請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/71803
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 鄧茂華(Mao-Hua Teng) | |
dc.contributor.author | Yu-Chieh Huang | en |
dc.contributor.author | 黃郁傑 | zh_TW |
dc.date.accessioned | 2021-06-17T06:10:22Z | - |
dc.date.available | 2021-11-29 | |
dc.date.copyright | 2018-11-29 | |
dc.date.issued | 2018 | |
dc.date.submitted | 2018-11-20 | |
dc.identifier.citation | [1] R. P Feynman, “There's plenty of room at the bottom”, Engineering and Science, 1960, 23(5), 22-36.
[2] M. Tomita, Y. Saito, and T. Hayashi, “LaC2 encapsulated in graphite nano-particle”, Jap. J. Appl. Phys., 1993, 32, L280-282. [3] R. S. Ruoff, D.C. Lorents, R. Malhotra and S. Subramoney, “Single crystal metals encapsulated in carbon nanoparticles”, Science, 1993, 259, 602-604. [4] P. Tartaj, M. del Puerto Morales, S. Veintemillas-Verdaguer, T. González-Carreño, and C.J. Serna, “The preparation of magnetic nanoparticles for applications in biomedicine”, J. Phys. D: Appl. Phys., 2003, 36(13), R182. [5] S.R. Chung, K.W. Wang, M.H. Teng, and T.P. Perng, “Electrochemical hydrogenation of nanocrystalline face-centered cubic Co powder”, Int. J. Hydrog. Energy., 2009, 34(3), 1383-1388. [6] X.G. Liu, B. Li, D.Y. Geng, W. B. Cui, F. Yang, Z.G. Xie, and Z.D. Zhang, “(Fe, Ni)/C nanocapsules for electromagnetic-wave-absorber in the whole Ku-band”, Carbon, 2009, 47(2), 470-474. [7] J.J. Host, M.H. Teng, B.R. Elliott, J. H. Hwang, T.O. Mason, D.L. Johnson, and V.P. Dravid, “Graphite encapsulated nanocrystals produced using a low carbon: metal ratio”, J. Mater. Res., 1996, 12(5), 1268-1273. [8] C.C. Chiu, J.C. Lo, and M.H. Teng, “A novel high efficiency method for the synthesis of graphite encapsulated metal (GEM) nanoparticles”, Diam. Relat. Mater., 2012, 24, 179-183. [9] 許舜婷(2016)“輸入微量液態碳源對合成石墨包裹奈米鎳晶粒及電弧型態轉變之研究”,碩士論文,國立臺灣大學地質科學系,共75頁。 [10] M.H. Teng, H.Y. Lin, C.C. Chiu, and Y.C. Huang, “Using liquid organic compounds to improve the encapsulation efficiency in the synthesis of graphite encapsulated metal nanoparticles by an arc-discharge method”, Diam. Relat. Mater., 2017, 80, 133-139. [11] M. Planck (1914). The theory of heat radiation (2nd edition). Philadelphia, U.S.A.: P. Blakiston’s Son & Co. [12] R. Loudon (2000). The quantum theory of light (3rd edition). Oxford, England: Oxford University Press. [13] C. Kittel (2004). Introduction to solid state physics (8th edition). U.S.A.: John Wiley & Sons. [14] C.M. Lai and S.L Lee, “Novel effects and applications of nanometer materials”, Chemistry (The Chinese Chem. Soc., Taipei), 2003, 61(4), 585-597. [15] A.S. Edelstein and R.C. Cammarata (1998). Nanomaterials: Synthesis, properties, and applications. Boca Raton, U.S.A.: CRC Press. [16] R. Kubo, “Electronic properties of metallic fine particles I”, J. Phys. Soc. Jpn., 1965, 17(6), 975-986. [17] K. Aoki, T. Kawaguchi, and K. Ohta, “The largest blueshifts of the [OIII] emission line in two narrow-line quasars”, Astrophy. J., 2005, 618(2), 601. [18] A. Kolhatkar, A. Jamison, D. Litvinov, R. Willson, and T. Lee, “Review: tuning the magnetic properties of nanoparticles”, Int. J. Mol. Sci., 2013, 14, 15977-16009. [19] Colonel Wm. T. McLyman (2004). Transformer and inductor design handbook (3rd edition), Boca Raton, U.S.A.: CRC Press. [20] J. Crangle and G.M. Goodman, “The magnetization of pure iron and nickel”, Proc. Roy. Soc. Lond. A., 1971, 321, 477-491. [21] L. Rafiq Shah, B. Ali, S.K. Hasanain, A. Mumtaz, C. Baker, and S. lsmat Shah, “Effective magnetic anisotropy and coercivity in Fe nanoparticles prepared by inert gas condensation”, Int. J. Mod. Phys. B,2006, 20(1), 37-47. [22] P. Guardia, B. Batlle-Brugal, A.G. Roca, O. lglesias, M.P. Morales, C.J. Serna, and X. Batlle, “Surfactant effects in magnetite nanoparticles of controlled size”, J. Magn. Magn. Mater., 2007, 316(2), 756-759. [23] D. Caruntu, G. Caruntu, and C.J. O'Connor, “Magnetic properties of variable-sized Fe3O4 nanoparticles synthesized from non-aqueous homogeneous solutions of polyols”, J. Phys. D: Appl. Phys., 2007, 40(19), 5801. [24] T. Lin, H. Shao, Z. Guo, J. Luo, and J. Hao, “Size- and shape-controlled synthesis of monodisperse Co nanoparticles from cobalt acetate by thermal decomposition”, Rare Metals., 2009, 28(3), 241-244. [25] Z. Zhang, X. Chen, X. Zhang, and C. Shi, “Synthesis and magnetic properties of nickel and cobalt nanoparticles obtained in DMF solution”, Solid State Commun., 2006, 139, 403-405. [26] X. He, W. Zhong, C.T. Au, and Y. Du, “Size dependence of the magnetic properties of Ni nanoparticles prepared by thermal decomposition method”, Nanoscale Res. Lett., 2013, 8, 446. [27] H. Gleiter, “Nanocrystalline materials”, Prog. Mater., 1989, 33, 223-315. [28] M. Nastasi, D.M. Parkin, and H. Gleiter (2012). Mechanical properties and deformation behavior of materials having ultra-fine microstructures (Vol. 233). Berlin, Germany: Springer Science & Business Media. [29] Z.H. Loh, A.K. Samamta, and P.W.S Heng, “Review: overview of milling techniques for improving the solubility of poorly water-soluble drugs”, Asian J. Pharm. Sci., 2015, 10(4), 255-274. [30] T.P. Yadav, R.M. Yadav, and D.P. Singh, “Mechanical milling: a top-down approach foe the synthesis of nanomaterials and nanocomposites”, Nanosci. Nanotechnol.,2012, 2(3), 22-48. [31] U. Schubert and N. Hüsing (2012). Synthesis of inorganic materials (3rd edition). Weinheim, Germany: Wiley-VCH. [32] G.W. Morey, “Hydrothermal synthesis”, J. Amer. Ceram. Soc., 1953, 36(9), 279-285. [33] C.G. Granqvist and R.A. Buhrman, “Ultrafine metal nanoparticles”, J. Appl. Phys., 1976, 47 (5), 2200-2216. [34] D.A. Porter and K.E. Easterling (2004). Phase transformations in metals and alloys (2nd edition). Boca Raton, U.S.A.: CRC press. [35] H.W. Kroto, J.R. Heath, S.C. O'Brien, R.F. Curl, and R.E. Smalley, “C60: Buckminsterfullerene”, Nature, 1985, 318,162-163. [36] A. Goel, J.B. Howard, and J.B. Vander Sande, “Size analysis of single fullerene molecules by electron microscopy”, Carbon, 2004, 42, 1907-1915. [37] W. Krätschmer, L.D. Lamb, K. Fostiropoulos, and D.R. Huffman, “Solid C60: a new form of carbon”, Nature, 1990, 347, 354-358. [38] V.P. Dravid, J.J. Host, M.H. Teng, B.E.J. Hung, D.L. Johnson, T.O. Mason, and J.R. Weertman, “Controlled-size nanocapsules”, Nature, 1995, 602. [39] M.H. Teng, J.J. Host, J.H. Hwang, B.R. Elliott, J.R. Weertman, T.O. Mason, and D.L. Johnson, “Nanophase Ni particles produced by a blown arc method”, J. Mater. Res., 1995, 10(2), 233-236. [40] S.J. Lee, J. Jung, M.K. Kim, Y.R. Kim, and J.K. Park, “Synthesis of highly stable graphite-encapsulated metal (Fe, Co, and Ni) nanoparticles”, J. Mater. Sci., 2012, 47(23), 8112-8117. [41] B.R. Elliott, J.J. Host, V.P. Dravid, M.H. Teng, and J.H. Hwang, “A descriptive model linking possible formation mechanisms for graphite encapsulated nanocrystals to processing parameters”, J. Mater. Res., 1997, 12(12), 3328-3344. [42] C. Guerret-Piecourt, Y. Lebouar, and H. Pascard, “Relation between metal electronic structure and morphology of metal compounds inside carbon nanotubes”, Nature, 1994, 372(6508), 761-765. [43] Y. Saito, M, Okuda, T, Yoshikawa, A, Kasuya, and Y. Nishina, 'Correlation between volatility of rare-earth metals and encapsulation of their carbides in carbon nanocapsules', J. Phys. Chem., 1994, 98(27), 6696-6698. [44] S. Seraphin, D. Zhou, J. Jiao, M.A. Minke, S. Wang, T. Yadav, and J.C. Withers, “Catalytic role of nickel, palladium, and platinum in the formation of carbon nanoclusters”, Chem. Phys. Lett., 1994, 217(3), 191-195. [45] S. Seraphin, D. Zhou, and J. Jiao, “Filling the carbon nanocages”, J. Appl. Phys., 1996, 80(4), 2097-2104. [46] M. Singleton and P. Nash, “The C-Ni (Carbon-Nickel) system”, Bull. Alloy Phase Diagr., 1989, 10(2), 121-126. [47] T. J. Konno and R. Sinclair, “Crystallization of amorphous carbon in carbon-cobalt layered thin films”, Acta. Metall. Mater., 1995, 43(2), 471-484. [48] E. Yang, H. Chou, S. Tsumura, and M. Nagatsu, “Surface properties of plasma-functionalized graphite-encapsulated gold nanoparticles prepared by a direct current arc discharge method”, J. Phys. D: Appl. Phys., 2016, 49, 185304. [49] E.K. Athanassiou, R.N. Grass, and W.J. Stark, “Large-scale production of carbon-coated copper nanoparticles for sensor applications”, Nanotechnology, 2006, 17(6), 1668. [50] G. Vitulli, M. Bernini, S. Bertozzi, E. Pitzalis, P. Salvadori, S. Coluccia, and G. Martra, “Nanoscale copper particles derived from solvated Cu atoms in the activation of molecular oxygen”, Chem. Mat., 2002, 14(3), 1183-1186. [51] H. Yuan, F. Yan, C. Li, C. Zhu, X. Zhang, and Y. Chen, “Nickel nanoparticle encapsulated in few-layer nitrogen-doped graphene supported by nitrogen-doped graphite sheets as high-performance electromagnetic wave absorbing material”, ACS Appl. Mater. Interfaces., 2017, 10, 1399-1407. [52] R. Fuhrer, I.K. Herrmann, E.K. Athanassiou, R.N. Grass, and W.J. Stark, “Immobilized β-cyclodextrin on surface-modified carbon-coated cobalt nanomagnets: reversible organic contaminant adsorption and enrichment from water”, Langmuir, 2011, 27(5), 1924-1929. [53] E. Verrelli, D. Tsoukalas, K. Giannakopoulos, D. Kouvatsos, P. Normand, and D.E. loannou, “Nickel nanoparticle deposition at room temperature for memory applications”, Microelectron. Eng., 2007, 84(9), 1994-1997. [54] Y.D. Wang, X.P. Ai, and H.X. Yang, “Electrochemical hydrogen storage behaviors of ultrafine amorphous Co−B alloy particles”, Chem. Mater., 2004, 16(24), 5194-5197. [55] 林沛彥(1999)“石墨包裹奈米晶粒材料與機械設計”,學士論文,國立臺灣大學地質科學系,共72頁。 [56] 張麗娟(1999)“石墨包裹奈米鎳晶粒的純化分離效果初步研究”,碩士論文,國立臺灣大學地質科學系,共140頁。 [57] 林春長(2002)“石墨包裹奈米鈷晶粒之純化研究”,碩士論文,國立臺灣大學地質科學系,共126頁。 [58] 鄭啟煇(2002)“用電弧法在甲烷與氦氣混合氣體中合成石墨包裹奈米鎳晶粒的初步結果”,碩士論文,國立臺灣大學地質科學系,共69頁。 [59] 蕭敦仁(2005)“石墨包裹鎳奈米晶粒在高溫高壓下合成鑽石的初步探討”,碩士論文,國立臺灣大學地質科學系,共83頁。 [60] 陳永得(2006)“以人造鑽石及噴氣式電弧法合成石墨包裹奈米鐵晶粒之初步結果”,碩士論文,國立臺灣大學地質科學系,共88頁。 [61] 蕭崇毅(2006)“合成石墨包裹奈米金屬晶粒製程中熔融金屬內碳原料變化之初步研究”,碩士論文,國立臺灣大學地質科學系,共87頁。 [62] 李尚實(2006)“不同粒徑大小的石墨包裹奈米鎳晶粒在NP-9膠體系統中之分散研究”,碩士論文,國立臺灣大學地質科學系,共95頁。 [63] 蔡少葳(2007)“石墨包裹奈米鎳晶粒的緻密化之初步研究”,碩士論文,國立臺灣大學地質科學系,共75頁。 [64] 羅仁傑(2010)“石墨包裹奈米鐵晶粒的合成方法改進研究:石墨坩堝設計”,碩士論文,國立臺灣大學地質科學系,共71頁。 [65] 蕭淵隆(2010)“甲醇之蒸散速率效應對石墨包裹奈米鎳晶粒緻密化之研究”,碩士論文,國立臺灣大學地質科學系,共76頁。 [66] 呂睿晟(2011)“非鐵磁性石墨包裹奈米晶粒合成方法之初步研究”,碩士論文,國立臺灣大學地質科學系,共80頁。 [67] 邱志成(2012)“以高合成效率的製程方法合成石墨包裹奈米鐵、鈷、鎳以及銅晶粒之初步研究”,碩士論文,國立臺灣大學地質科學系,共105頁。 [68] 李雱雯(2013)“以退火改善石墨包裹奈米鐵晶粒之包裹良率”,碩士論文,國立臺灣大學地質科學系,共75頁。 [69] 李尚實(2015)“石墨包裹奈米鐵晶粒的純化及表面改質程序之研究”,博士論文,國立臺灣大學地質科學系,共153頁。 [70] 林宏益(2016)“電弧法合成石墨包裹奈米鎳晶粒-使用不同含碳量之液態碳源對於包裹良率變化的研究”,碩士論文,國立臺灣大學地質科學系,共79頁。 [71] M.H. Teng, S.W. Tsai, C.I. Hsiao, and Y.D. Chen, “Using diamond as a metastable phase carbon source to facilitate the synthesis of graphite encapsulated metal (GEM) nanoparticles by an arc-discharge method”, J. Alloys Compd., 2007, 434-435, 678-681. [72] S.S. Lee and M.H. Teng, “Dispersion of graphite encapsulated nickel nanoparticles in a NP-9 colloidal system”, Diam. Relat. Mater., 2011, 20, 183-186. [73] M.H. Teng, S.W. Tsai, and W.A. Chiou, “Magnetic packaging of graphite encapsulated nickel nanoparticles”, J. Alloys Compd., 2010, 495, 488-490. [74] J.C. Lo, J.C. Lu, and M.H. Teng, “A new crucible design of the arc-discharge method for the synthesis of graphite encapsulated metal (GEM) nanoparticles”, Diam. Relat. Mater., 2011, 20, 330-333. [75] S.S. Li, J.C. Lu, and M.H. Teng, “Synthesis of carbon encapsulated non-ferromagnetic metal nanoparticles”, Diam. Relat. Mater., 2012, 24, 88-92. [76] S.S. Li, C.C. Chiu, R.W. Chang, Y.H. Liou, and M.H. Teng, “Synthesis and properties of modified graphite encapsulated iron metal nanoparticles”, Diam. Relat. Mater., 2016, 63, 153-158. [77] F. Liang, M. Tanaka, S. Choi, and T. Watanabe, “Investigation of the relationship between arc-anode attachment mode and anode temperature for nickel nanoparticle production by a DC arc discharge”, J. Phys. D: Appl. Phys., 2016, 49(12), 125201. [78] E. Fitzer, W. Schaefer, and S. Yamada, S, “The formation of glasslike carbon by pyrolysis of polyfurfuryl alcohol and phenolic resin”, Carbon, 1969, 7(6), 643-648. [79] 汪建民(2014),材料分析(第二版),中國材料科學學會。 [80] B.D. Cullity and S.R. Stock (2001). Elements of X-ray Diffraction (3rd edition). New Jersey, U.S.A.: Prentice Hall. [81] W.H. Bragg and W.L. Bragg, “The Reflexion of X-rays by Crystals”. Proc. R. Soc. Lond. A., 1913, 88(605), 428–38. [82] I.R. Lewis and H.G.M. Edwards (2001). Handbook of Raman spectroscopy: from the research laboratory to the processing line. Boca Raton, U.S.A.: CRC Press. [83] F. Tuinstra and J.L. Koenig, “Raman spectrum of graphite”, J. Chem. Phys., 1970, 53(3), 1126-1130. [84] A.C. Ferrari and J. Robertson, “Interpretation of Raman spectra of disordered and amorphous carbon”, Phys. Rev. B, 2000, 61(20), 14095. [85] 鮑忠興、劉思謙(2012),近代穿透式電子顯微鏡實務(第二版),滄海書局。 [86] T. Kogure, “Chapter 2.9- electron microscopy”, Developments in clay science, 2013, 5, 275-317. [87] S. Brunauer, P.H. Emmett, and E. Teller, “Adsorption of gases in multimolecular layers”, J. Am. Chem. Soc., 1938, 60(2), 309-319. [88] C. Morterra and M.J.D. Low, “IR studies of carbons—VII. The pyrolysis of a phenol-formaldehyde resin”, Carbon, 1985, 23(5), 525-530. [89] H. Jiang, J. Wang, S. Wu, Z. Yuan, Z. Hu, R. Wu, and Q. Liu, “The pyrolysis mechanism of phenol formaldehyde resin”, Polym. Degrad. Stabil., 2012, 97(8), 1527-1533. [90] A.A. Setlur, J.M. Lauerhaas, J.Y. Dai, and R.P.H. Chang, (1998). “Formation of nanotubes, nanowires, and nanoparticles in a hydrogen arc”, Supercarbon: synthesis, properties and applications, 43-50, Berlin, Germany: Springer-VBH. [91] K.A. Trick and T.E. Saliba, “Mechanisms of the pyrolysis of phenolic resin in a carbon/phenolic composite”, Carbon, 1995, 33(11), 1509-1515. [92] I. Prigogine and I. Stengers (2018). Order out of chaos: Men’s new dialogue with nature (reprint edition). London, England: Verso Books. [93] T.H. Ko, W.S. Kuo, and Y.H. Chang, “Microstructural changes of phenolic resin during pyrolysis”, J. Appl. Polym. Sci., 2000, 81(5), 1084-1089. [94] R. Matassa, S. Orlanducci, E. Tamburri, V. Guglielmotti, D. Sordi, M.L. Terranova, and M. Rossi, “Characterization of carbon structures produced by graphene self‐assembly”, J. Appl. Crystallogr., 2014, 47(1), 222-227. [95] D. Xiao, X. Li, T. Shen, and M. Song, “Effect of LaB6 addition on microstructure and mechanical properties of ultrafine grained WC-Ni3Al alloys”, J. Cent. South Univ., 2015, 46(1), 81-87. [96] J.I. Langford and A.J.C. Wilson, “Scherrer after sixty years: a survey and some new results in the determination of crystallite size”, J. Appl. Crystallogr., 1978, 11(2), 102-113. [97] R.N. Pease and J.M. Morton, “Kinetics of dissociation of typical hydrocarbon vapors 1”, J. Am. Chem. Soc., 1933, 55(8), 3190-3200. [98] K. Bolton and J.E. Cullingworth, “Ghosh, BP, and Cobb”, J. Chem. Soc, 1942, 252. [99] A.P. Rudenko and B.A. Kazanskii, “Heterogeneous-catalytic course of benzene pyrolysis reactions”, Doklady Akademii Nauk SSSR, 1959, 128(1), 99-102. [100] K.C. Hou and H.B. Palmer, “The kinetics of thermal decomposition of benzene in a flow system”, J. Phys. Chem., 1965, 69(3), 863-868. [101] C.T. Brooks, S.J. Peacock, and B.G. Reubne, “Pyrolysis of benzene”, J. Chem. Soc., Faraday Trans., 1979, 75, 652-662. [102] C. Jacobelli, G. perez, C. Polcaro, E. Possagno, R. Bassanelli, and E. Lilla, “Formation of isomeric terphenyls and triphenylene by pyrolysis of benzene”, J. Anal. Appl. Pyrolysis, 1983, 5(3), 237-243. [103] S.C. Moldoveanu, “Pyrolysis of hydrocarbons”, Techniques and instrumentation in analytical chemistry, 2010, 28, 131-229. [104] H.J. Singh and R.D. Kern, “Pyrolysis of benzene behind reflected shock waves”, Combust. flame, 1983, 54(1-3), 49-59. [105] X. Xu and P.D. Pacey, “An induction period in the pyrolysis of acetylene”, Phys. Chem. Chem. Phys., 2001, 3(14), 2836-2844. [106] H. Wang and M. Frenklach, “A detailed kinetic modeling study of aromatics formation in laminar premixed acetylene and ethylene flames”, Combust. flame, 1997, 110(1-2), 173-221. [107] H. Wang, H. Yang, W. Chuang, X. Ran, Q. Shi, and Z. Wen, “Pyrolysis mechanism of carbon matrix precursor cyclohexane—The formation of condensed-ring aromatics and the growing process of molecules”, J. Mol. Graph., 2007, 25(6), 824-830. [108] S. Kawasumi, M. Egashira, and H. Katsuki, “Catalytic Formation of Graphite from benzene on iron powder”, J. Catal., 1981, 68(1), 237-241. [109] A.A. Susu and A.F. Ogunye, “Selective naphthene pyrolysis for ethylene with hydrogen as diluent”, Thermochim. Acta, 1979, 34(2), 197-210. [110] L.E. Gusel'nikov, V.V. Volkova, P.E. Ivanov, S.V. Inyushkin, L.V. Shevelkova, G. Zimmermann, and B. Ondruschka, “Direct infrared spectroscopic evidence of allyl radical and definition of the initiation step in thermal decomposition of cycloalkanes.: A comparison with very low pressure pyrolysis of alkenes”, J. Analy. Appl. Pyrolysis, 1991, 21(1-2), 79-93. [111] T. Kunugi, T. Kunugi, T. Sakai, K. Soma, and Y. Sasaki, “Kinetics and mechanism of thermal reaction of ethylene”, Ind. Eng. Chem. Fundamen., 1969, 8(3), 374-383. [112] C.S. McEnally and L.D. Pfefferle, “Experimental study of fuel decomposition and hydrocarbon growth processes for cyclohexane and related compounds in nonpremixed flames”, Combust. flame, 2004, 136(1-2), 155-167. [113] C.D. Zappielo, D.M. Nanicuacua, W.N. dos Santos, D.L. da Silva, L.H. Dall'Antônia, F.M.D. Oliveira, and C.R. Tarley, “Solid phase extraction to on-line preconcentrate trace cadmium using chemically modified nano-carbon black with 3-mercaptopropyltrimethoxysilane”, J. Braz. Chem. Soc., 2016, 27(10), 1715-1726. [114] X. Yu and L. Qiang, “Preparation for graphite materials and study on electrochemical degradation of phenol by graphite cathode”, Adv. Mater. Phys. Chem., 2012, 2, 63-68. [115] S. Zhao, J. Shi, X. Wei, X. Yan, L. Liu, “Effects of deposition temperature on microstructure of silicon carbide filaments with carbon core”, Aerospace Mater. Tech., 2011, 4, 36-40. [116] D.C. Elias, R.R. Nair, T.M.G. Mohiuddin, S.V. Morozov, P. Blake, M.P. Halsall, & K.S. Novoselov, “Control of graphene's properties by reversible hydrogenation: evidence for graphene”, Science, 2009, 323(5914), 610-613. [117] 游慈卉(2011)“使用顯微拉曼光譜儀研究多層石墨烯之氫化反應”,碩士論文,國立清華大學物理學系,共42頁。 [118] V. Sridhar and H. Park, “Sugar-derived disordered carbon nano-sheets as high-performance electrodes in sodium-ion batteries”, New J. Chem., 2017, 41(11), 4286-4290. [119] Z.Q. Li, C.J. Lu, Z.P. Zhou, and Z. Luo, “X-ray diffraction patterns of graphite and turbostratic carbon”, Carbon, 2007, 45(8), 1686-1695. [120] A.E.F. Gick, M.B.C Quigley, and P.H. Richards, “The use of electrostatic probes to measure the temperature profiles of welding arcs”, J. Phys. D: Appl. Phys., 1973, 6(16), 1941. [121] G. Cota-Sanchez, G. soucy, A. Huczko, and H. Lange, “Induction plasma synthesis of fullerenes and nanotubes using carbon black–nickel particles”, Carbon, 2005, 43(15), 3153-3166. [122] M.E. Law, P.R. Westmoreland, T.A. Cool, J. Wang, N, Hansen, C.A. Taatjes, and T. Kasper, “Benzene precursors and formation routes in a stoichiometric cyclohexane flame”, Proc. Combust. Inst., 2007, 31(1), 565-573. [123] R. Taylor, G.J. Langley, H.W. Kroto, and D.R. Walton “Formation of C60 by pyrolysis of naphthalene”, Nature, 1993, 366(6457), 728. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/71803 | - |
dc.description.abstract | 石墨包裹鎳奈米晶粒(graphite encapsulated nickel nanoparticles, Ni-GEM)是一種內核為鎳奈米金屬,外部為層狀石墨的核殼複合結構材料;因穩定的石墨殼層可以保護內部金屬,所以能夠展現被包裹金屬之多元特性與應用潛力。而Elliott等人於1997年提出的二步驟機制(two-step mechanism)是目前最能合理解釋以電弧法合成GEM晶粒的機制,並根據機制可知,於合併區內提供足量且均勻的碳蒸氣,是提升GEM晶粒之包裹良率與產率最根本的方法。
為了探討不同均勻度及形態的碳蒸氣對產物的影響,本研究選用工業中常見的膠體酚醛樹脂,在電弧區內提供初始碳源,並添加液態有機分子,如苯(benzene, C6H6)及環己烷(cyclohexane, C6H12),透過艙內間接加熱之坩堝蒸發後,有機蒸氣會隨著熱對流,由合併區外圍向內部提供碳源。根據產物之合成效率結果,單純添加3 g之酚醛樹脂作為碳源時,可以得到29%的最佳包裹良率與20 g/h之產率;而當添加了20 ml之苯與環己烷蒸氣後,其產率可達 29 g/h,並大幅提升包裹良率達80%。根據奈米顆粒之表面形態進行分類,可以觀察到獨特的分佈現象,例如使用酚醛樹脂與額外添加環己烷之產物具有約40 nm之大粒徑與小於5 nm之薄石墨層;反之,使用苯蒸氣之產物則具有20 nm之小粒徑與5-10 nm厚的石墨殼層。 本研究依照實驗結果並搭配烴類的熱裂解反應文獻,提出新的「三步驟」合成模型來解釋產物差異。苯與環己烷在熱裂解過程中除了具有不同的起始反應溫度外,亦會發生不同程度的縮合或降解反應,進而影響產物之最終形態。 最後,為了探討運作模型之適用性,本研究也嘗試合成低熔點之Cu-GEM,並使用具有相似性質之萘蒸氣進行Ni-GEM之合成,冀希建立相關初步概念假說,以提供未來深入研究之基礎。 | zh_TW |
dc.description.abstract | Graphite Encapsulated Nickel (Ni-GEM) nanoparticles are core-shell composite-structured materials with an inner core of nano-metal and an outer shell of graphite. The internal metal can be preserved and exhibit its characteristics because of the protection of the stable graphite shell. For example, the magnetic and microwave adsorption properties can be used in several fields, i.e., as the tracer in a structural geological survey or the surface coating of stealth aircraft in the national defense industry. According to the two-step mechanism proposed by Elliott et al. (1997), the most fundamental way to improve the encapsulation efficiency and production rate of GEM is to provide sufficient uniform carbon vapor in the coalescence area.
In order to investigate the effect of using different types and uniformity of the carbon vapors on products, phenol formaldehyde resin is used as the initial carbon source; besides, benzene and cyclohexane were injected into the heated alumina crucible to form vapors, providing carbons outside-in of the coalescence area. According to the results, simply adding 3 g of phenolic resin as the carbon source can obtain the best encapsulation efficiency of 29% and production rate of 20 g/h; when 20 ml of benzene and cyclohexane vapor were added, the production rate was 29 g/h, and the encapsulation efficiency was 80% for both. Moreover, the morphologies of nanoparticles show an interesting trend, that is, the Ni-GEM particles made from phenolic resin or cyclohexane vapors result in similar particle size (40 nm) with a thinner shell (less than 5 nm). However, the use of benzene vapors results in smaller particle size (20 nm) and thicker shell (5-10 nm) than ever before. According to the pyrolysis literature on hydrocarbons, it is known that the initial reaction temperature and reaction path of cyclohexane and benzene totally differ. Thus, a new “three-step” working model, in which the nanocarbon materials formed by the organic compounds will directly affect the experimental results, was proposed using the pyrolysis reaction. Last but not least, based on the applicability of this model, we aimed to synthesize Cu-GEM by this synthesis method and Ni-GEM with naphthalene vapor. This procedure is expected to establish a preliminary concept hypothesis for related research, and provide the foundation for more in-depth materials science research in the future. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T06:10:22Z (GMT). No. of bitstreams: 1 ntu-107-R05224202-1.pdf: 8370948 bytes, checksum: c084d7261bed735939a727c86eae7076 (MD5) Previous issue date: 2018 | en |
dc.description.tableofcontents | 致謝 i
中文摘要 ii Abstract iii 目錄 v 圖目錄 ix 表目錄 xiii 第一章 緒論 1 1.1 研究動機與目的 1 1.2 研究方法 3 1.3 本文內容 4 第二章 文獻回顧 6 2.1 奈米材料 6 2.1.1 量子尺寸效應 7 2.1.2 小尺寸效應 7 2.1.3 表面效應 8 2.1.4 奈米材料之性質 9 2.1.4.1 光學性質 9 2.1.4.2 磁性質 10 2.1.4.3 電性質 12 2.1.4.4 熱力學性質 12 2.1.5 奈米材料常見之合成技術 13 2.1.5.1 機械球磨粉碎法 13 2.1.5.2 液相法 15 2.1.5.3 氣相法 16 2.2 石墨包裹金屬奈米晶粒 19 2.2.1 新形態固體碳-C60與石墨包裹金屬奈米晶粒的發現 19 2.2.2 改良式鎢-碳電弧法與石墨包裹金屬奈米晶粒的發展 22 2.2.3 石墨包裹金屬奈米晶粒的相關合成機制、方式與應用 24 2.2.3.1 二步驟機制模型 24 2.2.3.2 水熱法合成步驟 29 2.2.3.3 相關領域之應用與未來發展 30 2.3 本研究團隊在石墨包裹金屬奈米晶粒之研究發展 33 2.3.1 機械與流程設計 34 2.3.2 產物之分散設計 35 2.3.3 產物之熱處理 36 2.3.4 陽極坩堝之改良 36 2.3.5 金屬之選擇 37 2.3.6 碳源之選擇 38 第三章 實驗方法 39 3.1 真空電弧蒸發裝置 39 3.1.1 電弧系統 40 3.1.2 冷卻系統 41 3.1.3 電源供應系統 42 3.2 實驗流程 44 3.2.1 原料配置 44 3.2.2 真空艙內環境配置與奈米顆粒之製備 45 3.2.2.1 使用膠體樹脂作為碳源 45 3.2.2.2 額外添加有機蒸氣 46 3.2.3 初產物之收集與純化 47 3.2.3.1 超音波震盪搭配酸溶法 47 3.2.3.2 磁選與離心法 48 3.3 分析儀器 48 3.3.1 X光粉末繞射儀 49 3.3.2 顯微拉曼光譜儀 51 3.3.3 高分辨解析率穿透式電子顯微鏡 54 3.3.4 比表面積分析儀 56 第四章 實驗結果與討論 58 4.1 使用樹脂膠體作為碳源之合成效率 59 4.1.1 使用膠體碳源之產率差異比較 61 4.1.1.1 酚醛樹脂熱裂解之固相產物 61 4.1.1.2 酚醛樹脂熱裂解之氣相產物 63 4.1.2 使用膠體碳源之包裹良率差異比較 64 4.1.2.1 酚醛樹脂固化結構 65 4.1.2.2 不同酚醛樹脂含量對包裹良率之影響 66 4.1.3膠體中單位體積含碳量與GEM晶粒合成效率之關係 67 4.2 添加有機分子作為額外氣態碳源 68 4.2.1 使用額外蒸氣作為碳源之合成效率 69 4.2.2合成產物形態觀察與分析 72 4.2.3合成產物之晶相與粒徑分析 75 4.2.4苯與環己烷之熱裂解與降解行為 81 4.2.4.1苯的熱裂解與催化反應 82 4.2.4.2環己烷的熱分解反應 86 4.2.5顯微拉曼光譜分析結果 89 4.2.5.1 退火處理前之Ni-GEM樣品 89 4.2.5.2 退火處理後之Ni-GEM樣品 92 4.2.6碳(002)面之X光繞射分析結果 95 4.3 研究假說 97 4.3.1運作模型 98 4.3.2機制之適用性 101 4.4 其他相似碳源以及石墨包裹銅奈米晶粒(Cu-GEM)之合成 101 4.4.1以萘蒸氣進行Ni-GEM之合成 102 4.4.2以苯蒸氣進行Cu-GEM之合成 105 第五章 結論與建議 109 參考文獻 112 附錄A 本研究團隊歷屆相關文獻 121 附錄B 實驗數據 123 | |
dc.language.iso | zh-TW | |
dc.title | 以電弧法合成石墨包裹鎳奈米晶粒並探討有機物熱裂解反應對產物之影響研究 | zh_TW |
dc.title | The Effect of Organic Compound Pyrolysis on Synthesizing Graphite Encapsulated Nickel Nanoparticles in an Arc-discharge System | en |
dc.type | Thesis | |
dc.date.schoolyear | 107-1 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 劉雅瑄(Ya-Hsuan Liou),鄧茂英(Mao-Ying Teng),余炳盛(Bing-Sheng Yu) | |
dc.subject.keyword | 石墨包裹,奈米鎳顆粒,物理氣相沉積,有機蒸氣,碳氫化合物熱裂解, | zh_TW |
dc.subject.keyword | graphite encapsulated,nickel nanoparticles,physical vapor deposition (PVD),organic vapors,pyrolysis of hydrocarbons, | en |
dc.relation.page | 129 | |
dc.identifier.doi | 10.6342/NTU201804257 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2018-11-21 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 地質科學研究所 | zh_TW |
顯示於系所單位: | 地質科學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-107-1.pdf 目前未授權公開取用 | 8.17 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。