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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 廖文彬(Wen-Bin Liau) | |
dc.contributor.author | Heng-Jui Chang | en |
dc.contributor.author | 張恒睿 | zh_TW |
dc.date.accessioned | 2021-06-16T05:14:12Z | - |
dc.date.available | 2019-09-05 | |
dc.date.copyright | 2014-09-05 | |
dc.date.issued | 2014 | |
dc.date.submitted | 2014-08-18 | |
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[54]李哲瑋 (2013). 聚(3-己基噻吩)-銀金屬複合材料之製備與形成機制探討. Department of Materials Science and Engineering College of Engineering, National Taiwan University. Master. [55]張廣平, 畢先同. (1994). 聚苯胺在依些有機溶劑中溶解性. 高分子學報. 北京, 中國科學院化學研究所. 1. [56]裘性天 , 黃亭凱. (2007). '特殊形貌銅與銀奈米材料製備之簡介.' Chem. Chin. Chem. Soc. 6: 9-16. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/56056 | - |
dc.description.abstract | 聚苯胺具有氧化還原性質,我們將聚苯胺置於溶液中還原銀離子使其變成銀金屬。本論文的重點就是釐清導電度對於銀金屬成長的影響,了解銀金屬成長的過程。因為只有去摻雜聚苯胺可以溶於溶劑之中,藉此分離出些微摻雜與完全去摻雜的兩種聚苯胺,這兩種聚苯胺的導電度也不同。我們也藉由膨潤效應來做出不同導電度的聚苯胺。
同時也釐清共溶劑在還原銀離子過程中所扮演的角色,這包括了膨潤效應、幫助銀離子更容易到達聚苯胺表面、造成結晶嗜好面,而這三個作用的交互影響會改變最終銀金屬所形成的型態,我們也以不同共溶劑成分比例來分析共溶劑影響的程度。 針對不同聚導電度苯胺在共溶劑下還原銀離子的實驗隨時間進行觀察,發現銀金屬隨導電度上升型態變化為顆粒狀、片狀、小規模堆疊、大規模堆疊。藉此了解銀金屬成長過程並建立成長機制,用以解釋及預測其他聚苯胺還原銀離子系統的結果。 | zh_TW |
dc.description.abstract | Polyaniline have redox properties. We put polyaniline into solution with silver ions. It can turn silver ions into silver. The focus of this thesis want to clarify the relationship between the conductivity of polyaniline and the morphology of silver. We want to know the growth mechanism of silver. Only dedopped polyaniline can dissolve in solvent. So, we can synthsize light-dopped polyanilin and dedopped polyaniline. We also use swelling effect to control the conductivity od polyaniline.
We want to know the effect of co-solvent during the process of reduction of silver ions. That includes swelling effect, the content of silver ions at polyaniline surface and preferred orientation effect. Those factors can affect the final morphology of silver. We control the ratio of co-solvent to analyze the degree of co-solvent effects. Base on different conductivities of polyaniline. The morphology of silvers are from particles to sheets to short-range packing to long-range packing with conductivity increased. We try to know and build up a mechanism of silver growth. Finally, we use the mechanism to explain and predict other systems. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T05:14:12Z (GMT). No. of bitstreams: 1 ntu-103-R01527056-1.pdf: 5557181 bytes, checksum: 806d62ea52b70c4d3954b7ccc55689bb (MD5) Previous issue date: 2014 | en |
dc.description.tableofcontents | 口試委員審定書............................................i
誌謝...................................................ii 中文摘要...............................................iii 英文摘要................................................iv 目錄....................................................v 圖目錄................................................viii 表目錄..................................................xi 第一章 緒論 1 第二章 文獻回顧 2 2-1 導電高分子 2 2-1-1 導電高分子的發現 2 2-1-2 摻雜與導電機制 2 2-1-3 導電高分子之應用 4 2-2 導電高分子聚苯胺 5 2-2-1 聚苯胺發現 5 2-2-2 聚苯胺性質及結構 5 2-2-3 聚苯胺聚合機制 7 2-3 聚苯胺和銀金屬複合材料 14 2-3-1 概說 14 2-3-2 銀金屬型態控制 14 2-3-3 聚苯胺還原銀離子 15 第三章 實驗 20 3-1實驗藥品 20 3-2 實驗儀器 23 3-3 實驗方法 26 3-3-1 聚苯胺合成與去摻雜 26 3-3-2 未摻雜聚苯胺薄膜製作 28 3-3-3 未摻雜聚苯胺薄膜與硝酸銀的還原反應 28 3-3-4 未摻雜聚苯胺薄膜浸泡溶劑後再與硝酸銀的還原反應 29 3-3-5 聚苯胺顆粒與硝酸銀還原反應 30 3-3-6 聚苯胺顆粒浸泡溶劑後再與硝酸銀的還原反應 30 3-3-7 聚苯胺薄膜浸泡共溶劑膨潤後秤重實驗 32 3-3-8 以氫氧化鈉水溶液去摻雜聚苯胺顆粒後還原銀離子實驗 32 第四章 結果與討論 35 4-1 性質鑑定 35 4-2 聚苯胺還原銀離子形成顆粒狀銀金屬 42 4-2-1 聚苯胺薄膜在水中還原銀離子 42 4-2-2 聚苯胺薄膜在共溶劑中膨潤後還原銀離子 46 4-2-3 聚苯胺薄膜共溶劑膨潤後在水中還原銀離子 48 4-3 聚苯胺還原銀離子形成顆粒狀與片狀銀金屬 51 4-3-1 聚苯胺薄膜在共溶劑中還原銀離子 51 4-3-2 隨時間觀察聚苯胺薄膜在共溶劑中還原銀離子 55 4-3-3 察聚苯胺薄膜在不同比例共溶劑中還原銀離子 61 4-4 聚苯胺還原銀形成銀金屬堆疊 67 4-4-1 聚苯胺顆粒在水中還原銀離子 67 4-4-2聚苯胺顆粒在共溶劑中膨潤後還原銀離子 69 4-4-3 聚苯胺顆粒在共溶劑中還原銀離子 72 4-4-4 隨時間觀察聚苯胺顆粒在共溶劑中還原銀離子 78 4-5 聚苯胺還原銀離子之成長機制 83 第五章 結論 88 參考文獻 89 | |
dc.language.iso | zh-TW | |
dc.title | 聚苯胺的導電度對銀金屬還原之影響及其成長機制 | zh_TW |
dc.title | The Influence of Conductivity of Polyaniline to the Growth Mechanism of Silver | en |
dc.type | Thesis | |
dc.date.schoolyear | 102-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 曾勝茂(Sheng-Mou Tseng),童世煌(Shih-Huang Tung),羅世強(Luo-Shyh Chyang) | |
dc.subject.keyword | 聚苯胺,銀,複合材料,還原,導電高分子, | zh_TW |
dc.subject.keyword | Polyaniline,Silver,Composite material,Reduction,Conducting polymer, | en |
dc.relation.page | 97 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2014-08-18 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
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