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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 鄭原忠(Yuan-Chung Cheng) | |
| dc.contributor.author | Hung-Hsuan Lin | en |
| dc.contributor.author | 林紘玄 | zh_TW |
| dc.date.accessioned | 2021-06-16T13:14:27Z | - |
| dc.date.available | 2016-07-31 | |
| dc.date.copyright | 2013-07-31 | |
| dc.date.issued | 2013 | |
| dc.date.submitted | 2013-07-30 | |
| dc.identifier.citation | [1] Robert E. Blankenship. Molecular Mechanisms of Photosynthesis. Blackwell Sci- ence, Oxford, 2002.
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Calhoun, Tae-Kyu Ahn Elizabeth L. Read, Toma ́sˇ Mancˇal, Yuan-Chung Cheng, Robert E. Blankenship, and Granham R. Fleming. Evidence for Wavelike Energy Transfer Thorough Quantum Coherence in Photo- synthetic Systems. Nature, 446:782, 2007. [9] Gabriela S. Schlau-Cohen, Akihito Ishizaki, Tessa R. Chalhoun, Naomi S. Gins- berg, Matteo Ballottari, Roberto Bassi, and Granham R. Fleming. Elucidation of the timescales and origins of quantum electronic coherence in LHCII. Nature, 4:389, 2012. [10] Niklas Christensson, Franz Milota, Jennifer A. Hauer, Joseph Sperling, Oliver Bixner, Attila L. Ne ́meth, and Harald F. Kauffmann. High Frequency Vibrational Modulations in Two-Dimensional Electronic Spetra and Their Resemblance to Elec- tronic Coherence Signatures. J. Phys. Chem. B, 115:5383, 2011. [11] Sergey Polyutov, Oliver Kuhn, and Tonu Pullerits. Exciton-Vibrational Coupling in Molecular Aggregates: Electronic versus Vibronic Dimer. Chem. Phys., 394:21, 2012. [12] Jordan M. 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Vibrational Coherence Transfer and Trap- ping as Sources for Long-Lived Quantum Beats in Polarized Emission from Energy Transfer Complexes. J. Phys. Chem. A, 108:11196, 2004. [28] Shaul Mukamel. Principles of Nonliear Optical Spectroscopy. Oxford University Press, New York, 1995. [29] Tobias Brixner, Jens Stenger, Harsha M. Vaswani, Minhaeng Cho, Robert E. Blankenship, and Graham R. Fleming. Two-Dimensional Spectroscopy of Elec- tronic Couplings in Photosynthesis. Nature, 434:625, 2005. [30] Minhaeng Cho and Graham R. Fleming. The Integrated Photon Echo and Solvation Dynamics. II. Peak Shifts and Two-Dimensional Photon Echo of a Coupled Chro- mophore System. J. Chem. Phys., 123:114506, 2005. [31] Minhaeng Cho, Tobias Brixner, Igor Stiopkin, Harsha Vaswani, and Graham R. Fleming. Two Dimensional Electronic Spectroscopy of Molecular Complexes. J. Chin, Chem. Soc., 53:15, 2006. [32] Sarah M. Gallagher Faeder and David M. Jonas. 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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/61819 | - |
| dc.description.abstract | 經過數十億年的演化,行光合作用的生物體(photosynthetic organism)已經 發展出精密的光捕獲系統 (light-harvesting system) 。這些系統可以有效率地捕捉光 能並將光能轉移到反應中心 (reaction centre)。近年來,科學家發展出二維電子光 譜(two-dimensional electronic spectroscopy)的技術,用以研究並瞭解光合作用系 統中的能量轉移的機制。在本論文中,吾人透過理論計算的方法去研究二維電子 光譜中量子拍(quantum beat)的現象,並檢驗如何辨別二維電子光譜中電子相干 性(electronic coherence)和振動相干性(vibrational coherence)。本研究工作發 現二維電子光譜可提供比過去認為更多的資訊並讓我們能更進一步瞭解光合作用 中能力轉移的機制。 | zh_TW |
| dc.description.abstract | Over billions of years, photosynthetic organisms have developed sophistic light-harvesting systems. These systems can efficiently capture solar energy and then transmit the energy to reaction centre with high quantum yield. We can learn about the mechanism of en- ergy transfer through two-dimensional (2D) electronic spectroscopy. So far, it is believed that the efficient energy transfer is related to quantum coherence. In this work, We study the coherence quantum beats in 2D electronic spectroscopy calculated by a theoretical method based on a time-nonlocal quantum master equation and a scheme for the evalua- tion of the third-order photon echo polarization. We aim to examine how electronic and vibrational coherence can be distinguished in 2D spectra. We do find unique characteris- tics of vibrational coherence that help us distinguish electronic and vibrational coherence. In this work we find that two-dimensional electronic spectroscopy provide more informa- tion and more understand the mechanism of energy transfer in photosynthetic organisms. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T13:14:27Z (GMT). No. of bitstreams: 1 ntu-102-R00223163-1.pdf: 10970378 bytes, checksum: 75fa59266b2e12a98634d24bf1c4b569 (MD5) Previous issue date: 2013 | en |
| dc.description.tableofcontents | 誌謝 i
中文摘要 iii 英文摘要 iv 1 Introduction 1 1.1 PhotosyntheticExcitationEnergyTransfer . . . . . . . . . . . . . . . . . 1 1.2 Two-DimensionalElectronicSpectroscopy. . . . . . . . . . . . . . . . . 6 2 Theoretical Background 13 2.1 Introduction................................. 13 2.2 Perturbative Evaluation of the Third-Order Polarization . . . . . . . . . . 15 2.3 Non-Markovian Evolution in the Presence of Laser Field . . . . . . . . . 18 2.4 TheTreatmentofVibrationalStates .................... 21 3 Vibrational Coherence of Monomer in 2D Spectrum 25 3.1 Model.................................... 25 3.2 VibronicLieshapein2DES......................... 30 3.3 TheeffectofHuang-Rhysfactors...................... 32 3.4 Theeffectofstrengthofsystem-bathcoupling . . . . . . . . . . . . . . . 32 3.5 Characteristicsofquantumbeats ...................... 33 4 Mixing Electronic-Vibrational Coherence of in 2D Spectra 47 4.1 DimerModel ................................ 47 4.2 Theeffectofelectroniccoupling ...................... 50 4.3 Thecharacteristicsofquantumbeats.................... 51 5 Conclusion 59 | |
| dc.language.iso | en | |
| dc.subject | 光譜學 | zh_TW |
| dc.subject | 動力學 | zh_TW |
| dc.subject | Kinetics | en |
| dc.subject | Spectroscopy | en |
| dc.title | 二維電子光譜中訊號振盪之理論研究: 電子相干性或是振動相干性 | zh_TW |
| dc.title | Origin of Quantum Beats in 2D Electronic Spectroscopy: Electronic versus Vibrational Coherences | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 101-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 金必耀(Bih-Yaw Jin),朱立岡(Li-Kang Chu) | |
| dc.subject.keyword | 動力學,光譜學, | zh_TW |
| dc.subject.keyword | Kinetics,Spectroscopy, | en |
| dc.relation.page | 71 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2013-07-30 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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