請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/58206完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 劉貴生(Guey-Sheng Liou) | |
| dc.contributor.author | Fang-Wei Li | en |
| dc.contributor.author | 李方瑋 | zh_TW |
| dc.date.accessioned | 2021-06-16T08:08:15Z | - |
| dc.date.available | 2022-07-31 | |
| dc.date.copyright | 2020-07-17 | |
| dc.date.issued | 2020 | |
| dc.date.submitted | 2020-07-14 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/58206 | - |
| dc.description.abstract | 本論文分成四個章節：第一章為緒論，講述電致變色現象以及奈米銀線材料；第二章則是合成高性能的電致變色材料 (NTPB-PA)，由於在苯基的對位上有二甲胺基基團，因此材料可以展現出多段變色的樣貌之外，所需的氧化電位也較低。接著材料與二氧化鋯進行反應形成混成材料，此步驟能提升電致變色的表現。最後，再將陰極變色材料紫精衍生物引入至電致變色元件，可以達到全波段遮蔽之效果；第三章則是成功的合成高長徑比之奈米銀線，透過引入具電活性的三苯胺為基底的電致變色材料作為鈍化層，其奈米銀線之電活性及與基材之間的附著力都能同時達到改善，並將此複材電極更進一步地製備出電致變色元件。而所有結果總結於第四章。 | zh_TW |
| dc.description.abstract | This study has been divided into four chapters. Chapter 1 is the general introduction of electrochromism and silver nanowires. In Chapter 2, the high-performance TPA-based electrochromic (EC) material, NTPB-PA, demonstrated multiple color appearance and lower oxidation states owing to dimethylamino groups at the para-position of the phenyl. Besides, functional hydroxyl groups on NTPB-PA backbones could be conducted to in-situ sol-gel reaction to form covalent bonds with zirconium dioxide (ZrO2). The results have been shown to enhance EC performance. Subsequently, anodic ECM, heptyl viologen (HV), is introduced into the electrochromic device (ECD) to construct ambipolar system and show the absorption of full-wavelength band during redox procedure. In chapter 3, silver nanowires (AgNWs) with high aspect ratio have been synthesized successfully. And the electrical stability issue of AgNWs was improved through introducing electroactive TPA-based polymer films as passivation layers onto the AgNW networks. At the same time, the adhesion between AgNWs and substrates increased. These hybrid electrodes, AgNW/TPPA hybrid electrodes were further applied to fabricate ECD. Finally, all the results are concluded in Chapter 4. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T08:08:15Z (GMT). No. of bitstreams: 1 U0001-1407202014392200.pdf: 9335530 bytes, checksum: a3e90f78b557f9a8d88f206bdf7af37a (MD5) Previous issue date: 2020 | en |
| dc.description.tableofcontents | ACKNOWLEDGEMENTS i ABSTRACT (in English) ii ABSTRACT (in Chinese) iii TABLE OF CONTENTS iv LIST OF TABLES x LIST OF FIGURES xi LIST OF SCHEMES xix CHAPTER 1 1 CHAPTER 2 59 CHAPTER 3 114 CHAPTER 4 149 | |
| dc.language.iso | en | |
| dc.subject | 電致變色 | zh_TW |
| dc.subject | 三苯胺 | zh_TW |
| dc.subject | 二氧化鋯混成材料 | zh_TW |
| dc.subject | 奈米銀線 | zh_TW |
| dc.subject | 鈍化層 | zh_TW |
| dc.subject | electrochromism | en |
| dc.subject | triphenylamine | en |
| dc.subject | ZrO2 hybrid | en |
| dc.subject | silver nanowire | en |
| dc.subject | passivation layer | en |
| dc.title | 高性能電致變色材料的設計與合成及製備電化學安定之奈米銀線電極 | zh_TW |
| dc.title | Design and Synthesis of High-Performance Electrochromic Material and Fabrication of Electrochemically Stable Silver Nanowire Electrodes | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 108-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 蕭勝輝(Sheng-Huei Hsiao),龔宇睿(Yu-Ruei Kung),張嘉文(Cha-Wen Chang) | |
| dc.subject.keyword | 電致變色,三苯胺,二氧化鋯混成材料,奈米銀線,鈍化層, | zh_TW |
| dc.subject.keyword | electrochromism,triphenylamine,ZrO2 hybrid,silver nanowire,passivation layer, | en |
| dc.relation.page | 153 | |
| dc.identifier.doi | 10.6342/NTU202001510 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2020-07-14 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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