請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/57280
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 林招松(Chao-Sung Lin) | |
dc.contributor.author | Hsiang-Yu Su | en |
dc.contributor.author | 蘇香宇 | zh_TW |
dc.date.accessioned | 2021-06-16T06:40:12Z | - |
dc.date.available | 2024-08-01 | |
dc.date.copyright | 2014-08-21 | |
dc.date.issued | 2014 | |
dc.date.submitted | 2014-07-30 | |
dc.identifier.citation | 1. M. Gavrila, J.P. Millet, H. Mazille, D. Marchandise, J.M. Cuntz, 'Corrosion behaviour of zinc–nickel coatings, electrodeposited on steel', Surface and Coatings Technology, 123 (2000) 164-172
2. K.R. Baldwin, M.J. Robinson, C.J.E. Smith, 'The corrosion resistance of electrodeposited zinc-nickel alloy coatings', Corrosion Science, 35 (1993) 1267-1272 3. W. Trabelsi, P. Cecilio, M.G.S. Ferreira, M.F. Montemor, “Electrochemical assessment of the self-healing properties of Ce-dopedsilane solutions for the pre-treatment of galvanised steel substrates”, Progress in Organic Coatings, 54 (2005) 276-284 4. J. Zhao, G. Frankel, R. McCreery, “Corrosion protection of untreated AA-2024-T3 in chloride solution by a chromate conversion coating monitored with Raman spectroscopy”, Journal of Electrochemical Society, 145 (1998) 2258-2264 5. M. Kendig, R. Buchheit, “Corrosion inhibition of aluminum and aluminum alloys by soluble chromates, chromate coatings, and chromate-free coatings”, Corrosion, 59 (2003) 379-400 6. M. Kendig, S. Jeanjaquet, R. Addison, J. Waldrop, 'Role of hexavalent chromium in the inhibition of corrosion of aluminum alloys', Surface and Coatings Technology, 140 (2001) 58-66 7. R. Twite, G. Bierwagen, 'Review of alternatives to chromate for corrosion protection of aluminum aerospace alloys', Progress in Organic Coatings, 33 (1998) 91-100 8. P. Schmutz, V. Guillaumin, R. Lillard, J. A. Lillard,b, G. Frankel, 'influence of dichromate ions on corrosion processes on pure magnesium', Journal of Electrochemical Society, 150 (2003) B99-B110 9. A.R. Shashikala1, R .Umarani, S.M. Mayanna, A.K.Sharma, 'Chemical conversion coatings on magnesium alloys - A comparative study', International Journal of Electrochemical Science, 3 (2008) 993-1004 10. N. Tanga, J. van Ooij, G. Gorecki, 'Comparative EIS study of pretreatment performance in coated metals', Progress in Organic Coatings, 30 (1997) 255-263 11. X. Zhang, W.G. Sloof, A. Hovestad, E.P.M. van Westing, H. Terryn, J.H.W. de Wit,'Characterization of chromate conversion coatings on zinc using XPS and SKPFM', Surface and Coatings Technology, 197 (2005) 168-176 12. X. Zhang, C. Bos, W.G. Sloof, A. Hovestad, H. Terryn, J.H.W. de Wit, 'Comparison of the morphology and corrosion performance of Cr(VI)- and Cr(III)-based conversion coatings on zinc', Surface and Coatings Technology, 199 (2005) 92-104 13. E. Almeida, T.C Diamantino, M.O Figueiredo, C. Sa, 'Oxidising alternative species to chromium VI in zinc galvanised steel surface treatment. Part 1:A morphological and chemical study', Surface and Coatings Technology, 106 (1998) 8-17 14. L. Xia, R.L. McCreery, 'Chemistry of a chromate conversion coating on aluminum alloy AA2024‐T3 probed by vibrational spectroscopy', Journal of Electrochemical Society, 145 (1998) 3083-3089 15. B.Thaddeus, H. Okamoto, P. Subramanian, 'Binary alloy phase diagrams ', ASM international, Ohio (1990) 16. M. Pourbaix, 'Atlas of electrochemical equilibria in aqueous solutions', Second edition, NACE, Houston, Texas, USA (1966) 17. GDP Growth (annual %), In The World Bank. Retrieved May 27, 2014, form http://databank.worldbank.org/data/home.aspx 18. U.R. Evans, 'An introduction to metallic corrosion', Edward Arnold Ltd., Ohio (1981) 19. H.H. Uhlig, 'Corrosion and corrosion control: An introduction to corrosion science and engineering', Wiley, New York (1971) 20. M.G. Fontana, 'Corrosion engineer' McGRAW-Hill, Michigan (1986) 21. ISO 9223, 'Corrosion of metals and alloys - Classification of corrosivity of atmospheres' 22. 羅俊雄,劉益雄,陳桂清,柯正龍,'台灣大氣腐蝕環境分類與港灣構造物防蝕策略探討',港灣報導,期87,頁1-20,(2010) 23. H. Tamura, 'The role of rust in corrosion and corrosin protection of iron and steel', Corrosion Science, 50, (2008) 1872-1883 24. W.F. Smith, 'Structure and properties of engineering alloy', McGRAW-Hill, New York (1993) 25. 莊東漢,”材料破損分析”,五南圖書(2007) 26. C O. Obuekwe, D.W.S. Westlake, F.D. Cook, J.W. Costerton, 'Surface changes in mild steel coupons from the action of corrosion-causing bacteria', Applied and Environmental Microbiology, 41 (1981) 766-774 27. A.R. Marder, 'The metallurgy of zinc-coated steel', Progress in Materials Science, 45 (2000) 191-271 28. C.H. Xu, W. Gao, “Pilling-Bedworth Ratio for Oxidation of Alloys,” Material Research Innovations, 3 (2000) 231-235 29. 陳黼澤,'替代六價鉻製程研究',台灣大學博士論文,中華民國98年11月 30. B. Lengyel, Z. Baroti-Labar, R. Kahan, 'Study of chromate coatings by means of electrode impedance measurements', Materials Chemistry, 7 (1982) 183-193 31. J. Treverton, N. Davies, 'XPS study of chromate pretreatment of aluminum', Metals Technology, 4 (1977) 480-489 32. H. Katzman, G. Malouf, R. Bauer, 'Corrosion-protective chromate coatings on aluminum', Applied Surface Science, 2 (1979) 416-432 33. A.E. Huge, R.J. Taylor, B.R.W. Hinton, 'Chromate conversion caotings on 2024 Al alloy', Surface and Interface Analysis, 25 (1997) 223-234 34. L. Assem, H. Zhu, 'Chromium Toxicological Overview', Institute of Environment and Health, Cranfield University (2007) 35. G. Li, N. Liyuan, J. Lian, Z. Jiang, 'A black phosphate coating for C1008 steel', Surface and Coatings Technology, 176 (2004) 215–221 36. A. Losch , J.W. Schultze , 'A new electrochemical method for the determination of the free surface of phosphate layers', Applied Surface Science, 52 (1991) 29-38 37. C.M. Wang, H.C. Liau, W.T. Tsai, 'Effects of temperature and applied potential on the microstructure and electrochemical behavior of manganese phosphate coating', Surface and Coatings Technology, 201 (2006) 2994–3001 38. M.F. Morks, 'Magnesium phosphate treatment for steel', Materials Letters, 58 (2004) 3316–3319 39. P.E. Tegehall, N.G. Vannerberg, 'Nucleation and formation of zinc phosphate conversion coating on cold-rolled steel', Corrosion Science, 32 (1991) 635-652 40. C.Y. Tsai, J.S. Liu, P.L. Chen, C.S. Lin, 'A two-step roll coating phosphate/molybdate passivation treatment for hot-dip galvanized steel sheet', Corrosion Science, 52 (2010) 3385-3393 41. C.Y. Tsai, J.S. Liu, P.L. Chen, C.S. Lin, 'Effect of Mg2+ on the microstructure and corrosion resistance of the phosphate conversion coating on hot-dip galvanized sheet steel', Corrosion Science, 52 (2010) 3907-3916 42. C.Y. Tsai, J.S. Liu, P.L. Chen, C.S. Lin, 'A roll coating tungstate passivation treatment for hot-dip galvanized sheet steel', Surface and Coating Technology, 205 (2011) 5124-5129 43. P.E. Tegehall, 'The Mechanism of Chemical Activation with Titanium Phosphate Colloids in the formation of zinc phosphate conversioncoatings', Colloids and Surfaces, 49 (1990) 373-383 44. M.Wolpers, J.Angeli, 'Activation of galvanized steel surfaces before zinc phosphating- XPS and GDOES investigations', Applied Surface Science, 179 (2001) 281-291 45. K. Ishizuka, H. Shindo, K. Hayashi, 'Phosphate-treated galvanized steel sheet excellent in corrosion resistance and paintability', US 6, 596,414 B1, United State Patent 46. N. Satoh, 'Effects of heavy metal additions and crystal modification on the zinc phosphating of electrogalvanized steel sheet', Surface and Coating Technology, 30 (1987) 171-181. 47. N. Sato, T. Minami, H. Kono, “Analysis of metallic components in zinc phosphate films using electron spin resonance and X-ray fluorescence”, Surface and Coating Technology, 37 (1989) 23-30 48. D. Zimmermann, A.G. Munoz, J.W. Schultze, “Microscopic local elements in the phosphating process”, Electrochima Acta, 48 (2003) 3267-3277. 49. N. Sato, T. Minami, “Relationship between the formation of zinc phosphate crystals and their electrochemical properties”, Surface and Coating Technology, 34 (1988)331–343. 50. K. Ogle, A. Tomandl, N. Meddahi, M. Wolpers, The alkaline stability of phosphate coatings I: ICP atomic emission spectroelectrochemistry, Corrosion Science, 46 (2004) 979-995 51. A. Tomandl, M. Wolpers, K. Ogle, The alkaline stability of phosphate coatings II: In situ Raman spectroscopy, Corrosion Science, 46 (2004) 997-1011 52. V.F.C. Lins, G.F. de A. Reisb, C.R. de Araujoa, T. Matencio, 'Electrochemical impedance spectroscopy and linear polarization applied to evaluation of porosity of phosphate conversion coatings on electrogalvanized steels', Applied Surface Science, 253 (2006) 2875-2884 53. T. Minami, N. Sato, 'Analysis of Paramagnetic Transition Metal Components in Hopeite Films by ESR', Hyomen Kagaku, 7 (1988) 459-462 54. B.L. Lin, J.T. Lu, G. Kong, 'Effect of molybdate post-sealing on the corrosion resistance of zinc phosphate coatings on hot-dip galvanized steel', Corrosion Science, 50 (2008) 962-967 55. Y.Y. Xe, B.L. Lin, 'Effect of silicate pretreatment, post-sealing and additives on corrosion resistance of phosphated galvanized steel', Transactions of Nonferrous Metals Society of China, 17 (2007) 1248-1253 56. B.L. Lin, J.T. Lu, G. Kong, 'Synergistic corrosion protection for galvanized steel by phosphating and sodium silicates post-sealing', Surface and Coating Technology, 202 (2008) 1831-1838 57. D. Weng, P. Jokiel, A. Uebleis, H. Boehni, 'Corrosion and protection characteristics of zinc and manganese phosphate coatings', Surface and Coatings Technology, 88 (1996) 147-156 58. A.S. Akhtar, K.C. Wong, P.C. Wong, K.A.R. Mitchell, 'Effect of Mn2+ additive on the zinc phosphating of 2024-Al alloy', Thin Solid Films, 515 (2007) 7899–7905 59. A.S. Akhtar, D. Susac, P. Glaze, K.C., Wong, P.C. Wong, K.A.R. Mitchell, 'The effect of Ni2+ on zinc phosphating of 2024-T3 Al alloy', Surface and Coatings Technology, 187 (2004) 208–215 60. A.S. Akhtar, K.C. Wong, K.A.R. Mitchell, 'The effect of pH and role of Ni2+ in zinc phosphating of 2024-Al alloy Part I: Macroscopic studies with XPS and SEM', Applied Surface Science, 253 (2006) 493–501 61. A.S. Akhtar, D. Susac, P.C. Wong, K.A.R. Mitchell, 'The effect of pH and role of Ni2+ in zinc phosphating of 2024-Al alloy Part II: Microscopic studies with SEM and SAM', Applied Surface Science, 253 (2006) 502–509 62. P.E. Tegehall, “Colloidal titanium phosphate, the chemical activator in surface conditioning before zinc phosphating”, Colloids and Surfaces, 42 (1989) 155-164 63. 蔡承洋,”熱浸鍍鋅鋼板之磷酸鹽、鉬酸鹽與釩酸鹽複合鈍化處理”,台灣大學博士論文,中華民國100年7月 64. Material Safety Data Sheet of Potassium phosphate monobasic 65. Material Safety Data Sheet of Sodium phosphate monobasic anhydrous 66. Material Safety Data Sheet of Phosphoric Acid 67. D.J. Conley, C. Humborg, L. Rahm, 'Hypoxia in the Baltic Sea and basin-scale changes in phosphorus biogeochemistry', Environmental Science, 36 (2002) 5315-5320 68. T. H. Fang, 'Partitioning and behaviour of different forms of phosphorus in the Tanshui estuary and one of its tributaries, Northern Taiwan', Estuarine, Coastal and Shelf Science, 50 (2000) 689-701 69. S.K. Ning, Ni-Bin Chang, L. Yang, H.W. Chen, H.Y. Hsu, 'Assessing pollution prevention program by QUAL2E simulation analysis for the Kao-Ping River Basin, Taiwan', Journal of Environmental Management, 61 (2001) 61-76 70. M. Dabala, K. Brunelli, E. Napolitani, 'Cerium-based chemical conversion coating on AZ63 magnesium alloy', Surface and Coatings Technology, 172 (2003) 227-232 71. M. Dabala, K. Brunelli, I. Calliari, 'Effect of HCl pre-treatment on corrosion resistance of cerium-based conversion coatings on magnesium and magnesium alloys', Corrosion Science, 47 (2005) 989-1000 72. W. Pinc, S. Geng, M. O'Keefe, 'Effects of acid and alkaline based surface preparations on spray deposited cerium based conversion coatings on Al 2024-T3', Applied Surface Science, 255 (2009) 4061-4065 73. M.L. Zheludkevich, R. Serra, M.F. Montemor, 'Nanostructured sol–gel coatings doped with cerium nitrate as pre-treatments for AA2024-T3 Corrosion protection performance', Electrochimica Acta, 51 (2005) 208-217 74. K. Aramaki, 'Protection of zinc from corrosion by coverage with a hydrated cerium(III) oxide layer and ultrathin polymer films of a carboxylate self-assembled monolayer modified with alkyltriethoxysilanes', Corrosion Science, 49 (2007) 1963-1980 75. K. Aramaki, 'The inhibition effects of cation inhibitors on corrosion of zinc in aerated 0.5 M NaCl', Corrosion Science, 43 (2001) 1573-1588 76. K. Aramaki, 'Treatment of zinc surface with cerium(III) nitrate to prevent zinc corrosion in aerated 0.5 M NaCl', Corrosion Science, 43 (2001) 2201-2215 77. K. Aramaki, 'Synergistic inhibition of zinc corrosion in 0.5 M NaCl by combination of cerium(III) chloride and sodium silicate', Corrosion Science, 44 (2002) 871-886 78. K. Aramaki, 'Preparation of chromate-free, self-healing polymer films containing sodium silicate on zinc pretreated in a cerium(III) nitrate solution for preventing zinc corrosion at scratches in 0.5 M NaCl', Corrosion Science, 44 (2002) 1375-1389 79. K. Aramaki, 'Self-healing mechanism of an organosiloxane polymer film containing sodium silicate and cerium(III) nitrate for corrosion of scratched zinc surface in 0.5 M NaCl', Corrosion Science, 44 (2002) 1621-1632 80. K. Aramaki, 'XPS and EPMA studies on self-healing mechanism of a protective film composed of hydrated cerium(III) oxide and sodium phosphate on zinc', Corrosion Science, 45 (2003) 2621-2624 81. Material Safety Data Sheet of Tetraethyl orthosilicate 82. Material Safety Data Sheet of 3-Glycidoxypropyltrimethoxysilane 83. 黃劍鋒,”溶膠-凝膠原理與技術”,化學工業出版社 84. C.J. Brinker, G.W. Scherer, 'Sol-gel science- The Physics and Chemistry of Sol-Gel Process', Academic Press, Inc., (1990) 85. W. Ostwald, 'Studies on the formation and transformation of solid bodies', Zeitschrift fur physikalische Chemie, 22 (1897) 289-330 86. 張智中,'以溶膠-凝膠法製備有機無機混成相轉移材料微膠囊',中央大學碩士論文,中華民國95年7月 87. M.L. Zheludkevich, I.M. Salvado, M.G.S. Ferreira, 'Sol-gel coatings for corrosion protection of metals', Journal of Material Chemistry, 15 (2005) 5099-5111 88. L.L. Hench, J.K. West, 'The sol-gel Process', Chemical Reviews, 90 (1990) 33-72 89. A. Franquet, C. Le Pen, H. Terryn, J. Vereecken, 'Effect of bath concentration and curing time on the structure of non-functional thin organosilane layers on aluminium', Electrochimica Acta, 48 (2003) 1245-1255 90. J. Uchida, K. Kawakami, S. Sato, “The development of thinner chromium-free chemical for zinc plating”, Nihon Parkerizing Technical Report, 24 (2012) 91. D. Suryanarayana, K.L. Mittal, 'Effect of pH of Silane Solution on the Adhesion of Polyimide to a Silica Substrate', Journal of Applied Polymer Science, 29 (1984) 2039-2043 92. A. Sabata, W.J. Van Ooij, R.J. Koch, 'The interphase in painted metals pretreated by functional silanes', Journal of Adhesion Science and Technology, 7 (1993) 1153-1170 93. M. Tanoglu, S.H. McKnight, G.R. Palmese, J.W. Gillespie, 'Use of silane coupling agents to enhance the performance of adhesively bonded alumina to resin hybrid composites', International Journal of Adhesion & Adhesives, 18 (1998) 431-434 94. M.F. Montemor, A.M. Simoes, M.G.S. Ferreira, B. Williams, H. Edwards, 'The corrosion performance of organosilane based pre-treatments for coatings on galvanised steel', Progress in Organic Coatings, 38 (2000) 17-26 95. P. Puomi, H.M. Fagerholm, 'Performance of silane treated primed hot-dip galvanised steel', Anti-corrosion Methods and Materials, 48 (2001) 7-17 96. N.N. Voevodin, N.T. Grebasch, W.S. Soto, L.S. Kasten, J.T. Grant, F.E. Arnold, M.S. Donley, 'An organically modified zirconate film as a corrosion-resistant treatment for aluminum 2024-T3', Progress in Organic Coatings, 41 (2001) 287-293 97. T.L. Metroke, O. Kachurina, E.T. Knobbe, 'Spectroscopic and corrosion resistance characterization of GLYMO–TEOS Ormosil coatings for aluminum alloy corrosion inhibition', Progress in Organic Coatings, 44 (2002) 295-305 98. V. Palanivel, D. Zhu, W.J. van Ooij, 'Nanoparticle-filled silane films as chromate replacements for aluminum alloys', Progress in Organic Coatings, 47 (2003) 384-392 99. M.S. Donley, R.A. Mantz, A.N. Khramov, V.N. Balbyshev, L.S. Kasten, D.J. Gaspar, 'The self-assembled nanophase particle (SNAP) process: a nanoscience approach to coatings', Progress in Organic Coatings, 47 (2003) 401-415 100. A.N. Khramov, V.N. Balbyshev, N.N. Voevodin, M.S. Donley, 'Nanostructured sol–gel derived conversion coatings based on epoxy- and amino-silanes', Progress in Organic Coatings, 47 (2003) 207-213 101. D. Susac, X. Sun, K.A.R. Mitchell, 'Adsorption of BTSE and r-APS organosilanes on different microstructural regions of 2024-T3 aluminum alloy', Applied Surface Science, 207 (2003) 40-50 102. M.F. Montemor, A. Rosqvist, H. Fagerholm, M.G.S. Ferreira, 'The early corrosion behaviour of hot dip galvanised steel pre-treated with bis-1,2-(triethoxysilyl)ethane', Progress in Organic Coatings, 51 (2004) 188-194 103. D. Zhu, W.J. van Ooij, 'Corrosion protection of metals by water-based silane mixtures of bis-[trimethoxysilylpropyl]amine and vinyltriacetoxysilane', Progress in Organic Coatings, 49 (2004) 42-53 104. R. Zandi-zand, A. Ershad-langroudi, A. Rahimi, 'Silica based organic–inorganic hybrid nanocomposite coatings for corrosion protection', Progress in Organic Coatings, 53 (2005) 286-291 105. R. Zandi-zand, A. Ershad-langroudi, A. Rahimi, 'Organic–inorganic hybrid coatings for corrosion protection of 1050 aluminum alloy', Journal of Non-Crystalline Solids, 351 (2005) 1307-1311 106. A. Cabral, R.G. Duarte, M.F. Montemor, M.L. Zheludkevich, M.G.S. Ferreira, 'Analytical characterisation and corrosion behaviour of bis-[triethoxysilylpropyl]tetrasulphide pre-treated AA2024-T3', Corrosion Science, 47 (2005) 869-881 107. A. Pepe, P. Galliano, M. Aparicio, A. Duran, S. Cere’, 'Sol-gel coatings on carbon steel: Electrochemical evaluation', Surface & Coatings Technology, 200 (2006) 3486-3491 108. L. Jianguo, G. Gaoping, Y. Chuanwei, 'Enhancement of the erosion–corrosion resistance of Dacromet with hybrid SiO2 sol–gel', Surface & Coatings Technology, 200 (2006) 4967-4975 109. M.L. Zheludkevich, R. Serra, M.F. Montemor, I.M. Miranda Salvado, M.G.S. Ferreira, 'Corrosion protective properties of nanostructured sol–gel hybrid coatings to AA2024-T3', Surface & Coatings Technology, 200 (2006) 3084-3094 110. Y. Tamar, D. Mandler, 'Corrosion inhibition of magnesium by combined zirconia silica sol–gel films', Electrochimica Acta, 53 (2008) 5118-5127 111. Z. Feng, Y. Liu, G.E. Thompson, P. Skeldon, 'Crack-free sol-gel coatings for protection of AA1050 aluminium alloy', Surface and Interface Analysis, 42 (2010) 306-310 112. B. Naderi Zand, M. Mahdavian, 'Corrosion and adhesion study of polyurethane coating on silane pretreated aluminum', Surface & Coatings Technology, 203 (2009) 1677-1681 113. Z. Feng, Y. Liu, G.E. Thompson, P. Skeldon, 'Sol–gel coatings for corrosion protection of 1050 aluminium alloy', Electrochimica Acta, 55 (2010) 3518-3527 114. R.T. Sakai, F.M. da Cruz, H.G. de Melo, A.V. Benedetti, C.V. Santilli, P.H. Suegama, 'Electrochemical study of TEOS, TEOS/MPTS, MPTS/MMA and TEOS/MPTS/MMA fims on tin coated steel in 3.5% NaCl solution', Progress in Organic Coatings, 74 (2012) 288-301 115. N.N. Voevodin, N.T. Grebasch, W.S. Soto, F.E. Arnold, M.S. Donley, 'Potentiodynamic evaluation of sol-gel coatings with inorganic inhibitors', Surface and Coatings Technology, 140 (2001) 24-28 116. L.S. Kasten b, J.T. Grant, N. Grebasch, N. Voevodin, F.E. Arnold, M.S. Donley, 'An XPS study of cerium dopants in sol-gel coatings for aluminum 2024-T3', Surface and Coatings Technology, 140 (2001) 11-15 117. K. Aramaki, 'Self-healing mechanism of an organosiloxane polymer film containing sodium silicate and cerium(III) nitrate for corrosion of scratched zinc surface in 0.5 M NaCl', Corrosion Science, 44 (2002) 1621-1632 118. N.N. Voevodin, V.N. Balbyshev, M. Khobaib, M.S. Donley, 'Nanostructured coatings approach for corrosion protection', Progress in Organic Coatings, 47 (2003) 416–423 119. M.G.S. Ferreira, R.G. Duarte, M.F. Montemor, A.M.P. Simoes, 'Silanes and rare earth salts as chromate replacers for pre-treatments on galvanised steel', Electrochimica Acta, 49 (2004) 2927–2935 120. M. Garcia-Heras, A. Jimenez-Morales, B. Casal, J.C. GalvanS. Radzki, M.A. Villegas, 'Preparation and electrochemical study of cerium-silica sol-gel thin films', Journal of Alloys and Compounds, 380 (2004) 219–224 121. M.L. Zheludkevich, R. Serra, M.F. Montemor, M.G.S. Ferreira, 'Oxide nanoparticle reservoirs for storage and prolonged release of the corrosion inhibitors', Electrochemistry Communications, 7 (2005) 836–840 122. M.L. Zheludkevich, R. Serra, M.F. Montemor, K.A. Yasakau, I.M. Miranda Salvado, M.G.S. Ferreira, 'Nanostructured sol–gel coatings doped with cerium nitrate as pre-treatments for AA2024-T3 Corrosion protection performance', Electrochimica Acta, 51 (2005) 208–217 123. V. Palanivel, Y. Huang, W.J. van Ooij, 'Effects of addition of corrosion inhibitors to silane films on the performance of AA2024-T3 in a 0.5 M NaCl solution', Progress in Organic Coatings, 53 (2005) 153–168 124. W. Trabelsi, E. Triki, L. Dhouibi, M.G.S. Ferreira, M.L. Zheludkevich, M.F. Montemor, 'The use of pre-treatments based on doped silane solutions for improved corrosion resistance of galvanised steel substrates', Surface & Coatings Technology, 200 (2006) 4240–4250 125. D.G. Shchukin, M.L. Zheludkevich, K. Yasakau, S. Lamaka,M.G.S. Ferreira, H. Mohwald, 'Layer-by-Layer Assembled Nanocontainers for Self-Healing Corrosion Protection', Advanced Material, 18 (2006) 1672-1678 126. A. Pepe, M. Aparicio, A. Duran, S. Cer’e, 'Cerium hybrid silica coatings on stainless steel AISI 304 substrate', Journal of Sol-Gel Science Technology, 39 (2006) 131-138 127. W. Trabelsi, P. Cecilio, M.G.S. Ferreira, K. Yasakau, M.L. Zheludkevich, M.F. Montemor, 'Surface evaluation and electrochemical behaviour of doped silane pre-treatments on galvanised steel substrates', Progress in Organic Coatings, 59 (2007) 214–223 128. S.V. Lamaka, M.L. Zheludkevich, K.A. Yasakau, R. Serra, S.K. Poznyak, M.G.S. Ferreira, 'Nanoporous titania interlayer as reservoir of corrosion inhibitors for coatings with self-healing ability', Progress in Organic Coatings, 58 (2007) 127–135 129. M.L. Zheludkevich, D.G. Shchukin, K.A. Yasakau, H. Mhwald, M.G.S. Ferreira, 'Anticorrosion Coatings with Self-Healing Effect Based on Nanocontainers Impregnated with Corrosion Inhibitor', Chemistry of Materials, 19 (2007) 402-411 130. K.A. Yasakau, M.L. Zheludkevich, O.V. Karavai, M.G.S. Ferreira, 'Influence of inhibitor addition on the corrosion protection performance of sol–gel coatings on AA2024', Progress in Organic Coatings, 63 (2008) 352–361 131. D.G. Shchukin, S.V. Lamaka, K.A. Yasakau, M.L. Zheludkevich, M.G.S. Ferreira, H. Mohwald, 'Active Anticorrosion Coatings with Halloysite Nanocontainers', The Journal of Phtsical Chemistry C, 112 (2008) 958-964 132. H. Shi, F. Liu, E. Han, 'Corrosion behaviour of sol–gel coatings doped with cerium salts on 2024-T3 aluminum alloy', Materials Chemistry and Physics, 124 (2010) 291-297 133. X. Zhong, Q. Li, J. Hu, X. Yang, F. Luo, Y, Dai, 'Effect of cerium concentration on microstructure, morphology and corrosion resistance of cerium–silica hybrid coatings on magnesium alloy AZ91D', Progress in Organic Coatings, 69 (2010) 52–56 134. C. Motte, M. Poelman, A. Roobroeck, M. Fedel, F. Dflorian, M.G. Olivier, 'Improvement of corrosion protection offered to galvanized steel by incorporation of lanthanide modified nanoclays in silane layer', Progress in Organic Coatings, 74 (2012) 326–333 135. R.Z. Zand, K. Verbeken, A. Adriaens, 'Electrochemical Assessment of the Self-Healing Properties of Cerium Doped Sol-Gel Coatings on 304L Stainless Steel Substrates ', International Journal of Electrochemical Science, 7 (2012) 9592-9608 136. J. Cambon, F. Ansart, J. Bonino, V. Turq, 'Effect of cerium concentration on corrosion resistance and polymerization of hybrid sol–gel coating on martensitic stainless steel', Progress in Organic Coatings, 75 (2012) 486-493 137. R.Z. Zand, K. Verbeken, A. Adriaens, 'Influence of the Cerium Concentration on the Corrosion Performance of Ce-doped Silica Hybrid Coatings on Hot Dip Galvanized Steel Substrates', International Journal of Electrochemical Science, 8 (2013) 548-563 138. 曹楚南,張鋻清,”電化學阻抗譜導論”,科學出版社,(2001) 139. Tetraethyl Orthosilicate. (2014, April 16). In Wikipedia, the free encyclopedia. Retrieved May 23, 2014, from http://en.wikipedia.org/wiki/Tetraethyl orthosilicate 140. 3-Glycidoxypropyltrimethoxysilane. In Acros Organics. Retrived May 23, 2014, form http://www.acros.com/Product/Find.aspx?Product= 3-Glycidoxypropyltri -methoxysilane 141. N. Kanani, 'Electroplating-basic principles, process and practice', Elsevier, (2004) 300 142. W.M. Haynes, 'CRC handbook of chemistry and physics', 93rd edition, 2012-2013 143. R.D. Shannon, 'Revised Effective Ionic Radii and Systematic Studies of Interatomie Distances in Halides and Chaleogenides', Acta Crystallographica Section A, 32 (1976) 751-767 144. Y. Song, D. Shan, R. Cheng, F. Zhang, E.H. Han, “A novel phosphate conversion film on Mg-8.8Li alloy”, Surface and Coating technology, 203 (2009) 1107-1113 145. S. Maeda, M. Yamamoto, “The role of chromate treatment after phosphating in paint adhesion”, Progress in Organic Coatings, 33 (1998) 83-89 146. L. Salvati, L.E. Makovsky, J.M. Stencel, F.R. Brown, D.M. Hercules, 'Surface spectroscopic study of tungsten-alumina catalysts using x-ray photoelectron, ion scattering, and Raman spectroscopies', The Journal of Physical Chemistry, 85 (1981) 3700-3707 147. A.P. Grosvenor, M.C. Biesinger, R.C. Smart, N.S. McIntyre, 'New interpretations of XPS spectra of nickel metal and oxides', Surface Science, 600 (2006) 1771-1779 148. C.D. Wagner, W.M. Riggs, L.E. Davis, J.F. Moulder, 'Handbook of X-Ray Photoelectron Spectroscopy', (1979) 80 149. S.R. Kumar, M.N. Hedhili, H.N. Alshareef, S. Kasiviswanathan, 'Correlation of Mn charge state with the electrical resistivity of Mn doped indium tin oxide thin films', Applied Physics Letters, 97 (2010) 111909 150. A. Goux, T. Pauport’e, J. Chivot, D. Lincot, 'Temperature effects on ZnO electrodeposition', Electrochimica Acta, 50 (2005) 2239-2248 151. Y. Arnaud, E. Sahakian, M. Romand, J.C. Charbonnier, “Study of hopeite coatings.1. Pure hopeite thermal dehydration- dihydrate, Zn3(PO4)2•2H2O, structure conformation”, Applied Surface Science, 32 (1988) 281-295 152. Y. Arnaud, E. Sahakian, J. Lenoir, A. Roche, J.C. Charbonnier, “Study of hopeite coatings. 2. Study of polycationic hopeites- Structure and dehydration process”, Applied Surface Science, 32 (1988) 296-308 153. C. Cachet, F. Ganne, G. Maurin, J. Petitjean, V. Vivier, R. Wiart, “EIS investigation of zinc dissolution in aerated sulfate medium. Part I: Bulk zinc”, Electrochimca Acta, 47 (2001) 509–518. 154. C. Cachet, F. Ganne, G. Maurin, J. Petitjean, V. Vivier, R. Wiart, “EIS investigation of zinc dissolution in aerated sulfate medium. Part II: Zinc coatings”, Electrochimca Acta, 47 (2002) 3409-3422. 155. C. Liu, Q. Bi, A. Leyland, A. Matthews, 'An electrochemical impedance spectroscopy study of the corrosion behaviour of PVD coated steels in 0.5 N NaCl aqueous solution: Part I. Establishment of equivalent circuits for EIS data modeling', Corrosion Science, 45 (2003) 1243-1256. 156. C. Liu, Q. Bi, A. Leyland, A. Matthews, 'An electrochemical impedance spectroscopy study of the corrosion behaviour of PVD coated steels in 0.5 N NaCl aqueous solution: Part II.: EIS interpretation of corrosion behaviour', Corrosion Science, 45 (2003) 1257-1273. 157. A. Fujimori, 'Mixed-valent ground state of CeO2', Physical Review B, 28 (1983) 2281-2283 158. J.Z. Shyu, K. Otto, W.L.H. Watkins, G.W. Graham, R.K. Belitz, H.S. Gandhi, 'Characterization of Pd/alumina catalysts containing ceria', Journal of Catalysis, 114 (1988) 23-33 159. X. Yu, G. Li, “XPS study of cerium conversion coating on the anodized 2024 aluminum alloy”, Journal of Alloys and Compounds, 364 (2004) 193-198 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/57280 | - |
dc.description.abstract | 披覆在鐵基材料上的鋅層可以具有障蔽保護以及犧牲陽極保護的效果,然而鋅層在潮濕的環境下容易腐蝕,為了提升鍍鋅鋼件的抗蝕性,通常會在鍍鋅處理後進行表面鈍化處理。經六價鉻鈍化處理後的鍍鋅鋼件展現出優異的抗腐蝕性質,但六價鉻物質具有致癌性,同時也會嚴重污染生態環境,為此,近年來六價鉻物質被限制使用或漸漸禁用,而研究非六價鉻鈍化處理的鈍化技術變的勢在必行。
磷酸鹽鈍化處理被廣泛應用於現今工業,磷酸鋅皮膜晶粒(Zn3(PO4)2•4H2O,Hopeite)呈不規則狀,晶粒間沒有辦法完全接合,故晶粒間易有殘存孔隙或是皮膜較薄處,而這些缺陷處常常是腐蝕反應發生的起源,本研究嘗試在磷酸鹽鈍化處理液中加入添加劑Ni(NO3)2或Mn(NO3)2,藉以增加磷酸鹽皮膜成核點,進一步減少磷酸鹽皮膜孔隙率。實驗結果顯示,無論添加何種添加劑,磷酸鹽皮膜晶粒大小均隨著磷酸鹽鈍化處理液中添加劑的濃度增加而減小,各個式樣在動電位極化曲線、電化學交流阻抗頻譜、以及鹽霧試驗下的抗蝕性皆隨著磷酸鹽皮膜晶粒尺寸減小而增加。利用XRD繞射分析以及XPS對添加不同添加劑之磷酸鹽鈍化皮膜進行結構以及成分分析後發現,經由二價鎳離子修飾後的磷酸鹽皮膜主要由磷酸鋅水合物構成,而經由二價錳離子修飾的磷酸鹽皮膜則是由磷酸鋅水合物以及磷酸鋅錳水合物構成。添加二價鎳離子以及二價錳離子均可以細化磷酸鹽皮膜、降低皮膜孔隙率,但由其成分組成可以得知兩者細化之機制不同,提升抗蝕性的機制也有所不同。二價鎳離子主要藉由促進鋅離子溶出,增加磷酸鹽皮膜的成核點,進而使得磷酸鹽皮膜晶粒尺寸縮小、降低磷酸鹽皮膜孔隙率;而二價錳離子是藉由增加磷酸鹽鈍化處理時離子碰撞的機率,進而使磷酸鹽皮膜孔隙率降低。 隨著工業蓬勃的發展,磷所造成的環境汙染也日益受到重視,為了防治磷對環境造成的傷害,有許多替代方案也日益被提出。本研究亦嘗試將矽烷化合物以溶膠-凝膠法對熱浸鍍鋅鋼板進行輥塗型鈍化處理,結果顯示鈍化後的熱浸鍍鋅鋼板之抗蝕性與試片前處理方式、前軀體水解時的pH值、水解時間、以及溶膠-凝膠溶液成分組成息息相關。此部分的研究略分為三個階段,第一階段研究TEOS無機型溶膠-凝膠塗膜的配置方式對於熱浸鍍鋅鋼板抗蝕性的影響,並以此為基石,研究溶膠-凝膠塗膜的特性。相較於未鈍化前的熱浸鍍鋅鋼板,經過TEOS無機型溶膠-凝膠鈍化處理後的熱浸鍍鋅鋼板在鹽霧試驗以及電化學交流阻抗下的抗蝕性質明顯改善,然而,經由表面形貌觀察卻還是可以觀察到塗膜具有裂紋,而這些缺陷在鹽霧試驗期間就是腐蝕反應發生的起點。第二階段則是研究TEOS/GPTMS無機/有機複合型溶膠-凝膠塗膜對於熱浸鍍鋅鋼板抗蝕性的影響,根據實驗結果顯示適當調配前驅物成分之後可以改變塗膜的特性,使得塗膜不具有裂紋缺陷,因此熱浸鍍鋅鋼板的抗蝕性得到進一步的提升,另一方面,塗膜的漆膜附著性也隨著有機前驅物的添加而得到了大幅的改善。為了賦予塗膜腐蝕抑制能力,本研究於第三階段嘗試在無機/有機複合型溶膠-凝膠溶液中加入具有腐蝕抑制效果的無機鹽類(硝酸亞鈰Ce(NO3)3•6H2O),根據動電位極化曲線以及電化學交流阻抗頻譜分析的結果均指出,加入硝酸亞鈰的複合型溶膠-凝膠塗膜的腐蝕電流密度以及皮膜電容值均較未添加硝酸亞鈰前的無機/有機複合型溶膠-凝膠塗膜大,然而鹽霧試驗結果卻顯示含有硝酸亞鈰的複合型溶膠-凝膠塗膜具有較佳的抗蝕性,在Cross-cut鹽霧試驗中含有硝酸亞鈰的複合型溶膠-凝膠塗膜之塗膜缺陷區也保有較佳的耐蝕性,因此,混摻於複合型溶膠-凝膠溶液中的硝酸亞鈰在塗膜的腐蝕防護機制上扮演極重要的角色。 | zh_TW |
dc.description.abstract | Zinc coating provided two main functions on the steel substrate, the first one is the barrier protection which prevents the steel substrate form the corrosion factors attacking, and the other one is the sacrificial protection over the steel substrate. To further protect the Zn-coated steel against corrosion, hexavalent chromium (Cr6+) based passivation treatment is generally employed. However, the use of hexavalent chromium is restricted recently due to its high toxicity, signifying an urgent necessity to develop chrome-free treatments. Phosphate passivation treatment is generally adopted in order to enhance corrosion resistance of the steel substrate. Crystalline hopeite shows good adhesion on the zinc-coated substrate; however, the irregular crystals result in the existence of the opening pores on the coating, which is detrimental to corrosion resistance. The corrosion resistance of the coating is closely related to the coating porosity. Once the nucleation density is increased, the coating coverage is improved. The coating porosity is thus reduced, giving rise to better corrosion resistance. In this study, Ni2+ ions and Mn2+ ions were added separately to the treating solution in order to minimize the porosity of the phosphate conversion coating. Results showed the phosphate grain size and the coating porosity were reduced with the presence of Ni2+ or Mn2+ ions, and the corrosion resistance of the phosphate coating was thus enhanced. Although the nucleation sites of phosphate grains were increased with the presence of Mn2+ or Ni2+ in the phosphating solution, the mechanism of the nucleation site increment was different for the two cations. For the electrogalvanized steel phosphated in the presence of Ni2+, the enhanced dissolution of zinc played a major role in increasing the nucleation sites. On the other hand, the enhancement in nucleation rate in the presence of Mn2+ mainly resulted from the increased impingement of the reacting ions in the phosphate treating solution. In this study, the sol-gel passivation treatment on hot-dip galvanized sheet steels by using roll-coating was also concerned. The corrosion protection performance of the sol-gel coating on hot-dip galvanized sheet steel was closely related to the pre-treatment of the zinc-coated substrate, the pH value of the hydrolyzed solution, the hydrolysis time of the sol-gel solution, and the constituents of the so-gel solution. The pure inorganic coatings made from TEOS enhanced the corrosion resistance of the HDG steel under the salt spray test; however, its corrosion protection was limited by the presence of cracks. The incorporation of organic groups, GPTMS, reduced the volume shrinkage during the drying process. The formation of cracks was thus eliminated and the corrosion resistance of the HDG steel was further improved. Moreover, the paint adhesion was also enhanced with the addition of organic groups. The corrosion current density measured via potentiodynamic polarization and the coating capacitance evaluated via EIS increased with the addition of the cerium nitrate to the sol. This increase was likely due to the decrease in the compactness of the coating. However, the incorporated Ce species was leached out during corrosion. As a result, the addition of Ce nitrate to the sol studied improved the corrosion resistance of the coating, as evaluated via the salt spray test. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T06:40:12Z (GMT). No. of bitstreams: 1 ntu-103-F97527052-1.pdf: 9314205 bytes, checksum: de197ae30af49af29e646e9a83c8eb01 (MD5) Previous issue date: 2014 | en |
dc.description.tableofcontents | 口試委員會審定書 i
致謝 ii 中文摘要 iv 英文摘要 vi 總目錄 viii 圖目錄 xii 表目錄 xx 第一章 緒論 1 第二章 文獻回顧 5 2-1 鋼鐵材料 5 2-2 鋼鐵材料的腐蝕行為 5 2-2-1 腐蝕的定義與機構 5 2-2-2 台灣的腐蝕環境 7 2-2-3 鋼鐵材料的腐蝕 8 2-3 鋼鐵材料的腐蝕防護 10 2-4 鍍鋅底材及其腐蝕行為 12 2-4-1 Pilling-Bedworth ratio 14 2-5 鍍鋅層的表面鈍化處理 17 2-5-1 鈍化處理製程 18 2-5-2 六價鉻鈍化處理 22 2-5-3 磷酸鹽鈍化處理 27 2-5-4 稀土鹽類鈍化處理 32 2-5-5 溶膠-凝膠法(有機矽烷化合物鈍化處理) 34 2-6 分析方法與原理 52 2-6-1 電化學量測法 52 2-6-3 電化學交流阻抗頻譜 56 2-6-4 皮膜孔隙率量測原理 62 第三章 實驗步驟與方法 63 3-1 添加劑對於浸泡型磷酸鹽皮膜的影響 63 3-1-1 電鍍鋅鋼片 63 3-1-2 磷酸鹽鈍化處理 63 3-2 溶膠-凝膠法鈍化處理對抗蝕性的影響 64 3-2-1 熱浸鍍鋅鋼板 64 3-2-2 溶膠凝膠鈍化處理 65 3-3 微結構觀察及成分分析 67 3-3-1 掃描式電子顯微鏡 67 3-3-2 能量分散光譜儀 67 3-3-3 X光繞射分析 69 3-3-4 X光光電子化學分析 69 3-4 皮膜抗蝕性量測 69 3-4-1 開路電位量測 69 3-4-2 動電位極化曲線以及線性極化曲線量測 70 3-4-3 電化學交流阻抗頻譜分析 70 3-4-4 鹽霧試驗 71 3-5 漆膜附著性 72 第四章 實驗結果與討論 73 磷酸鹽鈍化處理 73 4-1 添加鎳離子對浸泡型磷酸鹽皮膜的影響 73 4-1-1 SEM表面形貌觀察及皮膜晶粒大小、密度量測 73 4-1-2 抗蝕性分析 79 4-2 添加錳離子對浸泡型磷酸鹽皮膜的影響 87 4-2-1 SEM表面形貌觀察及皮膜晶粒大小、密度量測 87 4-2-2 抗蝕性分析 93 4-3 添加不同添加劑的比較 98 4-3-1 X-ray結構分析 98 4-3-2 X光光電子成分分析 104 4-4 磷酸鹽皮膜成膜機構 109 4-4-1 含二價鎳離子之磷酸鹽皮膜成膜機構 109 4-4-2 含二價錳離子之磷酸鹽皮膜成膜機構 113 4-5 磷酸鹽皮膜抗蝕機構 116 4-5-1 添加不同添加劑的比較 121 4-5-2 皮膜成分對皮膜抗蝕性的影響 126 溶膠-凝膠法鈍化處理 131 4-6 單一型溶膠-凝膠鈍化處理(Inorganic coating) 131 4-6-1 水解pH值以及酒精稀釋比例的影響 131 4-6-2 熱鹼前處理的影響 134 4-6-3 水解時間的影響 136 4-7 複合型溶膠-凝膠鈍化處理(Inorganic/organic hybrid coating) 148 4-7-1 水解時間的影響 148 4-7-2 SEM微結構觀察 150 4-7-3 鹽霧試驗 152 4-7-4 動電位極化曲線測試 152 4-7-5 電化學交流阻抗頻譜分析 153 4-8 混摻腐蝕抑制劑之複合型溶膠-凝膠鈍化處理 156 4-8-1 腐蝕抑制劑濃度的影響 156 4-8-2 SEM微結構觀察 160 4-8-3 XPS成分分析 162 4-8-4 動電位極化曲線 165 4-8-5 電化學交流阻抗頻譜分析 167 4-8-6 模擬刮痕槽自我癒合能力測試 169 4-8-7 Cross-cut鹽霧試驗測試 170 4-9 溶膠-凝膠塗膜成膜機構以及腐蝕保護機構 174 4-9-1 複合型溶膠-凝膠塗膜成膜機構以及腐蝕保護機構 174 4-9-2 混摻腐蝕抑制劑之複合型溶膠-凝膠塗膜成膜機構以及腐蝕保護機構 178 第五章 結論 183 第六章 未來展望 187 參考文獻 189 | |
dc.language.iso | zh-TW | |
dc.title | 鍍鋅鋼板之磷酸鹽鈍化處理及溶膠凝膠法鈍化處理 | zh_TW |
dc.title | Phosphate and Sol-Gel Passivation Treatments of Zinc-Coated Sheet Steels | en |
dc.type | Thesis | |
dc.date.schoolyear | 102-2 | |
dc.description.degree | 博士 | |
dc.contributor.oralexamcommittee | 蔡文達(Wen-Ta Tsai),莊東漢(Tung-Han Chuang),林景崎(Jing-Chie Lin),葛明德(Ming-Der Ger),陳蓓莉(Pei-Li Chen) | |
dc.subject.keyword | 鍍鋅鋼件,磷酸鹽鈍化處理,添加劑,溶膠-凝膠鈍化處理,腐蝕抑制劑,自我癒合能力,電化學交流阻抗頻譜分析, | zh_TW |
dc.subject.keyword | Zinc-Coated steel,Phosphate Passivation Treatment,Additive,Sol-Gel Passivation Treatment,Corrosion Inhibitor,Self-Healing Ability,Electrochemical Impedance Spectroscopy, | en |
dc.relation.page | 206 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2014-07-30 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-103-1.pdf 目前未授權公開取用 | 9.1 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。