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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 王立義 | |
dc.contributor.author | Wei-Chih Chen | en |
dc.contributor.author | 陳韋志 | zh_TW |
dc.date.accessioned | 2021-06-16T08:43:23Z | - |
dc.date.available | 2018-09-02 | |
dc.date.copyright | 2013-09-02 | |
dc.date.issued | 2013 | |
dc.date.submitted | 2013-08-22 | |
dc.identifier.citation | Ch 1
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/58995 | - |
dc.description.abstract | 本論文分為三個研究主題,第一個主題是調查染料分子與電洞傳導材料(hole transport material,HTM)之間結構相容性對元件效率的影響。在實驗方面,我們分別利用Z907以及在ancillary group的位置有噻吩單元取代之衍生物,CYC-B11,當一敏化劑並結合Poly(3-hexylphene) (P3HT)或(2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenylamine)9,9')-spirobifluorene (OMeTAD)作一HTM來進行全固態染敏化太陽能電池(solid-state dye-sensitized solar cells,ss-DSCs)的製備。研究發現CYC-B11/P3HT元件相較於Z907/P3HT與CYC-B11/OMeTAD兩元件有較高的短路電流密度。根據光致電子轉換效率(incident photo-to-electron conversion efficiency,IPCE)以及交流阻抗儀(impedance)的結果顯示,P3HT取代OMeTAD充當一HTM,在光電流上有著顯著的提升並與CYC-B11的吸收光譜是一致的,且在TiO2/dye/HTM之異質介面間的電荷轉移電阻(charge-transfer resistance)明顯下降。因此,CYC-B11/P3HT之ss-DSC在一較薄厚度(0.5 μm)之中孔徑材料TiO2下,其光電轉換效率可達3.66 %。
第二個主題,我們合成不同分子量之P3HT分別為65000(P3HT65)、47000(P3HT47)與25000(P3HT25) g/mol,並搭配CYC-B11為一染料製備ss-DSCs。根據空間電荷限制電流(space-charge-limited-current,SCLC)、impedance與IPCE的量測結果指出,P3HT之非結晶相可增加P3HT的電洞遷移率,且可有效降低元件之TiO2/dye/HTM之異質介面間的電荷轉移電阻(charge-transfer resistance),因而有效提升元件之光電流。此外,從暫態光電壓的實驗結果發現CYC-B11/P3HT47元件有較長的electron lifetime。此結果暗示P3HT47可有效地均勻覆蓋於吸附染料之TiO2表面,而導致電荷複合的機率降低,其將促使元件有較高的開路電壓。因此,CYC-B11/ P3HT47元件之光電轉換效率可達4.72 %,相較於CYC-B11/ P3HT25元件,其效率提升了接近50 %。為了進一步優越化元件效率,我們導入一染料CYC-B19,其相較於CYC-B11有更高的吸收係數與寬廣的吸收光譜,因此元件效率可進一步提升至4.85 %,且呈現不錯的再現性。 第三個主題是利用Grignard metathesis (GRIM)之聚合方式合成一共軛嵌段共聚高分子,poly(2,5-dihexyloxy-p-phenylene)-b-poly(3-hexylthiophene) (PPP-b-P3HT),並將其與P3HT分別當一HTM應用於ss-DSCs系統中。此共聚高分子以spin-drying方式的製膜過程中發現,P3HT鏈段會自主裝形成一fibrous-like之結晶結構,且長度約在數個微米的尺度,因此賦與此共聚高分子擁有較快的電洞遷移率。根據暫態光電壓的量測指出,CYC-B11/PPP-b-P3HT元件 相較於參考元件(CYC-B11/P3HT)有較長的electron lifetime。此外,比較兩元件之交流阻抗分析圖譜,其結果顯示CYC-B11/PPP-b-P3HT元件在TiO2/dye/HTM之異質介面間較容易進行電荷轉移。根據上述所觀察的現象暗示著PPP鏈段促進共聚高分子與染料之間有更緊密的接觸,進而大幅提升元件的光電轉換效率。因此,CYC-B11/PPP-b-P3HT元件其光電轉換效率可達4.65 %,此外,此研究也證實共聚高分子對於發展高效能之ss-DSCs而言是一良好的電洞傳輸材料。 第四個主題是導入一具吸光能力之compatibilizers於ss-DSCs系統中,並搭配在Red/NIR有高莫耳吸收係數的SQ2作一染料來探討其對元件光伏特性的影響。從實驗結果顯示此compatibilizer在此系統中,除了扮演共敏化劑的角色來提供可見光區額外的吸收之外,並同時充當dye/HTM之異質介面的修飾劑,進而有效降低異質介面間電荷轉移之電阻並減少charge recombination的機率,因此其光電轉換效率在AM 1.5G的條件下最高可達2.68 % (DS3),相較於參考元件足足提升了50 %。此外,此研究也有別於目前文獻所發表之共敏化劑或relay dye的功用,這對於發展高效能之ss-DSCs提供了一有效的研究方向。 | zh_TW |
dc.description.abstract | This thesis consists of three topics concerning solid-state dye-sensitized solar cells (ss-DSCs). In the first part, ss-DSCs are fabricated using Z907 or its thiophene derivative, CYC-B11, as a dye, and poly(3-hexylthiophene) (P3HT) or (2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenylamine)9,9')-spirobifluorene (OMeTAD) as a hole transport material (HTM). The effect of the structural compatibility of dye molecules with HTM on device performance is investigated. The CYC-B11/P3HT device has a much higher short-circuit current density than those for Z907/P3HT and CYC-B11/OMeTAD devices. Results from the incident photo-to-electron conversion efficiency and impedance measurements support the use of P3HT, in place of OMeTAD, as HTM markedly increases the photocurrent throughout the absorption spectrum of CYC-B11 and significantly reduces the charge-transfer resistance at the TiO2/dye/HTM interface. As a result, the CYC-B11/P3HT ss-DSC that is fabricated from a thin (0.5 μm) mesoporous TiO2 layer exhibits an outstanding power conversion efficiency (PCE) of 3.66%.
In the second part, we applied P3HT with three different molecular weights, 65000 (P3HT65), 47000 (P3HT47) and 25000 (P3HT25) g/mol, as HTM to fabricate ss-DSCs in which CYC-B11 was used as sensitizer. Results from the space-charge-limited-current, impedance and incident photo-to-electron conversion efficiency measurements indicate that the amorphous phase of P3HT increases its hole mobility and efficiently reduces the charge-transfer resistance at the TiO2/dye/HTM interface, thereby increasing the photocurrent. Moreover, the transient photovoltage experiments show that the CYC-B11/ P3HT47 device has the longest electron lifetime. This result suggests a complete coverage of the dyed-TiO2 surface with P3HT47, resulting in the suppression of charge recombination that causes the increase of open-circuit voltage. Accordingly, the CYC-B11/ P3HT47 device exhibits a striking PCE of 4.72 %, which is ~50 % better than that of the ss-DSCs using P3HT25 as HTM. The replacement of CYC-B11 with CYC-B19 as the sensitizer to improve the light-harvesting capability further increases the PCE up to 4.85 %. In the third part, An all-conjugated diblock copolymer, poly(2,5-dihexyloxy-p-phenylene)-b-poly(3-hexylthiophene) (PPP-b-P3HT), was synthesized and applied as HTM for the fabrication of ss-DSCs. This copolymer is characterized by an enhanced crystallinity, enabling its P3HT component to self-organize into interpenetrated and long-range ordered crystalline fibrils upon spin-drying and ultimately endowing itself to have a faster hole mobility than that of the parent P3HT homopolymer. Transient photovoltage measurements indicate that the photovoltaic cell based on PPP-b-P3HT as the HTM has a longer electron lifetime than that of the reference device based on P3HT homopolymer. Moreover, comparing the two ss-DSCs in terms of the electrochemical impedance spectra reveals that the transfer of charge carriers across the TiO2/dye/HTM interface is substantially easier in the PPP-b-P3HT device than in the P3HT cell. Above observations suggest that the PPP block facilitates an intimate contact between the copolymer and dye molecules absorbed on the nanoporous TiO2 layer, which significantly enhances the performance of the resulting device. Consequently, the PPP-b-P3HT ss-DSC exhibits a promising power conversion efficiency of 4.65%. This study demonstrates that conjugated block copolymers can function as superior HTMs of highly efficient ss-DSCs. In the last part, we introduced colored comptibilizers (namely DS1 and DS3) into the ss-DSCs with a squaraine dye (SQ2). The results imply that colored comptibilizers can act not only as interface modifiers between dye and hole transporting material (HTM) but also as co-sensitizers by forster energy transfer. Results from incident photo-to-electron conversion efficiency, surface energy and impedance measurements indicate that the introduction of colored comptibilier increase extra light-harvesting and efficiently reduce the charge-transfer resistance at the TiO2/dye/HTM interface, thereby increasing the photocurrent. Moreover, the transient photovoltage experiments show that the DS modified devices have the longer electron lifetime, leading to the increment of open-circuit voltage compared to the reference cell. This result suggests a complete coverage of the TiO2-SQ2 with OMeTAD through DSs treatment, resulting in the suppression of charge recombination between electrons from the TiO2 conduction band and dye cations. Consequently, the ss-DSC using SQ2 and OMeTAD as dye and HTM with the treatment of DS3 compabilizer, exhibits a promising PCE of 2.68 %, which is ~50 % better than that of the reference cell. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T08:43:23Z (GMT). No. of bitstreams: 1 ntu-102-D97549009-1.pdf: 11389748 bytes, checksum: 9e67365d058d23309d851fac4a4f4e48 (MD5) Previous issue date: 2013 | en |
dc.description.tableofcontents | 目錄
摘要 I ABSTRACT III 目錄 VI 圖目錄 IX 表目錄 XV 第一章 緒論 1 1.1 前言 1 1.2 太陽能電池的種類及發展現況 1 1.3 染敏化太陽能電池(dye-sensitized solar cells) 5 1.3.1 DSC之組成與工作原理 6 1.3.2 元件之光電效率分析 8 1.3.2.1 太陽光模擬光源 8 1.3.2.2 元件之性能參數 10 1.4 研究動機 12 1.5 參考文獻 13 第二章 文獻回顧 15 2.1 全固態染敏化太陽能電池(solid-state dye-sensitized solar cells,ss-DSCs) 15 2.2 ss-DSC之沿革與發展現況 16 2.2.1 以P-type無機半導體材料做一電洞傳導層 16 2.2.2 以有機小分子做一電洞傳導層 19 2.2.3 以共軛高分子做一電洞傳導層 31 2.3 參考文獻 41 第三章 探討釕金屬染料與電洞傳導材料之間結構相容性對全固態染敏化太陽能電池之光伏特性的影響 47 3.1 前言與研究目的 47 3.2 結果與討論 48 3.3 結論 58 3.4 實驗部分 58 3.4.1 染料與高分子之合成 58 3.4.2 元件製備 58 3.4.3 儀器設備 59 3.5 參考文獻 61 第四章 Poly(3-hexylthiophene)電洞傳導材料,其分子量對於全固態染敏化電池光伏特性之影響探討 63 4.1 前言與研究目的 63 4.2 結果與討論 64 4.3 結論 80 4.4 實驗部分 81 4.4.1 高分子合成 81 4.4.2 元件製備 81 4.4.3 儀器設備 82 4.5 參考文獻 83 第五章 導入具自組裝特性之共軛嵌段共聚物為電洞傳輸材料對全固態染敏化太陽能電池之光伏特性的影響與探討 87 5.1 前言與研究目的 87 5.2 結果與討論 88 5.3 結論 102 5.4 實驗部分 103 5.4.1 高分子合成 103 5.4.2 元件製備 106 5.4.3 儀器設備 107 5.5 參考文獻 108 第六章 結合可吸光之相容劑與方酸菁染料應用於全固態染敏化太陽能電池並探討其光伏特性的影響 112 6.1 前言與研究目的 112 6.2 結果與討論 113 6.3 結論 129 6.4 實驗部分 130 6.4.1 Comptibilizer合成 130 6.4.2 元件製備 131 6.4.3 儀器設備 131 6.5 參考文獻 132 第七章 總結 135 相關研究成果 138 圖目錄 圖 1-1 2000~2050/2100年再生能源市場評估[2] 2 圖 1-2 各類太陽能電池效率發展趨勢圖(NREL)[3] 4 圖 1-3 太陽能電池發展現況與未來產能預測圖[8] 5 圖 1-4 現今常用染料之化學結構與其對應之元件效率[11] 6 圖 1-5 DSC之工作原理示意圖[12] 7 圖 1-6 不同空氣質量(air mass)之太陽光源示意圖[15] 9 圖 1-7 太陽光源照射地表時產生之光學效應示意圖[15] 9 圖 1-8 AM0、AM 1.5D與AM 1.5G光源之光譜與照度差異[16] 10 圖 1-9 DSC之電流-電流特性圖[17] 10 圖 1-10 串聯電阻(Rs)與並聯電阻( Rsh)對元件之光伏特性影響之示意圖[18] 11 圖 1-11 太陽能電池之等效電路圖 11 圖 2-1 ss-DSCs之工作原理[1] 15 圖 2-2 結晶抑制劑THT加入前後之CuI膜之(a)(b)鳥瞰圖與(c)(d)截面圖之表面形態[6] 17 圖 2-3 導入一熔融鹽(a)前(b)後之CuI膜之表面形態[7] 18 圖 2-4 CsSnI3-xFx之(a)(c)晶格結構、(b)光學與(d)電子傳輸特性[10] 19 圖 2-5 spiro-OMeTAD之化學結構圖[15] 20 圖 2-6 tBP添加前後之(a)光伏特性圖與(b)暫態吸收光譜圖以及(c)在固定tBP濃度下,改變不同Li salt的濃度之暫態吸收光譜圖[17] 22 圖 2-7 tBP吸附於TiO2表面經理論計算(density functional theory,DFT)之(a)電荷分布圖(Oxygen(Red),titanium(white),nitrogen(blue)且圖中藍色區域表示低電子密度)與(b)幾何結構圖以及(c)電荷轉移機制圖之機制圖[20] 22 圖 2-8 (a)K63、K51與K68之化學結構圖與(b)對應元件之charge recombination rate constant (krec)及(c)電壓電流特性圖[25] 23 圖 2-9 CH3NH3PbI2Cl之(a)perovskite晶格結構與(b)光主動層之UV-vis吸收光譜以及分別在多孔性結構之TiO2與Al2O3之(c)charge transfer與charge transport之示意圖與(d)暫態光電流圖譜[27] 27 圖 2-10 (a)3D fibrous network TiO2之TEM影像及(b)元件之electron lifetime vs conductiviy特性圖(red:nanoparticle,blue:3D fibrous network)[34] 28 圖 2-11 (a)plasmonic ss-DSC之製作流程示意圖與對應之SEM影像及(b)元件之電壓電流特性圖與IPCE圖譜[37] 29 圖 2-12 plasmonic light-trapping示意圖[38] 29 圖 2-13 Forster energy transfer機制示意圖[39] 30 圖 2-14 (a)PTCDI與TT1之吸收與放光圖譜與其化學結構與(b)PTCDI添加前後之元件IPCE圖譜與光伏特性表[40] 30 圖 2-15目前應用於ss-DSCs之電洞傳輸材料的共軛高分子[42] 31 圖 2-16 (a)PEP之聚合機制[43]與(b)SSP之聚合方法與聚合前後之外觀型態[45] 32 圖 2-17 N719-TiO2與D102-TiO2經Li/tBP處理前後之能階變化示意圖與異質介面間電荷轉移機制圖[50] 34 圖 2-18 (a)SQ-1 dye與P3HT之化學結構與UV-vis吸收圖譜及(b)元件結構示意圖與對應之SEM影像與(c)最佳化元件之IPCE圖譜[51] 35 圖 2-19 (a)Sb2S3/P3HT元件之能階架構圖與結構示意圖與改變Sb2S3沉積時間之(b)UV-vis吸收光譜與(c)元件之IPCE圖譜[52] 36 圖 2-20 (a)TT1與P3HT之化學結構、能階架構圖與UV-vis吸收光譜圖與(b)元件之IPCE圖譜與暫態吸收光譜(blue line:TiO2/TTI/OMeTAD device)[61] 37 圖 2-21 (a)在TT1/P3HT系統可能發生的charge transfer與energy transfer之機制示意圖與(b)元件之暫態吸收光譜圖(A:TiO2/cheno/P3HT device, B:TiO2/TT1-cheno/P3HT device)[62] 38 圖 2-22 (a)electron channel於電洞傳導層中之元件結構示意圖與(b)分別導入PCBM於P3HT與PCPDTBT中之元件IPCE圖譜[64] 39 圖 2-23 (a)D131、C60衍生物與PCPDTBT之化學結構與UV-vis吸收光譜及對應之能階架構圖與元件結構圖和D131與C60衍生物共吸附於TiO2之元件(b)IPCE圖譜與(c)電壓電流特性圖[65] 40 圖 2-24 (a)元件所使用之共軛高分子當一HTM之化學結構與對應之能階架構圖與(b)Sb2S3之Sb原子與共軛高分子中相鄰之噻吩單元形成一配位鍵結示意圖 41 圖 3-1 CYC-B11與Z907染料之分子結構 48 圖 3-2 CYC-B11、Z907、P3HT與OMeTAD之(a)循環伏安分析圖(b)UV-vis吸收光譜與(c)ss-DSC之各組成之能階架構圖 49 圖 3-3 ss-DSC元件之結構示意圖 50 圖 3-4 多孔性TiO2薄膜之SEM圖(a)鳥瞰圖與(b)截面圖 51 圖 3-5 TiO2-CYC-B11/P3HT、TiO2-CYC-B11/OMeTAD、TiO2-Z907/P3HT和bare TiO2/P3HT之ss-DSCs在無照光環境下和AM 1.5G (100 mW/cm2)模擬光源下之電壓電流特性圖 52 圖 3-6 TiO2-CYC-B11/P3HT、TiO2-CYC-B11/OMeTAD、TiO2-Z907/P3HT和bare TiO2/P3HT之ss-DSCs之IPCE圖譜 54 圖 3-7過渡金屬錯合物在八面體的幾何結構中之不同的電子轉移形態之簡易分子軌域示意圖[19] 55 圖 3-8 TiO2-CYC-B11/P3HT、TiO2-CYC-B11/OMeTAD、TiO2-Z907/P3HT和bare TiO2/P3HT之ss-DSCs之交流阻抗分析Nyquist 56 圖 3-9 (a)Mesoporous-TiO2層數與其對應之厚度之對照圖(b)不同mesoporous TiO2厚度的CYC-B11/P3HT元件之光伏特性統計圖 57 圖 4-1 不同分子量之P3HT spin-cast膜之XRD圖 66 圖 4-2 ITO/PEDOT:PSS/P3HTs(P3HT65、P3HT47 or P3HT25)/Au電洞注入元件之描述電洞遷移率之ln(JL3/V2) v.s. (V/L)0.5關係圖 68 圖4-3 nanoporous TiO2之SEM圖(a)俯視圖與(b)截面圖 69 圖 4-4 CYC-B11染料與P3HT之分子結構 69 圖 4-5 CYC-B11溶液與不同分子量之P3HT薄膜(P3HT65、P3HT47及P3HT25)之 (a) 循環伏安分析圖(b)UV-vis吸收光譜與(c)ss-DSC之各組成之能階架構圖 70 圖 4-6 不同分子量之P3HT沉積於緻密層TiO2與多孔性TiO2之SEM圖 72 圖 4-7 CYC-B11/P3HT65、CYC-B11/P3HT47和CYC-B11/P3HT25之ss-DSCs元件之(a)電壓電流特性圖(b) 暫態光電壓(transient photovoltage)圖譜 75 圖 4-8 CYC-B11/P3HT65、CYC-B11/P3HT47和CYC-B11/P3HT25之ss-DSCs元件之(a)光致電子轉換效率(IPCE)圖譜(b)交流阻抗分析圖 78 圖 4-9為(a)TiO2-CYC-B11、(b)TiO2-CYC-B11/P3HT65、(c)TiO2-CYC-B11/P3HT47與(d)TiO2-CYC-B11/P3HT25之未蒸鍍Ag電極之AFM影像(scale bar為2×2 μm2) 79 圖 4-10(a)CYC-B19與CYC-B11在溶液下之UV-vis吸收圖譜(b)CYC-B19/P3HT47與CYC-B11/P3HT47元件之電壓電流特性圖 80 圖 5-1 P3HT與PPP-b-P3HT之化學結構圖 89 圖 5-2 (a)PPP-b-P3HT與(b)P3HT在濃度分別0.03及0.05 wt%經drop-cast成膜之TEM影像和(c)PPP-b-P3HT與(d)P3HT在濃度為15 mg/ml經spin-coat成膜之TEM影像 90 圖 5-3 (a) PPP、PPP-b-P3HT與P3HT經spin-coat成膜之WAXS圖(b) ITO/PEDOT:PSS/PPP-b-P3HT or P3HT /Au電洞注入元件之描述電洞遷移率之ln(JL3/V2) v.s. (V/L)0.5關係圖 93 圖 5-4 CYC-B11溶液與PPP-b-P3HT及P3HT薄膜之 (a) 循環伏安分析圖(b)UV-vis吸收光譜與(c)ss-DSC之各組成之能階架構圖 95 圖 5-5 CYC-B11/PPP-b-P3HT與CYC-B11/P3HT之ss-DSCs元件之(a)電壓電流特性圖(b) 暫態光電壓(transient photovoltage)圖譜 96 圖 5-6 CYC-B11/PPP-b-P3HT與CYC-B11/P3HT之ss-DSCs元件的光伏特性統計圖(7個元件平均計算而得) 97 圖 5-7 CYC-B11/PPP-b-P3HT與CYC-B11/P3HT之ss-DSCs元件之(a)光致電子轉換效率(IPCE)圖譜(b)交流阻抗分析圖 100 圖 5-9 (a)PPP-b-P3HT與(b)P3HT之1H-NMR光譜 104 圖 5-10 (a)PPP與(b)PPP-b-P3HT之GPC圖譜 105 圖 6-1 DS1、DS3、SQ2與OMeTAD之化學結構圖 113 圖 6-2 (a)DS1與(b)DS3在溶液中或TiO2表面以及SQ2 dye在TiO2表面之UV-vis吸收光譜 114 圖 6-3 DS1、DS3與SQ2溶液以及OMeTAD-Li薄膜之(a)循環伏安分析圖、(b)UV-vis吸收光譜與(c)各組成之能階架構圖 116 圖 6-4 (a)DS1與(b)DS3以及SQ2 dye在TiO2表面之螢光放光光譜與UV-vis吸收光譜 117 圖 6-5 ss-DSCs之組裝程序示意圖 118 圖 6-6 p-TiO2-SQ2/DS1/OMeTAD-Li、p-TiO2-SQ2/DS3/OMeTAD-Li與p-TiO2-SQ2/OMeTAD-Li元件之電壓電流特性圖 119 圖 6-7 TiO2-SQ2/DS1/OMeTAD-Li、TiO2-SQ2/DS3/OMeTAD-Li與TiO2-SQ2/OMeTAD-Li元件的光伏特性統計圖(8個元件平均計算而得) 120 圖 6-8 TiO2-SQ2/DS3/OMeTAD-Li元件在不同DS3濃度下之(a)電壓電流特性圖、(b)串聯電阻之量測數據與(c)IPCE圖譜 122 圖 6-9 p-TiO2-SQ2/DS3/OMeTAD-Li元件在不同DS3濃度下之交流阻抗分析圖 123 圖 6-10 (a) TiO2-SQ2/DS1/OMeTAD-Li與(b) TiO2-SQ2/DS3/OMeTAD-Li以及TiO2-SQ2/OMeTAD-Li元件之IPCE圖譜及其對應之UV-vis吸收光譜 124 圖 6-11 TiO2-SQ2/DS1/OMeTAD-Li、TiO2-SQ2/DS3/OMeTAD-Li與TiO2-SQ2/OMeTAD-Li元件之IPCE圖譜 125 圖 6-12 TiO2、TiO2-SQ2、TiO2-SQ2/DS1、TiO2-SQ2/DS3與OMeTAD-Li之接觸角圖 126 圖 6-13 TiO2-SQ2/DS1/OMeTAD-Li、TiO2-SQ2/DS3/OMeTAD-Li與TiO2-SQ2/OMeTAD-Li元件之交流阻抗分析圖 127 圖 6-14 TiO2-SQ2/DS1/OMeTAD-Li、TiO2-SQ2/DS3/OMeTAD-Li與TiO2-SQ2/OMeTAD-Li元件之暫態光電壓圖譜 128 圖 6-15 DS1與DS3之合成路徑 130 表目錄 表 2-1 染料之化學結構與對應之光伏特性參數 25 表 3-1 TiO2-CYC-B11/P3HT、TiO2-CYC-B11/OMeTAD、TiO2-Z907/P3HT和bare TiO2/P3HT之ss-DSCs元件的量測數據與交流阻抗分析 53 表 4-1 P3HT65、P3HT47與P3HT25之分子量、結晶區塊尺寸與載子遷移率之量測數據 66 表 4-2 不同分子量的P3HT之孔洞填充率的量測數據 72 表 4-3 CYC-B11/P3HT65、CYC-B11/P3HT47和CYC-B11/P3HT25之ss-DSCs元件的光伏特性之量測數據與交流阻抗分析 75 表 4-4 CYC-B19/P3HT47與CYC-B11/P3HT47元件之光伏特性的量測數據 80 表 5-1 PPP、PPP-b-P3HT與P3HT之分子特性之量測數據 89 表 5-2 PPP、PPP-b-P3HT與P3HT之XRD繞射峰之量測數據及載子遷移率 92 表 5-3 CYC-B11/PPP-b-P3HT與CYC-B11/P3HT之ss-DSCs元件的光伏特性之量測數據與交流阻抗分析 97 表 5-4 PPP、P3HT、TiO2、TiO2-CYC-B11與TiO2-CYC-B11/Li-tBP之接觸角與表面能之量測數據 101 表 6-1 p-TiO2-SQ2/DS1/OMeTAD-Li、p-TiO2-SQ2/DS3/OMeTAD-Li與p-TiO2-SQ2/OMeTAD-Li之ss-DSCs元件的光伏特性與交流阻抗分析之量測數據 120 表 6-2 TiO2-SQ2/DS3/OMeTAD-Li元件在不同DS3濃度下之光伏特性與交流阻抗分析之量測數據 122 表 6-3 TiO2、TiO2-SQ2、TiO2-SQ2/DS1、TiO2-SQ2/DS3與OMeTAD-Li之接觸角與表面能之量測數據 126 | |
dc.language.iso | zh-TW | |
dc.title | 全固態染敏電池之電洞傳導層/敏化劑介面的改良與性質探討 | zh_TW |
dc.title | Improvement of the Interface at Sensitizer/Hole Transport Material in Solid-State Dye-sensitized Solar Cells | en |
dc.type | Thesis | |
dc.date.schoolyear | 101-2 | |
dc.description.degree | 博士 | |
dc.contributor.oralexamcommittee | 何國川,吳春桂,戴子安,楊吉水,林建村 | |
dc.subject.keyword | 全固態染敏化太陽能電池,結構相容性,聚(3-己基噻,吩),電洞傳導材料,共軛嵌段共聚高分子,自主裝,相容劑, | zh_TW |
dc.subject.keyword | solid-state dye-sensitized solar cells,structural compatibility,poly(3-hexylthiophene),hole conductor,all-conjugated block copolymer,self-assembly,compatibilizer, | en |
dc.relation.page | 139 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2013-08-23 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
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