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  1. NTU Theses and Dissertations Repository
  2. 工學院
  3. 化學工程學系
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/60383
完整後設資料紀錄
DC 欄位值語言
dc.contributor.advisor吳哲夫(Jeffrey D. Ward)
dc.contributor.authorTing Changen
dc.contributor.author張庭zh_TW
dc.date.accessioned2021-06-16T10:16:50Z-
dc.date.available2020-07-17
dc.date.copyright2020-07-17
dc.date.issued2020
dc.date.submitted2020-07-07
dc.identifier.citation1. Sudalma, S.; Purwanto, P.; Santoso, L. W., The Effect of SO2 and NO2 from Transportation and Stationary Emissions Sources to SO42− and NO3− in Rain Water in Semarang. Procedia Environmental Sciences 2015, 23, 247-252.
2. Material Safety Data Sheet for Sulphur Dioxide. In 3 ed.; Afrox 2017.
3. Elguindi, N.; Granier, C.; Stavrakou, T.; Darras, S.; Bauwens, M.; Cao, H.; Chen, C.; Gon, H. D. v. d.; Dubovik, O.; Fu, T.-M.; Henze, D. K.; Jiang, Z.; Kuenen, J.; Kurokawa, J.-i.; Liousse, C.; Miyazaki, K.; Müller, J.-F.; Qu, Z.; Sekou, K.; Solmon, F.; Zheng, B., Analysis of recent anthropogenic surface emissions from bottom-up inventories and top-down estimates: are future emission scenarios valid for the recent past? . Earth and Space Science Open Archive 2020, 36.
4. Sofiev, M.; Winebrake, J. J.; Johansson, L.; Carr, E. W.; Prank, M.; Soares, J.; Vira, J.; Kouznetsov, R.; Jalkanen, J.-P.; Corbett, J. J., Cleaner fuels for ships provide public health benefits with climate tradeoffs. Nature Communications 2018, 9, 1-12.
5. Kampa, M.; Castanas, E., Human health effects of air pollution. Environ Pollut 2008, 151, (2), 362-7.
6. Sulphur oxides (SOx) and Particulate Matter (PM) – Regulation 14. http://www.imo.org/en/OurWork/Environment/PollutionPrevention/AirPollution/Pages/Sulphur-oxides-(SOx)-%E2%80%93-Regulation-14.aspx (5/25),
7. Sulphur limit in ECAs - increased risk of PSC deficiencies and detentions. https://www.dnvgl.com/news/sulphur-limit-in-ecas-increased-risk-of-psc-deficiencies-and-detentions-142911# (05/25).
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9. MARPOL Annex VI – Regulation 4. https://www.egcsa.com/regulatory/marpol-annex-vi-regulation-4/ (05/25),
10. Assessing the IMO Sulfur Cap Regulation: Implications to 2020 and beyond. https://www.gpca.org.ae/2019/01/30/assessing-the-imo-sulfur-cap-regulation-implications-to-2020-and-beyond/ (05/25),
11. Poullikkas, A., Review of Design, Operating, and Financial Considerations in Flue Gas Desulfurization Systems. Energy Technology Policy 2015, 2, (1), 92-103.
12. Lathinen, J. M., Closed-loop Exhaust Gas Scrubber Onboard a Merchant Ship-Technical, Economical, Environmental and Operational Viewpoints. Acta Wasaensia 2016, 161.
13. Siddiqi, M. A.; Krissmann, J.; PetersGerth, P.; Luckas, M.; Lucas, K., Spectrophotometric measurement of the vapour-liquid equilibria of (sulphur dioxide plus water). J. Chem. Thermodyn. 1996, 28, (7), 685-700.
14. Rodríguez-Sevilla, J.; Álvarez, M.; Díaz, M. C.; Marrero, M. C., Absorption Equilibria of Dilute SO2 in Seawater. Journal of Chemical Engineering Data 2004, 49, (6), 1710-1716.
15. Andreasen, A.; Mayer, S., Use of Seawater scrubbing for SO2 removal from marine engine exhaust gas. Energy Fuels 2007, 21, (6), 3274-3279.
16. Darake, S.; Hatamipour, M. S.; Rahimi, A.; Hamzeloui, P., SO 2 removal by seawater in a spray tower: Experimental study and mathematical modeling. Chemical Engineering Research and Design 2016, 109, 180-189.
17. Bandyopadhyay, A.; Biswas, M. N., Modeling of SO(2) scrubbing in spray towers. Sci Total Environ 2007, 383, (1-3), 25-40.
18. Flagiello, D.; Erto, A.; Lancia, A.; Di Natale, F., Experimental and modelling analysis of seawater scrubbers for sulphur dioxide removal from flue-gas. Fuel 2018, 214, 254-263.
19. Ibrahim, S. Process evaluation of a SOx and NOx exhaust gas cleaning concept for marine application. Master thesis, Chalmers University of Technology, 2016.
20. Simonsen, A. S. Modelling and Analysis of Seawater Scrubbers for Reducing SOx Emissions from Marine Engines. doctor thesis, Aalborg University, 2018.
21. Caiazzo, G.; Langella, G.; Miccio, F.; Scala, F., An experimental investigation on seawater SO2scrubbing for marine application. Environmental Progress Sustainable Energy 2013, 32, (4), 1179-1186.
22. Tang, X.-J.; Li, T.; Yu, H.; Zhu, Y.-M., Prediction model for desulphurization efficiency of onboard magnesium-base seawater scrubber. Ocean Engineering 2014, 76, 98-104.
23. Millero, F. J.; Feistel, R.; Wright, D. G.; McDougall, T. J., The composition of Standard Seawater and the definition of the Reference-Composition Salinity Scale. Deep Sea Research Part I: Oceanographic Research Papers 2008, 55, (1), 50-72.
24. Dickson, A. G., An exact definition of total alkalinity and a procedure for the estimation of alkalinity and total inorganic carbon from titration data. 1981, 28, (6), 609-623.
25. Handbook of methods for the analysis of the various parameters of the carbon dioxide system in sea water; version 2. DOE: 1994.
26. Sandler, S. I., Using Aspen plus in thermodynamics instruction : a step-by-step guide. 2015.
27. Emission Control MAN B W Two-stroke Diesel Engines; MAN B W Diesel A/S: Copenhagen, Denmark.
28. Rajput, R., A text book of automobile engineering. Firewall Media: 2008.
29. Rao, G. A. P.; Sharma, T. K., ENGINE EMISSION CONTROL TECHNOLOGIES: Design Modifications and Pollution Mitigation Techniques. In 1st ed.; Apple Academic Press: New York, 2020.
30. Wilhelm, E.; Battino, R.; Wilcock, R. J., Low-pressure solubility of gases in liquid water. Chemical Reviews 1977, 77, (2), 219-262.
31. Onda, K.; Takeuchi, H.; Okumoto, Y., Mass Transfer Coefficients Between Gas and Liquid Phases in Packed Columns. Journal of Chemical Engineering of Japan 1968, 1, (1), 56-62.
32. Codolo, M. C.; Bizzo, W. A., Experimental study of the SO2 removal efficiency and volumetric mass transfer coefficients in a pilot-scale multi-nozzle spray tower. International Journal of Heat and Mass Transfer 2013, 66, 80-89.
33. McCabe, W. L., Unit operations of chemical engineering. 6th ed. / Warren 1. McCabe, Julian C. Smith, Peter Harriott. ed.; McGraw Hill: Boston, 2001.
34. WÄRTSILÄ SCRUBBER PRODUCT GUIDE 2014.
35. Danckwerts, P. V., Gas-liquid reactions / P. V. Danckwerts. McGraw-Hill Book Co.: New York, 1970.
36. Zhu, Y.; Tang, X.; Li, T.; Ji, Y.; Liu, Q.; Guo, L.; Zhao, J., Shipboard trials of magnesium-based exhaust gas cleaning system. Ocean Engineering 2016, 128, 124-131.
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dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/60383-
dc.description.abstract由於國際海事組織的法規越來越嚴格,脫硫技術顯得日漸重要,其中常見的濕式噴霧塔脫硫技術可分為開環系統以及閉環系統,為了瞭解系統運作機制而使用Aspen Plus模擬此兩種系統,其中天星管理顧問股份有限公司提供海上試驗的洗滌塔測試結果,此結果有助於校正洗滌塔內的質傳速率,在開環系統中海水鹼度(alkalinity)及海水溫度對於系統有較大的影響,若應用在較高含硫量的燃油之廢氣則會需要更多的海水洗滌氣體中的二氧化硫,而閉環系統是由開環系統的結果所延伸出來的,閉環系統中所使用的海水流量比開環系統少,其中值得注意的是,在不同的操作條件下Na+/SO2的摩爾比都維持在18,雖然閉環系統未有實際的海上測試結果,不過其模擬數值可作為未來設計閉環系統的參考值。zh_TW
dc.description.abstractThe spray column is a widely used technology for desulphurization process in the marine industrial. Two types of desulphurization process, open loop and closed loop, simulate in the Aspen Plus. There is an open loop sea trial data provided by the Genius Star Management Consulting Co., Ltd. With this sea trial data the mass transfer rate is corrected in Aspen Plus. The seawater alkalinity and temperature influence the open loop system. The more seawater is required when the higher sulphur content fuel is applied on the ship engine. The closed loop process is the extension work from the open loop process. The required amount of seawater is much less than the open loop process. The Na+/SO2 mole ratio almost keep the same value 18 and the other results could be the reference for the company to design the closed loop system in the future.en
dc.description.provenanceMade available in DSpace on 2021-06-16T10:16:50Z (GMT). No. of bitstreams: 1
U0001-0707202009575200.pdf: 2639814 bytes, checksum: c61306fff48da2486e38a3962f416982 (MD5)
Previous issue date: 2020
en
dc.description.tableofcontents口試委員會審定書 i
誌謝 iii
摘要 v
Abstract vii
Table of Contents ix
List of Figures xi
List of Tables xv
1. Introduction 1
1.1. Overview 1
1.2. Literature survey 4
1.3. Motivation 8
1.4. Thesis organization 9
2. Methods 10
2.1. Seawater 10
2.2. pH value 13
2.3. Reaction 14
2.4. Exhaust gas 21
2.5. Scrubbing process 25
2.5.1. Open loop 26
2.5.2. Closed loop 30
3. Results 33
3.1. Open loop 33
3.2. Closed loop 53
4. Conclusions 65
Reference 66
dc.language.isoen
dc.subject洗滌塔zh_TW
dc.subject噴霧脫硫塔zh_TW
dc.subject開環系統zh_TW
dc.subject閉環系統zh_TW
dc.subject海上廢氣除硫系統zh_TW
dc.subjectspray columnen
dc.subjectopen loopen
dc.subjectclosed loopen
dc.subjectexhaust gas cleaning systemen
dc.subjectscrubberen
dc.title藉由海水洗滌去除海上機具廢氣之模擬zh_TW
dc.titleModeling of Seawater Scrubbing for Exhaust Gas Cleaning in Marine Applicationsen
dc.typeThesis
dc.date.schoolyear108-2
dc.description.degree碩士
dc.contributor.oralexamcommittee錢義隆(I-Lung Chien),陳誠亮(Cheng-Liang Chen),李豪業(Hao-Yeh Lee)
dc.subject.keyword洗滌塔,噴霧脫硫塔,開環系統,閉環系統,海上廢氣除硫系統,zh_TW
dc.subject.keywordscrubber,spray column,open loop,closed loop,exhaust gas cleaning system,en
dc.relation.page68
dc.identifier.doi10.6342/NTU202001351
dc.rights.note有償授權
dc.date.accepted2020-07-07
dc.contributor.author-college工學院zh_TW
dc.contributor.author-dept化學工程學研究所zh_TW
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