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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 韋文誠(Wen-Cheng Wei) | |
| dc.contributor.author | Te-Jung Huang | en |
| dc.contributor.author | 黃德榮 | zh_TW |
| dc.date.accessioned | 2021-06-16T13:14:07Z | - |
| dc.date.available | 2023-07-29 | |
| dc.date.copyright | 2013-08-16 | |
| dc.date.issued | 2013 | |
| dc.date.submitted | 2013-07-30 | |
| dc.identifier.citation | References
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/61811 | - |
| dc.description.abstract | 本研究選擇鉍鍶鐵及鉍鍶鈷鐵鈣鈦礦之陰極材料，運用於中溫型燃料電池 (600°C – 800°C)，使用X光繞射、電導率量測、離導率量測、熱膨脹，以及全電池電能輸出量測予以分析。從XRD分析中，成功利用EDTA-檸檬酸鰲合法製備出單一相鈣鈦礦結構粉體。其中，鍶摻雜鐵酸鉍的燒結樣品中，以50 %鍶摻雜鐵酸鉍的樣品在800°C時的電導率及離導率分別為1.5 S cm-1、0.011 S cm-1為最佳；在鍶鈷共摻雜鐵酸鉍燒結樣品中，以鍶摻雜50 %、鈷摻雜20 %的樣品在800°C時電導率及離導率分別為5.4 S cm-1、0.032 S cm-1為最佳。熱分析的結果顯示，鍶摻雜鐵酸鉍的熱膨脹係數隨鍶摻雜的量增加而增加，其從10.0 ppm K-1至15.1ppm K-1。而以鍶鈷共摻雜鐵酸鉍樣品中，熱膨脹係數以鈷摻雜20 % 達到最大，其值為19.1 ppm K-1。S50C20 在所有樣品中擁有最低的極化電阻值，0.1 Ω cm2。以鑭鍶鈷鐵作為陰極的單一陽極支撐全電池為標準電池，其I-V量測的結果中，以S50及S50C20為陰極組成的全電池，輸出分別為361 mW cm-2、405 mW cm-2，其皆高於標準電池的輸出，353 mW cm-2。 | zh_TW |
| dc.description.abstract | Two series perovskites, Bi1-xSrxFeO3-δ (x = 0.1-0.5) and Bi0.5Sr0.5CoyFe1-yO3-δ (y = 0-0.2), have been synthesized by EDTA-citric complexing method and characterized in intermediate-temperature range (600 to 800°C) by X-ray diffraction, electrical property study, thermal analysis and cell testing. The results show single-phase perovskite structure offering CTE values from 10.0 to 19.1 ppmk-1. Two samples S50 and S50C20 perform maximal electrical and ionic conductivities among the series. Polarization resistance from Nyquist plot depicts that S50C20 has a lowest value of 0.10 Ω.cm2. The cells with S50 or S50C20 cathode comparing to the standard cell with La0.6Sr0.4Co0.2Fe0.8O3-δ cathode show the power density 361 mWcm-2,405 mW cm-2 and 353 mW cm-2,respectively. The cells with Bi-base cathodes have a power density higher then that of STD cell. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T13:14:07Z (GMT). No. of bitstreams: 1 ntu-102-R00527050-1.pdf: 3203831 bytes, checksum: 010598e672fc850e3341ba316b641f05 (MD5) Previous issue date: 2013 | en |
| dc.description.tableofcontents | 誌謝 II
摘要 IV Abstract V List of Figures IX List oF Tables XIII Chapter 1 Introduction 1 Chapter 2 Literature Review 4 2.1 Bismuth Ferrite (BiFeO3) 4 2.1.1 Crystal Structure 4 2.1.2 Conductivity 5 2.1.3 Dielectric Property 5 2.2 Cathode Requirements 6 2.3 Development of Perovskite Cathodes 6 2.3.1 Manganite-based Cathodes 7 2.3.2 Cobaltite-based Cathodes 8 2.3.3 Cobaltite-based Cathodes 8 2.3.4 Ferro-cobaltite-based Cathodes 9 2.3.5 Nickelate-based Cathodes 9 2.4 Cell with (La, Sr)(Co, Fe) O3 Materials 10 2.4.1 General Performance 10 2.4.2 Electrical Property 11 2.4.3 Coefficient of Thermal Expansion (CTE) 12 2.5 Materials Design for Perovskite 13 2.5.1 Structure Field Map 13 2.5.2 Goldschmidt Tolerance Factor 14 2.5.3 Critical Radius 14 2.5.4 Potential Map of Perovskite Materials 15 Chapter 3 Experimental Procedure 36 3.1 Preparation of Materials 36 3.2 Material Characterization 36 3.2.1 X-Ray diffraction 36 3.2.2 Electrical and Ionic conductivity measurement 37 3.2.3 Thermal Expansion Analysis (TMA) 37 3.2.4 Electrochemical Impedance Spectrum (EIS) Analysis 38 3.3 Cell Fabrication and Testing 38 3.3.1 Anode Preparation 38 3.3.2 Slurry Preparation 8YSZ 38 3.3.3 Fabrication YSZ film by Slurry Spin-Coating 39 3.3.4 Cathode Preparation 39 3.3.5 Cell Testing 39 3.4 Transference number 40 Chapter 4 Results 43 4.1 Crystalline Structure 43 4.2 Electrical Conductivity 43 4.3 Ionic Conductivity 44 4.4 Transference Number 45 4.5 Coefficient of Thermal Expansion 45 4.6 Cell Microstructure and Performance 46 4.7 Area Specific Resistance (ASR) 47 4.8 Polarization Resistance (Rp) 47 4.9 X-Ray Photoelectron Spectroscopy (XPS) 48 Chapter 5 Discussion 81 5.1 Controlled Conductive Mechanism 81 5.2 Bonding in Bismuth Strontium Ferrites of Perovskite Structure 83 5.3 Relationship of CTE and Ionic conductivity 84 Chapter 6 Conclusions 92 6.1 Electrical and Thermal Property 92 6.2 Cell Performance and Polarization Resistance 93 Reference 94 | |
| dc.language.iso | en | |
| dc.subject | 固態電解質燃料電池 | zh_TW |
| dc.subject | 鈣鈦礦 | zh_TW |
| dc.subject | 鐵酸鉍 | zh_TW |
| dc.subject | 鈷 | zh_TW |
| dc.subject | 陰極 | zh_TW |
| dc.subject | SOFC | en |
| dc.subject | perovskite | en |
| dc.subject | bismuth ferrite | en |
| dc.subject | cobalt | en |
| dc.subject | cathode | en |
| dc.title | 氧化鉍基鈣鈦礦陰極材料用於中溫型燃料電池之研究 | zh_TW |
| dc.title | Bismuth-based perovskite as cathode materials for intermediate -temperature solid oxide fuel cells | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 101-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 郭俞麟(Yu-Lin Kuo),洪逸明,馬小康(Hsiao-Kan Ma) | |
| dc.subject.keyword | 固態電解質燃料電池,鈣鈦礦,鐵酸鉍,鈷,陰極, | zh_TW |
| dc.subject.keyword | SOFC,perovskite,bismuth ferrite,cobalt,cathode, | en |
| dc.relation.page | 105 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2013-07-30 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 材料科學與工程學系 | |
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