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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 顏溪成(Shi-Chern Yen) | |
dc.contributor.author | Ying-Chu Chen | en |
dc.contributor.author | 陳盈竹 | zh_TW |
dc.date.accessioned | 2021-06-16T16:24:39Z | - |
dc.date.issued | 2013 | |
dc.date.submitted | 2013-01-23 | |
dc.identifier.citation | [1] Fawwaz T. Ulaby, Eric Michielssen, Umberto Ravaioli, Fundamentals of Applied Electromagnetics, 6th, 2010, Prentice Hall.
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/63139 | - |
dc.description.abstract | 氫氧化鐵(FeOOH)因其可逆之氧化還原反應電位處在低(負)電位區,被視為是相異於廣泛應用在超級電容負極之碳材料以外的另一選擇。其優異的能量與功率密度,以及寬廣的電位操作範圍,更保證了其應用於非對稱式超級電容器的可行性。此類結合氫氧化鐵負極的非對稱式金屬氧化物電容器,改善了過往結合碳材之非對稱式電容器之電容效能。
本研究中主要利用定電位陽極沉積法將奈米結構之氫氧化鐵直接沉積在可曲撓之碳布基材上,並透過添加不同濃度之包覆劑(氟化銨,NH4F)與控制不同沉積時間來觀察材料形貌的改變以及其對於電化學特性的影響。經由掃描式電子顯微鏡來觀察表面型態、X光電子能譜儀觀察其化學鍵結的組成以及利用X 光繞射儀等對材料作定性分析。並經由循環伏安法、不同掃描速率之充放電測試,比較不同形貌的氫氧化鐵其電化學電容效能。 再者,將氫氧化鐵與二氧化錳(MnO2)組合成非對稱式金屬氧化物電容器。利用In-situ X光吸收光譜探討此非對稱式電容器之氧化價數以及晶格鍵長隨充放電過程的變化,以及利用電化學交流阻抗圖譜法分析不同工作電壓下此元件各介面之電阻與電解液中離子擴散阻值的改變。結合上述實驗所得觀察與實際電容器充放電測試結果,有助於廣泛瞭解此元件之操作機制,並以此作日後為對元件效能改善之基礎。 | zh_TW |
dc.description.abstract | The Iron Oxyhydroxide (FeOOH) has been considered as an alternative anode material other than the common carbon-based electrode for supercapacitor due to its negative reversible redox potential. Its superior specific energy, specific power and wide potential window made it an attractive candidate for negative electrode in asymmetric supercapacitor. Combination of FeOOH with other transition-metal oxide cathodes as asymmetric supercapacitor could get a better capacitive performance compared to those adopted in carbon-based anode.
Herein, we adopt a potentiostatically anodic electrodeposition route to prepare nanostructured FeOOH with different morphologies on the flexible carbon cloth substrate. Different morphologies of FeOOH were obtained by controlling the growth rate of various facets of the deposited oxide using capping agent. The morphologies of the resulting FeOOH were characterized via the scanning electron microscope; the chemical bonding and the crystal structure of FeOOH were identified by x-ray photoelectron spectroscopy and X-ray diffractometer. The correlation between morphologies and the electrochemical performance were investigated through cyclic voltammogram and chronopotentiometric system at different current densities. Moreover, we combine the FeOOH anode and MnO2 cathode into an asymmetric supercapacitor. The change of its oxidation state and the variation of bond-length during the charge/discharge process were directly visualized by the in-situ X-ray absorption spectroscopy. The resistance along the carrier transport (including charge transfer resistance, diffusion resistance, etc.) under various working potential was also investigated using electrochemical impedance spectroscopy. Combining these two observations and the capacitive behavior of the asymmetric cell can provide a comprehensive understanding of its operating mechanism and provide insights for further performance enhancements. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T16:24:39Z (GMT). No. of bitstreams: 1 ntu-102-R98524026-1.pdf: 15161088 bytes, checksum: b6c0d541457df3deefb157ff12b159bd (MD5) Previous issue date: 2013 | en |
dc.description.tableofcontents | 致 謝 I
摘 要 II ABSTRACT IV 第一章 緒 論 1 第二章 理論基礎與文獻回顧 4 2-1 電化學原理 4 2-1-1 前言 4 2-1-2 電極電位與電流 4 2-2 電化學電容器之儲存機制 6 2-2-1 電雙層電容器 6 2-2-2 擬電容器 8 2-3 電化學電容器之組裝 18 2-3-1 對稱式電容器 18 2-3-2 非對稱式電容器 19 2-4 擬電容特性之評估方式 30 2-5 電化學交流阻抗頻譜分析原理 37 2-5-1 交流阻抗分析原理 37 2-5-2 等效電路 41 2-6 X光吸收光譜(X-RAY ABSORPTION SPECTROSCOPY)原理 48 2-6-1 同步輻射光之簡介 48 2-6-2 X光吸收光譜分析原理 49 2-7 研究動機 55 第三章 實驗方法與步驟 57 3-1 電極製備 57 3-1-1 電極基材之前處理 57 3-1-2 陽極沈積鐵氧化物 58 3-1-3 陽極沈積錳氧化物 60 3-2 鐵氧化物電極之材料特性分析 60 3-2-1 微觀組織鑑定 60 3-2-2 結晶結構分析 61 3-2-3 化學組成與化和狀態分析 62 3-2-4 活性物質定量分析 62 3-3 電極之電化學特性評估 63 3-3-1 循環伏安曲線量測 63 3-3-2 計時電位曲線量測 64 3-3-3 電化學交流阻抗分析 65 3-4 X光吸收光譜之臨場(IN SITU)試驗 66 第四章 實驗結果與討論 68 4-1 奈米鐵氧化物之材料特性及擬電容行為研究 68 4-1-1 奈米鐵氧化物電極之表面型態 68 4-1-2 奈米鐵氧化物電極之結晶結構 70 4-1-3 奈米鐵氧化物電極之化學組成與化合狀態分析 73 4-1-4 奈米鐵氧化物電極之擬電容特性 77 4-2 陽極沈積條件與氫氧化鐵擬電容性質的關係 80 4-2-1 沉積時間對氫氧化鐵電極材料特性的影響 80 4-2-2 沉積時間對氫氧化鐵電極擬電容特性的影響 84 4-3 奈米氫氧化鐵電極之電化學性質 87 4-4 利用IN SITU X光吸收光譜技術探討非對稱式電容陰極(氫氧化鐵)、陽極(二氧化錳)之擬電容機制 95 4-4-1 氫氧化鐵電極於充放電過程中in situ X光吸收光譜分析 96 4-4-2 錳氧化物電極於充放電過程中in situ X光吸收光譜分析 105 4-5 利用交流阻抗頻譜分析探討奈米氫氧化鐵電極之阻抗特性 110 4-6 非對稱式電容(陰極:氫氧化鐵,陽極:二氧化錳)之電化學性質 119 第五章 結 論 125 第六章 未來研究方向 129 第七章 參考文獻 130 | |
dc.language.iso | zh-TW | |
dc.title | 奈米結構之氫氧化鐵作為新穎負極材料於非對稱式電化學電容之應用 | zh_TW |
dc.title | Nanostructured Iron Oxyhydroxide (FeOOH) as A Novel Anode Material for Asymmetric Electrochemical Capacitor | en |
dc.type | Thesis | |
dc.date.schoolyear | 101-1 | |
dc.description.degree | 碩士 | |
dc.contributor.coadvisor | 林麗瓊(Li-Chyong Chen),陳貴賢(Kuei-Hsien Chen) | |
dc.subject.keyword | 氫氧化鐵,超級電容,曲撓,儲能,機制, | zh_TW |
dc.subject.keyword | Iron Oxyhydroxide,Supercapacitor,Flexible,Charge Storage,Mechanism, | en |
dc.relation.page | 137 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2013-01-23 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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ntu-102-1.pdf 目前未授權公開取用 | 14.81 MB | Adobe PDF |
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