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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/69429完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳俊維(Chun-Wei Chen) | |
| dc.contributor.author | Yung-Han Tsai | en |
| dc.contributor.author | 蔡詠涵 | zh_TW |
| dc.date.accessioned | 2021-06-17T03:15:29Z | - |
| dc.date.available | 2023-07-19 | |
| dc.date.copyright | 2018-07-19 | |
| dc.date.issued | 2018 | |
| dc.date.submitted | 2018-07-06 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/69429 | - |
| dc.description.abstract | 二維氧化物是二維材料中的一大類別，而二維氧化物又可以區分成兩個小類：二維金屬氧化物及二維鈣鈦礦氧化物。二維氧化物有相當多元的結構及電性，因其具有量子侷限效應及表面效應，二維氧化物相較於其塊材，具有許多特殊的物理及化學性質，二維氧化物常用於電容、二次電池及催化劑領域中。
Ca2Nb3O10 (CNO)是鈣鈦礦結構的二維氧化物，他是一種N型寬能隙的半導體，其導帶底部位置與常用於太陽能電池吸光層的有機-無機鈣鈦礦接近，因此CNO相當適合作為有機-無機鈣鈦礦太陽能電池的電子傳輸層，用來接收吸光層產生的電子，且不讓電洞進入。此外，相較於一般需要高溫(> 500 ˚C)燒結的二氧化鈦電子傳輸層，CNO的鍍膜僅須相對低溫(< 150 ˚C)的溶劑製程。 本論文中，使用低溫的Langmuir-Blodgett沉積法來製作CNO電子傳輸層，並製做成有機-無機鈣鈦礦太陽能電池，最好的元件效率為14.10%，與一般高溫二氧化鈦電子傳輸層製成的元件效率相當(14.07%)，另外，CNO電子傳輸層擁有更好的電子傳輸能力。論文中證明了CNO是非常有潛力的電子傳輸層，可用來製做全鈣鈦礦結構的太陽能電池。 | zh_TW |
| dc.description.abstract | Two-dimensional (2D) oxides are a large group of 2D materials. These 2D oxides can be divided into two subgroups: 2D metal oxides and 2D perovskite oxides. They are rich in structural diversity, electronic properties, and have novel physical and chemical properties from quantum confinement or surface effects comparing to their bulk states. 2D oxides are widely applied in the nanocapacitors, secondary batteries, and photocatalysts fields.
Among the 2D perovskite oxides, Ca2Nb3O10 (CNO) atomic sheet is an n-type wide bandgap semiconductor. It has well aligned conduction band minimum with that of the lead halide perovskite, which is an efficient light absorber for solar cell application. These properties make CNO a promising electron transport material to extract electrons and block holes from lead halide perovskite light absorber. On the other hand, comparing to the conventional high temperature (> 500 ˚C) sintered compact-TiO2 electron transport layer, CNO can be deposited with relative low temperature (< 150 ˚C) solution process. In this work, we deposited CNO with low temperature Langmuir-Blodgett deposition method as electron transport layer to fabricate perovskite solar cell. The resultant devices showed best efficiency of 14.10%, which is compatible to the conventional high-temperature sintered compact-TiO2 device (14.07%). Moreover, the CNO based devices showed better electron transport ability than the conventional ones. Our work showed that CNO atomic sheet is a highly promising electron transport material for low-temperature solution processed all perovskite structure solar cells. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T03:15:29Z (GMT). No. of bitstreams: 1 ntu-107-R05527026-1.pdf: 4455921 bytes, checksum: 1356a02ca37c50482e34589ac20845b9 (MD5) Previous issue date: 2018 | en |
| dc.description.tableofcontents | 口試委員會審定書 #
TABLE OF CONTENT i 誌謝 ii 中文摘要 iv ABSTRACT v CONTENTS vi LIST OF FIGURES ix LIST OF TABLES xvi Chapter 1 Introduction 1 1.1 Two-dimensional oxide nanosheets 1 1.1.1 Introduction of oxide nanosheets 1 1.1.2 Structure of oxide nanosheets 2 1.1.3 Properties of oxide nanosheets 4 1.2 Solar cells and perovskite solar cells 7 1.2.1 Sun, energy and solar cells 7 1.2.2 Structure and properties of perovskite 9 1.2.3 History of perovskite solar cells 12 1.3 Motivation 15 Chapter 2 Literature Review 16 2.1 Two dimensional oxide materials 16 2.1.1 Synthesis and deposition of oxide nanosheets 16 2.1.2 Application of oxide nanosheets 20 2.2 Perovskite solar cells 25 2.2.1 Deposition of perovskite thin film 25 2.2.2 Device architectures of perovskite solar cells 28 2.2.3 Transport layers in perovskite solar cells 30 2.3 Two-dimensional materials for perovskite solar cells 36 2.3.1 Two-dimensional materials as electrodes 36 2.3.2 Two-dimensional materials as electron transport layers 38 2.3.3 Two-dimensional materials as hole transport layers 40 Chapter 3 Experimental section 42 3.1 Fabrication of perovskite solar cells 42 3.1.1 Synthesis of Ca2Nb3O10 atomic sheet 42 3.1.2 Deposition of Ca2Nb3O10 atomic sheet 43 3.1.3 Device fabrication 44 3.2 Working mechanism of perovskite solar cells 46 3.3 Photovoltaic characteristic 48 3.3.1 Solar spectrum 48 3.3.2 I-V characteristic of the photovoltaic devices 49 3.3.3 Incident photo-to-current efficiency 52 3.4 Characteristic and measurement 54 3.4.1 Transmission electron microscope 54 3.4.2 Scanning electron microscope 55 3.4.3 Atomic force microscopy 56 3.4.4 Photoluminescence and time-resolved photoluminescence 57 Chapter 4 Two-dimensional perovskite oxide atomic sheets as electron transport layer 59 4.1 Introduction 59 4.2 Surface coverage of different layers of Ca2Nb3O10 atomic sheet 62 4.3 Performances of perovskite solar cells with Ca2Nb3O10 atomic sheets 66 4.4 Electron transport properties in Ca2Nb3O10 atomic sheet 71 4.5 Conclusion 76 Chapter 5 Future prospect 77 REFERENCE 79 | |
| dc.language.iso | en | |
| dc.subject | 鈣鈦礦太陽能電池 | zh_TW |
| dc.subject | 電子傳輸層 | zh_TW |
| dc.subject | 二維氧化物 | zh_TW |
| dc.subject | 鈣鈦礦氧化物 | zh_TW |
| dc.subject | Ca2Nb3O10 | zh_TW |
| dc.subject | perovskite oxide | en |
| dc.subject | electron transport layer | en |
| dc.subject | perovskite solar cell | en |
| dc.subject | Ca2Nb3O10 | en |
| dc.subject | Two-dimensional oxide | en |
| dc.title | 原子級厚度之二維鈣鈦礦氧化物在鈣鈦礦太陽能電池中電子傳輸層的應用 | zh_TW |
| dc.title | Two-dimensional atomically thin perovskite oxide as electron transport layer for perovskite solar cells | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 106-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳學禮(Hsuen-Li Chen),闕居振(Chu-Chen Chueh) | |
| dc.subject.keyword | 二維氧化物,Ca2Nb3O10,鈣鈦礦氧化物,鈣鈦礦太陽能電池,電子傳輸層, | zh_TW |
| dc.subject.keyword | Two-dimensional oxide,Ca2Nb3O10,perovskite oxide,perovskite solar cell,electron transport layer, | en |
| dc.relation.page | 94 | |
| dc.identifier.doi | 10.6342/NTU201801306 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2018-07-09 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 材料科學與工程學系 | |
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