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dc.contributor.advisor | 溫政彥(Cheng-Yen Wen) | |
dc.contributor.author | I-Kuan Lin | en |
dc.contributor.author | 林宜寬 | zh_TW |
dc.date.accessioned | 2021-06-17T02:11:00Z | - |
dc.date.available | 2020-08-24 | |
dc.date.copyright | 2020-08-24 | |
dc.date.issued | 2020 | |
dc.date.submitted | 2020-08-18 | |
dc.identifier.citation | 1. Zheng, Y.; Jiao, Y.; Zhu, Y.; Li, L. H.; Han, Y.; Chen, Y.; Du, A.; Jaroniec, M.; Qiao, S. Z., Hydrogen Evolution by a Metal-free Electrocatalyst. Nat. Commun. 2014, 5 (1), 1-8. 2. Wu, W.; Wang, L.; Yu, R.; Liu, Y.; Wei, S. H.; Hone, J.; Wang, Z. L., Piezophototronic Effect in Single‐Atomic‐Layer MoS2 for Strain‐Gated Flexible Optoelectronics. Adv. Mater. 2016, 28 (38), 8463-8468. 3. David, L.; Bhandavat, R.; Singh, G., MoS2/Graphene Composite Paper for Sodium-Ion Battery Electrodes. ACS Nano 2014, 8 (2), 1759-1770. 4. Stephenson, T.; Li, Z.; Olsen, B.; Mitlin, D., Lithium Ion Battery Applications of Molybdenum Disulfide (MoS2) Nanocomposites. Energy Environ. Sci. 2014, 7 (1), 209-231. 5. Acerce, M.; Voiry, D.; Chhowalla, M., Metallic 1T Phase MoS2 Nanosheets as Supercapacitor Electrode Materials. Nat. Nanotechnol. 2015, 10 (4), 313-318. 6. Radisavljevic, B.; Radenovic, A.; Brivio, J.; Giacometti, V.; Kis, A., Single-Layer MoS2 Transistors. Nat. Nanotechnol. 2011, 6 (3), 147-150. 7. Radisavljevic, B.; Whitwick, M. B.; Kis, A., Integrated Circuits and Logic Operations Based on Single-Layer MoS2. ACS Nano 2011, 5 (12), 9934-9938. 8. Chhowalla, M.; Shin, H. S.; Eda, G.; Li, L.-J.; Loh, K. P.; Zhang, H., The Chemistry of Two-Dimensional Layered Transition Metal Dichalcogenide Nanosheets. Nat. Chem. 2013, 5 (4), 263-275. 9. Bertolazzi, S.; Brivio, J.; Kis, A., Stretching and Breaking of Ultrathin MoS2. ACS Nano 2011, 5 (12), 9703-9709. 10. Elias, D.; Gorbachev, R.; Mayorov, A.; Morozov, S.; Zhukov, A.; Blake, P.; Ponomarenko, L.; Grigorieva, I.; Novoselov, K.; Guinea, F., Dirac Cones Reshaped by Interaction Effects in Suspended Graphene. Nat. Phys. 2011, 7 (9), 701-704. 11. Mayorov, A. S.; Gorbachev, R. V.; Morozov, S. V.; Britnell, L.; Jalil, R.; Ponomarenko, L. A.; Blake, P.; Novoselov, K. S.; Watanabe, K.; Taniguchi, T., Micrometer-Scale Ballistic Transport in Encapsulated Graphene at Room Temperature. Nano Lett. 2011, 11 (6), 2396-2399. 12. Wilson, J. A.; Yoffe, A., The Transition Metal Dichalcogenides Discussion and Interpretation of the Observed Optical, Electrical and Structural Properties. Adv. Phys. 1969, 18 (73), 193-335. 13. Kuc, A.; Zibouche, N.; Heine, T., Influence of Quantum Confinement on the Electronic Structure of the Transition Metal Sulfide TS2. Phys. Rev. B 2011, 83 (24), 245213. 14. Splendiani, A.; Sun, L.; Zhang, Y.; Li, T.; Kim, J.; Chim, C.-Y.; Galli, G.; Wang, F., Emerging Photoluminescence in Monolayer MoS2. Nano Lett. 2010, 10 (4), 1271-1275. 15. Tuxen, A.; Kibsgaard, J.; Gøbel, H.; Lægsgaard, E.; Topsøe, H.; Lauritsen, J. V.; Besenbacher, F., Size Threshold in the Dibenzothiophene Adsorption on MoS2 Nanoclusters. ACS Nano 2010, 4 (8), 4677-4682. 16. Novoselov, K. S.; Jiang, D.; Schedin, F.; Booth, T.; Khotkevich, V.; Morozov, S.; Geim, A. K., Two-Dimensional Atomic Crystals. Proc. Natl. Acad. Sci. 2005, 102 (30), 10451-10453. 17. Joensen, P.; Frindt, R.; Morrison, S. R., Single-Layer MoS2. Mater. Res. Bull. 1986, 21 (4), 457-461. 18. Zeng, Z.; Yin, Z.; Huang, X.; Li, H.; He, Q.; Lu, G.; Boey, F.; Zhang, H., Single‐Layer Semiconducting Nanosheets: High‐Yield Preparation and Device Fabrication. Angew. Chem. 2011, 123 (47), 11289-11293. 19. Coleman, J. N.; Lotya, M.; O’Neill, A.; Bergin, S. D.; King, P. J.; Khan, U.; Young, K.; Gaucher, A.; De, S.; Smith, R. J., Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials. Science 2011, 331 (6017), 568-571. 20. Castellanos-Gomez, A.; Barkelid, M.; Goossens, A.; Calado, V. E.; van der Zant, H. S.; Steele, G. A., Laser-Thinning of MoS2: on Demand Generation of a Single-Layer Semiconductor. Nano Lett. 2012, 12 (6), 3187-3192. 21. Liu, K.-K.; Zhang, W.; Lee, Y.-H.; Lin, Y.-C.; Chang, M.-T.; Su, C.-Y.; Chang, C.-S.; Li, H.; Shi, Y.; Zhang, H., Growth of Large-Area and Highly Crystalline MoS2 Thin Layers on Insulating Substrates. Nano Lett. 2012, 12 (3), 1538-1544. 22. Lee, Y. H.; Zhang, X. Q.; Zhang, W.; Chang, M. T.; Lin, C. T.; Chang, K. D.; Yu, Y. C.; Wang, J. T.; Chang, C. S.; Li, L. J.; Lin, T. W., Synthesis of Large-Area MoS2 Atomic Layers with Chemical Vapor Deposition. Adv. Mater. 2012, 24 (17), 2320-5. 23. Zhou, W.; Yin, Z.; Du, Y.; Huang, X.; Zeng, Z.; Fan, Z.; Liu, H.; Wang, J.; Zhang, H., Synthesis of Few‐Layer MoS2 Nanosheet‐Coated TiO2 Nanobelt Heterostructures for Enhanced Photocatalytic Activities. Small 2013, 9 (1), 140-147. 24. Liu, H.; Antwi, K. A.; Ying, J.; Chua, S.; Chi, D., Towards Large Area and Continuous MoS2 Atomic Layers via Vapor-Phase Growth: Thermal Vapor Sulfurization. Nanotechnology 2014, 25 (40), 405702. 25. Zhan, Y.; Liu, Z.; Najmaei, S.; Ajayan, P. M.; Lou, J., Large‐Area Vapor‐Phase Growth and Characterization of MoS2 Atomic Layers on a SiO2 Substrate. Small 2012, 8 (7), 966-971. 26. Lin, Y.-C.; Zhang, W.; Huang, J.-K.; Liu, K.-K.; Lee, Y.-H.; Liang, C.-T.; Chu, C.-W.; Li, L.-J., Wafer-Scale MoS2 Thin Layers Prepared by MoO3 Sulfurization. Nanoscale 2012, 4 (20), 6637-6641. 27. Lee, Y. H.; Zhang, X. Q.; Zhang, W.; Chang, M. T.; Lin, C. T.; Chang, K. D.; Yu, Y. C.; Wang, J. T. W.; Chang, C. S.; Li, L. J., Synthesis of Large-Area MoS2 Atomic Layers with Chemical Vapor Deposition. Adv. Mater. 2012, 24 (17), 2320-2325. 28. Van Der Zande, A. M.; Huang, P. Y.; Chenet, D. A.; Berkelbach, T. C.; You, Y.; Lee, G.-H.; Heinz, T. F.; Reichman, D. R.; Muller, D. A.; Hone, J. C., Grains and Grain Boundaries in Highly Crystalline Monolayer Molybdenum Disulphide. Nat. Mater. 2013, 12 (6), 554-561. 29. Lee, Y.-H.; Yu, L.; Wang, H.; Fang, W.; Ling, X.; Shi, Y.; Lin, C.-T.; Huang, J.-K.; Chang, M.-T.; Chang, C.-S., Synthesis and Transfer of Single-Layer Transition Metal Disulfides on Diverse Surfaces. Nano Lett. 2013, 13 (4), 1852-1857. 30. Yang, L.; Fu, Q.; Wang, W.; Huang, J.; Huang, J.; Zhang, J.; Xiang, B., Large-Area Synthesis of Monolayered MoS2(1− x)Se2x with a Tunable Band Gap and its Enhanced Electrochemical Catalytic Activity. Nanoscale 2015, 7 (23), 10490-10497. 31. Li, M.-Y.; Shi, Y.; Cheng, C.-C.; Lu, L.-S.; Lin, Y.-C.; Tang, H.-L.; Tsai, M.-L.; Chu, C.-W.; Wei, K.-H.; He, J.-H., Epitaxial Growth of a Monolayer WSe2-MoS2 Lateral pn Junction with an Atomically Sharp Interface. Science 2015, 349 (6247), 524-528. 32. Liu, H.; Wong, S. L.; Chi, D., CVD Growth of MoS2‐Based Two‐Dimensional Materials. Chem. Vap. Depos. 2015, 21 (10-11-12), 241-259. 33. Zou, X.; Zhang, Y., Noble Metal-Free Hydrogen Evolution Catalysts for Water Splitting. Chem. Soc. Rev. 2015, 44 (15), 5148-5180. 34. Ding, Q.; Song, B.; Xu, P.; Jin, S., Efficient Electrocatalytic and Photoelectrochemical Hydrogen Generation Using MoS2 and Related Compounds. Chem 2016, 1 (5), 699-726. 35. Jaramillo, T. F.; Jørgensen, K. P.; Bonde, J.; Nielsen, J. H.; Horch, S.; Chorkendorff, I., Identification of Active Edge Sites for Electrochemical H2 Evolution from MoS2 Nanocatalysts. Science 2007, 317 (5834), 100-102. 36. Zhang, J.; Wu, J.; Guo, H.; Chen, W.; Yuan, J.; Martinez, U.; Gupta, G.; Mohite, A.; Ajayan, P. M.; Lou, J., Unveiling Active Sites for the Hydrogen Evolution Reaction on Monolayer MoS2. Adv. Mater. 2017, 29 (42), 1701955. 37. Hinnemann, B.; Moses, P. G.; Bonde, J.; Jørgensen, K. P.; Nielsen, J. H.; Horch, S.; Chorkendorff, I.; Nørskov, J. K., Biomimetic Hydrogen Evolution: MoS2 Nanoparticles as Catalyst for Hydrogen Evolution. J. Am. Chem. Soc. 2005, 127 (15), 5308-5309. 38. Kong, D.; Wang, H.; Cha, J. J.; Pasta, M.; Koski, K. J.; Yao, J.; Cui, Y., Synthesis of MoS2 and MoSe2 Films with Vertically Aligned Layers. Nano Lett. 2013, 13 (3), 1341-1347. 39. Kibsgaard, J.; Chen, Z.; Reinecke, B. N.; Jaramillo, T. F., Engineering the Surface Structure of MoS2 to Preferentially Expose Active Edge Sites for Electrocatalysis. Nat Mater 2012, 11 (11), 963-9. 40. Li, H.; Tsai, C.; Koh, A. L.; Cai, L.; Contryman, A. W.; Fragapane, A. H.; Zhao, J.; Han, H. S.; Manoharan, H. C.; Abild-Pedersen, F., Activating and Optimizing MoS2 Basal Planes for Hydrogen Evolution Through the Formation of Strained Sulphur Vacancies. Nat. Mater. 2016, 15 (1), 48-53. 41. Zhu, J.; Wang, Z.-C.; Dai, H.; Wang, Q.; Yang, R.; Yu, H.; Liao, M.; Zhang, J.; Chen, W.; Wei, Z., Boundary Activated Hydrogen Evolution Reaction on Monolayer MoS2. Nat. Commun. 2019, 10 (1), 1-7. 42. Ota, K.-I.; Nishigori, S.; Kamiya, N., Dissolution of Platinum Anodes in Sulfuric Acid Solution. J. Electroanal. Chem. Interf. Electrochem. 1988, 257 (1-2), 205-215. 43. Chen, R.; Yang, C.; Cai, W.; Wang, H.-Y.; Miao, J.; Zhang, L.; Chen, S.; Liu, B., Use of Platinum as the Counter Electrode to Study the Activity of Nonprecious Metal Catalysts for the Hydrogen Evolution Reaction. ACS Energy Lett. 2017, 2 (5), 1070-1075. 44. Wei, R.; Fang, M.; Dong, G.; Ho, J. C., Is Platinum a Suitable Counter Electrode Material for Electrochemical Hydrogen Evolution Reaction? Sci. Bull. 2017, 62 (14), 971-973. 45. Koch, C.; Rinke, T. J., Lithography: Theory and Application of Photoresists, Developers, Solvents and Etchants. Microchemicals, Washington, D. C.,(2008/2009): 2006. 46. Bard, A. J.; Faulkner, L. R., Fundamentals and applications. Electrochemical Methods 2001, 2 (482), 580-632. 47. Li, H.; Lu, G.; Yin, Z.; He, Q.; Li, H.; Zhang, Q.; Zhang, H., Optical Identification of Single- and Few-Layer MoS2 Sheets. Small 2012, 8 (5), 682-6. 48. Lee, C.; Yan, H.; Brus, L. E.; Heinz, T. F.; Hone, J.; Ryu, S., Anomalous Lattice Vibrations of Single- and Few-Layer MoS2. ACS Nano 2010, 4 (5), 2695-2700. 49. Li, H.; Zhang, Q.; Yap, C. C. R.; Tay, B. K.; Edwin, T. H. T.; Olivier, A.; Baillargeat, D., From Bulk to Monolayer MoS2: Evolution of Raman Scattering. Adv. Funct. Mater. 2012, 22 (7), 1385-1390. 50. Xu, M.; Fujita, D.; Gao, J.; Hanagata, N., Auger Electron Spectroscopy: a Rational Method for Determining Thickness of Graphene Films. ACS Nano 2010, 4 (5), 2937-2945. 51. Zhang, J.; Yu, H.; Chen, W.; Tian, X.; Liu, D.; Cheng, M.; Xie, G.; Yang, W.; Yang, R.; Bai, X., Scalable Growth of High-Quality Polycrystalline MoS2 Monolayers on SiO2 with Tunable Grain Sizes. ACS Nano 2014, 8 (6), 6024-6030. 52. Tan, L. K.; Liu, B.; Teng, J. H.; Guo, S.; Low, H. Y.; Loh, K. P., Atomic Layer Deposition of a MoS2 Film. Nanoscale 2014, 6 (18), 10584-10588. 53. Yu, Y.; Huang, S. Y.; Li, Y.; Steinmann, S. N.; Yang, W.; Cao, L., Layer-Dependent Electrocatalysis of MoS2 for Hydrogen Evolution. Nano Lett. 2014, 14 (2), 553-8. 54. Li, G.; Zhang, D.; Qiao, Q.; Yu, Y.; Peterson, D.; Zafar, A.; Kumar, R.; Curtarolo, S.; Hunte, F.; Shannon, S., All the Catalytic Active Sites of MoS2 for Hydrogen Evolution. J. Am. Chem. Soc. 2016, 138 (51), 16632-16638. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/67995 | - |
dc.description.abstract | 當今社會,能源上的需求極為重要,在眾多能源當中,氫氣為極具發展潛力的能源。為了更有效利用這些能源,必須尋找合適的催化劑。白金為優秀的催化劑,然而其在地球含量稀少且價格昂貴,限制了它在電解水上的應用。二硫化鉬具有良好的理論產氫效率,且地球含量豐富,為極具潛力之催化劑。此研究中之二硫化鉬使用化學氣相沉積系統成長於二氧化矽基板,透過長時間產氫反應,比較反應前後催化劑的效率改變。產氫反應造成二硫化鉬結構上的破壞,導致催化效率的下降。若以白金作為對電極,金屬沉積會改變催化劑的本質,並參與產氫反應,進而影響催化劑的效率。透過此研究,日後研究在電極的選擇上需更加注意,也對於二硫化鉬於產氫反應之穩定性更加了解。 | zh_TW |
dc.description.abstract | Owing to increasing energy demands, much research has been devoted to developing sustainable energy. Among the methods for harvesting solar energy, hydrogen production through electrocatalysis or photoelectrocatalysis of water splitting is a promising one. For mass production, finding suitable catalysts for the hydrogen evolution reaction (HER) is essential. Platinum is an excellent catalyst for hydrogen production; however, the rare amount of platinum in the earth and its high price limit the use of platinum in industrial applications. Molybdenum disulfide (MoS2) is a potential candidate to replace platinum, because it is of a high theoretic catalytic efficiency and earth abundance. In this research, MoS2 atomic layers are fabricated by chemical vapor deposition (CVD) for the use as the HER catalyst. The HER efficiencies of pristine MoS2 and the MoS2 that has been through a long-term electrochemical reaction are compared. After HER, destruction of the MoS2 structure results in decreased efficiency. In addition, deposition of metal on the working electrode in the electrochemical test also affects the catalytic efficiency. This research provides more insights into the selection of electrode materials for electrochemical reactions. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T02:11:00Z (GMT). No. of bitstreams: 1 U0001-1708202017291600.pdf: 8990370 bytes, checksum: 8241229b0490e62e9d8741241b00341d (MD5) Previous issue date: 2020 | en |
dc.description.tableofcontents | 口試委員會審定書 # 誌謝 i 中文摘要 ii ABSTRACT iii CONTENTS iv LIST OF FIGURES vii LIST OF TABLES xiii Chapter 1 緒論 1 Chapter 2 文獻回顧 2 2.1 二硫化鉬之基礎性質 2 2.1.1 成分及晶體結構 2 2.1.2 機械性質 4 2.1.3 電子性質 4 2.1.4 化學性質 6 2.2 二硫化鉬之製備方法 7 2.2.1 機械劈裂法 8 2.2.2 電化學鋰插層法 8 2.2.3 溶液震盪法 8 2.2.4 化學氣相沉積法 9 2.3 產氫反應 11 2.3.1 產氫反應機制 12 2.3.2 產氫反應之重要參數 13 2.3.3 二硫化鉬之產氫活性位置 15 2.3.4 對電極材料 20 Chapter 3 實驗方法分析儀器 22 3.1 化學氣相沉積法 22 3.1.1 實驗藥品 22 3.1.2 基板清洗 22 3.1.3 化學氣相沉積法系統與製程 22 3.2 產氫元件製作 23 3.2.1 實驗藥品 23 3.2.2 蒸鍍電極 24 3.2.3 轉印 24 3.2.4 旋轉塗佈光阻 24 3.2.5 軟烤 25 3.2.6 曝光 25 3.2.7 顯影 25 3.2.8 硬烤 26 3.3 電化學量測 26 3.3.1 三電極系統 26 3.3.2 線性掃描伏安法 27 3.4 薄膜分析與鑑定 27 3.4.1 光學顯微鏡 27 3.4.2 拉曼光譜 29 3.4.3 光致發光 31 3.4.4 掃描式電子顯微鏡 32 3.4.5 歐傑電子能譜儀 33 3.4.6 穿透式電子顯微鏡 36 Chapter 4 結果與討論 38 4.1 二硫化鉬薄膜成長 38 4.1.1 化學氣相沉積法 38 4.2 電化學量測及分析 40 4.2.1 微電池系統量測及分析 41 4.2.2 改良式電化學系統:以白金作為對電極 44 4.2.3 改良式電化學系統:以碳作為對電極 45 4.2.4 顯微結構分析 47 Chapter 5 結論 50 REFERENCE 51 | |
dc.language.iso | zh-TW | |
dc.title | 二硫化鉬原子層材料於產氫反應之顯微分析 | zh_TW |
dc.title | Microscopic Analysis of Molybdenum Disulfide Atomic Layers in Hydrogen Evolution Reaction | en |
dc.type | Thesis | |
dc.date.schoolyear | 108-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 李紹先(Shao-Sian Li),王迪彥(Di-Yan Wang) | |
dc.subject.keyword | 產氫反應,過渡金屬二硫屬化物,二硫化鉬,化學氣相沉積,穿透式電子顯微鏡, | zh_TW |
dc.subject.keyword | hydrogen evolution reaction,transition metal dichalcogenides,molybdenum disulfide,chemical vapor deposition,transmission electron microscopy, | en |
dc.relation.page | 55 | |
dc.identifier.doi | 10.6342/NTU202003823 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2020-08-19 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
Appears in Collections: | 材料科學與工程學系 |
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