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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 賈儀平(Yeeping Chia) | |
| dc.contributor.author | I-Hsin Yao | en |
| dc.contributor.author | 饒以馨 | zh_TW |
| dc.date.accessioned | 2021-06-16T03:40:32Z | - |
| dc.date.available | 2015-03-16 | |
| dc.date.copyright | 2015-03-16 | |
| dc.date.issued | 2015 | |
| dc.date.submitted | 2015-02-13 | |
| dc.identifier.citation | 丁力行 (2000) 土壤及地下水污染整治法實務與因應對策。永然文化，共224頁。
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/54879 | - |
| dc.description.abstract | RCA(Radio Corporation of America)桃園廠於1987年發現廠區土壤和地下水受含氯有機化合物污染，污染源可能來自於廢液滲漏或傾倒。主要污染物為四氯乙烯、三氯乙烯、1,1,1-三氯乙烷等含氯有機化合物及其降解產物，為重質非水相液體(Dense Non-Aqueous Phase Liquid, or DNAPL)。在地下水中溶解度極低，難以使用抽除或處理的方式完全清除。此場址已發現污染約二十餘年，本研究將整理此場址之歷史資料，並且評估整治措施之成效及後續待加強之工作。
桃園廠區歷經多次現地調查與採樣分析，淺處為約20公尺厚的礫石含水層，深處則為砂泥互層組成的含水層。當地的水力梯度指出，溶解於地下水中的污染物在水平方向是往北傳輸，而垂直方向則是往深處流動。污染物多分布於廠區西北與北側，1998年曾挖除污染的土壤加以曝氣及現地抽氣方式清除土污染，並採用抽水與處理方式進行先導性地下水污染整治，但未實質改善。後續試驗現地化學氧化整治法亦未成功，2005年起在廠區使用加強式還原脫氯法進行現地生物整治，將糖蜜和生物營養製劑注入地下水，加速含氯有機化合物脫氯降解作用。七年後地下水中四氯乙烯及三氯乙烯污染濃度多已大幅降低至管制標準以下，然而經生物降解後產生的氯乙烯難以繼續降解，部分監測井的氯乙烯污染濃度仍超過管制標準，而且毒性更強。此外多年來污染物已擴展至廠外鄰近地區，未來亟需思考如何清除地下水中的氯乙烯，並整治廠外的地下水污染。 | zh_TW |
| dc.description.abstract | Soil and groundwater at the Radio Corporation of America (RCA) Taoyuan Plant in Taiwan were found contaminated by chlorinated volatile organic compounds (VOCs) in 1987. The pollution may be attributed to improper dumping or leakage of chlorinated solvents. The major pollutants are tetrachloroethylene (PCE), trichloroethylene (TCE), 1, 1, 1- trichloroethane (1, 1, 1-TCA) and their degradation byproducts. These VOCs are dense non-aqueous phase liquids (DNAPLs) which can hardly be dissolved in groundwater. The residual DNAPLs along the migration pathway usually dissolve very slowly in groundwater, and thus become long-term contamination sources.
Site characterization indicated that the uppermost aquifer is a thick gravel layer. The deep aquifer is composed of sand interbedded with mud layers. Groundwater flows northward horizontally and downward vertically. Contamination was found primarily in the northwest and north sides of the plant. The pump and treat method had been implemented, but failed to remediate groundwater contamination. Enhanced reductive dechlorination method has been adopted to clean up contaminants since 2005. By injecting reducing agents, the aquifer condition became favorable to anaerobic biodegradation. The concentration of PCE and TCE in the groundwater reduced significantly at most wells seven years later. However, the concentration of vinyl chloride (VC), a highly toxic chemical produced through biodegradation processes, exceeded the regulatory standard at many wells. Besides, the contaminants have migrated off-site for years. Therefore, an effective solution for the cleanup of VC contamination and off-site contamination should be considered in the future. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T03:40:32Z (GMT). No. of bitstreams: 1 ntu-104-R01224207-1.pdf: 3291847 bytes, checksum: 23f677b68ac481396cf94f352e1172a0 (MD5) Previous issue date: 2015 | en |
| dc.description.tableofcontents | 口試委員會審定書…………………………………………………………………….i
致謝……………………………………………………………………………………ii 摘要…………………………………………………………………………………...iii Abstract……………………………………………………………………………….iv 目錄…………………………………………………………………………………....v 圖目…………………………………………………………………………………..vii 表目…………………………………………………………………………………...ix 第一章 緒論…………………………………………………………………………..1 1.1 研究動機與目的…………………………………………………………….1 1.2 研究方法…………………………………………………………………….2 第二章 RCA桃園廠地下水污染…………………………………………………….4 2.1 污染事件發生背景………………………………………………………….4 2.2 污染物特性………………………………………………………………….5 第三章 水文地質條件………………………………………………………………..9 3.1 地理位置…………………………………………………………………….9 3.2 地層性質與地質調查……………………………………………………...10 3.3 水文………………………………………………………………………...12 第四章 加強還原脫氯整治前污染物分布狀況……………………………………15 4.1 污染初期…………………………………………………………………...15 4.2 先導試驗：抽水與處理整治法…………………………………………...16 4.3 先導試驗：現地化學氧化法……………………………………………...21 4.4 先導試驗：加強還原脫氯法……………………………………………...23 第五章 加強還原脫氯法整治技術…………………………………………………25 5.1 生物降解整治原理………………………………………………………...25 5.2 生物降解整治文獻回顧…………………………………………………...25 5.3 RCA桃園廠加強還原脫氯法……………………………………………...28 5.4 國外案例研究—萊康明公司超級基金整治場址………………………...29 第六章 加強還原脫氯整治後污染物分布狀況……………………………………32 6.1 污染物濃度分布…………………………………………………………...32 6.2 氯乙烯污染演變…………………………………………………………...44 第七章 RCA桃園廠外地下水污染分布…………………………………………...46 第八章 討論：氯乙烯後續整治……………………………………………………52 第九章 結論與建議…………………………………………………………………56 參考文獻……………………………………………………………………………..58 附錄A RCA桃園廠監測井資料暨污染物濃度表……………………………….68 | |
| dc.language.iso | zh-TW | |
| dc.title | RCA桃園廠地下水污染物分布與演變 | zh_TW |
| dc.title | Distribution and Evolution of Groundwater Contamination at the RCA Taoyuan Plant | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 103-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳文福(Wen-Fu Chen),吳先琪(Shian-Chee Wu),劉雅瑄(Ya-Hsuan Liou) | |
| dc.subject.keyword | RCA桃園廠,地下水,污染整治,四氯乙烯,三氯乙烯,氯乙烯, | zh_TW |
| dc.subject.keyword | RCA Taoyuan Plant,groundwater,contamination remediation,tetrachloroethylene,trichloroethylene,vinyl chloride, | en |
| dc.relation.page | 80 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2015-02-13 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 地質科學研究所 | zh_TW |
| 顯示於系所單位： | 地質科學系 | |
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|---|---|---|---|
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