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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/56506完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 何國川(Kuo-Chuan Ho) | |
| dc.contributor.author | Wan-Hsuan Chou | en |
| dc.contributor.author | 周宛璇 | zh_TW |
| dc.date.accessioned | 2021-06-16T05:32:00Z | - |
| dc.date.available | 2024-08-20 | |
| dc.date.copyright | 2014-08-21 | |
| dc.date.issued | 2014 | |
| dc.date.submitted | 2014-08-13 | |
| dc.identifier.citation | 高分子膠態電解液，可望改善其長期操作之穩定性。
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/56506 | - |
| dc.description.abstract | 在電致色變領域中提及對於全可見光波段皆具有吸收能力(或全波段吸收)之元件的文獻相當有限。電致色變材料具有互補顏色有其潛力組成全波段吸收的電致色變元件。相較於其他文獻需繁複的合成方法及製程，本研究提供一種簡單的方式以建立一個可從全黑轉變至透明之電致色變元件。近年來，金屬超分子系統在許多電化學系統具有良好的表現，包含其在電致色變之應用。一些過渡金屬像是鐵和釕曾被提及做為此種金屬超分子材料之金屬離子的來源。本篇論文主要以無機金屬離子與有機配位基分子所合成之金屬超分子材料搭配有機高分子聚苯胺-聚苯乙烯磺酸混合物，進行研究與討論其於電致色變上之性質。本研究是以化學合成之含釕金屬超分子高分子(Ru(II)-MEPE)為主要的電致色變材料。在此研究中，含釕之超分子高分子的光學、電化學性質皆會有詳盡的研究，其呈現紅色且因為其電荷傳導是透過金屬到配位基之電荷轉移方式，因此具有良好且可逆的氧化還原反應和高穿透度變化(在510奈米波長下為ΔT=52%)；透過EQCM分析薄膜電量及質量變化，我們可以了解陰離子及溶劑在進行氧化還原時的莫耳通量；另一方面，聚苯胺聚合過程摻入聚苯乙烯磺酸可以改善其在水中的分散性，著色態呈綠色，可與前面提及之Ru(II)-MEPE組成互補式的電致色變元件。這兩種薄膜材料都可以簡單的噴塗塗佈法在ITO基材上製作成膜。本研究所組成的互補式電致色變元件其氧化還原反應之操作電位窗在-1.5 V及1.5 V之間 (Ru-MEPE vs. PANI:PSS)。電位在-1.5 V時，元件呈現黑色，當電位上升至1.5 V時，元件呈透明。兩極之電量搭配影響電致色變元件之穿透度變化，因此，在嘗試過多種組合後，最好的比例是元件之電量為0.75時具有最好的穿透度變化及長期穩定性，其最明顯的穿透度變化發生在波長510奈米處，為40.1%，相較於其他兩個波長550奈米及700奈米之穿透度變化分別為28.6%及32.2%。著去色時間定義為95%變色時，此元件之著色時間為4.0 s和去色時間1.3 s。至於電化學分析之量測，此元件可在操作200圈後於某定波長仍保持大部分的穿透度變化。 | zh_TW |
| dc.description.abstract | Only a few limited researches devoting to electrochromic devices (ECDs) having absorption in the entire visible range (or all-band absorption). Electrochromic materials with complementary colour have potential to be fabricated as ECDs having all-band absorption. Comparing with other complicated syntheses of black-to-transparent ECDs, this work provides a simple way to build up a black-to-transparent ECD. Metallo-supramolecular polymers (MEPEs) are metallic-organic complexes. In recent year, MEPEs have shown good performance in many electrochemical systems including eletrochrmism. Several transition metal ions, such as iron (Fe) and ruthenium (Ru), have been proposed as the source of material ions for MEPEs. In this work, optical, electrochemical properties of Ru-based MEPE are presented. Ru-based MEPE, having red colour, offers great redox reversibility and high transmittance change (ΔT=52% at 510 nm) because of the metal-to-ligand charge transfer (MLCT). From EQCM analysis, the molar flux of the anion and solvent could be calculated through the charge and mass change of the thin film. On the other hand, polyaniline doped with polystyrene sulfonate (PANI:PSS) is water-dispersible and suitable to arrange in pairs with Ru-MEPE. These two thin-film materials are easily prepared and coated on ITO substrate by spray coating. The redox reaction for the complementary ECD consisting of Ru-MEPE/PANI:PSS can be driven between -1.5 V and 1.5 V. The ECD becomes black at -1.5 V (Ru-MEPE vs. PANI:PSS) while it is colourless at 1.5 V. The influence of the charge capacity ratio of the two electrodes on the transmittance change of the ECDs has been tried, and the best condition is found at a charge capacity of 0.75. Its largest transmittance change is about 40.1% at 510 nm, as compared to 28.6% and 32.3%, at 550 nm and 700 nm, respectively. The switching times (defined as the time it takes for reaching 95% saturated transmittance change at 510 nm) are 4.0 s for darkening and 1.3 s for bleaching. From the electrochemical analysis, we prepared stable ECD with only a small transmittance decay after 200 cycles at the specific wavelength. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T05:32:00Z (GMT). No. of bitstreams: 1 ntu-103-R01549013-1.pdf: 10760473 bytes, checksum: 26eb860c2dfc4960ccbc008a77eb03fd (MD5) Previous issue date: 2014 | en |
| dc.description.tableofcontents | 目錄
致謝 I 中文摘要 II Abstract III 目錄 IV 表目錄 VII 圖目錄 VIII 符號說明 XIII 縮寫說明 XV 第一章 緒論 1 前言 1 電致色變技術簡介 3 1-2-1電致色變技術之發展 3 1-2-2 電致色變材料與元件類型 4 1-2-2-1 電致色變材料 4 1-2-2-2 電致色變元件之類型與結構 7 1-2-3 電致色變元件之性能要求 13 第二章 文獻回顧與研究動機 14 2-1 金屬超分子系統之介紹 14 2-1-1 配位基 17 2-1-2側鏈含有聯啶之共軛高分子 18 2-1-3配位高分子系統 22 2-2 金屬超分子高分子 (MEPEs) 26 2-3 導電高分子簡介 30 2-3-1 導電高分子之發展及應用 31 2-3-2 導電高分子之導電機制 34 2-3-2-1 能帶理論 35 2-3-2-2 導電高分子理論 38 2-4 導電高分子PANI及其複合膜 40 2-4-1 聚苯胺(PANI)簡介 40 2-4-2 PANI之光電行為 42 2-4-3 PANI複合材料應用於電致色變之發展 46 2-5 研究動機與架構 49 第三章 實驗部分 51 3-1 實驗儀器 51 3-2 實驗藥品 52 3-3 實驗方法 53 3-3-1導電玻璃前處理 53 3-3-2 藥品前處理 53 3-3-3 電致色變薄膜製備 54 3-3-3-1 Ru-MEPE 化學合成方法 54 3-3-3-2 水溶性PANI:PSS 化學合成方法 55 3-3-4 電致色變薄膜之製備 56 3-3-4-1 Ru-MEPE 薄膜製備 56 3-3-4-2 PANI:PSS 薄膜製備 57 3-3-5 電解質之製備 57 3-3-5-1 LiClO4+HClO4+ACN液態電解質 57 3-3-6 電致色變元件之組裝與封裝 58 3-4 分析方法 60 3-4-1 電化學特性分析 60 3-4-1-1 薄膜電化學特性分析-三極式 60 3-4-1-2 元件電化學特性分析-二極式 60 3-4-2 In-situ UV-VIS 光譜分析 60 第四章 含釕金屬超分子薄膜 64 4-1 Ru-MEPE 薄膜之化學合成 65 4-2 電化學性質量測 68 4-3 表面形態分析 70 4-4光學性質測試 71 4-5 著色效率 74 4-6 離子進出Ru-MEPE薄膜之行為 76 4-6-1 在白金石英震盪電極上製備Ru-MEPE薄膜 76 4-6-2 離子進出薄膜之原位(in situ)分析 76 4-6-3 EQCM 分析 79 4-6-3-1 陰陽離子進出Ru-MEPE薄膜之行為 79 4-6-3-2 Ru-MEPE的氧化還原方程式 85 4-7 Ru-MEPE氧化還原反應之機制討論 86 第五章 聚苯胺複合薄膜 88 5-1 PANI:PSS薄膜分析 88 5-1-1 PANI:PSS化學合成 88 5-1-2電化學性質 90 5-1-3光學性質測試 93 5-1-4表面形態分析 97 第六章 電致色變元件特性分析 100 6-1 Ru-MEPE 與 PANI:PSS之元件組成與封裝 100 6-1-1 元件設計方程式 100 6-1-2 元件封裝 107 6-1-3 操作電位窗之選擇 107 6-1-4光學性質量測 111 6-1-5 元件之長期穩定性 113 第七章 結論與建議 116 7-1 結論 116 7-2 建議 117 第八章 參考文獻 118 | |
| dc.language.iso | zh-TW | |
| dc.subject | 著色效率 | zh_TW |
| dc.subject | 以釕金屬超分子 | zh_TW |
| dc.subject | 聚苯胺/聚苯乙烯磺酸 | zh_TW |
| dc.subject | 互補式電致色變元件 | zh_TW |
| dc.subject | 可見光全波段吸收 | zh_TW |
| dc.subject | Ru-based MEPE | en |
| dc.subject | PANI:PSS | en |
| dc.subject | complementary electrochromic device | en |
| dc.subject | all-band absorption in the visible range | en |
| dc.subject | coloration efficiency | en |
| dc.title | 以釕金屬超分子與聚苯胺摻混聚苯乙烯磺酸組成可見光全波段吸收之電致色變元件 | zh_TW |
| dc.title | An Electrochromic Device Having Absorption in the Entire Visible Range with Ruthenium-based Metallo-supramolecular Polymers and Polyaniline-Poly(4-styrenesulfonate) Composite Films | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 102-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 周澤川(Tse-Chuan Chou),楊明長(Ming-Chang Yang),吳春桂,陳林祈(Lin-Chi Chen) | |
| dc.subject.keyword | 可見光全波段吸收,著色效率,互補式電致色變元件,聚苯胺/聚苯乙烯磺酸,以釕金屬超分子, | zh_TW |
| dc.subject.keyword | all-band absorption in the visible range,coloration efficiency,complementary electrochromic device,PANI:PSS,Ru-based MEPE, | en |
| dc.relation.page | 125 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2014-08-13 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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