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DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 謝國煌 | |
dc.contributor.author | Yun-Wen Pan | en |
dc.contributor.author | 潘韵文 | zh_TW |
dc.date.accessioned | 2021-06-17T02:00:24Z | - |
dc.date.available | 2022-07-27 | |
dc.date.copyright | 2017-07-27 | |
dc.date.issued | 2017 | |
dc.date.submitted | 2017-07-19 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/67955 | - |
dc.description.abstract | 本研究乃利用N,N’-dicarbazolyl-2,5-benzene (mCP)及N,N’-dicarbazolyl-3,6- benzene (pCP)雙取代咔唑單體作為前驅物,並引入矽苯衍生物經由鈴木-宮浦 (Suzuki-Miyaura) 偶聯反應進行一系列共聚高分子之合成。目前被廣泛使用之磷光主發光體材料幾乎皆含有咔唑 (carbazole)基團,因咔唑擁有良好的電洞傳遞性質與較高的三重態能階。藉由矽原子sp3混成軌域之四面體結構可將共聚物當中之苯環間隔開來,進而中斷高分子主鏈之共軛效應,使高分子之三重態能隙提高並具有良好的熱穩定性質,又於矽苯衍生物側鏈引入巨大的取代基團能抑制分子之相互堆疊,避免客發光體因自我聚集 (self-aggregation) 造成濃度焠熄 (concentration quench) 的現象。
由於多苯環結構剛硬且具有強π-π作用力,經熱示差掃描卡計及熱重分析儀之分析,共聚高分子皆有高玻璃轉移溫度與熱裂解溫度,且透過能量轉移實驗,其高三重態能隙亦可使能量有效傳遞至客發光體,此外,由電化學研究之結果顯示,高分子 mCP-SiCz 與 pCP-SiCz 擁有較高之 HOMO 能階,良好的電洞傳遞性質進而提升高分子發光二極體 (Polymer Light-Emitting Diode, PLED) 之效率。 藍色磷光元件以mCP-SiCz混摻25 %之FIrpic與40 %之Si2OXD有最佳表現,其元件結構為ITO / PEDOT:PSS / mCP-SiCz:FIrpic 20 %:Si2OXD 40 % / Mg / Ag,最大亮度為5158 cd/m2,最高效率達8.32 cd/A。 | zh_TW |
dc.description.provenance | Made available in DSpace on 2021-06-17T02:00:24Z (GMT). No. of bitstreams: 1 ntu-106-R03524040-1.pdf: 11841994 bytes, checksum: e33eb51fc7268b31553e4b084995c3e7 (MD5) Previous issue date: 2017 | en |
dc.description.tableofcontents | 口試委員會審定書 .............................................................................................. i
摘要 ................................................................................................................... ii Abstract............................................................................................................. iii 目錄 .................................................................................................................. iv 圖目錄 .............................................................................................................. vii 表目錄 ............................................................................................................... x 第一章 緒論 ....................................................................................................... 1 1-1 前言 ............................................................................................................. 1 1-2 有機發光二極體之發展與應用 ..................................................................... 2 1-3 研究動機與目的 ........................................................................................... 4 第二章 文獻回顧 ................................................................................................ 5 2-1 有機材料之發光原理 ................................................................................... 5 2-1-1 螢光與磷光理論 ....................................................................................... 5 2-1-2 能量轉移機制 ........................................................................................... 6 2-2 高分子有機發光二極體之原理與結構 .......................................................... 8 2-2-1 電激發光原理 ........................................................................................... 8 2-2-2 電激發光元件結構 .................................................................................... 9 2-3 高分子有機發光二極體元件之材料 ............................................................ 12 2-3-1 陽極與陰極材料 ..................................................................................... 12 2-3-2 電洞與電子注入材料 .............................................................................. 13 2-3-3 電洞傳遞材料 ......................................................................................... 14 2-3-4 電子傳遞材料 ......................................................................................... 16 2-3-5 主發光體材料 ......................................................................................... 19 2-3-6 客發光體材料 ......................................................................................... 22 2-4 分子結構設計 ............................................................................................ 24 第三章 實驗部分 .............................................................................................. 25 3-1 實驗儀器 ................................................................................................... 25 3-2 實驗藥品與溶劑 ......................................................................................... 28 3-2-1 實驗藥品 ................................................................................................ 28 3-2-2 試劑與溶劑.............................................................................................. 31 3-3 合成步驟 ................................................................................................... 32 第四章 結果與討論 .......................................................................................... 57 4-1 高分子合成策略與方法 .............................................................................. 57 4-2 熱性質分析 ................................................................................................ 63 4-3 光學性質分析 ............................................................................................ 66 4-3-1 能量轉移實驗 ......................................................................................... 74 4-4 電化學性質分析 ......................................................................................... 78 4-5 高分子有機發光二極體元件製備與性質探討 .............................................. 83 4-5-1 元件製作流程 ......................................................................................... 84 4-5-2 電激發光元件之最佳化 ........................................................................... 86 4-5-3 mCP-SiC8、pCP-SiC8、mCP-Siph、pCP-Siph 及 pCP-SiCz 電激發光 元件最佳化探討................................................................................................ 92 第五章 結論 ..................................................................................................... 96 第六章 參考文獻 .............................................................................................. 97 附錄 I 化合物之 1H 與13C 核磁共振光譜 ....................................................... 103 附錄 Ⅱ 高分子之 1H 核磁共振光譜 ................................................................. 130 | |
dc.language.iso | zh-TW | |
dc.title | "1,3-及1,4-雙取代咔唑單體與矽苯衍生物共聚高分子之合成及其於高分子有機發光二極體之應用" | zh_TW |
dc.title | Synthesis and Characterization of Polymers with 1,3- and 1,4-Bicarbazole-Substituted Arylsilane Derivatives as Host for Polymer Light Emitting Diodes | en |
dc.type | Thesis | |
dc.date.schoolyear | 105-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 邱文英,莊清男 | |
dc.subject.keyword | 高分子發光二極體,高三重態能隙,?唑,矽苯衍生物,鈴木-宮浦反應, | zh_TW |
dc.subject.keyword | PLED,high triplet energy,carbazole,mCP,arylsilane,Suzuki coupling, | en |
dc.relation.page | 136 | |
dc.identifier.doi | 10.6342/NTU201701580 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2017-07-19 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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