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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 駱尚廉(Shang-Lien Lo) | |
dc.contributor.author | Zong-Long Lin | en |
dc.contributor.author | 林宗龍 | zh_TW |
dc.date.accessioned | 2021-06-16T23:53:44Z | - |
dc.date.available | 2014-08-09 | |
dc.date.copyright | 2012-08-09 | |
dc.date.issued | 2012 | |
dc.date.submitted | 2012-07-19 | |
dc.identifier.citation | 參考文獻
Balej, J. and Regner, A.(1960) 'Loslichkeit von kalimpersulfate in water'. Collection of Czechoslovak Chemical Communications, 25, 1685-1687. Behrman, E. J., and Dean, D.H.(1999) 'Sodium peroxydisulfate is a stable and cheap substitute for ammonium peroxydisulfate (persulfate) in polyacrylamide gel electrophoresis.' Journal of Chromatography B, 723 (1-2), 325-326. Berlin, A.A., Kislenko, V.N., and Gitman, A.Y.(1986) 'Kinetic peculiarities of persulfate decomposition in the presence of salts of sarboxylic-acids.' Ukrainskii Khimicheskii Zhurnal, 52(8), 827-831. Buxton, G.V., Greenstock , C.L., Helman, W.P. and Ross, A.B.(1988) 'Critical-review of rate constants for reactions of hydrated electrons, hydrogen-atoms and hydroxyl radicals in aqueous-solution.' Journal of Physical and Chemical Reference Data, 17(2), 513-886. Cahill, T.M., Thomas, C.M., Schwarzbach, S.E., and Seiber, J.N.(2001) 'Accumulation of trifluoroacetate in seasonal wetlands in California.' Environmental Science & Technology, 35(5), 820-825. Faria, P.C.C., Orfao, J.M. and Pereir, M.F.R.(2009) 'Activated carbon and ceria catalysts applied to the catalytic ozonation of dyes and textile effluents.' Applied Catalysis B-Environmental, 88 (3-4), 341-350. Fujii, S., Polprasert, C.S., Tanaka, N. Lien, P.H, and Qiu, Y.(2007) 'New POPs in the water environment: distribution, bioaccumulation and treatment of perfluorinated compounds - a review paper.' Journal of Water Supply Research and Technology-Aqua, 56(5), 313-326. Gauden, P. A., Szmechtig-Gauden, E., Rychlicki, Duber, G.S., Garbacz, J. K. and Buczkowski, R.(2006) 'Changes of the porous structure of activated carbons applied in a filter bed pilot operation.' Journal of Colloid and Interface Science, 295 (2), 327-347. Georgi, A., and Kopinke, F.D.(2005) 'Interaction of adsorption and catalytic reactions in water decontamination processes Part I. Oxidation of organic contaminants with hydrogen peroxide catalyzed by activated carbon.' Applied Catalysis B-Environmental, 58(1-2), 9-18. Gilliland, F.D. and Mandel, J.S.(1993)'Mortality among employees of a perfluorooctanoic acid production plant.'Journal of Occupational and Environmental Medicine, 35, 950-954. Goulden, P.D., and Anthony, D.H.J.(1978) 'Kinetics of uncatalyzed peroxydisulfate oxidation of organic material infresh-water.' Analytical Chemistry, 50(7), 953-958. Hansen K.J., Luebeker, D.J., Bass, N.M., Butenhoff, J. L., Secat, A.M.(2002) 'Interactions of fluorochemicals with rat liver fatty acid-binding protein.' Toxicology, 15(3), 175-185. Hansen, K.J., Johnson, H.O., Eldrige, J.S., Butenhoff, J.L. and Dick, L.A. (2002) 'Quantitative characterization of trace levels of PFOS and PFOA in the Tennessee river'. Environmental Science & Technology, 36, 1681-1685. Hekster, F.M., Laane, R. and Voogt, D.(2003) 'Environmental and toxicity effects of perfluoroalkylated substances.' Reviews of Environmental Contamination and Toxicology, 179, 99-121. Hori, H., Hayakawa, E., Einaga, H., Kutsuna , S., Koike K., Ibusuki , T., Kiatagawa, H. and Arakawa, R.(2004) 'Decomposition of environmentally persistent perfluorooctanoic acid in water by photochemical approaches.' Environmental Science & Technology, 38(22), 6118-6124. Hori, H., Yamamoto, A., Hayakawa, E., Taniyasu, S., Yamashita, N., Kutsuna, S.(2005) 'Efficient decomposition of environmentally persistent perfluorocarboxylic acids by use of persulfate as a photochemical oxidant.' Environmental Science & Technology, 39(7), 2383-2388. Hori, H., Nagaoka, Y., Murayama, M. and Kutsuna, S.(2008) 'Efficient decomposition of perfluorocarboxylic acids and alternative fluorochemical surfactants in hot water.' Environmental Science & Technology, 42(19), 7438-7443. Horng, R.S., and Tseng, I.C.(2008) 'Regeneration of granular activated carbon saturated with acetone and isopropyl alcohol via a recirculation process under H2O2/UV oxidation.' Journal of Hazardous Materials, 154(1-3), 366-372. House, D.A.(1962) 'Kinetics and mechanism of oxidations by peroxydisulfate.' Chemical Reviews, 62(3), 185. Huang, K.C., Couttenye, R.A., and Hoag, G.E.(2002) 'Kinetics of heat-assisted persulfate oxidation of methyl tert-butyl ether (MTBE).' Chemosphere, 49(4), 413-420. Huang, K.C., Hoag, G.E., Chheda, P., Woody, B.A. and Dobbs, G.M.(2001) 'Oxidation of chlorinated ethenes by potassium permanganate: a kinetics study.' Journal of Hazardous Materials, 87(1-3), 155-169. Huie, R.E., and Clifton, C.L.(1990) 'Temperature-dependence of the rate constants for reactions of the sulfate radical, SO4-, with anions.' Journal of Physical Chemistry, 94(23), 8561-8567. Huie, R.E., Clifton, C.L. and Neta, P.(1991) 'Electron-transfer reaction-rates and equilibria of the carbonate and sulfate radical-anions.' Radiation Physics and Chemistry, 38(5), 477-481. Huling, S.G., and Hwang, S.(2010) 'Iron amendment and fenton oxidation of MTBE-spent granular activated carbon.' Water Research, 44(8), 2663-2671. Kim, I.K., and Huang, C.P.(2005) 'Sonochemical degradation of polycyclic aromatic sulfur hydrocarbons (PASHs) in aqueous solutions exemplified by benzothiophene.' Journal of the Chinese Institute of Engineers, 28(7), 1107-1118. Kolthoff, I.M. and Miller, I.K.(1951) 'The Chemistry of persulfate, the kinetics and mechanism of the decomposition of the persulfateion in aqueous medium.' Journal of the American Chemical Society, 73 (7), 3055-3059. Legan, R.W.(1982) 'Ultraviolet-light takes on cpi role.' Chemical Engineering, 89(2), 95-100. Liang, C.J., Bruell, C.J. Marley, M.C., and Sperry, K.L.(2003) 'Thermally activated persulfate oxidation of trichloroethylene (TCE) and 1,1,1-trichloroethane (TCA) in aqueous systems and soil slurries.' Soil & Sediment Contamination, 12(2), 207-228. Liang, C.J., Lin, Y.T., and Shih, W.H.(2009) 'Treatment of Trichloroethylene by Adsorption and Persulfate Oxidation in Batch Studies.' Industrial & Engineering Chemistry Research, 48(18), 8373-8380. Liang, C.J., and Su, H.W.(2009) 'Identification of Sulfate and Hydroxyl Radicals in Thermally Activated Persulfate.' Industrial & Engineering Chemistry Research, 48(11), 5558-5562. Liang, C.J., Wang, Z.S. and Bruell, C.J.(2007) 'Influence of pH on persulfate oxidation of TCE at ambient temperatures.' Chemosphere, 66(1), 106-113. Liang, C.J., Wang, Z.S. and Mohant, N.Y.(2006) 'Influences of carbonate and chloride ions on persulfate oxidation of trichloroethylene at 20 degrees C.' Science of the Total Environment, 370(2-3), 271-277. Martin, J.W., Franklin, J. Hanson, M.L., Solomon, K.R., Mabury, S.A. Ellis, D. A., Scott, B.F. and Muir, D.C.G.(2000) 'Detection of chlorodifluoroacetic acid in precipitation: A possible product of fluorocarbon degradation.' Environmental Science & Technology, 34(2), 274-281. Martin, J.W.(2003) ' Environmental (per-)halogenated acid: dection, distribution and bioaccumulation'. Ph.D. Dissertation, University of Guelph, Canada. Moore, J., Rodericks, J., Turnbul, D., Warren-Hicks, W.(2003) ' Environmental and health assessment of perfluorooctane sulfonic acid and its Salts.' 3M Company. Moriwaki, H., Takagi, Y., Tanaka, M. K. Tsuruho, K., Okitsu and Maeda , Y. (2005) 'Sonochemical decomposition of perfluorooctane sulfonate and perfluorooctanoic acid.' Environmental Science & Technology, 39(9), 3388-3392. Osgerby, I.T.(2006) 'ISCO technology overview: Do you really understand the chemistry. ' Contaminated Soils, Sediments and Water, Massachusetts, Amherst, 10, 287-308. Organisation for Economic Co-operation and Development, (2002)'Hazard assessment of perfluorooctane sulfonate and its salts, environment directorate joint meeting of the chemicals committe and the working party on chemicals, Pesticides and Biothechnology,' Paris, France. Qiu,Y.(2007)'Study on treatment technologies for perfluorochemicals in wastewater.' Ph.D dissertation, University of Kyoto, Japan. Qu,Y., Zhang, C., Li, F., Bo, X., Liu, G., Zhou, Q.(2009) 'Equilibrium and kinetics study on the adsorption of perfluorooctanoic acid from aqueous solution onto powdered activated carbon.' Journal of Hazardous Materials, 169 (1-3), 146-152. Renner, R.(2006) 'It's in the microwave popcorn, not the teflon pan.' Environmental Science & Technology, 40(1), 4. Schroder, H. F. and Meesters, R.J.W.(2005) 'Stability of fluorinated surfactants in advanced oxidation processes - A follow up of degradation products using flow injection-mass spectrometry, liquid chromatography-mass spectrometry and liquid chromatography-multiple stage mass spectrometry.' Journal of Chromatography, 1082 (1), 110-119. Taves, D.R.(1968) 'Evidence that there are 2 forms of fluoride in human serum.' Nature, 217(5133), 1050. Truax, C.T.(1993) 'Investigation of the in situ KMnO4 oxidation of resdual DNAPLs located below the groundwater table'. Master Thesis, University of Waterloo, Canada. US-EPA(2002)'Perfluorooctyl sulfonates, proposed significant new use rule.' Part 721, USA. Yang, X., Yang, S.Y., Wang, L.L., Shao, X.T., Niu, R., Shan, L. and Zhang, W.Y.(2011) 'Activated carbon catalyzed persulfate oxidation of azo dye acid orange 7 in aqueous solution.' Huanjing Kexue, 32(7), 1960-1966. Yu, Q., Zhang, R.Q., Deng, S.B., Huang, J., and Yu, G.(2009) 'Sorption of perfluorooctane sulfonate and perfluorooctanoate on activated carbons and resin: kinetic and isotherm study.' Water Research, 43(4), 1150-1158. 3M company (2000) 'Work in progress on environmental fate and transport'. 3M company (2001) 'Environmental monitoring-multi-city study. Water, sludge, sediment, POTW effuent and landfill leachate samples.' 3M company (2002) 'Final report, perfluorooctanesulfonate, potassium salt (PFOS): a flow-through bioconcentration test with bluegill (Lepomis macrochirus) by Wildlife International Ltd.' 行政院環保署,(2006),「毒性化學物質管理法」。 李維豐、黃宛淇、廖述良,(2006)「我國全氟辛烷磺酸鹽管理制度與策略之探討」中華民國環境工程學會環境規劃與管理研討會。 李維豐,(2006),「全氟辛烷磺酸鹽有效管理制度與策略之研究以臺灣為例」,碩士論文,國立中央大學環境工程研究所。 李育輯,(2010),「微波活化過硫酸鹽破壞去除水中全氟辛酸之研究」,博士論文,國立臺灣大學環境工程學研究所。 行政院環保署,(2010),「環境檢驗電子報」。 林怡伶,(2011),「利用過硫酸鹽在室溫下氧化全氟辛酸之研究」,碩士論文,國立臺灣大學環境工程學研究所 。 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/65610 | - |
dc.description.abstract | This research is to decomposition of persistant and bioaccumulative perfluorooctanoic acid(PFOA) in water with activated-carbon catalyzed persulfate (S2O82-) under ambient temperatures. The main objective of the usearch was of investigat the effect of temperatures (25, 35 and 45oC), initial pH (2.5, 7.0 and 11.0), and the persulfate doses and activated-carbon doses on the PFOA decomposition study. Three different system were studied: Persulfate (PS) only system and active-carbon (Ac) only system and PS+AC system. The result showed that the PS+AC system has a better decompostion capability than that of PS only system. But the AC only system could remove more perfluorooctanoic acid from water, it did not decompose perfluorooctanoic acid.
The best operation for the PS+AC system is high temperature coupled with low pH, which can accelerated the free radical (SO4-˙) generation, to decompose PFOA. At pH of 2.5, temperature of 45 oC, PS dose of 60.25 mM, AC dose of 1g/L, and shake rate of 100 rpm, 85% PFOA were decomposes and 79% of fluoride-ions were released to the water. Experimental of the PS only system could be simulated with pseudo first-order kinetics of the PFOA degradation; while those of the PS+AC system and the AC only system could be well simulated with pseudo second-order kinetics. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T23:53:44Z (GMT). No. of bitstreams: 1 ntu-101-R99541124-1.pdf: 3324677 bytes, checksum: 0b8f46ec9546029b3c76249dbbce59c3 (MD5) Previous issue date: 2012 | en |
dc.description.tableofcontents | 口試委員審定書 ii
誌謝 iv 摘要 vi Abstract viii 總目錄 x 圖目錄 xiv 表目錄 xviii 第一章 緒論 1 1.1前言 1 1.2 研究目的 2 1.3研究內容 2 第二章 文獻回顧 3 2.1全氟化合物之污染及危害 3 2.1.1全氟化合物之基本介紹 3 2.1.2 全氟辛酸之物化特性 4 2.1.3 全氟辛酸之危害及環境宿命 6 2.1.4 全氟辛酸對人體影響 7 2.2 台灣全氟化合物之使用現況 8 2.3 全氟化合物之處理技術 10 2.3.1 光化學氧化法 10 2.3.2 超音波氧化法 12 2.3.3 活性碳吸附法 13 2.3.4 高溫焚化法 14 2.4 過硫酸鹽氧化劑之應用 14 2.4.1過硫酸鹽之物化性質 14 2.4.2過硫酸鹽溶於水中的反應 16 2.4.3過硫酸鹽之作用機制 19 2.4.4過硫酸鹽之實際應用 20 2.5活性碳催化過硫酸鹽之理論 22 2.5.1吸附理論 22 2.5.2影響吸附因素 22 2.5.3等溫吸附模式 23 2.5.4 Freundlich等溫吸附式 23 2.5.5 Langmuir等溫吸附式 23 2.5.6動力吸附模式 24 2.5.7活性碳催化過硫酸鹽理論 25 第三章 實驗方法與材料 27 3.1 研究架構 27 3.2實驗試劑與裝置 29 3.2.1實驗使用試劑 29 3.2.2實驗使用儀器裝置 30 3.3 實驗分析方法 32 3.3.1高效液相層析儀 32 3.3.2離子層析儀 34 3.4 PFOA降解實驗 34 3.4.1 pH之影響試驗 35 3.4.2 溫度之影響試驗 35 3.4.3 過硫酸鹽之劑量試驗 35 3.4.4 活性碳之劑量試驗 36 第四章 結果與討論 37 4.1 背景實驗結果 37 4.2 過硫酸鹽氧化全氟辛酸之實驗結果 38 4.2.1 過硫酸鹽劑量之實驗結果 38 4.2.2 pH之影響實驗結果 41 4.2.3 溫度之影響實驗結果 45 4.3 活性碳吸附全氟辛酸實驗結果 49 4.3.1 掃描式電子顯微鏡分析 49 4.3.2 比表面積測定結果 51 4.3.3 界達電位測定結果 52 4.3.4 等溫吸附模式模擬 52 4.3.5 AC劑量之影響實驗結果 54 4.3.6 不同pH下AC吸附全氟辛酸之結果 57 4.3.7 溫度對吸附之影響實驗結果 60 4.4 活性碳催化過硫酸鹽氧化全氟辛酸實驗結果 63 4.4.1 AC催化PS降解PFOA實驗結果 63 4.4.2 PS+AC系統之PS 劑量影響 70 4.4.3 PS+AC系統之pH影響實驗結果 71 4.4.4 PS+AC系統之溫度影響實驗結果 76 第五章 結論與建議 83 5.1結論 83 5.2建議 85 參考文獻 87 附錄 93 | |
dc.language.iso | zh-TW | |
dc.title | 利用活性碳催化過硫酸鹽在室溫下氧化全氟辛酸之研究 | zh_TW |
dc.title | Activated Carbon Catalyzed Persulfate Oxidation of PFOA at Ambient Temperature | en |
dc.type | Thesis | |
dc.date.schoolyear | 100-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 官文惠(Wen-Hui Kuan),郭繼汾,胡景堯 | |
dc.subject.keyword | 全氟辛酸,過硫酸鹽,活性碳催化,化學氧化,活性碳吸附, | zh_TW |
dc.subject.keyword | PFOA,Persulfate,Activated Carbon Catalyzed,Chemical Oxidation,Activated Carbon Adsorption, | en |
dc.relation.page | 104 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2012-07-19 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
顯示於系所單位: | 環境工程學研究所 |
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