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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 邱勝賢(Sheng-Hsien Chiu) | |
dc.contributor.author | Min-Yen Ku | en |
dc.contributor.author | 古旻諺 | zh_TW |
dc.date.accessioned | 2021-06-17T01:30:14Z | - |
dc.date.available | 2027-12-31 | |
dc.date.copyright | 2017-08-14 | |
dc.date.issued | 2017 | |
dc.date.submitted | 2017-08-03 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/67388 | - |
dc.description.abstract | 以環三聚藜烴為基礎的分子籠可與市售之Sc3N@C80 形成準囚籠錯合物,藉此有效提升Sc3N@C80 在氘-氯仿中的溶解度。該金屬富勒烯的兩結構異構物 (Sc3N@D5h-C80 與 Sc3N@Ih-C80) 被包覆於分子籠內後,可在1H 及13C NMR 光譜中表現不同的特徵訊號,無須使用13C-濃化的樣品即可直接鑑定其結構異構物。 | zh_TW |
dc.description.abstract | A cyclotriveratrylene-based molecular cage forms hemicarceplexes that significantly increase the solubility of commercially available Sc3N@C80 in CDCl3. When incarcerated within the molecular cage, the two structural isomers of this metallofullerene, Sc3N@D5h-C80 and Sc3N@Ih-C80, displayed characteristic signals in both 1H and 13C NMR spectra, allowing direct identification of each isomer without the need to enrich the sample with 13C atoms. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T01:30:14Z (GMT). No. of bitstreams: 1 ntu-106-F00223137-1.pdf: 4687895 bytes, checksum: c55a8a55ef75bf7d5d822b0911a982ba (MD5) Previous issue date: 2017 | en |
dc.description.tableofcontents | 摘要 ..................................................................................... I
Abstract .............................................................................. II 論文發表 ............................................................................ III 目錄 ....................................................................................V 圖目錄 ...............................................................................VII 表目錄 ..............................................................................VIII 流程目錄 ........................................................................... IX 第一章 ................................................................................ 1 1.1 簡介 .............................................................................. 2 1.1.1 超分子化學 ................................................................ 2 1.1.2 富勒烯與金屬富勒烯 .................................................. 3 1.1.3 囚籠與環三聚藜烴 ..................................................... 4 1.1.4 環三聚藜烴與富勒烯 .................................................. 5 1.2 研究動機 ....................................................................... 8 1.3 分子籠設計與準囚籠錯合物之合成 ................................ 9 1.4 (Sc3N@C80)@4 的 1H 及 13C NMR 光譜................. 14 1.5 結論 ............................................................................. 17 第二章 ............................................................................... 19 2.1 車輪烷簡介 .................................................................. 20 2.2 以尿素為辨識單元的車輪烷 ......................................... 22 2.3 研究動機 ...................................................................... 25 2.4 大環分子之合成與鍵結測試 ......................................... 26 2.5 結論 ............................................................................. 30 參考文獻 ............................................................................ 31 附錄 1 ................................................................................ 34 附錄 2 ................................................................................ 56 | |
dc.language.iso | zh-TW | |
dc.title | 利用 NMR 光譜鑑定準囚籠錯合物中的金屬富勒烯之結構異構物 | zh_TW |
dc.title | Hemicarceplex Formation Allows Ready Identification of the Isomers of the Metallofullerene Sc3N@C80 Using 1H and 13C NMR Spectroscopy | en |
dc.type | Thesis | |
dc.date.schoolyear | 105-2 | |
dc.description.degree | 博士 | |
dc.contributor.oralexamcommittee | 陳平(Richard P. Cheng),賴建成(Chien-Chen Lai),李文山(Wen-Shan Li),徐秀福(Hsiu-Fu Hsu) | |
dc.subject.keyword | 環三聚藜烴,準囚籠錯合物,金屬富勒烯,結構異構物, | zh_TW |
dc.subject.keyword | cyclotriveratrylene,hemicarceplex,metallofullerene,structural isomer, | en |
dc.relation.page | 93 | |
dc.identifier.doi | 10.6342/NTU201702481 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2017-08-04 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 化學研究所 | zh_TW |
顯示於系所單位: | 化學系 |
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