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| ???org.dspace.app.webui.jsptag.ItemTag.dcfield??? | Value | Language |
|---|---|---|
| dc.contributor.advisor | 鄭如忠 | |
| dc.contributor.author | Meng-Chiao Lin | en |
| dc.contributor.author | 林孟橋 | zh_TW |
| dc.date.accessioned | 2021-06-16T10:21:51Z | - |
| dc.date.available | 2018-08-26 | |
| dc.date.copyright | 2013-08-26 | |
| dc.date.issued | 2013 | |
| dc.date.submitted | 2013-08-16 | |
| dc.identifier.citation | 參考文獻
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/60566 | - |
| dc.description.abstract | 本研究設計合成含噻吩-呋喃共軛臂鏈之星狀(star-shaped,S)小分子並應用於溶液製程有機太陽能電池。利用雙噻吩(bi-thiophene,TT)為S之核心，逐步反應形成含有四個噻吩-呋喃共軛臂鏈之S-TT。進一步比較以TT為中心含兩個噻吩-呋喃共軛臂鏈之線性(linear,L)小分子材料(L-TT)，探討多維共軛臂鏈對小分子光電物理性質之影響。此系列S-TT與L-TT在一般有機溶劑有良好的溶解度。因S-TT 有較多的共軛臂鏈，因此比 L-TT 具備更好的熱穩定性。由紫外光-可見光光譜發現，S-(TT)在薄膜狀態下其吸收波長較L-(TT)紅位移，顯示多維共軛臂鏈的導入能有效提供分子間引力，幫助成膜性。由光電子光譜實驗顯示，多維共軛臂鏈可有效改變TT核心的旋轉角度，並有效調控HOMO能階。理論計算結果推測，多維共軛臂鏈能有效調整小分子之能階與多維方向的電子分佈。初步將小分子材料與PC61BM混摻(1:1,w/w)製備成太陽能電池之主動層，元件採用反式結構，其中氧化锌作為元件電子選擇層和三氧化鉬為電洞選擇層，再使用銀為陽極和氧化銦錫為陰極。在 AM 1.5 照度下S-(TT)之光伏參數:開路電壓為0.81 V，短路電流為1.62 mAcm
-2，填充因子為0.30，轉換效率為0.40%。L-(TT)之開路電壓為0.88V，短路電流為 1.09mAcm-2，填充因子為0.33，轉換效率為0.32 %。結果顯示多維共軛臂鏈的導入能有效增加小分子吸收太陽光特性，增加光電轉換效率。 | zh_TW |
| dc.description.abstract | A novel four-arm star-shaped (S) small molecule based on oligo(thienylfuran)s as conjugated arms and bithiophene (TT) as central core, was synthesized for solution-processable organic solar cells (OSC). To systematically investigate the characteristics of multi-dimensional conjugated systems, a two-arm linear-shaped (L) small molecule based on the same conjugated arms as that of S-TT was further synthesized. S-TT, as well as L-TT, both presented satisfactory solubility in common organic solvents. The nature of addition arms of S-(TT) exhibited better thermal stability than did L-(TT). According to the UV-vis measurements, the onset wavelengths of S-(TT) displayed a red-shift about 38 nm from solution state to film state, which is larger than that of L-(TT)(~7 nm). This implies that the addition conjugated arms of S-(TT) would incur a dense packing between molecules in film state. The tailoring of HOMO levels of L-TT and S-TT could be accomplished by utilizing the twisted central TT core. Computational analysis provided further evidences that the additional conjugated arms of multi-dimensional conjugated systems were capable of adjusting energy levels and electronic distribution. Inverted OSCs with ZnOx and MoO3 as an electron extraction layer and a hole extraction layer, respectively were fabricated by spin-coating the blend of L-TT or S-TT as donor and the fullerene derivative (PC61BM) as acceptor. The preliminary photovoltaic performances indicate that the photocurrent and power conversion efficiency were benefited greatly by inserting multi-dimensional conjugated arms in small molecule. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T10:21:51Z (GMT). No. of bitstreams: 1 ntu-102-R00549028-1.pdf: 4822044 bytes, checksum: e2e19fedad84802be2786312e9e982f9 (MD5) Previous issue date: 2013 | en |
| dc.description.tableofcontents | 目錄
口委審定書..................................................I 謝辭......................................................II 中文摘要 .................................................III 英文摘要 ..................................................IV 目錄 ......................................................V 圖目錄 ...................................................VII 表目錄 ....................................................IX 第一章 緒論 ...............................................1 1.1 前言 ..................................................1 1.2 太陽能發展歷史及太陽能電池介紹 .............................2 1.3 太陽放射光譜圖 ..........................................7 1.4 太陽能電池基本特性參數 ....................................9 1.5 有機太陽能電池工作原理 .................................. 11 1.6 有機太陽能元件的發展 ....................................13 1.6.1 單層結構（single layer）..................,,......... 13 1.6.2 雙層結構（bilayer）異質接面（heterojuncion）結構.........14 1.6.3 單層異質接面結構（bulk heterojunction）................15 第二章 文獻回顧與研究動機 ....................................16 2.1 線型小分子系統 .........................................17 2.2 星狀小分子系統 .........................................22 2.3 研究動機 ..............................................27 第三章 實驗內容 ............................................29 3.1 使用藥品與溶劑 .........................................29 3.2 使用儀器 ..............................................31 3.3 實驗流程圖 ............................................35 3.4 合成流程 ..............................................36 第四章 結果與討論 ..........................................49 4.1 小分子材料基本性質 ......................................49 4.2 熱性質 ................................................51 4.3 型態性質 ..............................................52 4.4 光學性質 ..............................................54 4.5 低能光電子能階之量測 ....................................56 4.6 電化學特性 ............................................58 4.7 理論計算 ..............................................60 4.8 元件光伏特性分析 ........................................64 第五章 結論 ..............................................68 參考文獻 ..................................................69 附錄 .....................................................74 | |
| dc.language.iso | zh-TW | |
| dc.subject | 小分子 | zh_TW |
| dc.subject | 噻 | zh_TW |
| dc.subject | 吩 | zh_TW |
| dc.subject | 有機太陽能電池 | zh_TW |
| dc.subject | 呋 | zh_TW |
| dc.subject | 喃 | zh_TW |
| dc.subject | 星狀 | zh_TW |
| dc.subject | 多維共軛 | zh_TW |
| dc.subject | organic solar cell | en |
| dc.subject | Furan | en |
| dc.subject | star-shaped | en |
| dc.subject | small molecule | en |
| dc.subject | Thiophene | en |
| dc.title | 合成星狀噻吩-呋喃小分子於溶液製程有機太陽能電池的應用 | zh_TW |
| dc.title | Synthesis of Star-Shaped Oligo(thienylfuran)s for Solution-Processed Organic Photovoltaics | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 101-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 李榮和,陳志平,陳錦地,王杏如 | |
| dc.subject.keyword | 噻,吩,有機太陽能電池,呋,喃,小分子,星狀,多維共軛, | zh_TW |
| dc.subject.keyword | Thiophene,Furan,star-shaped,small molecule,organic solar cell, | en |
| dc.relation.page | 86 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2013-08-16 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| Appears in Collections: | 高分子科學與工程學研究所 | |
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| ntu-102-1.pdf Restricted Access | 4.71 MB | Adobe PDF |
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