary ECDs using PBV and Prussian blue thin films 82 4.3 Conclusions 92 Chapter 5 Conclusions and Suggestions 93 5.1 Conclusions 93 5.2 Suggestions 95 References 97 Appendix-Curriculum Vitae 111 | |
dc.language.iso | en | |
dc.title | 聚(丁基紫精)薄膜的電化學穩定性改善與電致變色元件應用 | zh_TW |
dc.title | Improving the electrochemical stability of poly(butyl viologen) thin films for electrochromic devices | en |
dc.type | Thesis | |
dc.date.schoolyear | 107-2 | |
dc.description.degree | 碩士 | |
dc.contributor.coadvisor | 何國川(Kuo-Chuan Ho) | |
dc.contributor.oralexamcommittee | 林正嵐(Cheng-lan Lin),朱治偉(Chih-Wei Chu) | |
dc.subject.keyword | 電致色變元件,微電極,掃描電化學顯微鏡,表面修飾,長期穩定性,聚紫精,電化學石英晶體微天平, | zh_TW |
dc.subject.keyword | Electrochromic device,Electrochemical quartz crystal,Poly(butyl viologen) microbalance,Redox stability,Scanning electrochemical microscopy,Indium tin oxide,Surface modification., | en |
dc.relation.page | 116 | |
dc.identifier.doi | 10.6342/NTU201902009 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2019-07-26 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-108-1.pdf 目前未授權公開取用 | 8.72 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。