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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 趙基揚(Chi-Yang Chao) | |
| dc.contributor.author | Cheng-Hung Liao | en |
| dc.contributor.author | 廖晟宏 | zh_TW |
| dc.date.accessioned | 2021-06-17T06:03:49Z | - |
| dc.date.available | 2022-01-29 | |
| dc.date.copyright | 2019-01-29 | |
| dc.date.issued | 2019 | |
| dc.date.submitted | 2019-01-27 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/71582 | - |
| dc.description.abstract | 本研究從商業上可獲得的三嵌段共聚物SEBS磺化獲得磺酸鋰(SO3-Li)系鏈(苯乙烯-乙烯/丁烯-苯乙烯)嵌段共聚物(SSEBS)，作為鋰離子電池（LIB）中負極的活性石墨與活性Si@G(矽在石墨上)的保護塗層。保護塗層應防止液體電解質與石墨和Si@G直接接觸，從而避免液體電解質的負面影響，例如石墨剝落和不希望的SEI形成，因此改善了LIB的長期穩定性。
在SSEBS中，SO3-Li基團接枝到聚苯乙烯上使磺化聚苯乙烯區域具有鋰離子傳導能力的鋰離子，而聚(乙烯/丁基)區段提供塗層的延展性和柔韌性以適應 充放電循環過程中石墨和Si@G的體積變化； 此外，PS的芳環與石墨表面之間的π-π相互作用也提供SSEBS與石墨的強黏附力。 在研究中，我們系統地改變了石墨與Si@G上的SSEBS數量，以優化電池性能。結果表明，保護塗層可以有效地提高負極的電化學穩定性，而不會犧牲電池的性能。 | zh_TW |
| dc.description.abstract | This work employed lithium sulfonate (SO3-Li) tethered poly(styrene-block-(ethylene-ran-butylene)-block-styrene) (SSEBS), obtained from sulfonation of commercial available triblock copolymer SEBS, to serve as the protective coating on the active graphite and active Si@G (silicon on graphite) of the anode in a lithium ion battery (LIB). The protective coating should prevent direct contact of liquid electrolyte with the graphite and Si@G, thus to avoid the negative effects of the liquid electrolyte such as exfoliation of graphite and undesired SEI formation, and therefore improve the long term stability of the LIB.
In SSEBS, the SO3-Li groups are grafting onto polystyrene to allow the sulfonated polystyrene domains having lithium ion conducting capability of lithium ion, while the poly(ethylene-ran-butylene) segment provide the ductility and flexibility of the coating layer to accommodate the volume change of graphite and Si@G during charging and discharging cycles. Moreover, the π-π interaction between the aromatic ring of PS and the graphite surface should provide strong adhesion of SSEBS to the graphite. In this work, we systematically varied the amount of SSEBS on the graphite/Si@G to optimize the battery performance. It is demonstrated that the protective coating could effectively improve the electrochemical stability of the anode without sacrificing the battery performance. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T06:03:49Z (GMT). No. of bitstreams: 1 ntu-108-R05527061-1.pdf: 8734127 bytes, checksum: 0b0a1f52dbaad6a95274bcaae9b70be1 (MD5) Previous issue date: 2019 | en |
| dc.description.tableofcontents | 口試委員會審定書 i
致謝 ii 中文摘要 iii Abstract iv 目錄 v 圖索引 viii 表索引 xv 第1章 緒論 1 1.1 研究背景 1 1.2 研究動機 1 第2章 文獻回顧 3 2.1 聚電解質（Polyelectrolytes）的介紹 3 2.1.1 聚電解質的性質 3 2.1.2 聚電解質的應用 4 2.1.3 SSEBS的發展與應用 5 2.2 鋰離子電池的工作原理和特點 8 2.2.1 工作原理 8 2.2.2 鋰電池研究的歷史發展 12 2.3 石墨負極材料的介紹 16 2.3.1 石墨類碳材的結構 16 2.3.2 石墨類碳材的插鋰行為 18 2.3.3 固體電解質介面(SEI) 21 2.3.4 石墨類碳材的電化學性能 22 2.3.5 人工固體電解質介面（A-SEI） 24 2.3.6 表面改質 30 2.4 矽負極材料的介紹 35 2.4.1 用於鋰離子電池的純矽粉末負極 35 2.4.2 矽負極材料的奈米結構 40 2.4.3 矽負極的固體電解質介面(SEI) 45 2.4.4 矽負極的表面改質 48 2.5 Si@G複合負極材料的介紹 60 2.5.1 Si@G複合材料 60 第3章 實驗步驟與原理 71 3.1 實驗藥品 71 3.2 實驗儀器 74 3.3 材料製備 75 3.3.1 SSEBS的合成 75 3.3.2 SSEBS薄膜製備 76 3.3.3 SSEBS塗覆NG與Si@G 77 3.3.4 NG與Si@G電極的塗佈 77 3.3.5 CR2032鈕扣型電池組裝 78 3.4 材料分析 79 3.4.1 SSEBS-OH磺酸化程度的鑑定 79 3.4.2 熱分析 80 3.4.3 薄膜機械強度分析 80 3.4.4 電化學阻抗頻譜分析 80 3.4.5 電池循環充放電量測 81 3.4.6 電極表面形貌分析 81 第4章 結果與討論 82 4.1 SSEBS-OH磺酸化程度的鑑定 82 4.2 SSEBS薄膜製備 84 4.3 SSEBS的熱分析 85 4.4 SSEBS薄膜的機械性質 86 4.5 SSEBS塗覆於天然石墨（NG） 87 4.5.1 Formation測試 88 4.5.2 C-rate測試與循環穩定性測試(Long term stability) 92 4.6 SSEBS塗覆於矽碳(Si@G) 96 4.6.1 Formation測試 97 4.6.2 循環測試（Long term stability） 99 第5章 結論 103 第6章 未來展望 104 附錄 105 參考文獻 106 | |
| dc.language.iso | zh-TW | |
| dc.subject | Si@G負極 | zh_TW |
| dc.subject | 石墨負極 | zh_TW |
| dc.subject | 保護層 | zh_TW |
| dc.subject | 鋰離子電池 | zh_TW |
| dc.subject | 三嵌段共聚物 | zh_TW |
| dc.subject | SSEBS | zh_TW |
| dc.subject | 單離子導體 | zh_TW |
| dc.subject | Si@G anode | en |
| dc.subject | SSEBS | en |
| dc.subject | single-ion conductor | en |
| dc.subject | lithium ion batteries | en |
| dc.subject | protective layer | en |
| dc.subject | graphite anode | en |
| dc.subject | triblock copolymer | en |
| dc.title | 單離子導電嵌段共聚物作為鋰離子電池之石墨和Si@G負極保護塗層之研究 | zh_TW |
| dc.title | Single Ion Conducting Block Copolymer for Protective Coating of Graphite and Si@G Anode of Lithium Ion Batteries | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 107-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 吳乃立(Nae-Lih Wu),方家振(Chia-Chen Fang) | |
| dc.subject.keyword | 三嵌段共聚物,SSEBS,單離子導體,鋰離子電池,保護層,石墨負極,Si@G負極, | zh_TW |
| dc.subject.keyword | triblock copolymer,SSEBS,single-ion conductor,lithium ion batteries,protective layer,graphite anode,Si@G anode, | en |
| dc.relation.page | 115 | |
| dc.identifier.doi | 10.6342/NTU201900165 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2019-01-28 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 材料科學與工程學系 | |
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