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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳立仁 | |
| dc.contributor.author | Yi-Ting Hsieh | en |
| dc.contributor.author | 謝佾廷 | zh_TW |
| dc.date.accessioned | 2021-06-17T02:18:50Z | - |
| dc.date.available | 2017-08-25 | |
| dc.date.copyright | 2017-08-25 | |
| dc.date.issued | 2017 | |
| dc.date.submitted | 2017-08-21 | |
| dc.identifier.citation | Chen, S. H. and L. J. Chen. “Liquid–liquid equilibria for the ternary system water + octane + 2-butyloxy-ethanol.” Fluid Phase Equilibria 399, 16-21, 2015
Chiu, C. D., L. J. Chen, F. S. Shau, W. J. Cheng and J. G. Wu. “Oil chain-length effect on wetting transitions in ternary water + oil + surfactant mixtures.” J.Phys. Chem. B 106, 12782-12786, 2002. Fleming, P.D. III and J. E. Vinatieri. “The role of critical phenomena in oil recovery systems employing surfactants.” J. Colloid Interface Sci. 81, 319, 1981. Gullickson, N.D., J. F. Scamehorn and J. F. Harwell. Surfactant-based Seperation Process; Scamehorn, J. F., Harwell, J.F., Eds.; Surfactant Science Series 33; Marcel Dekker: New york, 1989; Chapter 6. Herrmann, C. U., G. Klar, and M. Kahlweit, “On the phase inversion in H2O-oil-noninoic surfactant systems and related phenomena.” J. Colloid Interface Sci. 82, 6, 1980. Hu, H. H., C. D. Chiu and L. J. Chen. “Liquid-liquid equilibria for the ternary system water + n-dodecane+ 2-(2-n-hexyloxyethoxy)ethanol.” Fluid Phase Equilibria 164, 187-194, 1999. Hu, H. H. and L. J. Chen. “Liquid-liquid equilibria for the ternary system water + n-tetradecane + 2-(2-n-hexyloxyethoxy)ethanol at 293.15 K and 303.15 K.” J. Chem. Eng. Data 45, 304-307, 2000. Kahlweit, M. “The phase behavior of systems of the type H2O-oil-nonionic surfactant-electrolyte.” Journal of Colloid and Interface Science Vol. 90, 1982 Kahlweit, M., E. Lessner, and R. Strey. “ Influence of the properties of the oil and the surfactant on the phase behavior of systems of the type H2O-oil-nonionic surfactant.” J. Phys. Chem. 87, 5032-5040, 1983 Kahlweit, M. and R. Strey. “Phase behavior of ternary system of the type H2O-oil-nonionic amphiphile (microemulsions),” Angewandte Chemie International Edition in English 24, 654-668, 1985. Kahlweit, M., R. Strey, P. Firman, D. Haase, J. Jen and R. Schomacker. “General patterns of the phase behavior of mixtures of H2O, nonpolar solvents, amphiphiles, and electrolytes.” Langmuir 4, 499-511, 1988. Knickerbocker, B., C. Pesheck, L. Scriven and H. Davis. “Phase behavior of alcohol-hydrocarbon-brine mixtures.” Journal of Physical Chemistry 83, 1984-1990,1979 Liang, X. F., C. Guo, J. H. Ma, J. Wang, S. Chen and H. Z. Liu, “Temperature dependent aggregation and disaggregation of Poly(ethylene oxide) -poly(propylene oxide)-poly(ethylene glycol) Block copolymer in aqueous solution.” J. Phys. Chem. B 111, 13217,2007. Lin, S. Y., C. H. Su and L. J. Chen. “Liquid–liquid equilibria for the binary systems of propylene glycol ether + water measured by the phase volume method.” Journal of the Taiwan Institute of Chemical Engineers 45, 63-67, 2014. Schubert, K.V., R. Strey and M. Kahlweit. “A new purification technique for alkyl polyglycol ethers and miscibility gaps for water-CiEj.” Journal of Colloid and Interface Science 141, 21-29, 1991. Schubert, K. V., G. Busse, R. Strey and M. Kahlweit. “Microemulsions with formamide as polar solvent.” The Journal of Physical Chemistry 97, 248-254, 1993. Scriven, L. E., Micellization, Solubilization and Microemulsion, Vol. 2, K. L. Mittal, Ed., Plenum Press, New York, pp 877, 977. Su, C. H. and L. J. Chen. “Liquid-liquid equilibrium for the ternary system water + dodecane + propylene glycol n-propyl ether.” Journal of Chemical & Engineering Data 56, 589-594, 2011. Su, C. H. and L. J. Chen. “Liquid-liquid equilibria for the ternary system (water + hexadecane + dipropylene glycol n-propyl ether).” Fluid Phase Equilibria 346, 20-24, 2013 Walker, J.S. and C. A. Vause. “Reappearing phases.” Scientific American 256, 98-105, 1987. Winsor, P. A. “Hydrotropy, solubilisation and related emulsification process.” Transactions of the Faraday Society 44, 376-398, 1948 | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/68365 | - |
| dc.description.abstract | 本論文中研究水+油+非離子型界面活性劑在不同溫度下的相行為，使用的油為正癸烷，界面活性劑為CiPj或CiEj，兩者皆為醇醚類化合物。CiPj為CH3(CH2)i-1(OCH2CH(CH3))jOH之縮寫，其中i代表非極性碳氫鏈長度，而j代表丙烯氧基的數目。CiEj為CH3(CH2)i-1(OCH2CH2)jOH之縮寫，i代表的也是碳氫鏈長度，但j代表的是乙烯氧基的數目。我們研究三成分水+正癸烷+C3P2系統在283.15、298.15、313.15 K的相行為，以及三成分水+正癸烷+C6E2系統在283.15、293.15、303.15 K的相行為。將配好的三成分溶液放入恆溫水槽，等待平衡後觀察分相的情形，並使用氣相層析儀分析各相的成分組成，並將結果繪製成共六張三角相圖。其中水+正癸烷+C6E2系統在283.15 K和293.15 K兩個溫度下有三液相平衡區，且在三相區的周圍有三個兩相區；其餘的系統則只有一個大的兩相區。 | zh_TW |
| dc.description.abstract | In this study, we investigate phase behavior of the ternary water + n-decane + nonionic surfactant system. We use two kinds of surfactant, CiPj or CiEj, both are alcohol ethers. CiPj is the abbreviation of CH3(CH2)i-1(OCH2CH(CH3))jOH, the letter i stands for the length of hydrocarbon chain, and j stands for the amount of oxypropylene group. CiEj is the abbreviation of CH3(CH2)i-1(OCH2CH2)jOH, the letter i also stands for the length of hydrocarbon chain, while j stands for the amount of oxyethylene group. We put the sample into the thermostatic water bath, waiting for its equilibrium and observe the phase behavior. Then, we use gas chromatography to analyze each phase’s composition, and plot the results on the ternary diagram. We found out for water + n-decane + C6E2 at 283.15 K and 293.15 K, there will have a three-phase coexisting region, around that region will have three two-phase coexisting region. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-17T02:18:50Z (GMT). No. of bitstreams: 1 ntu-106-R03524073-1.pdf: 2195017 bytes, checksum: 4090b643058680ed7452530495144a5a (MD5) Previous issue date: 2017 | en |
| dc.description.tableofcontents | 摘要 i
Abstract ii 目錄 iii 表目錄 v 圖目錄 vii 第一章 緒論 1 第二章 文獻回顧 4 2-1 三成分水+油+非離子界面活性劑系統的相行為 4 2-2 魚形相圖（Fish-shaped phase diagram） 8 2-3 三角相圖 9 第三章 實驗藥品、設備與實驗方法 16 3-1實驗藥品 16 3-1-1 製作三角相圖用 藥品 16 3-1-2 清潔用 藥品 16 3-2 實驗設備 17 3-2-1 控溫系統 17 3-2-2 氣相層析儀（Gas chromatography） 17 3-2-3 其他儀器 19 3-3 實驗方法 20 3-3-1 製作三角相圖 20 3-3-2 清潔步驟 23 第四章 三成分系統之相行為的實驗結果 25 4-1 氣相層析儀的校正 25 4-2水+正癸烷+C3P2三成分系統的相行為 26 4-3 水+正癸烷+C6E2三成分系統的相行為 27 第五章 結論 49 參考文獻 51 | |
| dc.language.iso | zh-TW | |
| dc.subject | 液-液相平衡 | zh_TW |
| dc.subject | 界面活性劑 | zh_TW |
| dc.subject | 三角相圖 | zh_TW |
| dc.subject | surfactants | en |
| dc.subject | ternary phase diagram | en |
| dc.subject | liquid-liquid equilibrium | en |
| dc.title | 三成分水+正癸烷+界面活性劑C3P2和水+正癸烷+界面活性劑C6E2系統之相行為研究 | zh_TW |
| dc.title | A Study on Phase Behavior of the Ternary Water + N-decane + Surfactant C3P2 and Water + N-decane + Surfactant C6E2 System | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 105-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 黃世宏,程學恒 | |
| dc.subject.keyword | 界面活性劑,三角相圖,液-液相平衡, | zh_TW |
| dc.subject.keyword | surfactants,ternary phase diagram,liquid-liquid equilibrium, | en |
| dc.relation.page | 53 | |
| dc.identifier.doi | 10.6342/NTU201704153 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2017-08-21 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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