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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 楊宗傑 | |
dc.contributor.author | Yuan-Ling Sun | en |
dc.contributor.author | 孫元玲 | zh_TW |
dc.date.accessioned | 2021-06-17T02:18:18Z | - |
dc.date.available | 2020-09-01 | |
dc.date.copyright | 2017-09-13 | |
dc.date.issued | 2017 | |
dc.date.submitted | 2017-08-23 | |
dc.identifier.citation | 參考文獻
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/68346 | - |
dc.description.abstract | 聚甲基丙烯酸甲酯(Polymethylmethacrylate, PMMA)為牙科常見之贗復物材料,多用於活動式局部義齒、全口活動義齒或臨時牙冠等。PMMA其韌性強、剛性較弱之特質,在治療過程中經常與金屬材料搭配使用以加強材料強度,然而PMMA與金屬之鍵結強度極差,必須透過其他黏著塗料作為接著媒介。
本研究將以嘗試不同材料tetraethoxysilane(TEOS)、polydopamine(pDA)改質不鏽鋼金屬表面以提升PMMA與不鏽鋼之黏著強度(bond strength);並以乙醇及丙酮做溶劑,配製不同比例10-methyacryloyloxydecyl dihydrogen phosphate (10-MDP)金屬底劑、調整PMMA之聚合時間及條件,以觀察MDP單體本身之黏著能力,以及尋找較佳之使用方式;此外,亦添加pDA粉末至MDP底劑嘗試改良金屬底劑,以增強黏著強度。 本研究中之黏著強度均由萬能材料試驗機(universal testing machine,Instron-5566)進行剪力黏著強度測試(shear bond strength test),並以電子能譜儀(XPS)分析其斷裂面,以得知其斷裂方式及位置,再使用紅外線光譜儀(ATR-FTIR)檢測PMMA聚合程度,並與剪力黏著強度測試結果比較其相關性。 結果顯示,TEOS分子不論水解或未水解皆無法在不鏽鋼試片上形成適當厚度之完整薄膜,且與不鏽鋼亦無法產生良好鍵結,經由酸洗及鹼洗處理不鏽鋼表面亦無法改善其材料附著能力。自製MDP底劑中,25wt%之MDP底劑且聚合時間為4小時時,可測得Bond strength 11.99±2.4(MPa),為本次所有實驗組別中最佳之黏著強度。在以pDA塗層改質之不鏽鋼試片測試顯示,pDA在不鏽鋼與PMMA間可扮演鍵結之角色,其中5mg/ml dopmaine在所有組別中能達到最佳之黏著強度(2.91±0.7MPa),且polydopamine相較於MDP能有較高之生物相容性,故雖未能超越市售接著劑強度,但仍有其未來發展性。 | zh_TW |
dc.description.abstract | Polymethylmethacrylate(PMMA) have been used more frequently in dental prosthesis, such as removable partial denture, complete denture or temporary crown. The higher toughness and weaker rigidity of PMMA cause that PMMA has to go with metal material, such as stainless steel. However, the bonding strength between PMMA and stainless steel is so weak that the primer should be used as an adhesion media.
Therefore, the purpose of this study is to develop different material—tetraethoxysilane(TEOS), Polydopamine(pDA)—to increase the bonding strength of PMMA and stainless steel; use 10-methyacryloyloxydecyl dihydrogen phosphate(10-MDP) to produce primers with different concentration and try to find a better condition of packing PMMA. Furthermore, we try to enhance bond strength of MDP primer by adding pDA powder. All the bonding strength was tested through shear bond strength test by the universal testing machine(Universal testing machine, Instron-5566). In addition, the analyzation of fracture surface was observed by X-ray photoelectron spectroscopy(XPS)to learned about the fracture type and position , and the degree of polymerization was tested by infrared spectroscopy(ATR-FTIR)was compared with the results of shear bond test to figure out the correlation. The results suggest that TEOS can not form a appropriate thick of film on the stainless steel discs which were even pretreat by acid and alkane. In the group of lab-produce MDP primer, 25wt%MDP whose curing time is 4 hours reveals the highest bond strength in this research. The results of different concentration of dopamine show that 5mg/ml dopamine solution has the highest shear bond strength. Though, the bond strength of 5mg/ml dopamine is not as high as commercial primers’, it literally has better biocompatibility. So, pDA still exhibit its potential for the development of bonding agent in future. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T02:18:18Z (GMT). No. of bitstreams: 1 ntu-106-R04450008-1.pdf: 10856217 bytes, checksum: dc1a14ed549cb51cae55d030b2431dba (MD5) Previous issue date: 2017 | en |
dc.description.tableofcontents | 誌謝 I
摘要 II ABSTRACT III 目錄 IV 圖目錄 VII 表目錄 IX 第1章 前言 1 第2章 文獻回顧 2 2.1 牙科用樹脂與不鏽鋼 2 2.1.1 聚甲基丙烯酸甲酯(polymethyl methacrylate,PMMA) 2 2.1.2 牙科用樹脂材料 3 2.1.3 牙科用合金 5 2.1.4 不鏽鋼金屬材料成分性質與結構 6 2.2 金屬底劑(metal primer) 8 2.2.1 金屬底劑介紹 8 2.2.2 金屬底劑(metal primer)之作用機制 9 2.3 多巴胺(dopamine) 10 2.3.1 聚多巴胺(Polydopamine, pDA) 10 2.4 四乙氧基矽烷(TEOS) 14 2.5 文獻回顧結論 15 第3章 研究動機及目的 16 3.1 研究動機 16 3.2 研究目的 16 第4章 材料與方法 18 4.1 實驗材料 18 4.1.1 實驗藥品 18 4.1.2 市售商品 22 4.2 實驗儀器 24 4.3 PMMA操作及不鏽鋼前處理 25 4.3.1 PMMA接著與聚合 25 4.3.2 實驗樣品製備 26 4.4 剪切黏著力強度測試Shear Bond Strength Test 27 4.4.1 市售金屬底劑試片製備 29 4.4.2 四乙氧基矽烷 (tetraethoxysilane, TEOS) 30 4.4.3 聚多巴胺(polydopamine) 32 4.4.4 不同比例MDP溶液 33 4.4.5 25wt%MDP添加pDA粉末試片製備 34 4.4.6 不同聚合時間 36 4.4.7 水浴及無水浴 37 4.5 PMMA聚合程度測試 39 4.5.1 說明 39 4.5.2 實驗步驟 39 4.6 斷裂面分析 41 4.6.1 說明 41 4.6.2 實驗步驟 41 4.7 實驗材料成分分析 42 4.7.1 以EDS分析不鏽鋼之成分 42 4.7.2 以LC/MS分析市售MDP primer 之成分 42 第5章 結果 43 5.1 剪力黏著力強度測試(Shear bond strength test) 43 5.1.1 市售金屬底劑 43 5.1.2 四乙氧基矽烷 (tetraethoxysilane, TEOS) 45 5.1.3 聚多巴胺塗層(polydopamine coating) 46 5.1.4 不同比例MDP溶液 48 5.1.5 25wt%MDP添加pDA粉末 50 5.1.6 不同聚合時間 51 5.1.7 水浴與無水浴 53 5.2 PMMA聚合程度分析 54 5.3 斷裂面分析 57 5.4 實驗材料成分分析 61 5.4.1 以EDS分析不鏽鋼之成分 61 5.4.2 以LC-MS分析市售MDP primer之成分 63 第6章 討論 64 6.1 剪力黏著力測試 64 6.1.1 市售金屬底劑 64 6.1.2 四乙氧基矽烷(TEOS) 64 6.1.3 聚多巴胺塗層(polydopamine coating) 65 6.1.4 不同比例之MDP金屬底劑 65 6.1.5 25wt%MDP添加pDA粉末 66 6.1.6 不同聚合時間 66 6.1.7 水浴與無水浴 66 6.2 PMMA 聚合程度分析 67 6.3 斷裂面分析 67 6.4 實驗材料成分分析 68 6.4.1 以EDS分析不鏽鋼之成分 68 6.4.2 LC/MS 68 第7章 結論 69 參考文獻 70 | |
dc.language.iso | zh-TW | |
dc.title | 改良不鏽鋼金屬表面及金屬底劑
以提升聚甲基丙烯酸甲酯及不鏽鋼之鍵結強度 | zh_TW |
dc.title | Modified stainless steel surfaces and metal primer
to enhance bond strength between poly(methylmethacrylate) and stainless steels | en |
dc.type | Thesis | |
dc.date.schoolyear | 105-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 李伯訓,鄭國忠,羅世強 | |
dc.subject.keyword | 聚多巴胺,四乙氧基矽烷,聚甲基丙烯酸甲酯,樹脂,不鏽鋼,剪力鍵結強度測試,10-(2-甲基丙烯?氧基)磷酸單癸酯, | zh_TW |
dc.subject.keyword | polydopamine,TEOS,Polymethylmethacrylate,resin,stainless steel,shear bond test,bonding strength, | en |
dc.relation.page | 74 | |
dc.identifier.doi | 10.6342/NTU201703239 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2017-08-23 | |
dc.contributor.author-college | 醫學院 | zh_TW |
dc.contributor.author-dept | 口腔生物科學研究所 | zh_TW |
顯示於系所單位: | 口腔生物科學研究所 |
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