請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/71267完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱靜雯 | |
| dc.contributor.author | Tzung-Han Lin | en |
| dc.contributor.author | 林宗翰 | zh_TW |
| dc.date.accessioned | 2021-06-17T05:01:53Z | - |
| dc.date.available | 2023-08-01 | |
| dc.date.copyright | 2018-08-01 | |
| dc.date.issued | 2018 | |
| dc.date.submitted | 2018-07-24 | |
| dc.identifier.citation | 1. Tumanskii, B.; Pine, P.; Apeloig, Y.; Hill, N. J.; West, R., J. Am. Chem. Soc. 2005, 127, 8248-8249.
2. Kira, M.; Ishida, S.; Iwamoto, T.; Ichinohe, M.; Kabuto, C.; Ignatovich, L.; Sakurai, H., Chem. Lett. 1999, 28, 263-264. 3. Wang, L.; Lim, Y.; Li, Y.; Ganguly, R.; Kinjo, R., Molecules 2016, 21, 990. 4. Zabula, A. V.; Hahn, F. E.; Pape, T.; Hepp, A., Organometallics 2007, 26, 1972-1980. 5. Wang, W.; Inoue, S.; Enthaler, S.; Driess, M., Angew. Chem. Int. Ed. 2012, 51, 6167-6171. 6. Çetinkaya, E.; Hitchcock, P. B.; Küçükbay, H.; Lappert, M. F.; Al-Juaid, S., J. Organomet. Chem. 1994, 481, 89-95. 7. Hahn, F. E.; Wittenbecher, L.; Le Van, D.; Zabula, A. V., Inorg. Chem. 2007, 46, 7662-7667. 8. Zabula, A. V.; Hahn, F. E., Eur. J. Inorg. Chem. 2008, 2008, 5165-5179. 9. Braunschweig, H.; Gehrhus, B.; Hitchcock Peter, B.; Lappert Michael, F., Z. Anorg. Allg. Chem. 1995, 621, 1922-1928. 10. Zabula, A. V.; Pape, T.; Hepp, A.; Schappacher, F. M.; Rodewald, U. C.; Pöttgen, R.; Hahn, F. E., J. Am. Chem. Soc. 2008, 130, 5648-5649. 11. Hsu, C. Y.; Chan, L. W.; Lee, G. H.; Peng, S. M.; Chiu, C. W., Dalton Trans. 2015, 44, 15095-15098. 12. Heitmann, D.; Pape, T.; Hepp, A.; Muck-Lichtenfeld, C.; Grimme, S.; Hahn, F. E., J. Am. Chem. Soc. 2011, 133, 11118-11120. 13. Benedek, Z.; Szilvási, T., Organometallics 2017, 36, 1591-1600. 14. Bruck, A.; Gallego, D.; Wang, W.; Irran, E.; Driess, M.; Hartwig, J. F., Angew. Chem. Int. Ed. 2012, 51, 11478-11482. 15. Gallego, D.; Bruck, A.; Irran, E.; Meier, F.; Kaupp, M.; Driess, M.; Hartwig, J. F., J. Am. Chem. Soc. 2013, 135, 15617-15626. 16. Zhu, C.; Takaya, J.; Iwasawa, N., Org. Lett. 2015, 17, 1814-1817. 17. Takaya, J.; Nakamura, S.; Iwasawa, N., Chem. Lett. 2012, 41, 967-969. 18. Herrmann, R.; Braun, T.; Mebs, S., Eur. J. Inorg. Chem. 2014, 2014, 4826-4835. 19. Lin, T.-P.; Gabbaï, F. P., Polyhedron 2017, 125, 18-25. 20. Cook, N. C.; Lyons, J. E., J. Am. Chem. Soc. 1965, 87, 3283-3284. 21. Hao, L.; Harrod, J. F.; Lebuis, A. M.; Mu, Y.; Shu, R.; Samuel, E.; Woo, H. G., Angew. Chem. Int. Ed. 1998, 37, 3126-3129. 22. Arrowsmith, M.; Hill, M. S.; Hadlington, T.; Kociok-Köhn, G.; Weetman, C., Organometallics 2011, 30, 5556-5559. 23. Oshima, K.; Ohmura, T.; Suginome, M., J. Am. Chem. Soc. 2012, 134, 3699-3702. 24. Dudnik, A. S.; Weidner, V. L.; Motta, A.; Delferro, M.; Marks, T. J., Nat. Chem. 2014, 6, 1100-1107. 25. Fan, X.; Zheng, J.; Li, Z. H.; Wang, H., J. Am. Chem. Soc. 2015, 137, 4916-4919. 26. Rao, B.; Chong, C. C.; Kinjo, R., J. Am. Chem. Soc. 2018, 140, 652-656. 27. Kaithal, A.; Chatterjee, B.; Gunanathan, C., Org. Lett. 2016, 18, 3402-3405. 28. Lin, T. P.; Peters, J. C., J. Am. Chem. Soc. 2013, 135, 15310-15313. 29. (a) Alvarez-Rodriguez, L.; Brugos, J.; Cabeza, J. A.; Garcia-Alvarez, P.; Perez-Carreno, E.; Polo, D., Chem. Commun. 2017, 53, 893-896; (b) Brugos, J.; Cabeza, J. A.; Garcia-Alvarez, P.; Perez-Carreno, E.; Polo, D., Dalton Trans. 2018, 47, 4534-4544. 30. (a) Álvarez‐Rodríguez, L.; Brugos, J.; Cabeza Javier, A.; García‐Álvarez, P.; Pérez‐Carreño, E., Chem. Eur. J. 2017, 23, 15107-15115; (b) Brugos, J.; Cabeza, J. A.; García-Álvarez, P.; Pérez-Carreño, E., Organometallics 2018, 37, 1507-1514. 31. Dickschat, J. V.; Urban, S.; Pape, T.; Glorius, F.; Hahn, F. E., Dalton Trans. 2010, 39, 11519-11521. 32. Charmant, J. P.; Haddow, M. F.; Hahn, F. E.; Heitmann, D.; Fröhlich, R.; Mansell, S. M.; Russell, C. A.; Wass, D. F., Dalton Trans. 2008, 6055-6059. 33. Fleischer, H.; Schollmeyer, D., Inorg. Chem. 2004, 43, 5529-5536. 34. Janes, T.; Zatsepin, P.; Song, D., Chem. Commun. 2017, 53, 3090-3093. 35. Graux, L. V.; Giorgi, M.; Buono, G.; Clavier, H., Dalton Trans. 2016, 45, 6491-6502. 36. Takaoka, A.; Mendiratta, A.; Peters, J. C., Organometallics 2009, 28, 3744-3753. 37. Sabater, S.; Mata, J. A.; Peris, E., Nat. Commun. 2013, 4, 2553. 38. (a) Zanardi, A.; Mata, J. A.; Peris, E., J. Am. Chem. Soc. 2009, 131, 14531-14537; (b) Zanardi, A.; Corberán, R.; Mata, J. A.; Peris, E., Organometallics 2008, 27, 3570-3576. 39. Barranco, E. M.; Crespo, O.; Concepción Gimeno, M.; Laguna, A.; Jones, P. G.; Ahrens, B., Inorg. Chem. 2000, 39, 680-687. 40. (a) ; (b) Leznoff, D. B.; Xue, B.-Y.; Batchelor, R. J.; Einstein, F. W. B.; Patrick, B. O., Inorg. Chem. 2001, 40, 6026-6034; (c) ; (d) Abdou, H. E.; Mohamed, A. A.; Fackler, J. P., Inorg. Chem. 2005, 44, 166-168. 41. (a) Yan, Y. K.; Melchart, M.; Habtemariam, A.; Sadler, P. J., Chem Commun. 2005, 4764-4776; (b) Ang, W. H.; Daldini, E.; Juillerat-Jeanneret, L.; Dyson, P. J., Inorg. Chem. 2007, 46, 9048-9050; (c) Ang, W. H.; Daldini, E.; Scolaro, C.; Scopelliti, R.; Juillerat-Jeannerat, L.; Dyson, P. J., Inorg. Chem. 2006, 45, 9006-9013. 42. Jantke, D.; Cokoja, M.; Pöthig, A.; Herrmann, W. A.; Kühn, F. E., Organometallics 2013, 32, 741-744. 43. Kisan, S.; Krishnakumar, V.; Gunanathan, C., ACS Catal. 2017, 7, 5950-5954. 44. Kaithal, A.; Chatterjee, B.; Gunanathan, C., J. Org. Chem. 2016, 81, 11153-11161. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/71267 | - |
| dc.description.abstract | 碳烯的重類似物近年來受到越來越多的關注，取代碳異環碳烯(N-heterocyclic carbene)中的碳原子成重十四族的元素也發現了許多出乎預期的反應。在本篇論文中合成了單牙及三牙的金屬烯配位基，在單牙的鍺烯與錫烯與零價鈀金屬的反應中成功的分離出雙鍺烯、錫烯鈀金屬錯化合物，然而在與鉛烯的反應中，則觀察到了氧化反應的發生而不是與金屬形成錯化合物。此外，我們也利用三牙的鍺烯配位基合成了具有未鍵結磷配位基的釕金屬錯化合物，此錯化合物也可以當作一個特別的骨架去合成同核及異核雙金屬錯化合物。且單核及雙核的釕金屬錯化合物在吡啶的硼氫化反應中也表現出不同反應的活性與選擇性。 | zh_TW |
| dc.description.abstract | Being the heavier analogue of N-heterocyclic carbene, NHE (E = Si, Ge, Sn, Pb) metallylenes have received more and more attention recently. Substituting the central divalent carbon of N-heterocyclic carbene with heavier group 14 elements has led to the discovery of several unexpected reactions in the past few years. In this study, pincer type PEP and monodentate metallylene were synthesized and isolated. The coordination chemistry of N,N-dimesityl-substituted benzannulated germylene and stannylene towards Pd0 complex are investigated. However, exploring reactivity of plumbylene ,We observed NMR-active and paramagnetic products in the oxidation reaction. Additionally, The coordination of a P-Ge-P tridendent pincer ligand bearing a germylene coordination site toward ruthenium complex was investigated. The resulting unsymmetrical phosphine-germyl complex of Ru featuring a uncoordinated phosphine side-arm turns out to be an intriguing platform for constructing bimetallic system including Ru-Ru and Ru-Au systems. Catalytic performance of the mono- and bi-metallic Ru(arene)PGeP based complexes in hydroboration of pyridine was also examined. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T05:01:53Z (GMT). No. of bitstreams: 1 ntu-107-R05223135-1.pdf: 4952482 bytes, checksum: 85dfd1dce40b59f1c6d7179e340e08ed (MD5) Previous issue date: 2018 | en |
| dc.description.tableofcontents | 中文摘要 i
ABSTRACT ii CONTENTS iii LIST OF FIGURES iv LIST OF SCHEMES vi Chapter 1. Introduction 1 1.1 Metallylenes 1 1.1.1 Germylene 4 1.1.2 Stannylene 6 1.1.3 Plumbylene 9 Molecular Design 15 Chapter 2. Results and Discussion 17 2.1 Syntheses of monodentate metallylenes 17 2.2 Syntheses of PEP metallylenes 19 2.3 Coordination chemistry of monodentate metallylene 23 2.4 Coordination chemistry of PGeP metallylene 28 2.4.1 Bimetallic complexes supported by PGeP ligand 34 2.4.2 Brief summary of coordination chemistry of PGeP 40 2.5 Hydroboration of pyridine using PGeP-Ru(cymene) derivatives as catalyst 42 Chapter 3. Conclusion 48 References 49 Chapter 4. Appendix 54 | |
| dc.language.iso | en | |
| dc.subject | 鍺烯 | zh_TW |
| dc.subject | 三牙配位基 | zh_TW |
| dc.subject | 釕金屬錯化合物 | zh_TW |
| dc.subject | 硼氫化反應 | zh_TW |
| dc.subject | 鉛烯 | zh_TW |
| dc.subject | 錫烯 | zh_TW |
| dc.subject | stannylene | en |
| dc.subject | tridentate ligand | en |
| dc.subject | ruthenim complexes | en |
| dc.subject | hydroboration | en |
| dc.subject | germylene | en |
| dc.subject | plumbylene | en |
| dc.title | 苯環金屬烯的反應性探討 | zh_TW |
| dc.title | Reactivity Studies of Benzannulated Metallylenes | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 106-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 王朝諺,陳喧應 | |
| dc.subject.keyword | 鍺烯,錫烯,鉛烯,三牙配位基,釕金屬錯化合物,硼氫化反應, | zh_TW |
| dc.subject.keyword | germylene,stannylene,plumbylene,tridentate ligand,ruthenim complexes,hydroboration, | en |
| dc.relation.page | 157 | |
| dc.identifier.doi | 10.6342/NTU201801825 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2018-07-25 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-107-1.pdf 未授權公開取用 | 4.84 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。