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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/60666完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 楊燿州(Yao-Joe Yang) | |
| dc.contributor.author | Po-Cheng Huang | en |
| dc.contributor.author | 黃柏承 | zh_TW |
| dc.date.accessioned | 2021-06-16T10:25:19Z | - |
| dc.date.available | 2013-08-16 | |
| dc.date.copyright | 2013-08-16 | |
| dc.date.issued | 2013 | |
| dc.date.submitted | 2013-08-15 | |
| dc.identifier.citation | [1] 張正華等人，《有機與塑膠太陽能電池》，五南圖書，台北市，2007
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/60666 | - |
| dc.description.abstract | 在本研究中，我們利用化學水溶液法(Chemical solution method)合成氧化鋅奈米結構，運用化學水溶液法製程低溫、簡單的特性，簡便的合成氧化鋅材料，並藉由調配不同有機胺的成分比例，達成不同形貌的氧化鋅奈米結構，其中包含氧化鋅奈米線(ZnO nanowire)、無基板氧化鋅奈米線薄膜(Substrate-free ZnO nanowire film)、星狀氧化鋅奈米顆粒(Star-like ZnO nanoparticles)，我們分別探討反應時間對各結構的成長厚度及型態的影響。材料特性鑑定方面，透過SEM、X光繞射分析、氮氣等溫吸附等方法，來探討三種不同形貌的氧化鋅奈米結構、結晶方向、比表面積及孔隙率等。本研究也分別利用上述三種氧化鋅奈米結構，結合商用N719染料、I-/I3-碘系電解液及鉑相對電極組裝成染料敏化太陽能電池，經太陽能電池特性測量，氧化鋅奈米線工作電極擁有最高1.9%的光電轉換效率，並產生8.54mA/cm2的短路電流，同時也分析比較各結構之差異。入射光子-電流轉換效率(IPCE)方面，測得最高IPCE轉換效率為26.85%。本研究也從電化學交流阻抗圖譜去分析各結構對於染料敏化太陽能電池的阻抗影響，透過等效模型來驗證氧化鋅在電子擴散速率上的優勢。 | zh_TW |
| dc.description.abstract | In this work, we present three ZnO nanostructures synthesized by chemical solution method. Solution approaches to synthesize ZnO nanostructures are appealing because of their low growth temperature and good potential for scaling-up. By modifying different Amine ingredients, three types of ZnO nanostructures were grown, including ZnO nanowire array, substrate-free ZnO nanowire film, and Star-like ZnO nanoparticles. The influences of reaction times on the thickness and morphology of nanostructures were also presented. The XRD patterns showing highly diffraction intensity in z-direction ZnO nanowire were observed. The development of dye-sensitized solar cell utilized these nanostructures as photo anodes were presented. The dye-sensitized solar cell comprises a FTO glass with dense ZnO nanostructures as working electrode, a platinized FTO glass as counter electrode, N719-based dye, and I-/I3- liquid electrolyte. The dye-sensitized solar cell fabricated using such nanostructures yields a highest power conversion efficiency of 1.9% and the IPCE photo-current efficiency is up to 26.85%. Electrochemical impedance spectroscopy is applied to investigate the characteristics of dye-sensitized solar cells in this study. The improvement of the electron transport in the ZnO photo anode has also been demonstrated. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T10:25:19Z (GMT). No. of bitstreams: 1 ntu-102-R00522712-1.pdf: 7167187 bytes, checksum: f43fdc4312321fdfb1b4de40fc2fccb8 (MD5) Previous issue date: 2013 | en |
| dc.description.tableofcontents | 致謝 I
摘要 III Abstract IV 目錄 V 表目錄 VIII 圖目錄 IX 符號說明 XII 第一章 緒論 1 1.1 前言 1 1.2 太陽能電池概述 2 1.2.1 矽基型太陽能電池 2 1.2.2 無機化合物半導體太陽能電池 3 1.2.3 有機化合物太陽能電池 4 1.3 文獻回顧 7 1.3.1 化學水溶液法製備氧化鋅奈米結構 7 1.3.2 氧化鋅染料敏化太陽能電池 12 1.4 研究動機與目的 22 1.5 論文架構 23 第二章 基礎理論與元件設計 24 2.1 染料敏化太陽能電池原理 24 2.1.1 工作原理及電子傳遞流程 24 2.1.2 染料敏化太陽能電池之電池特性 28 2.1.2.1 太陽光光譜 28 2.1.2.2 太陽能電池等效電路 29 2.1.2.3 伏安特性曲線(Volt-Ampere curve) 30 2.1.2.4 開路電壓(Open circuit voltage, VOC) 32 2.1.2.5 短路電流(Short circuit current, ISC) 33 2.1.2.6 填充因子(Fill factor, FF) 33 2.1.2.7 光電轉換效率(Power conversion efficiency, η) 33 2.1.2.8 入射光子-電流轉換效率(Incident photon to current conversion efficiency, IPCE) 34 2.1.2.9 電化學交流阻抗分析(Electrochemical impedance spectroscopy, EIS) 35 2.2 氧化鋅合成理論 44 2.2.1 氧化鋅簡介 44 2.2.2 氧化鋅奈米結構合成法 46 2.2.2.1 氣相合成法(Vapor phase synthesis, VPS) 46 2.2.2.2 溶膠-凝膠法(Sol-gel method) 48 2.2.2.3 模板法(Template synthesis) 48 2.2.2.4 電化學沉積法(Electrochemical deposition) 48 2.2.3 化學水溶液法(Chemical aqueous solution method) 49 2.2.4 氧化鋅材料於染料敏化太陽能電池之應用 52 2.3 本研究之染料敏化太陽能電池設計 53 2.3.1 電池設計 53 2.3.2 電池陽極 54 2.3.3 有機染料 56 2.3.4 電解質 58 2.3.5 相對電極 59 第三章 製程方法與步驟 60 3.1 實驗製作總流程 60 3.2 實驗所需藥品 63 3.3 氧化鋅工作電極製作 64 3.3.1 基板前處理 64 3.3.2 一維氧化鋅奈米線陣列 65 3.3.3 無基板氧化鋅奈米線薄膜製備 68 3.3.4 星狀氧化鋅奈米顆粒團簇製備 69 3.3.5 氧化鋅奈米線與奈米顆粒複合結構製備 71 3.4 有機染料製備 72 3.5 電解液製備 72 3.6 相對電極製備 73 3.7 染料敏化太陽能電池組裝 73 第四章 實驗結果與量測討論 75 4.1 氧化鋅奈米結構製作結果 75 4.1.1 一維氧化鋅奈米陣列 75 4.1.2 無基板氧化鋅奈米線薄膜 80 4.1.3 星狀氧化鋅奈米顆粒團簇 84 4.1.4 氧化鋅奈米線與星狀奈米顆粒複合結構 88 4.1.5 X光繞射分析 (XRD) 89 4.2 染料敏化太陽能電池特性量測 (I-V curve) 90 4.1 量測設備架設 90 4.2 伏安特性曲線量測結果 92 4.3 入射光子-電流轉換效率量測 (IPCE) 97 4.3.1 量測設備架設 97 4.3.2 入射光子-電流轉換效率量測 98 4.4 電化學交流阻抗分析 (EIS) 99 4.4.1 量測設備架設 99 4.4.2 電化學阻抗圖譜與分析 99 第五章 結論與未來展望 103 5.1 結論 103 5.2 未來展望 104 參考文獻 106 附錄 A：X光繞射分析(X-ray diffraction) 117 附錄 B：吸附理論 118 B.1 吸附特性 118 B.2 吸附平衡 118 B.3 Isotherm等溫曲線 118 | |
| dc.language.iso | zh-TW | |
| dc.subject | 奈米顆粒 | zh_TW |
| dc.subject | 化學水溶液法 | zh_TW |
| dc.subject | 氧化鋅 | zh_TW |
| dc.subject | 奈米線 | zh_TW |
| dc.subject | 染料敏化太陽能電池 | zh_TW |
| dc.subject | Dye-sensitized solar cell | en |
| dc.subject | Zinc Oxide | en |
| dc.subject | Nanowire | en |
| dc.subject | Nanoparticle | en |
| dc.subject | Chemical solution method | en |
| dc.title | 以化學水溶液法合成多形貌氧化鋅奈米結構及其於染料敏化太陽能電池之應用 | zh_TW |
| dc.title | ZnO Nanostructures Synthesis by Chemical Solution Method and Its Application in Dye-Sensitized Solar Cell | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 101-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳國聲(Kuo-Shen Chen),蘇裕軒(Yu-Hsuan Su),范士岡(Shih-Kang Fan) | |
| dc.subject.keyword | 化學水溶液法,氧化鋅,奈米線,奈米顆粒,染料敏化太陽能電池, | zh_TW |
| dc.subject.keyword | Chemical solution method,Zinc Oxide,Nanowire,Nanoparticle,Dye-sensitized solar cell, | en |
| dc.relation.page | 119 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2013-08-15 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 機械工程學研究所 | zh_TW |
| 顯示於系所單位： | 機械工程學系 | |
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