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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 廖文彬(Wen-Bin Liau) | |
dc.contributor.author | Po-Chuan Liao | en |
dc.contributor.author | 廖柏筌 | zh_TW |
dc.date.accessioned | 2021-06-17T00:53:07Z | - |
dc.date.available | 2021-02-10 | |
dc.date.copyright | 2020-02-10 | |
dc.date.issued | 2020 | |
dc.date.submitted | 2020-02-04 | |
dc.identifier.citation | 1.陳柏仰, 聚(3-己基噻吩)溶液製備銀金屬與成長機制之探討. 國立臺灣大學材料科學與工程學研究所碩士論文, 2018.
2.李哲瑋, 聚(3-己基噻吩)-銀金屬複合材料之製備與形成機制探討. 國立臺灣大學材料科學與工程學研究所碩士論文, 2013. 3.邱淵, 不同溶劑對聚(3-己基噻吩)-銀金屬複合材料製備與形成機制探討之影響. 國立臺灣大學工學院高分子科學與工程學研究所碩士論文, 2015. 4.黃柏誠, 聚苯乙烯/聚苯胺核殼顆粒還原銀金屬之形貌與成長機制探討. 國立臺灣大學材料科學與工程學研究所碩士論文, 2018. 5.張恒睿, 聚苯胺的導電度對銀金屬還原之影響及其成長機制. 國立臺灣大學材料科學與工程學研究所碩士論文, 2014. 6.H.L. Wang, et al., Tailoring conducting polymer chemistry for the chemical deposition of metal particles and clusters. Chemistry of Materials, 2007. 19(3): p. 520-525. 7.G. Wei, et al., One-step synthesis of silver nanoparticles, nanorods, and nanowires on the surface of DNA network. Journal of Physical Chemistry B, 2005. 109(18): p. 8738-8743. 8.H. Wang, J. Lin, and Z.X. Shen, Polyaniline (PANi) based electrode materials for energy storage and conversion, Journal of Science: Advanced Materials and Devices, 2016. 1(3): p. 225-255. 9.Y.H. Zhang, Y. Duan, and J. Liu, The Effect of Intermolecular Hydrogen Bonding on the Polyaniline Water Complex. Journal of Cluster Science, 2017. 28(3): p. 1071-1081. 10.M. Canales, D. Curco, and C. Aleman, Modeling of Amorphous Polyaniline Emeraldine Base. Journal of Physical Chemistry B, 2010. 114(30): p. 9771-9777. 11.N. Mlalila, H. Swai, A. Hilonga, and D. Kadam, Optimized Preparation of Silver Nanoparticles from Polyethylene Glycol and Formaldehyde. International Research Journal of Pure & Applied Chemistry, 2016. 13: p. 1-9. 12.G.M. Neelgund, et al., Single-step, size-controlled synthesis of colloidal silver nanoparticles stabilized by octadecylamine. Applied Surface Science, 2015. 356: p. 726-731. 13.H. Hiramatsu and F.E. Osterloh, A simple large-scale synthesis of nearly monodisperse gold and silver nanoparticles with adjustable sizes and with exchangeable surfactants. Chemistry of Materials, 2004. 16(13): p. 2509-2511. 14.R.L. Smith, Predicting evaporation rates and times for spills of chemical mixtures. Annals of Occupational Hygiene, 2001. 45(6): p. 437-445. 15.R. Bubbico, and B. Mazzarotta, Predicting evaporation rates from pools. Chemical Engineering Transactions, 2016. 48: p. 49-54. 16.Y.N. Xia, et al., Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics? Angewandte Chemie-International Edition, 2009. 48(1): p. 60-103. 17.V. Germain, et al., Stacking faults in formation of silver nanodisks. Journal of Physical Chemistry B, 2003. 107(34): p. 8717-8720. 18.A.I. Kirkland, et al., STRUCTURAL STUDIES OF TRIGONAL LAMELLAR PARTICLES OF GOLD AND SILVER. Proceedings of the Royal Society of London Series a-Mathematical Physical and Engineering Sciences, 1993. 440(1910): p. 589-609. 19.A.B. Anderson and H.A. Asiri, Reversible potentials for steps in methanol and formic acid oxidation to CO2; adsorption energies of intermediates on the ideal electrocatalyst for methanol oxidation and CO2 reduction. Physical Chemistry Chemical Physics, 2014. 16(22): p. 10587-10599 20.W.M. Haynes, CRC Handbook of Chemistry and Physics, 93rd Edition, 2012. 21.Y. Chu, P. Chen, J. Tang, and P. Rao, Engineer in Situ Growth of α-Al2O3 Whiskers by Axial Screw Dislocations. Crystal Growth & Design, 2017. 22.J. Zhang, F. Huang, and Z. Lin, Progress of nanocrystalline growth kinetics based on oriented attachment. Nanoscale, 2010. 2(1): p. 18-34. 23.F. Huang, H.Z. Zhang, and J.F. Banfield, The role of oriented attachment crystal growth in hydrothermal coarsening of nanocrystalline ZnS. Journal of Physical Chemistry B, 2003. 107(38): p. 10470-10475. 24.H.Z. Zhang and J.F. Banfield, Kinetics of crystallization and crystal growth of nanocrystalline anatase in nanometer-sized amorphous titania. Chemistry of Materials, 2002. 14(10): p. 4145-4154. 25.W.P. Davey, Precision measurements of the lattice constants of twelve common metals. Physical Review, 1925. 25(6): p. 753-761. 26.M. Maillard, S. Giorgio, and M.P. Pileni, Silver nanodisks. Advanced Materials, 2002. 14(15): p. 1084-+. 27.X.S. Shen, et al., Anisotropic Growth of One-Dimensional Silver Rod-Needle and Plate-Belt Heteronanostructures Induced by Twins and hcp Phase. Journal of the American Chemical Society, 2009. 131(31): p. 10812-+ 28.K. Tzou and R.V. Gregory, A METHOD TO PREPARE SOLUBLE POLYANILINE SALT-SOLUTIONS - INSITU DOPING OF PANI BASE WITH ORGANIC DOPANTS IN POLAR-SOLVENTS. Synthetic Metals, 1993. 53(3): p. 365-377. 29.A. Das, Revisiting Stacking Fault Energy of Steels. Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science, 2016. 47A(2): p. 748-768. 30.Y. Gao, et al., Facile synthesis of polyaniline-supported Pd nanoparticles and their catalytic properties toward selective hydrogenation of alkynes and cinnamaldehyde. Chemistry of Materials, 2008. 20(8): p. 2839-2844. 31.P. Xu, et al., Facile Synthesis and Electrical Properties of Silver Wires through Chemical Reduction by Polyaniline. Journal of Physical Chemistry C, 2010. 114(50): p. 22147-22154. 32.D.L. Yang and B.R. Mattes, Polyaniline emeraldine base in N-methyl-2-pyrrolidinone containing secondary amine additives: A rheological investigation of solutions. Journal of Polymer Science Part B-Polymer Physics, 2002. 40(23): p. 2702-2713. 33.A.M. Saxman, R. Liepins, and M. Aldissi, Polyacetylene: Its synthesis, doping and structure. Progress in Polymer Science, 1985. 11(1-2): p.59-89. 34.H. Shirakawa and S. Ikeda, INFRARED SPECTRA OF POLY(ACETYLENE). Polymer Journal, 1971. 2(2): p. 231-+. 35.H. Shirakawa, et al., SYNTHESIS OF ELECTRICALLY CONDUCTING ORGANIC POLYMERS - HALOGEN DERIVATIVES OF POLYACETYLENE, (CH)X. Journal of the Chemical Society-Chemical Communications, 1977(16): p. 578-580. 36.C.K. Chiang, et al., ELECTRICAL-CONDUCTIVITY IN DOPED POLYACETYLENE. Physical Review Letters, 1977. 39(17): p. 1098-1101. 37.J.C. Chiang and A.G. Macdiarmid, POLYANILINE - PROTONIC ACID DOPING OF THE EMERALDINE FORM TO THE METALLIC REGIME. Synthetic Metals, 1986. 13(1-3): p. 193-205. 38.臺大化學系普化教學組, 導電塑膠聚苯胺. 2015. 39.B.A. Averill and P. Eldredge, Principles of General Chemistry. 2004. 40.工業技術研究院材料與化工研究所知識推廣室, 共軛性導電高分子材料技術簡介. 工業材料雜誌, 2010. 288 期. 41.D.R. Askeland, et al., The Science and Engineering of Materials. 1996. 42.L. Beverina, G.A. Pagani, and M. Sassi, Multichromophoric electrochromic polymers: colour tuning of conjugated polymers through the side chain functionalization approach. Chemical Communications, 2014. 50(41): p. 5413-5430. 43.J.L. Bredas and G.B. Street, Polarons, bipolarons, and solitons in conducting polymers. Accounts of Chemical Research, 1985. 18(10): p. 309-315. 44.G. Sonmez, et al., A red, green, and blue (RGB) polymeric electrochromic device (PECD): The dawning of the PECD era. Angewandte Chemie-International Edition, 2004. 43(12): p. 1498-1502. 45.A. Kotwal and C.E. Schmidt, Electrical stimulation alters protein adsorption and nerve cell interactions with electrically conducting biomaterials. Biomaterials, 2001. 22(10): p. 1055-1064. 46.B. Lakard, et al., Effect of ultrasounds on the electrochemical synthesis of polypyrrole, application to the adhesion and growth of biological cells. Bioelectrochemistry, 2009. 75(2): p. 148-157. 47.T.J. Rivers, T.W. Hudson, and C.E. Schmidt, Synthesis of a novel, biodegradable electrically conducting polymer for biomedical applications. Advanced Functional Materials, 2002. 12(1): p. 33-37. 48.W.H. Kim, et al., Molecular organic light-emitting diodes using highly conducting polymers as anodes. Applied Physics Letters, 2002. 80(20): p. 3844-3846. 49.T. Erb, et al., Correlation between structural and optical properties of composite polymer/fullerene films for organic solar cells. Advanced Functional Materials, 2005. 15(7): p. 1193-1196. 50.A. Tsumura, H. Koezuka, and T. Ando, MACROMOLECULAR ELECTRONIC DEVICE - FIELD-EFFECT TRANSISTOR WITH A POLYTHIOPHENE THIN-FILM. Applied Physics Letters, 1986. 49(18): p. 1210-1212. 51.A. Ohtani, et al., Synth. Met., 1993. 55-57: p. 3696. 52.A. Mirmohseni and A. Oladegaragoze, Anti-corrosive properties of polyaniline coating on iron. Synthetic Metals, 2000. 114(2): p. 105-108. 53.A. Olad and H. Rasouli, Enhanced corrosion protective coating based on conducting polyaniline/zinc nanocomposite. Journal of Applied Polymer Science, 2009. 115(4): p. 2221-2227. 54.Y. Wei, et al., Polyaniline as corrosion protection coatings on cold rolled steel. Polymer, 1995. 36(23): p. 4535-4537 55.L.Y. Yang, and W.B. Liau, Environmental responses of polyaniline inverse opals:Application to gas sensing. Synthetic Metals, 2010. 160, p. 609-614. 56.L.Y. Yang, and W.B. Liau, Environmental responses of nanostructured polyaniline films based on polystyrene–polyaniline core–shell particles. Synthetic Metals, 2009. 115, p. 28-32. 57.B. Malhotra, C. Dhand, R. Lakshminarayanan, N. Dwivedi, S. Mishra, P. Solanki, V. Mayandi, R. Beuerman, and S. Ramakrishna, Polyaniline-based biosensors. Nanobiosensors in Disease Diagnosis, 2018. 4(25). 58.O. Abreu, J. Larrieux, and K. Levon, Ionophore/Lipid Bilayer Assembly on Soft Organic Electrodes for Potentiometric Detection of K+ Ions. Aspects on Fundaments and Applications of Conducting Polymers, 2012 59.M.C. Bernard and V.T. Bich, Synth. Met., 1999. 101: p. 811. 60.A. Lodha, et al., Effect of annealing on electrical conductivity and morphology of polyaniline films. Journal of Applied Polymer Science, 2001. 82(14): p. 3602-3610. 61.K. Tzou and R.V. Gregory, MECHANICALLY STRONG, FLEXIBLE HIGHLY CONDUCTING POLYANILINE STRUCTURES FORMED FROM POLYANILINE GELS. Synthetic Metals, 1993. 55(2-3): p. 983-988. 62.D.L. Yang and B.R. Mattes, Polyaniline emeraldine base in N-methyl-2-pyrrolidinone containing secondary amine additives B - Characterization of solutions and thin films. Synthetic Metals, 2002. 129(3): p. 249-260. 63.D.L. Yang, G. Zuccarello, and B.R. Mattes, Physical stabilization or chemical degradation of concentrated solutions of polyaniline emeraldine base containing secondary amine additives. Macromolecules, 2002. 35(13): p. 5304-5313. 64.H. Letheby, XXIX.-On the production of a blue substance by the electrolysis of sulphate of aniline. Journal of the Chemical Society, 1862. 15(0): pp. 161-163. 65.P.N. Adams, P.J. Laughlin, and A.P. Monkman, Synthesis of high molecular weight polyaniline at low temperatures. Synthetic Metals, 1996. 76(1): pp. 157-160. 66.H. Goto, et al., J. Chem. Educ., 2008. 85: p. 1067. 67.L.L. Lu, et al., Free-Standing Copper Nanowire Network Current Collector for Improving Lithium Anode Performance. Nano Letters, 2016. 16(7): p. 4431-4437. 68.J.Y. Piquemal, et al., One-step construction of silver nanowires in hexagonal mesoporous silica using the polyol process. Materials Research Bulletin, 2003. 38(3): p. 389-394. 69.Y.G. Sun, et al., Polyol synthesis of uniform silver nanowires: A plausible growth mechanism and the supporting evidence. Nano Letters, 2003. 3(7): p. 955-960. 70.Y.G. Sun, et al., Uniform silver nanowires synthesis by reducing AgNO3 with ethylene glycol in the presence of seeds and poly(vinyl pyrrolidone). Chemistry of Materials, 2002. 14(11): p. 4736-4745. 71.C.J. Murphy, et al., One-dimensional colloidal gold and silver nanostructures. Inorganic Chemistry, 2006. 45(19): p. 7544-7554. 72.T.K. Huang, et al., Growth of Cu nanobelt and Ag belt-like materials by surfactant-assisted galvanic reductions. Langmuir, 2007. 23(10): p. 5722-5726. 73.H. Choi and S.H. Park, Seedless growth of free-standing copper nanowires by chemical vapor deposition. Journal of the American Chemical Society, 2004. 126(20): p. 6248-6249. 74.M.Y. Yen, et al., Synthesis of cable-like copper nanowires. Advanced Materials, 2003. 15(3): p. 235-+. 75.D. Chirvase, et al., Electrical and optical design and characterisation of regioregular poly(3-hexylthiophene-2,5diyl)/fullerene-based heterojunction polymer solar cells. Synthetic Metals, 2003. 138(1-2): p. 299-304. 76.P. Xu, et al., Multifunctional polymer-metal nanocomposites via direct chemical reduction by conjugated polymers. Chemical Society Reviews, 2014. 43(5): p. 1349-1360. 77.D.A. Porter and K.E. Easterling, Phase Transformations in Metals and Alloys, SECOND EDITION, 1981: pp. 185-197. 78.L. Ratke, and P.W. Voorhees, Growth and Coarsening. Ostwald Ripening in Material Processing, 2002: pp. 117-118. 79.R.L. Penn and J.F. Banfield, Imperfect oriented attachment: Dislocation generation in defect-free nanocrystals. Science, 1998. 281(5379): p. 969-971. 80.S.B. Simonsen, et al., Direct Observations of Oxygen-induced Platinum Nanoparticle Ripening Studied by In Situ TEM. Journal of the American Chemical Society, 2010. 132(23): p. 7968-7975. 81.D. Paramelle, et al., A rapid method to estimate the concentration of citrate capped silver nanoparticles from UV-visible light spectra. Analyst, 2014. 139(19): p. 4855-4861 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/66715 | - |
dc.description.abstract | 聚苯胺具有氧化還原的性質,中間氧化態的聚苯胺其氧化還原電位可以將銀離子還原成銀原子。此外,我們發現作為凝膠化抑制劑(gel inhibitor)加入聚苯胺溶液中的HPMI(heptamethyleneimine)同樣可以還原銀離子。在我們的系統中,聚苯胺與HPMI都與銀金屬的還原有密不可分的關係。
本研究以鹼式中間氧化態聚苯胺(emeraldine base, EB)製備薄膜,利用薄膜作為基板於硝酸銀的甲醇溶液中還原出網狀銀金屬。本文旨在探討此系統中銀網結構成長機制。經XRD及TEM的鑑定發現此網狀銀金屬的晶體方位排列具有高度的一致性,且主要晶面為{111}面族並以<110>的晶面成長方向。我們建立起銀金屬的成核成長模型,透過對於成核成長速度的調控,我們可以成長出不同型態的銀金屬,包含三角或六角片狀、銀帶、銀網等結構。另外藉由調控EB薄膜中的HPMI含量,來釐清聚苯胺與HPMI在反應過程中各自的角色。 | zh_TW |
dc.description.abstract | Polyaniline has redox properties. Emeraldine state of polyaniline can be the reducing agent to silver ions. Furthermore, we find that HPMI (heptamethyl-leneimine), as a kind of gel inhibitor for polyaniline solution, is the reducing agent to silver ions, too. In our systems, both polyaniline and HPMI are important to the reduction of silver ions.
In this study, emeraldine base(EB) is made into films. We put the film into silver nitrate methanol solution to make mesh-liked silver. This thesis is aimed to investigate the mechanism of the mesh-like silver. Through XRD and TEM diffraction pattern, it was found that the structure of the mesh-liked silver has a high degree of crystal orientation consistency, and the main crystal faces are the {111} face family and the <110> crystal face growth direction. We constructed the nucleation-growth competition model. Through the control of nucleation and growth rate, we can synthesize different type of silver, included triangular or hexangular silver plate, belt-like silver and mesh-like silver. Also, we adjusted the content of HPMI in the EB film to clarify the role of polyaniline and HPMI in the experiments. | en |
dc.description.provenance | Made available in DSpace on 2021-06-17T00:53:07Z (GMT). No. of bitstreams: 1 ntu-109-R06527018-1.pdf: 10148993 bytes, checksum: 3e92f39346a724de4faf54cca833ed64 (MD5) Previous issue date: 2020 | en |
dc.description.tableofcontents | 第一章 緒論 1
第二章 文獻回顧 2 2-1 導電高分子 2 2-1-1 發展歷史 2 2-1-2 導電原理 3 2-2 聚苯胺 7 2-2-1 特性 8 2-2-2 聚苯胺的溶劑 9 2-3 一維銀金屬 14 2-3-1 銀金屬簡介與應用 14 2-3-2 一維銀金屬 14 2-3-3 聚(3-己基噻吩)還原一維銀金屬 16 2-3-4 聚苯胺還原一維銀金屬 20 2-4 銀金屬的成核成長 24 2-4-1 金屬材料的結晶行為 24 2-4-2 Ostwald ripening與oriented attachment 29 2-5 研究動機 33 第三章 實驗 34 3-1 實驗藥品 34 3-2 實驗儀器 36 3-3 實驗方法 38 第四章 結果與討論 41 4-1 EB薄膜與硝酸銀反應 41 4-1-1 溶劑的選擇 41 4-1-2 EB薄膜與硝酸銀甲醇溶液反應 44 4-2 HPMI還原銀實驗 49 4-2-1 HPMI的角色確認 49 4-2-2 HPMI還原銀實驗 52 4-3 Ex-situ SEM觀察銀網的成長 58 4-4 EB薄膜成長出銀帶、銀網機制之建立 66 4-5 EB的薄膜形態與組成成分影響 72 4-6 銀網的TEM鑑定 79 4-6-1 銀網的TEM鑑定簡介 79 4-6-2 EB薄膜(EB:HPMI=1:0.5)還原之銀網TEM 88 4-6-3 EB薄膜(EB:HPMI=1:1)還原之銀網TEM 92 4-7 EB薄膜HPMI控制 98 第五章 結論 104 參考文獻 105 | |
dc.language.iso | zh-TW | |
dc.title | 以去摻雜聚苯胺薄膜製備網狀銀金屬與成長機制的探討 | zh_TW |
dc.title | Preparation and growth mechanism of mesh-liked silver by emeraldine base film | en |
dc.type | Thesis | |
dc.date.schoolyear | 108-1 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 顏鴻威(Hung-Wei Yen),曾勝茂 | |
dc.subject.keyword | 聚苯胺,硝酸銀,奈米銀帶,網狀結構,HPMI,成長機制, | zh_TW |
dc.subject.keyword | polyaniline,silver nitrate,silver nanowire,mesh-like structure,HPMI,growth mechanism, | en |
dc.relation.page | 112 | |
dc.identifier.doi | 10.6342/NTU202000318 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2020-02-04 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
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