請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/62369
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 何國川(Kuo-Chuan Ho) | |
dc.contributor.author | Yu-Yan Li | en |
dc.contributor.author | 利宇晏 | zh_TW |
dc.date.accessioned | 2021-06-16T13:44:07Z | - |
dc.date.available | 2018-07-18 | |
dc.date.copyright | 2013-07-18 | |
dc.date.issued | 2013 | |
dc.date.submitted | 2013-07-10 | |
dc.identifier.citation | [1] Gratzel, M., Photoelectrochemical cells, Nature 2001, 414, 338-344.
[2] Spitler, M. T., Dye photooxidation at semiconductor electrodes: A corollary to spectral sensitization in photography, Journal of Chemical Education 1983, 60, 330-332. [3] West, W., First hundred years of special sensitization, Photogr. Sci. Eng. 1974, 18, 35-48. [4] Green, M. A., Photovoltaic principles, Physica E: Low-Dimensional Systems and Nanostructures 2002, 14, 11-17. [5] Chapin, D. M.; Fuller, C. S.; Pearson, G. L., A new silicon p-n junction photocell for converting solar radiation into electrical power, Journal of Applied Physics 1954, 25, 676-677. [6] Altermatt, P. P., Models for numerical device simulations of crystalline silicon solar cells-a review, Journal of Computational Electronics 2011, 10, 314-330. [7] Arjunan, T. V.; Senthil, T. S., Review: Dye sensitised solar cells, Materials Technology 2013, 28, 9-14. [8] Li, Z. G.; Zhao, X. Y.; Li, X.; Gao, Z. Q.; Mi, B. X.; Huang, W., Organic thin-film solar cells: Devices and materials, Science China-Chemistry 2012, 55, 553-578. [9] Ranjan, S.; Balaji, S.; Panella, R. A.; Ydstie, B. E., Silicon solar cell production, Computers & Chemical Engineering 2011, 35, 1439-1453. [10] Wada, T.; Maeda, T., Characteristics of chemical bonds in CuInSe2 and its thin-film deposition processes used to fabricate solar cells, Japanese Journal of Applied Physics 2011, 50. [11] Chidichimo, G.; Filippelli, L., Organic solar cells: problems and perspectives, International Journal of Photoenergy 2010. [12] Nielsen, T. D.; Cruickshank, C.; Foged, S.; Thorsen, J.; Krebs, F. C., Business, market and intellectual property analysis of polymer solar cells, Solar Energy Materials and Solar Cells 2010, 94, 1553-1571. [13] Spanggaard, H.; Krebs, F. C., A brief history of the development of organic and polymeric photovoltaics, Solar Energy Materials and Solar Cells 2004, 83, 125-146. [14] Nijs, J. F.; Szlufcik, J.; Poortmans, J.; Sivoththaman, S.; Mertens, R. P., Advanced manufacturing concepts for crystalline silicon solar cells, Ieee Transactions on Electron Devices 1999, 46, 1948-1969. [15] Saga, T., Advances in crystalline silicon solar cell technology for industrial mass production, NPG Asia Materials 2010, 2, 96-102. [16] Guha, S., Materials aspects of amorphous silicon solar cells, Current Opinion in Solid State & Materials Science 1997, 2, 425-429. [17] Kazmerski, L. L., Solar photovoltaics R&D at the tipping point: A 2005 technology overview, Journal of Electron Spectroscopy and Related Phenomena 2006, 150, 105-135. [18] Green, M. A., Silicon solar cells: evolution, high-efficiency design and efficiency enhancements, Semiconductor Science and Technology 1993, 8, 1-12. [19] Wenham, S. R.; Green, M. A., Silicon solar cells, Progress in Photovoltaics: Research and Applications 1996, 4, 3-33. [20] Rech, B.; Wagner, H., Potential of amorphous silicon for solar cells, Applied Physics A: Materials Science and Processing 1999, 69, 155-167. [21] Schwartz, R. J., Review of silicon solar cells for high concentrations, Solar Cells 1982, 6, 17-38. [22] Aberle, A. G., Surface passivation of crystalline silicon solar cells: a review, Progress in Photovoltaics: Research and Applications 2000, 8, 473-487. [23] Dross, F.; Baert, K.; Bearda, T.; Deckers, J.; Depauw, V.; El Daif, O.; Gordon, I.; Gougam, A.; Govaerts, J.; Granata, S.; Labie, R.; Loozen, X.; Martini, R.; Masolin, A.; O'Sullivan, B.; Qiu, Y.; Vaes, J.; Van Gestel, D.; Van Hoeymissen, J.; Vanleenhove, A.; Van Nieuwenhuysen, K.; Venkatachalam, S.; Meuris, M.; Poortmans, J., Crystalline thin-foil silicon solar cells: where crystalline quality meets thin-film processing, Progress in Photovoltaics: Research and Applications 2012, 20, 770-784. [24] McCann, M. J.; Catchpole, K. R.; Weber, K. J.; Blakers, A. W., A review of thin-film crystalline silicon for solar cell applications. Part 1: Native substrates, Solar Energy Materials and Solar Cells 2001, 68, 135-171. [25] Strumpel, C.; McCann, M.; Beaucarne, G.; Arkhipov, V.; Slaoui, A.; Svrcek, V.; del Canizo, C.; Tobias, I., Modifying the solar spectrum to enhance silicon solar cell efficiency - An overview of available materials, Solar Energy Materials and Solar Cells 2007, 91, 238-249. [26] Lee, A. H. I.; Chen, H. H.; Kang, H. Y., A model to analyze strategic products for photovoltaic silicon thin-film solar cell power industry, Renewable & Sustainable Energy Reviews 2011, 15, 1271-1283. [27] Peter, L. M., Towards sustainable photovoltaics: the search for new materials, Philosophical transactions. Series A, Mathematical, physical, and engineering sciences 2011, 369, 1840-56. [28] Birkmire, R. W.; Eser, E., Polycrystalline thin film solar cells: Present status and future potential, Annual Review of Materials Science 1997, 27, 625-653. [29] Chopra, K. L.; Paulson, P. D.; Dutta, V., Thin-film solar cells: an overview, Progress in Photovoltaics: Research and Applications 2004, 12, 69-92. [30] Birkmire, R. W.; McCandless, B. E., CdTe thin film technology: Leading thin film PV into the future, Current Opinion in Solid State and Materials Science 2010, 14, 139-142. [31] Bosio, A.; Romeo, A.; Menossi, D.; Mazzamuto, S.; Romeo, N., The second-generation of CdTe and CuInGaSe2 thin film PV modules, Crystal Research and Technology 2011, 46, 857-864. [32] Konovalov, I., Material requirements for CIS solar cells, Thin Solid Films 2004, 451, 413-419. [33] Ahn, S.; Kim, C.; Yun, J. H.; Gwak, J.; Jeong, S.; Ryu, B.-H.; Yoon, K., CuInSe2 (CIS) thin film solar cells by direct coating and selenization of solution precursors, Journal of Physical Chemistry C 2010, 114, 8108-8113. [34] Fornari, R., Optimal-growth conditions and main features of GaAs since-crystals for solar-cell technology - A review, Solar Energy Materials 1985, 11, 361-379. [35] Radziemska, E., Thermal performance of Si and GaAs based solar cells and modules: a review, Progress in Energy and Combustion Science 2003, 29, 407-424. [36] Li, G.; Shrotriya, V.; Huang, J. S.; Yao, Y.; Moriarty, T.; Emery, K.; Yang, Y., High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends, Nature Materials 2005, 4, 864-868. [37] Kim, J. Y.; Kim, S. H.; Lee, H. H.; Lee, K.; Ma, W. L.; Gong, X.; Heeger, A. J., New architecture for high-efficiency polymer photovoltaic cells using solution-based titanium oxide as an optical spacer, Advanced Materials 2006, 18, 572-576. [38] Kim, J. Y.; Lee, K.; Coates, N. E.; Moses, D.; Nguyen, T. Q.; Dante, M.; Heeger, A. J., Efficient tandem polymer solar cells fabricated by all-solution processing, Science 2007, 317, 222-225. [39] Chen, H. Y.; Hou, J. H.; Zhang, S. Q.; Liang, Y. Y.; Yang, G. W.; Yang, Y.; Yu, L. P.; Wu, Y.; Li, G., Polymer solar cells with enhanced open-circuit voltage and efficiency, Nature Photonics 2009, 3, 649-653. [40] Ma, W. L.; Yang, C. Y.; Gong, X.; Lee, K.; Heeger, A. J., Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology, Advanced Functional Materials 2005, 15, 1617-1622. [41] Gerischer, H.; Michel-Beyerle, M. E.; Rebentrost, F.; Tributsch, H., Sensitization of charge injection into semiconductors with large band gap, Electrochimica Acta 1968, 13, 1509-1515. [42] Tributsc.H; Gerische.H, Elektrochemische untersuchungen uber den mechanismus der sensibilisierung and ubersensibilisierung an ZnO-einkristallen, Berichte der Bunsen-Gesellschaft fur Physikalische Chemie 1969, 73, 251-260. [43] Tsubomura, H.; Matsumura, M.; Nomura, Y.; Amamiya, T., Dye sensitized zinc-oxide-aqueous-electrolyte-platinum photocell, Nature 1976, 261, 402-403. [44] O'Regan, B.; Gratzel, M., A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films, Nature 1991, 353, 737-740. [45] Gratzel, M., Solar energy conversion by dye-sensitized photovoltaic cells, Inorganic Chemistry 2005, 44, 6841-6851. [46] Yella, A.; Lee, H. W.; Tsao, H. N.; Yi, C.; Chandiran, A. K.; Nazeeruddin, M. K.; Diau, E. W.; Yeh, C. Y.; Zakeeruddin, S. M.; Gratzel, M., Porphyrin-sensitized solar cells with cobalt (II/III)-based redox electrolyte exceed 12 percent efficiency, Science 2011, 334, 629-34. [47] Goncalves, L. M.; de Zea Bermudez, V.; Ribeiro, H. A.; Mendes, A. M., Dye-sensitized solar cells: A safe bet for the future, Energy & Environmental Science 2008, 1, 655-667. [48] Gratzel, M., Recent advances in sensitized mesoscopic solar cells, Accounts of Chemical Research 2009, 42, 1788-1798. [49] Wu, J. H.; Lan, Z.; Hao, S. C.; Li, P. J.; Lin, J. M.; Huang, M. L.; Fang, L. Q.; Huang, Y. F., Progress on the electrolytes for dye-sensitized solar cells, Pure and Applied Chemistry 2008, 80, 2241-2258. [50] Matthews, D.; Infelta, P.; Gratzel, M., Calculation of the photocurrent-potential characteristic for regenerative, sensitized semiconductor electrodes, Solar Energy Materials and Solar Cells 1996, 44, 119-155. [51] Kalyanasundaram, K.; Gratzel, M., Applications of functionalized transition metal complexes in photonic and optoelectronic devices, Coordination Chemistry Reviews 1998, 177, 347-414. [52] Namba, S.; Hishiki, Y., Color sensitization of zinc oxide with cyanine dyes, Journal of Physical Chemistry 1965, 69, 774-779. [53] Rensmo, H.; Keis, K.; Lindstrom, H.; Sodergren, S.; Solbrand, A.; Hagfeldt, A.; Lindquist, S. E.; Wang, L. N.; Muhammed, M., High light-to-energy conversion efficiencies for solar cells based on nanostructured ZnO electrodes, Journal of Physical Chemistry B 1997, 101, 2598-2601. [54] Vogel, R.; Hoyer, P.; Weller, H., Quantum-sized PbS, CdS, Ag2S, Sb2S3, and Bi2S3 particles as sensitizeds for various nanoporous wide-bandgap semiconductors, Journal of Physical Chemistry 1994, 98, 3183-3188. [55] Wang, J.; Yan, J. Q.; Zhang, H., AKR-deficiency disturbs the balance of some signal transduction pathways in Arabidopsis thaliana, Plant Physiology and Biochemistry 1999, 37, 465-471. [56] Spanhel, L.; Anderson, M. A., Synthesis of porous quantum-size CdS membranes-photoluminescence phase-shift and demodulation measurements, Journal of the American Chemical Society 1990, 112, 2278-2284. [57] Nah, Y. C.; Paramasivam, I.; Schmuki, P., Doped TiO2 and TiO2 nanotubes: Synthesis and applications, Chemphyschem 2010, 11, 2698-2713. [58] Gratzel, M., Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells, Journal of Photochemistry and Photobiology a-Chemistry 2004, 164, 3-14. [59] Hagfeldt, A.; Gratzel, M., Molecular photovoltaics, Accounts of Chemical Research 2000, 33, 269-277. [60] Koelsch, M.; Cassaignon, S.; Minh, C. T. T.; Guillemoles, J. F.; Jolivet, J. P., Electrochemical comparative study of titania (anatase, brookite and rutile) nanoparticles synthesized in aqueous medium, Thin Solid Films 2004, 451, 86-92. [61] Park, N. G.; van de Lagemaat, J.; Frank, A. J., Comparison of dye-sensitized rutile- and anatase-based TiO2 solar cells, Journal of Physical Chemistry B 2000, 104, 8989-8994. [62] Nazeeruddin, M. K.; Zakeeruddin, S. M.; Humphry-Baker, R.; Jirousek, M.; Liska, P.; Vlachopoulos, N.; Shklover, V.; Fischer, C. H.; Gratzel, M., Acid-base equilibria of (2,2 '-bipyridyl-4,4 '-dicarboxylic acid)ruthenium(II) complexes and the effect of protonation on charge-transfer sensitization of nanocrystalline titania, Inorganic Chemistry 1999, 38, 6298-6305. [63] Nazeeruddin, M. K.; Pechy, P.; Renouard, T.; Zakeeruddin, S. M.; Humphry-Baker, R.; Comte, P.; Liska, P.; Cevey, L.; Costa, E.; Shklover, V.; Spiccia, L.; Deacon, G. B.; Bignozzi, C. A.; Gratzel, M., Engineering of efficient panchromatic sensitizers for nanocrystalline TiO2-based solar cells, Journal of the American Chemical Society 2001, 123, 1613-1624. [64] Kusama, H.; Sayama, K., Theoretical study on the intermolecular interactions of black dye dimers and black dye-deoxycholic acid complexes in dye-sensitized solar cells, Journal of Physical Chemistry C 2012, 116, 23906-23914. [65] Wang, P.; Zakeeruddin, S. M.; Humphry-Baker, R.; Moser, J. E.; Gratzel, M., Molecular-scale interface engineering of TiO2 nanocrystals: Improving the efficiency and stability of dye-sensitized solar cells, Advanced Materials 2003, 15, 2101-2104. [66] Mishra, A.; Fischer, M. K. R.; Bauerle, P., Metal-free organic dyes for dye-sensitized solar cells: from structure: property relationships to design rules, Angewandte Chemie-International Edition 2009, 48, 2474-2499. [67] Kim, S.; Lee, J. K.; Kang, S. O.; Ko, J.; Yum, J. H.; Fantacci, S.; De Angelis, F.; Di Censo, D.; Nazeeruddin, M. K.; Gratzel, M., Molecular engineering of organic sensitizers for solar cell applications, Journal of the American Chemical Society 2006, 128, 16701-16707. [68] Yum, J.-H.; Hagberg, D. P.; Moon, S.-J.; Karlsson, K. M.; Marinado, T.; Sun, L.; Hagfeldt, A.; Nazeeruddin, M. K.; Graetzel, M., A light-resistant organic sensitizer for solar-cell applications, Angewandte Chemie-International Edition 2009, 48, 1576-1580. [69] Lin, J. T.; Chen, P.-C.; Yen, Y.-S.; Hsu, Y.-C.; Chou, H.-H.; Yeh, M.-C. P., Organic dyes containing furan moiety for high-performance dye-sensitized solar cells, Organic Letters 2009, 11, 97-100. [70] Li, B.; Wang, L. D.; Kang, B. N.; Wang, P.; Qiu, Y., Review of recent progress in solid-state dye-sensitized solar cells, Solar Energy Materials and Solar Cells 2006, 90, 549-573. [71] Wolfbauer, G.; Bond, A. M.; Eklund, J. C.; MacFarlane, D. R., A channel flow cell system specifically designed to test the efficiency of redox shuttles in dye sensitized solar cells, Solar Energy Materials and Solar Cells 2001, 70, 85-101. [72] Wang, Z. S.; Sayama, K.; Sugihara, H., Efficient eosin Y dye-sensitized solar cell containing Br-/Br3- electrolyte, Journal of Physical Chemistry B 2005, 109, 22449-22455. [73] Sapp, S. A.; Elliott, C. M.; Contado, C.; Caramori, S.; Bignozzi, C. A., Substituted polypyridine complexes of cobalt(II/III) as efficient electron-transfer mediators in dye-sensitized solar cells, Journal of the American Chemical Society 2002, 124, 11215-11222. [74] Liu, Y.; Jennings, J. R.; Huang, Y.; Wang, Q.; Zakeeruddin, S. M.; Gratzel, M., Cobalt redox mediators for ruthenium-based dye-sensitized solar cells: A combined impedance spectroscopy and near-IR transmittance study, Journal of Physical Chemistry C 2011, 115, 18847-18855. [75] Min, J.; Won, J.; Kang, Y. S.; Nagase, S., Benzimidazole derivatives in the electrolyte of new-generation organic dye-sensitized solar cells with an iodine-free redox mediator, Journal of Photochemistry and Photobiology a-Chemistry 2011, 219, 148-153. [76] Tian, H.; Yu, Z.; Hagfeldt, A.; Kloo, L.; Sun, L., Organic redox couples and organic counter electrode for efficient organic dye-sensitized solar cells, Journal of the American Chemical Society 2011, 133, 9413-9422. [77] Liu, Y.; Hagfeldt, A.; Xiao, X. R.; Lindquist, S. E., Investigation of influence of redox species on the interfacial energetics of a dye-sensitized nanoporous TiO2 solar cell, Solar Energy Materials and Solar Cells 1998, 55, 267-281. [78] Cong, J.; Yang, X.; Kloo, L.; Sun, L., Iodine/iodide-free redox shuttles for liquid electrolyte-based dye-sensitized solar cells, Energy & Environmental Science 2012, 5, 9180-9194. [79] Murakami, T. N.; Gratzel, M., Counter electrodes for DSC: Application of functional materials as catalysts, Inorganica Chimica Acta 2008, 361, 572-580. [80] Peng, Z.; Yang, H., Designer platinum nanoparticles: Control of shape, composition in alloy, nanostructure and electrocatalytic property, Nano Today 2009, 4, 143-164. [81] Barefoot, R. R.; VanLoon, J. C., Determination of platinum and gold in anticancer and antiarthritic drugs and metabolites, Analytica Chimica Acta 1996, 334, 5-14. [82] Gasteiger, H. A.; Kocha, S. S.; Sompalli, B.; Wagner, F. T., Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs, Applied Catalysis B-Environmental 2005, 56, 9-35. [83] Slavcheva, E.; Ganske, G.; Topalov, G.; Mokwa, W.; Schnakenberg, U., Effect of sputtering parameters on surface morphology and catalytic efficiency of thin platinum films, Applied Surface Science 2009, 255, 6479-6486. [84] Papageorgiou, N., Counter-electrode function in nanocrystalline photoelectrochemical cell configurations, Coordination Chemistry Reviews 2004, 248, 1421-1446. [85] Li, P.; Wu, J.; Lin, J.; Huang, M.; Lan, Z.; Li, Q., Improvement of performance of dye-sensitized solar cells based on electrodeposited-platinum counter electrode, Electrochimica Acta 2008, 53, 4161-4166. [86] Tsekouras, G.; Mozer, A. J.; Wallace, G. G., Enhanced performance of dye sensitized solar cells utilizing platinum electrodeposit counter electrodes, Journal of the Electrochemical Society 2008, 155, K124-K128. [87] Olsen, E.; Hagen, G.; Lindquist, S. E., Dissolution of platinum in methoxy propionitrile containing LiI/I-2, Solar Energy Materials and Solar Cells 2000, 63, 267-273. [88] Wu, M.; Ma, T., Platinum-free catalysts as counter electrodes in dye-sensitized solar cells, ChemSusChem 2012, 5, 1343-1357. [89] Choi, H. J.; Gong, H. H.; Park, J.-Y.; Hong, S. C., Characteristics of dye-sensitized solar cells with surface-modified multi-walled carbon nanotubes as counter electrodes, Journal of Materials Science 2013, 48, 906-912. [90] Malara, F.; Manca, M.; Lanza, M.; Huebner, C.; Piperopoulos, E.; Gigli, G., A free-standing aligned-carbon-nanotube/nanocomposite foil as an efficient counter electrode for dye solar cells, Energy & Environmental Science 2012, 5, 8377-8383. [91] Munkhbayar, B.; Hwang, S.; Kim, J.; Bae, K.; Ji, M.; Chung, H.; Jeong, H., Photovoltaic performance of dye-sensitized solar cells with various MWCNT counter electrode structures produced by different coating methods, Electrochimica Acta 2012, 80, 100-107. [92] Cruz, R.; Pacheco Tanaka, D. A.; Mendes, A., Reduced graphene oxide films as transparent counter-electrodes for dye-sensitized solar cells, Solar Energy 2012, 86, 716-724. [93] Wang, H.; Hu, Y. H., Graphene as a counter electrode material for dye-sensitized solar cells, Energy & Environmental Science 2012, 5, 8182-8188. [94] Veerappan, G.; Bojan, K.; Rhee, S. W., Sub-micrometer-sized graphite as a conducting and catalytic counter electrode for dye-sensitized solar cells, ACS Applied Materials & Interfaces 2011, 3, 857-862. [95] Wei, Y. S.; Jin, Q. Q.; Ren, T. Z., Expanded graphite/pencil-lead as counter electrode for dye-sensitized solar cells, Solid-State Electronics 2011, 63, 76-82. [96] Brennan, L. J.; Byrne, M. T.; Bari, M.; Gun'ko, Y. K., Carbon nanomaterials for dye-sensitized solar cell applications: A bright future, Advanced Energy Materials 2011, 1, 472-485. [97] Peng, T.; Sun, W.; Sun, X.; Huang, N.; Liu, Y.; Bu, C.; Guo, S.; Zhao, X.-Z., Direct tri-constituent co-assembly of highly ordered mesoporous carbon counter electrode for dye-sensitized solar cells, Nanoscale 2013, 5, 337-341. [98] Imoto, K.; Suzuki, M.; Takahashi, K.; Yamaguchi, T.; Komura, T.; Nakamura, J.; Murata, K., Activated carbon counter electrode for dye-sensitized solar cell, Electrochemistry 2003, 71, 944-946. [99] Wu, M.; Lin, X.; Wang, T.; Qiu, J.; Ma, T., Low-cost dye-sensitized solar cell based on nine kinds of carbon counter electrodes, Energy & Environmental Science 2011, 4, 2308-2315. [100] Cho, S.; Hwang, S. H.; Kim, C.; Jang, J., Polyaniline porous counter-electrodes for high performance dye-sensitized solar cells, Journal of Materials Chemistry 2012, 22, 12164-12171. [101] Li, Q.; Wu, J.; Tang, Q.; Lan, Z.; Li, P.; Lin, J.; Fan, L., Application of microporous polyaniline counter electrode for dye-sensitized solar cells, Electrochemistry Communications 2008, 10, 1299-1302. [102] Keothongkham, K.; Pimanpang, S.; Maiaugree, W.; Saekow, S.; Jarernboon, W.; Amornkitbamrung, V., Electrochemically deposited polypyrrole for dye-sensitized solar cell counter electrodes, International Journal of Photoenergy 2012, 2012, 1-7. [103] Wu, J.; Li, Q.; Fan, L.; Lan, Z.; Li, P.; Lin, J.; Hao, S., High-performance polypyrrole nanoparticles counter electrode for dye-sensitized solar cells, Journal of Power Sources 2008, 181, 172-176. [104] Trevisan, R.; Dobbelin, M.; Boix, P. P.; Barea, E. M.; Tena-Zaera, R.; Mora-Sero, I.; Bisquert, J., PEDOT nanotube arrays as high performing counter electrodes for dye sensitized solar cells. Study of the interactions among electrolytes and counter electrodes, Advanced Energy Materials 2011, 1, 781-784. [105] Kitamura, K.; Shiratori, S., Layer-by-layer self-assembled mesoporous PEDOT-PSS and carbon black hybrid films for platinum free dye-sensitized-solar-cell counter electrodes, Nanotechnology 2011, 22. [106] Park, S. H.; Kim, J. U.; Lee, J. K.; Kim, M. R., Photovoltaic properties of dye-sensitized solar cells with thermal treated PEDOT:PSS as counter electrodes, Molecular Crystals and Liquid Crystals 2007, 471, 113-121. [107] Lee, K. M.; Hsu, C. Y.; Chen, P. Y.; Ikegami, M.; Miyasaka, T.; Ho, K. C., Highly porous PProDOT-Et2 film as counter electrode for plastic dye-sensitized solar cells, Physical Chemistry Chemical Physics 2009, 11, 3375-3379. [108] Tai, Q.; Chen, B.; Guo, F.; Xu, S.; Hu, H.; Sebo, B.; Zhao, X. Z., In situ prepared transparent polyaniline electrode and its application in bifacial dye-sensitized solar cells, ACS Nano 2011, 5, 3795-3799. [109] Bu, C.; Tai, Q.; Liu, Y.; Guo, S.; Zhao, X., A transparent and stable polypyrrole counter electrode for dye-sensitized solar cell, Journal of Power Sources 2013, 221, 78-83. [110] Jiang, Q. W.; Li, G. R.; Gao, X. P., Highly ordered TiN nanotube arrays as counter electrodes for dye-sensitized solar cells, Chemical Communications 2009, 6720-6722. [111] Li, G. R.; Wang, F.; Song, J.; Xiong, F. Y.; Gao, X. P., TiN-conductive carbon black composite as counter electrode for dye-sensitized solar cells, Electrochimica Acta 2012, 65, 216-220. [112] Wang, Y.; Wu, M.; Lin, X.; Hagfeldt, A.; Ma, T., Optimization of the performance of dye-sensitized solar cells based on Pt-like TiC counter electrodes, European Journal of Inorganic Chemistry 2012, 3557-3561. [113] Kung, C. W.; Chen, H. W.; Lin, C. Y.; Huang, K. C.; Vittal, R.; Ho, K. C., CoS acicular nanorod arrays for the counter electrode of an efficient dye-sensitized solar cell, ACS Nano 2012, 6, 7016-7025. [114] Sun, H.; Qin, D.; Huang, S.; Guo, X.; Li, D.; Luo, Y.; Meng, Q., Dye-sensitized solar cells with NiS counter electrodes electrodeposited by a potential reversal technique, Energy and Environmental Science 2011, 4, 2630-2637. [115] Wu, M.; Lin, X.; Hagfeldt, A.; Ma, T., Low-cost molybdenum carbide and tungsten carbide counter electrodes for dye-sensitized solar cells, Angewandte Chemie - International Edition 2011, 50, 3520-3524. [116] Wu, M.; Wang, Y.; Lin, X.; Yu, N.; Wang, L.; Wang, L.; Hagfeldt, A.; Ma, T., Economical and effective sulfide catalysts for dye-sensitized solar cells as counter electrodes, Physical Chemistry Chemical Physics 2011, 13, 19298-19301. [117] Wu, M.; Zhang, Q.; Xiao, J.; Ma, C.; Lin, X.; Miao, C.; He, Y.; Gao, Y.; Hagfeldt, A.; Ma, T., Two flexible counter electrodes based on molybdenum and tungsten nitrides for dye-sensitized solar cells, Journal of Materials Chemistry 2011, 21, 10761-10766. [118] Wu, M.; Lin, X.; Wang, Y.; Wang, L.; Guo, W.; Qi, D.; Peng, X.; Hagfeldt, A.; Gratzel, M.; Ma, T., Economical Pt-free catalysts for counter electrodes of dye-sensitized solar cells, Journal of the American Chemical Society 2012, 134, 3419-3428. [119] Bajpai, R.; Roy, S.; Kulshrestha, N.; Rafiee, J.; Koratkar, N.; Misra, D. S., Graphene supported nickel nanoparticle as a viable replacement for platinum in dye sensitized solar cells, Nanoscale 2012, 4, 926-930. [120] Joshi, P.; Zhou, Z.; Poudel, P.; Thapa, A.; Wu, X. F.; Qiao, Q., Nickel incorporated carbon nanotube/nanofiber composites as counter electrodes for dye-sensitized solar cells, Nanoscale 2012, 4, 5659-5664. [121] Huang, K. C.; Wang, Y. C.; Chen, P. Y.; Lai, Y. H.; Huang, J. H.; Chen, Y. H.; Dong, R. X.; Chu, C. W.; Lin, J. J.; Ho, K. C., High performance dye-sensitized solar cells based on platinum nanoparticle/multi-wall carbon nanotube counter electrodes: The role of annealing, Journal of Power Sources 2012, 203, 274-281. [122] Liu, C. Y.; Huang, K. C.; Wang, C. C.; Ho, K. C., Enhanced efficiency of dye-sensitized solar cells with counter electrodes consisting of platinum nanoparticles and nanographites, Electrochimica Acta 2012, 59, 128-134. [123] Adachi, T.; Hoshi, H., Preparation and characterization of Pt/carbon counter electrodes for dye-sensitized solar cells, Materials Letters 2013, 94, 15-18. [124] Chen, J. G.; Wei, H. Y.; Ho, K. C., Using modified poly(3,4-ethylene dioxythiophene): Poly(styrene sulfonate) film as a counter electrode in dye-sensitized solar cells, Solar Energy Materials and Solar Cells 2007, 91, 1472-1477. [125] Tai, S. Y.; Liu, C. J.; Chou, S. W.; Chien, F. S. S.; Lin, J. Y.; Lin, T. W., Few-layer MoS2 nanosheets coated onto multi-walled carbon nanotubes as a low-cost and highly electrocatalytic counter electrode for dye-sensitized solar cells, Journal of Materials Chemistry 2012, 22, 24753-24759. [126] Luo, J.; Niu, H. J.; Wen, H. L.; Wu, W. J.; Zhao, P.; Wang, C.; Bai, X. D.; Wang, W., Enhancement of the efficiency of dye-sensitized solar cell with multi-wall carbon nanotubes/polypyrrole composite counter electrodes prepared by electrophoresis/electrochemical polymerization, Materials Research Bulletin 2013, 48, 988-994. [127] Yue, G.; Wu, J.; Xiao, Y.; Lin, J.; Huang, M.; Lan, Z., Application of poly(3,4-ethylenedioxythiophene): Polystyrenesulfonate/ polypyrrole counter electrode for dye-sensitized solar cells, Journal of Physical Chemistry C 2012, 116, 18057-18063. [128] Han, L.; Koide, N.; Chiba, Y.; Islam, A.; Mitate, T., Modeling of an equivalent circuit for dye-sensitized solar cells: improvement of efficiency of dye-sensitized solar cells by reducing internal resistance, Comptes Rendus Chimie 2006, 9, 645-651. [129] Han, L.; Koide, N.; Chiba, Y.; Mitate, T., Modeling of an equivalent circuit for dye-sensitized solar cells, Applied Physics Letters 2004, 84, 2433-2435. [130] Lin, C. Y.; Lin, J. Y.; Wan, C. C.; Wei, T. C., High-performance and low platinum loading electrodeposited-Pt counter electrodes for dye-sensitized solar cells, Electrochimica Acta 2011, 56, 1941-1946. [131] Peter, L. M., Dye-sensitized nanocrystalline solar cells, Physical Chemistry Chemical Physics 2007, 9, 2630-2642. [132] Gratzel, M., Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells, Journal of Photochemistry and Photobiology A: Chemistry 2004, 164, 3-14. [133] Suzuki, K.; Yamaguchi, M.; Kumagai, M.; Yanagida, S., Application of carbon nanotubes to counter electrodes of dye-sensitized solar cells, Chemistry Letters 2003, 32, 28-29. [134] Huang, K. C.; Wang, Y. C.; Dong, R. X.; Tsai, W. C.; Tsai, K. W.; Wang, C. C.; Chen, Y. H.; Vittal, R.; Lin, J. J.; Ho, K. C., A high performance dye-sensitized solar cell with a novel nanocomposite film of PtNP/MWCNT on the counter electrode, Journal of Materials Chemistry 2010, 20, 4067-4073. [135] Wang, H. Y.; Wang, F. M.; Wang, Y. Y.; Wan, C. C.; Hwang, B. J.; Santhanam, R.; Rick, J., Electrochemical formation of Pt nanoparticles on multiwalled carbon nanotubes: Useful for fabricating electrodes for use in dye-sensitized solar cells, Journal of Physical Chemistry C 2011, 115, 8439-8446. [136] Han, J.; Kim, H.; Kim, D. Y.; Jo, S. M.; Jang, S. Y., Water-soluble polyelectrolyte-grafted multiwalled carbon nanotube thin films for efficient counter electrode of dye-sensitized solar cells, ACS Nano 2010, 4, 3503-3509. [137] Yen, M. Y.; Hsiao, M. C.; Liao, S. H.; Liu, P. I.; Tsai, H. M.; Ma, C. C. M.; Pu, N. W.; Ger, M. D., Preparation of graphene/multi-walled carbon nanotube hybrid and its use as photoanodes of dye-sensitized solar cells, Carbon 2011, 49, 3597-3606. [138] Roy-Mayhew, J. D.; Bozym, D. J.; Punckt, C.; Aksay, I. A., Functionalized graphene as a catalytic counter electrode in dye-sensitized solar cells, ACS Nano 2010, 4, 6203-6211. [139] Acharya, K. P.; Khatri, H.; Marsillac, S.; Ullrich, B.; Anzenbacher, P.; Zamkov, M., Pulsed laser deposition of graphite counter electrodes for dye-sensitized solar cells, Applied Physics Letters 2010, 97. [140] Murakami, T. N.; Ito, S.; Wang, Q.; Nazeeruddin, M. K.; Bessho, T.; Cesar, I.; Liska, P.; Humphry-Baker, R.; Comte, P.; Pechy, P.; Gratzel, M., Highly efficient dye-sensitized solar cells based on carbon black counter electrodes, Journal of the Electrochemical Society 2006, 153, A2255-A2261. [141] Huang, Z.; Liu, X.; Li, K.; Li, D.; Luo, Y.; Li, H.; Song, W.; Chen, L.; Meng, Q., Application of carbon materials as counter electrodes of dye-sensitized solar cells, Electrochemistry Communications 2007, 9, 596-598. [142] Li, K.; Luo, Y.; Yu, Z.; Deng, M.; Li, D.; Meng, Q., Low temperature fabrication of efficient porous carbon counter electrode for dye-sensitized solar cells, Electrochemistry Communications 2009, 11, 1346-1349. [143] Imoto, K.; Takahashi, K.; Yamaguchi, T.; Komura, T.; Nakamura, J. I.; Murata, K., High-performance carbon counter electrode for dye-sensitized solar cells, Solar Energy Materials and Solar Cells 2003, 79, 459-469. [144] Wu, M.; Lin, X.; Wang, T.; Qiu, J.; Ma, T., Low-cost dye-sensitized solar cell based on nine kinds of carbon counter electrodes, Energy and Environmental Science 2011, 4, 2308-2315. [145] Liu, G.; Wang, H.; Li, X.; Rong, Y.; Ku, Z.; Xu, M.; Liu, L.; Hu, M.; Yang, Y.; Xiang, P.; Shu, T.; Han, H., A mesoscopic platinized graphite/carbon black counter electrode for a highly efficient monolithic dye-sensitized solar cell, Electrochimica Acta 2012, 69, 334-339. [146] Lee, B.; Buchholz, D. B.; Chang, R. P. H., An all carbon counter electrode for dye sensitized solar cells, Energy and Environmental Science 2012, 5, 6941-6952. [147] Kay, A.; Gratzel, M., Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon powder, Solar Energy Materials and Solar Cells 1996, 44, 99-117. [148] Hu, H.; Chen, B. L.; Bu, C. H.; Tai, Q. D.; Guo, F.; Xu, S.; Xu, J. H.; Zhao, X. Z., Stability study of carbon-based counter electrodes in dye-sensitized solar cells, Electrochimica Acta 2011, 56, 8463-8466. [149] Wu, H.; Lv, Z.; Chu, Z.; Wang, D.; Hou, S.; Zou, D., Graphite and platinum's catalytic selectivity for disulfide/thiolate (T2/T-) and triiodide/iodide (I3-/I-), Journal of Materials Chemistry 2011, 21, 14815-14820. [150] Lee, W. J.; Ramasamy, E.; Lee, D. Y.; Song, J. S., Efficient dye-sensitized cells with catalytic multiwall carbon nanotube counter electrodes, ACS Applied Materials & Interfaces 2009, 1, 1145-1149. [151] Veerappan, G.; Kwon, W.; Rhee, S. W., Carbon-nanofiber counter electrodes for quasi-solid state dye-sensitized solar cells, Journal of Power Sources 2011, 196, 10798-10805. [152] Veerappan, G.; Bojan, K.; Rhee, S. W., Sub-micrometer-sized graphite as a conducting and catalytic counter electrode for dye-sensitized solar cells, ACS Applied Materials and Interfaces 2011, 3, 857-862. [153] Jawhari, T.; Roid, A.; Casado, J., Raman spectroscopic characterization of some commercially available carbon black materials, Carbon 1995, 33, 1561-1565. [154] Katagiri, G.; Ishida, H.; Ishitani, A., Raman spectra of graphite edge planes, Carbon 1988, 26, 565-571. [155] Rouquerol, J.; Avnir, D.; Everett, D. H.; Fairbridge, C.; Haynes, M.; Pernicone, N.; Ramsay, J. D. F.; Sing, K. S. W.; Unger, K. K., Guidelines for the characterization of porous solids, 1994; Vol. 87, pp 1-9. [156] Hsieh, C. K.; Tsai, M. C.; Su, C. Y.; Wei, S. Y.; Ye | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/62369 | - |
dc.description.abstract | 由於石油供應的短缺,太陽能電池的開發已經是綠色能源研究領域的重要一環。作為新一代的太陽能電池,染料敏化太陽能電池在近年來已被廣泛研究,因其具有一些優勢例如組裝簡易、可撓、價格低廉。
與其他種類的太陽能電池相比較,具有組裝簡易以及價格低廉特色的染料敏化太陽能電池已被研究具有超越12%的光電轉換效能。時至今日,白金作為對電極材料因具有良好的催化活性以及導電性,使得染料敏化太陽能電池光電轉換效率有良好的表現,因此被廣泛的研究。然而,白金為一種稀有的金屬材料,利用常見的製備白金膜的方式,像是真空濺鍍、熱裂解,其價格是相當昂貴的。因此若利用白金作為對電極材料,則會因其本身的高價位限制了染料敏化太陽能電池原本價格低廉的優勢。由近幾年發表的文獻報導可知,使用非白金材料以取代白金並運用於染料敏化太陽能電池的對電極催化層已是趨勢。一般常見的非白金對電極催化層材料大致上可分為三類,包括碳材、導電高分子,以及過渡金屬化合物。為了開發高效能的非白金對電極,本篇論文包含了兩部分研究。第一部分的研究是使用不同維度結構的石墨作為染料敏化太陽能電池對電極的催化層材料。第二部分的研究則是以鎳金屬奈米粒子以及導電高分子聚二氧乙基噻吩-聚苯乙烯磺酸(poly (3, 4-ethylene dioxythiophene): poly (styrene sulfonate), PEDOT:PSS) 的複合材料作為對電極的催化層材料。 為了研究出於染料敏化太陽能電池較高效能的石墨對電極,本研究論文的第一部分將比較三種不同維度結構的石墨,包含一維結構的石墨奈米線(1-D-GNF)、二維結構的天然石墨(2-D-NtG),以及三維結構的奈米石墨(3-D-NnG),運用於對電極的催化還原層。運用nafionR117的分散效果,分別將三種石墨分散於乙醇中,並運用滴塗漿料於ITO導電玻璃的塗佈方式,將含有石墨的漿料滴製成膜。在此部分的研究將對三種石墨性質加以鑑定與討論,例如表面結構、結構缺陷的含量、比表面積,以及導電性。3-D-NnG擁有最好的效率表現,為7.88%,與白金的8.38%效能相比相當接近,主要原因是3-D-NnG擁有最多含量的結構缺陷,使其擁有較佳的催化還原能力。另一方面,比起3-D-NnG,1-D-GNF以及2-D-NtG所擁有的結構缺陷都較少,也因此較差的催化還原能力導致了較低的效能表現(1-D-GNF為3.60%,2-D-NtG為2.99%)。而在此部分研究,三種維度石墨的催化還原能力也被常見的電化學分析方式以及旋轉電極檢視。 為了開發出適合的材料運用於染料敏化太陽能電池的催化還原層,有相當多關於複合材料,通常是兩種材料複合並提供個別的材料本性優勢,進而達到整體元件較高的效能。本論文的第二部分主要是將金屬鎳的奈米粒子,以及PEDOT:PSS相混合製成漿料,並用刮刀式塗佈法,將此複合材料塗佈於FTO導電玻璃上,製成對電極的催化還原層。金屬鎳的奈米粒子已被報導具有優良的催化還原性以及導電性,然而其高密度以及易聚集的本性,金屬鎳的奈米粒子形成的薄膜容易龜裂和由基材脫落。而PEDOT:PSS作為染料敏化太陽能電池的對電極材料也已經被廣泛報導,然而此種高分子較差的導電性以及催化活性限制了應用範圍。金屬鎳的奈米粒子以及PEDOT:PSS組成的複合材料可發揮出較高的元件性能(複合材料光電轉換效率為7.01%,而白金效率為7.63%),因為金屬鎳的奈米粒子可提供較佳的導電性以及催化還原能力,而PEDOT:PSS則可提供較佳的基材附著能力。因此導致金屬鎳的奈米粒子以及PEDOT:PSS低效率的因素(金屬鎳的奈米粒子效率為0.24%、PEDOT:PSS的效率為4.36%)在此論文已經被研究解決。不同材料組成的催化還原層的性質以及表面結構也被清楚分析。複合薄膜比白金組成的催化還原薄膜具有更好的長程穩定性,因此比起白金,此複合薄膜在商品化的應用上更具有價值潛力。 | zh_TW |
dc.description.abstract | The development of solar energy is one of the most important studies in the field of green energy because of the deficiency of oil energy. Dye-sensitized solar cells (DSSCs), as a new generation solar cell, have been investigated widely for the recent years due to some advantages such as simple fabrication, flexibility, and low-cost.
Compared to the other types of solar cells, DSSCs with the properties of low-cost and easy fabrication have been developed to reach the high efficiency exceeding 12%. Up to date, platinum (Pt) has remained the widely used electro-catalytic material as the counter electrode (CE) because of the properties of superior electro-catalytic ability and conductivity which cause the good performance in DSSCs. However, as one of the rare metal materials, the cost of DSSCs is expensive by the conventional preparations such as sputtering method, thermal decomposition method. Pt with the high price will limit the application of DSSCs because the property of low-cost, one of the advantages of DSSCs, will be also limited. From the reports published for the recent years, there is a trend which is using Pt-free materials to replace Pt as the counter electrode for DSSCs. In general, there are three kind of materials to be used as the Pt-free electro-catalytic film, including carbon, conductive polymer, and transition metal compound. In order to develop the efficient Pt-free electro-catalytic film, this thesis includes two parts. The first part is about using different dimensional structures of graphite as the counter electrode for DSSCs. The second part is combining nickel nanoparticles and poly (3, 4-ethylene dioxythiophene): poly (styrene sulfonate) (PEDOT:PSS) into a composite film as the counter electrodes for DSSCs. For investigating the better performance of graphite as the counter electrode for DSSCs, the first part of this thesis is comparing the three different dimensional structures of graphite, including one dimensional graphite nanofiber (1-D-GNF), two dimensional natural graphite (2-D-NtG), and three dimensional nanographite (3-D-NnG), used as the electro-catalytic film. The graphite were dispersed in the solution of ethanol mixed with nafionR117, and then coated on the ITO glass substrates by drop-casting. The characteristics of the three different dimensional structures of graphite are discussed, including the morphology, degree of defect, surface area, and conductivity. 3-D-NnG shows the best performance of 7.88% , which is close to the performance of Pt (8.38%), due to its higher degree of defect causing the more superior electro-catalytic ability . On the other hand , 1-D-GNF and 2-D-NtG show the lower degree of defect compared to 3-D-NnG that cause the poorer performance (1-D-GNF is 3.60% and 2-D-NtG is 2.99%). Moreover, the electro-catalytic ability of graphite was also investigated by some common electrochemical methods and quantified by rotating disk electrode (RDE). In order to develop the suitable materials as the electro-catalytic film for DSSCs, there are many reports about using the composite film which the two materials can provide each their advantages to obtain the higher efficiency for DSSCs. The second part of this thesis is about blending nickel nanoparticles and PEDOT:PSS into the slurry, and coating the slurry on FTO glass substrates by the doctor-blade method as the composite film. The superior electro-catalytic ability and conductivity of nickel nanoparticles has been widely reported, but the high density and aggregation of nickel nanoparticles will let the film crack and detach from the substrate. PEDOT:PSS has been also widely reported and applied as the counter electrode for DSSCs, but its poor conductivity and electro-catalytic ability will limit its application. The composite film of nickel nanoparticles and PEDOT:PSS distributes the good performance (7.01%, the performance of Pt is 7.63%) for DSSCs because the good performance can be attributed to the good catalytic ability, conductivity of nickel nanoparticles and the good adhesion of PEDOT:PSS. The disadvantages of nickel nanoparticles and PEDOT:PSS which cause the lower performance (nickel nanoparticles is 0.24%, PEDOT:PSS is 4.36%) compared to the composite film have been solved in this study. The morphologies and characteristics of the films containing the various materials were also specified. The long-term stability of the composite film is better than the Pt film that means the composite film is more suitable for the commercial purpose than the Pt film. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T13:44:07Z (GMT). No. of bitstreams: 1 ntu-102-R00524046-1.pdf: 4201458 bytes, checksum: 5d6a20ca981147d31be38882eccf274d (MD5) Previous issue date: 2013 | en |
dc.description.tableofcontents | Chinese abstract (中文摘要) I
Abstract Ⅲ Table of contents V List of tables VIII List of figures IX Chapter 1 Introduction 1 1.1. The importance of investigating the solar energy 1 1.2. Solar cells 1 1.3. Silicon solar cells 4 1.4. Inorganic compound solar cells 7 1.5. Organic materials-based solar cells 9 1.6. Dye-sensitized solar cells (DSSCs) 11 1.6.1. Introduction to DSSCs 11 1.6.2. Photoanode 16 1.6.3. Dye-sensitizer 20 1.6.4. Electrolyte 22 1.6.5. Counter electrode 24 1.6.5.1. Platinum counter electrode (Pt-CE) 24 1.6.5.2. Carbon counter electrode 25 1.6.5.3. Conductive polymer counter electrode 26 1.6.5.4. Metal-based materials counter electrode 27 1.6.5.5. Composite materials counter electrode 28 1.7. Theoretic power conversion efficiency 29 1.7.1. Photovoltaic parameters of a solar cell 29 1.7.2. Definition of air mass (AM) 29 1.8. Motivation and research objectives 30 Chapter 2 Experimental Section 32 2.1. Instruments 32 2.2. Materials 34 2.3. Experimental procedures 36 2.3.1. Substrates and reagents 36 2.3.2. TiO2 film preparation 36 2.3.3. Dye-sensitized TiO2 film preparation 36 2.3.4. Pt film preparation 37 2.3.5. Liquid electrolyte preparation 37 2.3.6. Cell assembling 37 2.3.7. Photocurrent density-voltage (J-V) characteristic 37 2.3.8. Impedance measurement 37 2.3.9. Incident photon-to-current conversion efficiency (IPCE) 38 2.3.10.Rotating disk electrode (RDE) 38 Chapter 3 Graphites with Different Dimensional Structures as Catalysts for Counter Electrodes in Dye-sensitized Solar Cells 39 3.1. Introduction 39 3.2. Results and discussions 41 3.2.1. Characteristics of GNF, NtG, and NnG 41 3.2.2. The properties of the films of GNF, NtG, and NnG 44 3.2.3. Photovoltaic performance of the dye-sensitized solar cells with GNF, NtG, NnG, and Pt as the counter electrode materials 45 3.2.4. Electrochemical impedance spectroscopy studies of the counter electrodes with GNF, NtG, NnG, and Pt 46 3.2.5. Electro-catalytic abilities of the films of GNF, NtG, NnG, and Pt by cyclic voltammetry and by rotating disk electrode system 47 3.2.6. Tafel-polarization measurements of the electro-catalytic abilities for the counter electrodes with GNF, NtG, NnG, and Pt 51 Chapter 4 A Composite Catalytic Film of Ni-NPs/PEDOT:PSS for Counter Electrodes in Dye-sensitized Solar Cells 53 4.1. Introduction 53 4.2. Results and discussions 55 4.2.1. Surface morphologies and characteristics of PEDOT:PSS, Ni-NPs/PEDOT:PSS, and Pt films 55 4.2.2. Photovoltaic performance of dye–sensitized solar cells with PEDOT:PSS, Ni-NPs, Ni-NPs/PEDOT:PSS, and Pt films as counter electrodes 59 4.2.3. Electrochemical impedance spectroscopy studies of the counter electrodes with PEDOT:PSS, Ni-NPs, Ni-NPs/PEDOT:PSS, and Pt 61 4.2.4. Tafel-polarization measurements of the electro-catalytic abilities for the counter electrodes with PEDOT:PSS, Ni-NPs, Ni-NPs/PEDOT:PSS, and Pt 62 4.2.5. Cyclic voltammetry analyses of the electro-catalytic ability of triiodide ions reduction for the electrodes with PEDOT:PSS, Ni-NPs/PEDOT:PSS, and Pt films 64 4.2.6. Incident photon-to-current conversion efficiency analyses for DSSC with PEDOT:PSS, Ni-NPs, Ni-NPs/PEDOT:PSS, and Pt films as CEs 66 Chapter 5 Conclusions and Suggestions 68 5.1. Conclusions 68 5.1.1. Graphites with different dimensional structures as catalysts for counter electrodes in dye-sensitized solar cells (chapter 3) 68 5.1.2. A composite catalytic film of Ni-NPs/PEDOT:PSS for counter electrodes in dye-sensitized solar cells (chapter 4) 69 5.2. Suggestions 70 5.2.1. Graphite-based counter electrode 70 5.2.2. Composite film-based counter electrode 70 References 71 Appendix A Surfactant-modified Polypyrrole as the Catalysts used for Counter Electrodes in Dye–sensitized Solar Cells 89 A.1. Introduction 89 A.2. Experimental section 91 A.2.1. Materials 91 A.2.2. Synthesis of polypyrrole nanopartic 91 A.2.3. reparation of the photoanode and counter electrode and characterization of the counter electrode 92 A.2.4. Cell assembly and measurements 92 A.3. Results and discussions 93 A.3.1. The properties of the films of surfactant-modified polypyrrole 93 A.3.2. Photovoltaic performance of the dye–sensitized solar cells with surfactant-modified polypyrrole, and Pt as the counter electrode materials 93 A.4. Conclusions 95 References 96 Appendix B Supporting Information 99 Appendix C Curriculum Vitae 104 | |
dc.language.iso | en | |
dc.title | 以石墨及複合材料之無鉑對電極應用於染料敏化太陽能電池 | zh_TW |
dc.title | Graphite and Composite Material Applied as
the Platinum-Free Counter Electrode for Dye-Sensitized Solar Cells | en |
dc.type | Thesis | |
dc.date.schoolyear | 101-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 顏溪成(Shi-Chern Yen),陳林祈(Lin-Chi Chen),周澤川(Tse-Chuan Chou) | |
dc.subject.keyword | 對電極,染料敏化太陽能電池,石墨,聚二氧乙基?吩-聚苯乙烯磺酸,無鉑,金屬鎳的奈米粒子,旋轉電極, | zh_TW |
dc.subject.keyword | Counter electrode,Dye-sensitized solar cell,Graphite,PEDOT:PSS,Pt-free,Nickel nanoparticle,Rotating disk electrode, | en |
dc.relation.page | 104 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2013-07-10 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-102-1.pdf 目前未授權公開取用 | 4.1 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。