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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 吳紀聖(Chi-Sheng Wu) | |
| dc.contributor.author | Tien-Lun Cheng | en |
| dc.contributor.author | 鄭天倫 | zh_TW |
| dc.date.accessioned | 2021-06-16T08:47:53Z | - |
| dc.date.available | 2013-08-26 | |
| dc.date.copyright | 2013-08-26 | |
| dc.date.issued | 2013 | |
| dc.date.submitted | 2013-08-20 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/59066 | - |
| dc.description.abstract | 苯酚是世界主要水汙染物之一，常用於染色、樹脂合成上的工業用途，存在於工業廢水中，對於環境造成嚴重的危害。本研究以溶凝膠法製備TiO2，將TiO2覆膜在蜂巢狀陶瓷載體上，為了避免觸媒掉進載體孔洞中造成觸媒浪費，TiO2覆膜多層在蜂巢狀陶瓷載體上，並鍛燒於500 oC至形成銳鈦晶相，由SEM圖可以得知，覆膜三次後，觸媒均勻附著於載體表面。蜂巢式反應器中，於載體的每一個通道內置入PMMA(Poly(methyl methacrylate))側面發光光纖，光可經由光線傳送並照射到觸媒表面，在光纖的側面鑿洞以增加側面發光強度，以可固定深度的切割器固定切割深度，並於將光纖尾端接觸反應器內不鏽鋼面，增加光反射，經過光纖照明實驗，對於經過表面處理的光纖，可以增加30.7%的光強度。以此實驗裝置進行苯酚水溶液降解反應，以4-氨基安替比林直接光度法將溶液變色，並利用UV-Vis分光光度計進行苯酚濃度的測量，進而得到轉化率。光源為200W汞燈，光強度為2 W/cm2。由液相批次反應器可以內照明蜂巢式反應器的理想滯留時間為180分鐘，且TiO2觸媒優於含金屬Mn的TiO2觸媒，可以得到最大轉化率0.259。 | zh_TW |
| dc.description.abstract | Phenol is one of the major waster water pollutants in the world and wildly used in dye, resin synethsis industry. In the research, sol-gel prepared TiO2 was coated on the monolith multiple times to form multilayer structure. The catalyst was calcined to transform into anatase state at 500 °C. From SEM images, uniform catalyst layer can be achieved by multiple times of coating. PMMA(Poly(methyl methacrylate)) with caves which can increase the side emission of light were put inside each channel of monolith. The depth of each cave was kept constant by a modified cutter. The end of each fiber contacted with the inner side of the reactor’s stainless steel wall, which was provided as a reflective plane to enhance the light irradiation. From the results of optical fiber illumination experiment, the light intensity can be enhaced for 30.7% for cutted optical fibers. The light source was a 200 W mecury lamp to provide 2 W/cm2 light intensity. The batch reactor’s experimental results showd the best residence time for the internally illuminated monolith reactor system is 180 minutes. TiO2 catalyst shows better performance that Mn loaded TiO2 catalyst. The conversion achieved 0.259 with UVA light intensity of 2 W/cm2 at 25°C. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T08:47:53Z (GMT). No. of bitstreams: 1 ntu-102-R00524096-1.pdf: 1782416 bytes, checksum: 957de937b2e918f980fce6ba828973ea (MD5) Previous issue date: 2013 | en |
| dc.description.tableofcontents | 摘要 I
Abstract II 目錄 III 圖目錄 VI 表目錄 IX 第一章 緒論 1 第二章 文獻回顧 2 2-1 光觸媒反應原理 2 2-2 光觸媒降解之原理 3 2-3 光催化降解反應器簡介 5 2-4 熱水解法製備二氧化鈦 8 2-5 苯酚的簡介 9 2-5-1苯酚降解程序簡介 10 2-6 4-氨基安替比林直接光度法 13 2-7 苯酚光催化降解反應的中間產物 15 2-8 金屬負載對光催化降解反應的影響 16 2-9 光纖簡介 20 2-9-1 PMMA材料的UV吸收光譜 20 2-7 蜂巢狀反應器 21 2-7-1蜂巢狀載體(Monolithic support)簡介 21 2-7-2蜂巢狀陶瓷反應器(Honeycomb monolith reactor) 22 第三章 實驗方法 31 3-1 實驗藥品與器材 31 3-1-1 藥品 31 3-1-2 器材 31 3-2 實驗步驟 33 3-2-1負載不同金屬TiO2觸媒粉體製備 33 3-2-2苯酚水溶液濃度測量 33 3-2-3浸漬覆膜法(Dip-coating method) 35 3-2-4光纖照明實驗 37 3-3 觸媒特性分析原理與方法 38 3-3-1儀器型號與規格 38 3-3-2紫外光-可見光光譜儀(UV-VIS) 38 3-3-3掃描式電子顯微鏡(SEM) 40 3-3-4 X光繞射儀(XRD) 41 3-4 光催化活性檢測 45 3-4-1液相批次反應器 45 3-4-2內照明蜂巢式反應器 45 3-4-3光源光譜介紹 48 3-4-4苯酚水溶液降解 49 第四章 觸媒特性分析結果與討論 53 4-1 觸媒製備 53 4-1-1 TiO2覆膜液 53 4-2 觸媒檢測與特性分析 53 4-2-1 UV-VIS 53 4-2-2 XRD 54 4-2-3 SEM 55 第五章 光催化降解結果與討論 57 5-1 液相批次反應器 57 5-2 內照明蜂巢式反應器 58 5-2-1 空白實驗 58 5-2-2內照明蜂巢式反應器系統轉化率 59 5-2-3 苯酚光催化降解反應中間產物對於4-氨基安替比林直接光度法的影響 61 第六章 光纖照明實驗結果與討論 63 第七章 結論 64 參考文獻 65 個人小傳 69 附錄 70 A. 液相批次反應器加入雙氧水 70 B. 內照明蜂巢式反應器系統轉化率 70 C. 內照明蜂巢式反應器系統轉化率 71 | |
| dc.language.iso | zh-TW | |
| dc.title | 以內照式蜂巢式反應器光降解苯酚廢水 | zh_TW |
| dc.title | Remediation of phenol in wastewater by internally illuminated monolith reactor | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 101-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 徐振哲(Cheng-Che Hsu),張淑閔(Sue-min Chang) | |
| dc.subject.keyword | 蜂巢式反應器,苯酚,二氧化鈦觸媒, | zh_TW |
| dc.subject.keyword | Monolith reactor,TiO2 photocatalyst,Phenol, | en |
| dc.relation.page | 71 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2013-08-20 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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