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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 李岳聯 | |
| dc.contributor.author | Chien-Yu Huang | en |
| dc.contributor.author | 黃千彧 | zh_TW |
| dc.date.accessioned | 2021-06-17T03:27:53Z | - |
| dc.date.available | 2023-04-18 | |
| dc.date.copyright | 2018-04-18 | |
| dc.date.issued | 2018 | |
| dc.date.submitted | 2018-03-28 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/69786 | - |
| dc.description.abstract | 本篇論文分為兩部分，第一部分為鋁合金前處理對於石墨烯與鋁合金之間的附著性與抗蝕性影響，第二部分則為多層石墨烯之分散與噴塗對於鋁合金之抗蝕性分析。第一部分中我們以化學氣相沈積法製備單層石墨烯並轉印製鋁合金表面，並使用常見的酸洗液，如硫酸、硝酸、磷酸做鋁合金之酸洗，而後以接觸角儀測量不同液體與不同表面之接觸角，計算出表面能以分析石墨烯與鋁合金表面之附著度。實驗中以拉曼光譜儀分析石墨烯是否具有明顯之缺陷、以極化曲線測定單層石墨烯覆蓋於鋁合金後之抗蝕能力、以原子力顯微鏡分析不同表面處理所造成之鋁合金表面高低起伏，由上述實驗分析出硝酸前處理後鋁合金的表面最適合石墨烯附著。
第二部分我們使用購買之氧化石墨烯分散液，以硼氫化鈉做為還原劑，將氧化石墨烯還原後以高能超音波均質機還原之氧化石墨烯分散至無水酒精中，以噴塗方式將還原之氧化石墨烯噴塗至鋁合金表面，達到多層石墨烯的效果，並以極化曲線分析其抗蝕能力，以原子力顯微鏡觀察其表面形貌、以掃描式電子顯微鏡配以聚焦離子束切割，觀測噴塗之石墨稀薄膜厚度。由此方法有效解決化學氣相沈積法所製備之石墨烯無法大量、大面積合成的問題，以提高石墨烯作為抗蝕塗層之實際應用能力。 | zh_TW |
| dc.description.abstract | This study is divided into two prats. The first part presents an investigation into the effect of surface pretreatment on the electrochemical characteristics and corrosion behavior on graphene coated 6061 aluminum alloy (Al 6061). The corrosion properties of graphene coated 6061 aluminum alloy with different surface pretreatments were studied using electrochemical impedance spectroscopy (EIS), and polarization measurement. Surface morphologies of pretreated and coated samples were analyzed by atomic force microscopy (AFM). The integrity of graphene transferred from the growth Cu substrate was examined by Raman spectroscopy. We also investigated the adhesion between the graphene and Al 6061 by measuring the water and diiodomethane contact angle, and calculating the surface free energy of various pretreated samples.
In the second part, solving the problem that chemical vapor deposition graphene can not be made and transferred in large area, we reduced graphene oxide by NaBH4 and spray it on the surface of 6061 aluminum. The corrosion properties of reduced graphene oxide film is analyzed by potentiodyanmic polarization, and the topography and thickness of reduced graphene oxide film is observed by AFM and scanning electron microscopy (SEM). | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T03:27:53Z (GMT). No. of bitstreams: 1 ntu-107-R05525124-1.pdf: 11104333 bytes, checksum: b97d4c6deb9e639a3618f8144446557c (MD5) Previous issue date: 2018 | en |
| dc.description.tableofcontents | 口試委員會審定書 #
誌謝 I 中文摘要 III ABSTRACT IV 目錄 V 圖目錄 IX 表目錄 XII 第 1 章 前言 1 第 2 章 文獻探討 3 2.1 鋁合金簡介 3 2.1.1 鋁合金種類 3 2.1.2 6061 鋁合金介紹 8 2.2 鋁合金的表面處理 9 2.3 石墨烯簡介 13 2.3.1 石墨烯之性質與應用 13 2.3.2 CVD 石墨烯之抗蝕應用 17 2.3.3 r-GO 之抗蝕應用 22 第 3 章 實驗方法及步驟 27 3.1 試片表面前處理 27 3.2 製程條件 27 3.3 化學氣相沉積法製備石墨烯 28 3.4 Reduced Graphene Oxide (r-GO) 製備 30 3.5 表面性質分析 32 3.5.1 表面能量測 32 3.5.2 拉曼光譜 34 3.6 石墨稀薄膜抗蝕性質分析 35 3.6.1 動電位極化曲線 35 3.7 表面微結構觀察 37 3.7.1 原子力顯微鏡 37 3.7.2 掃描式電子顯微鏡與聚焦離子束 40 第 4 章 實驗結果與討論 42 4.1 材料特性性質分析 42 4.1.1 表面能量測 42 4.1.2 單層石墨烯之拉曼光譜 44 4.2 單層石墨稀薄膜抗蝕性分析 48 4.2.1 極化曲線 48 4.3 單層石墨烯表面形貌觀測 54 4.3.1 AFM觀察 54 4.4 r-GO之物性觀察 59 4.4.1 顏色比較 59 4.4.2 AFM觀察 61 4.5 r-GO之抗蝕性質分析 64 4.5.1 極化曲線 64 4.6 r-GO之微結構觀測 67 4.6.1 SEM 與 FIB 觀察 67 第 5 章 討論 71 第 6 章 結論 75 REFERENCE 78 | |
| dc.language.iso | zh-TW | |
| dc.subject | 石墨烯 | zh_TW |
| dc.subject | 抗蝕 | zh_TW |
| dc.subject | 表面處理 | zh_TW |
| dc.subject | Anticorrosion | en |
| dc.subject | Graphene | en |
| dc.subject | Surface Pretreatment | en |
| dc.title | 石墨烯塗層對鋁合金表面抗蝕性質之影響 | zh_TW |
| dc.title | The Effect of Corrosion Performance for Graphene Coating on 6061 Aluminum Alloy | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 106-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 宋家驥,鄭憶中,簡順億 | |
| dc.subject.keyword | 石墨烯,表面處理,抗蝕, | zh_TW |
| dc.subject.keyword | Graphene,Surface Pretreatment,Anticorrosion, | en |
| dc.relation.page | 85 | |
| dc.identifier.doi | 10.6342/NTU201800706 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2018-03-29 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 工程科學及海洋工程學研究所 | zh_TW |
| 顯示於系所單位： | 工程科學及海洋工程學系 | |
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