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| ???org.dspace.app.webui.jsptag.ItemTag.dcfield??? | Value | Language |
|---|---|---|
| dc.contributor.advisor | 趙基揚(Chi-Yang Chao) | |
| dc.contributor.author | Yi-Ling Liu | en |
| dc.contributor.author | 劉怡伶 | zh_TW |
| dc.date.accessioned | 2021-06-17T04:31:29Z | - |
| dc.date.available | 2023-08-15 | |
| dc.date.copyright | 2018-08-15 | |
| dc.date.issued | 2018 | |
| dc.date.submitted | 2018-08-11 | |
| dc.identifier.citation | [1] Lin, D.; Liu, Y.; Cui, Y., 'Reviving the Lithium Metal Anode for High-Energy Batteries', Nature Nanotechnology 2017, 12, 194-206.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/70574 | - |
| dc.description.abstract | 本研究以陰離子聚合法及後續的官能基修飾開發新型態ABCBA五嵌段共聚高分子以作為鋰金屬負極及微孔隔離膜Celgard 2320之間的保護層，目的為提升鋰金屬電池的穩定性與安全性。在五嵌段共聚高分子中，A嵌段為具有單離子導體特性的磺酸化聚異戊二烯，懸垂於側鏈的高密度磺酸鋰負責鋰離子傳導，單離子導體特性可以抑制鋰枝晶成長；B嵌段為柔軟的聚異戊二烯，用以提供膜材所需彈性；C嵌段為剛硬的聚苯乙烯，用以提供膜材所需機械強度及尺度穩定性；又由於高分子鏈兩端皆為磺酸化聚異戊二烯，磺酸鋰間強烈的庫倫作用力會使A嵌段產生物理交聯，可更進一步提升膜材的機械強度以抵擋鋰枝晶成長。利用溶劑揮發法可製備出厚度小於20μm的獨立薄膜。材料鑑定首先進行薄膜的熱性質、微結構、機械強度及表面特性等分析以了解此材料的基本特性，接著進行電化學性質量測，最後組裝成以磷酸鋰鐵為正極、鋰金屬為負極的鈕扣型電池進行充放電測試，評估將此五嵌段共聚高分子作為鋰金屬電池之鋰金屬負極保護層的潛質。 | zh_TW |
| dc.description.abstract | A novel ABCBA pentablock copolymer is synthesized via anionic polymerization and the following functional group conversion to serve as a non-porous protective layer for lithium metal anode in lithium metal batteries located between the lithium metal anode and the mesoporous separator Celgard 2320. Within the pentablock copolymer, segment A is a single-ion conductor containing pendant lithium sulfonate group (-SO3Li) for the purpose of lithium ion transportation and of the suppression of lithium dendrite; segment B is flexible polyisoprene to provide the membrane with flexibility; while segment C is rigid polystyrene offering the membrane mechanical strength and dimensional stability. In addition to the above transport and mechanical properties achieving by each segment, strong ionic interaction between the terminal lithium sulfonate groups of the two A segments enabling physical crosslinking would further enhance the mechanical strength for blocking lithium dendrite growth. Free standing membranes with thickness less than 20μm are prepared by solvent-casting method. Microstructure as well as mechanical, thermal and surface properties of the membranes are studied. Electrochemical properties and charge-discharge tests are also performed to evaluate the potential of the pentablock protective layer for lithium metal anode in lithium metal batteries. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T04:31:29Z (GMT). No. of bitstreams: 1 ntu-107-R04527022-1.pdf: 5716778 bytes, checksum: 8fbbfa6ed1a789f36018bee3ad188fb0 (MD5) Previous issue date: 2018 | en |
| dc.description.tableofcontents | 口試委員會審定書 i
致謝 ii 中文摘要 iii Abstract iv 目錄 v 圖索引 viii 表索引 xii 第1章 緒論 1 1.1 研究背景 1 1.2 研究動機 1 第2章 文獻回顧 3 2.1 鋰金屬負極 3 2.1.1 鋰金屬負極的優勢及挑戰 3 2.1.2 鋰枝晶的成長機制 7 2.2 抑制鋰枝晶成長及提升庫倫效率方式 14 2.2.1 電解質改良 14 2.2.2 隔離膜修飾 20 2.2.3 鋰金屬負極保護層 21 2.3 嵌段共聚高分子電解質 29 2.3.1 嵌段共聚高分子的微結構 29 2.3.2 五嵌段共聚高分子 31 2.3.3 嵌段共聚高分子電解質在鋰金屬電池的應用 34 2.4 雙官能基陰離子起始劑 38 第3章 實驗步驟與原理 45 3.1 實驗藥品 45 3.2 實驗儀器 47 3.3 材料製備 49 3.3.1 IISII的合成 50 3.3.2 IISII-OH的合成 52 3.3.3 IISII-SO3Li的合成 54 3.3.4 IISII-SO3Li薄膜置備 54 3.3.5 CR2032鈕扣型電池組裝 55 3.4 材料分析 56 3.4.1 合成鑑定 56 3.4.2 熱分析 56 3.4.3 薄膜微結構分析 57 3.4.4 薄膜機械強度分析 57 3.4.5 薄膜表面接觸角量測 57 3.4.6 薄膜電解液吸收量量測 57 3.4.7 電化學阻抗頻譜分析 58 3.4.8 離子傳導度及鋰離子遷移係數量測 58 3.4.9 電池循環充放電量測 59 3.4.10 鋰金屬表面形貌分析 59 第4章 結果與討論 60 4.1 五嵌段共聚高分子的合成及其末端基改質 60 4.1.1 IISII的鑑定 60 4.1.2 IISII-OH的鑑定 68 4.1.3 IISII-SO3Li的鑑定 70 4.2 IISII-SO3Li薄膜製備 71 4.3 IISII-SO3Li的熱分析 72 4.4 IISII-SO3Li薄膜的微結構 73 4.5 IISII-SO3Li薄膜的機械性質及表面性質 75 4.6 IISII-SO3Li薄膜的電化學性質 78 4.7 Li/IISII-SO3Li/Celgard/LFP鋰金屬電池循環表現 82 4.7.1 鐵氟龍基底製備的薄膜之LFP-Li電池性能測試 82 4.7.2 玻璃基底製備的薄膜之LFP-Li電池性能測試 88 4.8 充放電後的鋰金屬表面形貌分析 93 第5章 結論 94 第6章 未來展望 95 附錄 96 參考文獻 103 | |
| dc.language.iso | zh-TW | |
| dc.subject | 鋰金屬保護層 | zh_TW |
| dc.subject | 鋰金屬電池 | zh_TW |
| dc.subject | 單離子導體 | zh_TW |
| dc.subject | 陰離子聚合法 | zh_TW |
| dc.subject | 五嵌段共聚高分子 | zh_TW |
| dc.subject | 鋰金屬枝晶 | zh_TW |
| dc.subject | Lithium Dendrite | en |
| dc.subject | Anionic Polymerization | en |
| dc.subject | Single-Ion Conductor | en |
| dc.subject | Lithium Metal Batteries | en |
| dc.subject | Protective Layer | en |
| dc.subject | Pentablock Copolymer | en |
| dc.title | 新型態帶有磺酸鋰側鏈之五嵌段共聚高分子:合成及其在鋰金屬電池之應用 | zh_TW |
| dc.title | Novel Pentablock Copolymers Bearing Pendant Lithium Sulfonates: Synthesis and Its Application in Lithium Metal Batteries | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 106-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 戴子安(Chi-An Dai),吳乃立(Nae-Lih Wu),方家振(Chia-Chen Fang) | |
| dc.subject.keyword | 五嵌段共聚高分子,陰離子聚合法,單離子導體,鋰金屬電池,鋰金屬保護層,鋰金屬枝晶, | zh_TW |
| dc.subject.keyword | Pentablock Copolymer,Anionic Polymerization,Single-Ion Conductor,Lithium Metal Batteries,Protective Layer,Lithium Dendrite, | en |
| dc.relation.page | 108 | |
| dc.identifier.doi | 10.6342/NTU201802924 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2018-08-13 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| Appears in Collections: | 材料科學與工程學系 | |
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| ntu-107-1.pdf Restricted Access | 5.58 MB | Adobe PDF |
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