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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱靜雯 | |
| dc.contributor.author | Li-Wei Chan | en |
| dc.contributor.author | 詹立暐 | zh_TW |
| dc.date.accessioned | 2021-06-16T13:26:08Z | - |
| dc.date.available | 2023-12-31 | |
| dc.date.copyright | 2013-07-30 | |
| dc.date.issued | 2013 | |
| dc.date.submitted | 2013-07-23 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/62070 | - |
| dc.description.abstract | 單芽氮異環碳烯之重元素相似物的性質及配位特性已經被研究了數十年，並
且在這方面有顯著的成果。然而，在單一分子中具有兩個以上的氮異環碳烯重元 素相似物卻是非常少見。因此，在本篇論文中，我們以合成具有高對稱性的多牙 氮異環碳烯重元素相似物為目標，其中包含了鍺烯、錫烯、r 及鉛烯，並對其做鑑 定及反應性的探討。在分子設計的部分，我們藉由立障極大的取代基，如：均三 甲苯和叔丁基，來穩定碳烯重元素相似物中的空軌域，並且以三亞苯作為分子骨 架來達成高對稱性分子的目的。鍺烯、錫烯、及鉛烯的合成，可以利用二價的鍺、 錫、鉛的前驅物，利用取代反應來獲得，並且以異核核磁共振光譜來證明其存在。 在矽烯的合成方面，我們先和成了四價的矽烷前驅物，之後再以強還原試劑將四 價矽還原成二價矽，但是在經過許多嘗試後，還是無法達到預期的結果。 | zh_TW |
| dc.description.abstract | Being the heavier analogues of N-heterocyclic carbene, the coordination chemistry
of the so-called NHE (E = Si, Ge, Sn, Pb) have been investigated for decades. However, while significant progresses were made in poly-NHCs, molecules bearing multiple NHE units have only been reported few times. In this work, the syntheses of symmetrically N,N’-substituted tritopic metallylenes featuring a rigid molecular backbone will be presented. Tritopic NHSi precursors, dichlorosilanes, obtained from deprotonated hexa-(alkylamino)triphenylene and SiCl4 failed in generating tri-silylene from chemical reductions with K, KC8, and LiNp. On the other hand, reaction of deprotonated hexamine and ECl2 (E = Sn, Pb) gives the desired tritopic metallylenes, which can also be prepared from the reaction of hexamine and E[N(TMS)2]2 (E = Ge, Sn, Pb). The only exception is the reaction of hexa-(tert-butylamino)triphenylene and Sn[N(TMS)2]2 that yields the imine coordinated stannylene. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T13:26:08Z (GMT). No. of bitstreams: 1 ntu-102-R00223116-1.pdf: 5528249 bytes, checksum: 294eb2e3fcb2006d0deceb3b9a9b0a5e (MD5) Previous issue date: 2013 | en |
| dc.description.tableofcontents | 口試委員會審定書 ............................................................................................................i
中文摘要 .......................................................................................................................... ii ABSTRACT .................................................................................................................... iii CONTENTS .....................................................................................................................iv LIST OF FIGURES ..........................................................................................................vi LIST OF SCHEMES ..................................................................................................... viii Chapter 1 Introduction .............................................................................................. 1 1.1 Carbene ........................................................................................................... 1 1.2 Metallylenes .................................................................................................... 4 1.2.1 Silylene .................................................................................................. 4 1.2.2 Germylene ............................................................................................. 6 1.2.3 Stannylene ............................................................................................. 9 1.2.4 Plumbylene .......................................................................................... 11 1.3 Reactivity of Metallylenes ............................................................................ 13 1.4 Research Objective ....................................................................................... 15 Chapter 2 Molecular Design and Synthetic Methods ........................................... 18 2.1 Molecular Design.......................................................................................... 18 2.2 Synthetic Methods ........................................................................................ 20 Chapter 3 Results and Discussion ........................................................................... 23 3.1 Synthesis of Hexaminotriphenylenes ........................................................... 23 3.2 Synthesis of N-Heterocyclic Silylenes.......................................................... 24 3.3 Synthesis of N-Heterocyclic Germylenes ..................................................... 26 3.4 Synthesis of N-Heterocyclic Stannylenes ..................................................... 28 v 3.5 Synthesis of N-Heterocyclic Plumbylenes.................................................... 32 3.6 UV-Vis Spectrum of N-Heterocyclic Metallylenes ...................................... 35 3.7 Reactivities of N-Heterocyclic Metallylenes ................................................ 36 Chapter 4 Conclusions ............................................................................................. 38 Chapter 5 Experimental Section ............................................................................. 39 REFERENCES ................................................................................................................ 50 APPENDIX…………………………………………………………………………….54 | |
| dc.language.iso | en | |
| dc.title | 三芽氮異環碳烯之重元素相似物的合成與鑑定 | zh_TW |
| dc.title | Syntheses of Tritopic N-Heterocyclic Metallylenes | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 101-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 詹益慈,王志傑 | |
| dc.subject.keyword | 矽烯,鍺烯,錫烯,鉛烯,均三甲苯,叔丁基,三亞苯, | zh_TW |
| dc.subject.keyword | metallylene,silylene,germylene,stannylene,plumbylene, | en |
| dc.relation.page | 104 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2013-07-23 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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