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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 鄭如忠 | |
| dc.contributor.author | Ren-Yu Liao | en |
| dc.contributor.author | 廖仁煜 | zh_TW |
| dc.date.accessioned | 2021-06-17T02:22:47Z | - |
| dc.date.available | 2017-08-25 | |
| dc.date.copyright | 2017-08-25 | |
| dc.date.issued | 2017 | |
| dc.date.submitted | 2017-08-19 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/68490 | - |
| dc.description.abstract | 由MDI合成具有反應選擇性的IDD後進一步合成一系列poly(urea/malonamide)直線型與透過收斂法合成樹枝狀陽離子界面活性劑衍生物，之後利用electrostatic interaction與氧化石墨接枝形成複合材料，使用TGA分析其接枝率，發現由於DG-2.5分子較大故有較大的立體障礙使得接枝率最低，並將奈米銀製備在poly(urea/malonamide)與氧化石墨複合材料的羰基官能基上，以UV-Vis以及TEM觀察奈米銀的生成和其附著情形，由TEM圖得知DG-2.5對於奈米銀的分佈和大小控制最好，因為DG-2.5有較多的官能基能穩定奈米銀的大小，相反的直線型的多呈現大小不一甚至聚集的情況，接著將材料取出以breath figure法和直接揮發製成蜂窩狀孔洞膜與平膜後發現只有DG-2.5與DG-1.5有機會形成蜂窩狀孔洞，之後滴上表面增強拉曼效應的待測物R6G，比較不同製程與不同代數以及直線型與樹枝狀結構之間的效應差別，得出DG-2.5為最佳的結果，並討論得出其它組別因為奈米銀成長的大小和分佈不一以及在成膜時較難以或無法形成孔洞，使得加成效應不如DG-2.5
此研究有別於過往一般界面活性劑以及表面增強拉曼效應的應用，在成蜂窩狀孔洞膜時直接分散了奈米銀粒子在膜當中，而不是先成膜再利用化學吸附，因此使得內外都能有奈米銀均勻的分佈，並且導入了氧化石墨增加了一定程度的表面增強拉曼效應，同時也使得所製成的膜能夠承受拉曼測量時的入射光，為首次有研究將界面活性劑與氧化石墨之複合材料應用於表面增強拉曼效應。 | zh_TW |
| dc.description.abstract | A series of linear type and dentritic type poly (urea/malonamide) cationic surfactants synthesized from IDD were successfully prepared as evidenced by NMR. Then, cationic surfactants were chosen to electrostatically adsorb on the negatively charged graphene oxide (GO) to form composites and the content of surfactant can be roughly estimated from TGA results. And DG-2.5 shows the lowest content becasuse DG-2.5 molecules are larger than other derivatives and the steric hindrance effect occurs. With carbonyl group on the poly (urea/malonamide) derivatives, silver nanoparticles can be prepared on the surfactants/GO composties to form the final products and as evidenced by UV-Vis and TEM. Then, the surface-enhanced Raman scattering (SERS) films can be obtained via breath figure process, but only DG-2.5 and DG-1.5 can form honeycomb-like films.
Results show that surface enhancement factors of honeycomb-like substrates are much higher than that of flat-film substrates and DG-2.5 shows the highest enhancement factor >105 because DG-2.5 has the most carbonyl groups on the molucules. Consequetly, the SERS films have been successfully obtained and this work shows the potential of application of surfactants/GO on SERS effect. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T02:22:47Z (GMT). No. of bitstreams: 1 ntu-106-R02549027-1.pdf: 6818267 bytes, checksum: d6f6a2a9104e2742b3f23f92c3f4343c (MD5) Previous issue date: 2017 | en |
| dc.description.tableofcontents | 口試委員會審定書 #
誌謝 i 中文摘要 ii ABSTRACT iii CONTENTS iv LIST OF FIGURES viii LIST OF TABLES xi Chapter 1 緒論 1 Chapter 2 文獻回顧與研究動機 2 2.1 界面活性劑 2 2.1.1 界面活性劑簡介 2 2.1.2 界面活性劑與氧化石墨 2 2.2 蜂窩狀孔洞高分子膜 11 2.2.1 蜂窩狀高分子膜簡介 11 2.2.2 Breath Figure方法簡介 11 2.2.3 Poly(urea/malonamide)dendrons應用於蜂窩狀高分子膜的策略 13 2.3 規則樹枝狀高分子 13 2.3.1 Dendrimer合成路徑 13 2.3.2 Dendrimer結構與特性 15 2.3.3 Dendrimer與線性高分子比較 16 2.3.4 反應選擇性 IDD 製備規則樹枝狀高分子 17 2.4 表面增強拉曼效應 19 2.5 研究動機 21 Chapter 3 實驗內容 22 3.1 藥品及溶劑 22 3.2 實驗儀器 24 3.3 實驗流程圖 26 3.4 異質雙官能基IDD合成及其衍生物 27 3.4.1 IDD之製備 27 3.4.2 poly(urea/malonamide)聚合物之合成 28 3.4.3 兩性型之陽離子界面活性劑合成 28 3.4.3.1 DG0.5之合成 29 3.4.3.2 DG1.0之合成 29 3.4.3.3 DG1.5之合成 29 3.4.3.4 DG2.0之合成 30 3.4.3.5 DG2.5之合成 30 3.4.3.6 LG1.0之合成 30 3.4.3.7 LG1.5之合成 31 3.4.3.8 LG2.0之合成 31 3.4.3.9 LG2.5之合成 32 3.4.3.10 LG3.0之合成 32 3.4.3.11 LG3.5之合成 32 3.4.3.12 Q-DG0.5之合成 33 3.4.3.13 Q-DG1.5之合成 33 3.4.3.14 Q-DG2.5之合成 34 3.4.3.15 Q-LG1.5之合成 34 3.4.3.16 Q-LG2.5之合成 34 3.4.3.17 Q-LG3.5之合成 35 3.5 陽離子界面活性劑與氧化石墨之複合材料製備 35 3.5.1 製備氧化石墨 35 3.5.2 製備陽離子界面活性劑與氧化石墨之複合材料 36 3.5.3 奈米銀之成核點還原 37 3.6 規則蜂窩狀高分子膜之製備 37 3.7 表面增強拉曼效應量測 38 Chapter 4 結果與討論 39 4.1兩性型之陽離子界面活性劑合成 39 4.1.1 Q-DG0.5之合成與結構鑑定 39 4.1.2 Q-DG1.5之合成與結構鑑定 40 4.1.3 Q-DG2.5之合成與結構鑑定 42 4.1.4 Q-LG1.5之合成與結構鑑定 43 4.1.5 Q-LG2.5之合成與結構鑑定 45 4.1.6 Q-LG3.5之合成與結構鑑定 46 4.2 陽離子界面活性劑與氧化石墨複合材料之合成與鑑定 48 4.2.1 陽離子界面活性劑與氧化石墨複合材料之鑑定 48 4.2.2 奈米銀之成核點還原 49 4.3 表面增強拉曼效應量測結果與討論 52 Chapter 5 結論 54 參考文獻 55 附錄 61 合成並鑑定具反應選擇性單體IDD與其衍生物 61 poly(urea/malonamide)聚合物之鑑定 64 DG-0.5之合成與結構鑑定 64 DG-1之合成與結構鑑定 66 DG-1.5之合成與結構鑑定 67 DG-2之合成與結構鑑定 70 DG-2.5之合成與結構鑑定 73 LG-1之合成與結構鑑定 75 LG-1.5之合成與結構鑑定 77 LG-2之合成與結構鑑定 79 LG-2.5之合成與結構鑑定 81 LG-3之合成與結構鑑定 83 LG-3.5之合成與結構鑑定 85 規則蜂窩狀高分子膜之製作88 | |
| dc.language.iso | zh-TW | |
| dc.subject | 氧化石墨烯 | zh_TW |
| dc.subject | 表面增強拉曼效應 | zh_TW |
| dc.subject | 奈米銀粒子 | zh_TW |
| dc.subject | 陽離子界面活性劑 | zh_TW |
| dc.subject | 蜂窩狀孔洞 | zh_TW |
| dc.subject | Cationic surfactant | en |
| dc.subject | surface-enhanced Raman scattering (SERS) | en |
| dc.subject | breath figure | en |
| dc.subject | honeycomb-like films | en |
| dc.subject | graphene oxide | en |
| dc.title | 規則樹枝狀高分子界面活性劑分散氧化石墨烯與成核奈米銀粒子應用於表面拉曼增強效應 | zh_TW |
| dc.title | Dendritic surfactants acting as graphene oxide dispersants and Ag nucleation sites for Surface Enhance Raman Scattering | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 105-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 劉定宇,劉英麟,童世煌,林慶炫 | |
| dc.subject.keyword | 陽離子界面活性劑,蜂窩狀孔洞,表面增強拉曼效應,氧化石墨烯,奈米銀粒子, | zh_TW |
| dc.subject.keyword | Cationic surfactant,surface-enhanced Raman scattering (SERS),breath figure,honeycomb-like films,graphene oxide, | en |
| dc.relation.page | 88 | |
| dc.identifier.doi | 10.6342/NTU201703895 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2017-08-20 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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| ntu-106-1.pdf 未授權公開取用 | 6.66 MB | Adobe PDF |
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