請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/54561
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 賴育英(Yu-Ying Lai) | |
dc.contributor.author | Quan-Hou Huang | en |
dc.contributor.author | 黃銓厚 | zh_TW |
dc.date.accessioned | 2021-06-16T03:04:27Z | - |
dc.date.available | 2020-08-07 | |
dc.date.copyright | 2020-08-07 | |
dc.date.issued | 2020 | |
dc.date.submitted | 2020-08-04 | |
dc.identifier.citation | 1. Kudo, A.; Miseki, Y., Heterogeneous photocatalyst materials for water splitting. Chem Soc Rev 2009, 38 (1), 253-78. 2. Grätzel, M., Photoelectrochemical cells. Nature 2001, 414 (6861), 338-344. 3. Kudo, A., Photocatalyst Materials for Water Splitting. Catalysis Surveys from Asia 2003, 7 (1), 31-38. 4. Rahman, M. Z.; Mullins, C. B., Understanding Charge Transport in Carbon Nitride for Enhanced Photocatalytic Solar Fuel Production. Accounts of Chemical Research 2019, 52 (1), 248-257. 5. Kubacka, A.; Fernández-García, M.; Colón, G., Advanced Nanoarchitectures for Solar Photocatalytic Applications. Chemical Reviews 2012, 112 (3), 1555-1614. 6. Wang, X.; Maeda, K.; Thomas, A.; Takanabe, K.; Xin, G.; Carlsson, J. M.; Domen, K.; Antonietti, M., A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nature Materials 2009, 8 (1), 76-80. 7. Ong, W.-J.; Tan, L.-L.; Ng, Y. H.; Yong, S.-T.; Chai, S.-P., Graphitic Carbon Nitride (g-C3N4)-Based Photocatalysts for Artificial Photosynthesis and Environmental Remediation: Are We a Step Closer To Achieving Sustainability? Chemical Reviews 2016, 116 (12), 7159-7329. 8. Wen, J.; Xie, J.; Chen, X.; Li, X., A review on g-C3N4-based photocatalysts. Applied Surface Science 2017, 391, 72-123. 9. Rahman, M. Z.; Ran, J.; Tang, Y.; Jaroniec, M.; Qiao, S. Z., Surface activated carbon nitride nanosheets with optimized electro-optical properties for highly efficient photocatalytic hydrogen production. Journal of Materials Chemistry A 2016, 4 (7), 2445-2452. 10. Rahman, M.; Davey, K.; Qiao, S.-Z., Counteracting Blueshift Optical Absorption and Maximizing Photon Harvest in Carbon Nitride Nanosheet Photocatalyst. Small 2017, 13 (23), 1700376. 11. Naseri, A.; Samadi, M.; Pourjavadi, A.; Moshfegh, A. Z.; Ramakrishna, S., Graphitic carbon nitride (g-C3N4)-based photocatalysts for solar hydrogen generation: recent advances and future development directions. Journal of Materials Chemistry A 2017, 5 (45), 23406-23433. 12. Wang, Y.; Di, Y.; Antonietti, M.; Li, H.; Chen, X.; Wang, X., Excellent Visible-Light Photocatalysis of Fluorinated Polymeric Carbon Nitride Solids. Chemistry of Materials 2010, 22 (18), 5119-5121. 13. Chen, J.; Dong, C.-L.; Zhao, D.; Huang, Y.-C.; Wang, X.; Samad, L.; Dang, L.; Shearer, M.; Shen, S.; Guo, L., Molecular Design of Polymer Heterojunctions for Efficient Solar–Hydrogen Conversion. Advanced Materials 2017, 29 (21), 1606198. 14. Luo, M.; Yang, Q.; Liu, K.; Cao, H.; Yan, H., Boosting photocatalytic H2 evolution on g-C3N4 by modifying covalent organic frameworks (COFs). Chemical Communications 2019, 55 (41), 5829-5832. 15. Stegbauer, L.; Schwinghammer, K.; Lotsch, B. V., A hydrazone-based covalent organic framework for photocatalytic hydrogen production. Chemical Science 2014, 5 (7), 2789-2793. 16. Vyas, V. S.; Haase, F.; Stegbauer, L.; Savasci, G.; Podjaski, F.; Ochsenfeld, C.; Lotsch, B. V., A tunable azine covalent organic framework platform for visible light-induced hydrogen generation. Nature Communications 2015, 6 (1), 8508. 17. Haase, F.; Banerjee, T.; Savasci, G.; Ochsenfeld, C.; Lotsch, B. V., Structure–property–activity relationships in a pyridine containing azine-linked covalent organic framework for photocatalytic hydrogen evolution. Faraday Discussions 2017, 201 (0), 247-264. 18. Biswal, B. P.; Vignolo-González, H. A.; Banerjee, T.; Grunenberg, L.; Savasci, G.; Gottschling, K.; Nuss, J.; Ochsenfeld, C.; Lotsch, B. V., Sustained Solar H2 Evolution from a Thiazolo[5,4-d]thiazole-Bridged Covalent Organic Framework and Nickel-Thiolate Cluster in Water. Journal of the American Chemical Society 2019, 141 (28), 11082-11092. 19. Pachfule, P.; Acharjya, A.; Roeser, J.; Langenhahn, T.; Schwarze, M.; Schomäcker, R.; Thomas, A.; Schmidt, J., Diacetylene Functionalized Covalent Organic Framework (COF) for Photocatalytic Hydrogen Generation. Journal of the American Chemical Society 2018, 140 (4), 1423-1427. 20. Banerjee, T.; Haase, F.; Savasci, G.; Gottschling, K.; Ochsenfeld, C.; Lotsch, B. V., Single-Site Photocatalytic H2 Evolution from Covalent Organic Frameworks with Molecular Cobaloxime Co-Catalysts. Journal of the American Chemical Society 2017, 139 (45), 16228-16234. 21. Jin, E.; Lan, Z.; Jiang, Q.; Geng, K.; Li, G.; Wang, X.; Jiang, D., 2D sp2 Carbon-Conjugated Covalent Organic Frameworks for Photocatalytic Hydrogen Production from Water. Chem 2019, 5 (6), 1632-1647. 22. Dai, C.; Liu, B., Conjugated polymers for visible-light-driven photocatalysis. Energy Environmental Science 2019, 13. 23. Yanagida, S.; Kabumoto, A.; Mizumoto, K.; Pac, C.; Yoshino, K., Poly(p-phenylene)-catalysed photoreduction of water to hydrogen. Journal of the Chemical Society, Chemical Communications 1985, (8), 474-475. 24. Sprick, R. S.; Bonillo, B.; Clowes, R.; Guiglion, P.; Brownbill, N. J.; Slater, B. J.; Blanc, F.; Zwijnenburg, M. A.; Adams, D. J.; Cooper, A. I., Visible-Light-Driven Hydrogen Evolution Using Planarized Conjugated Polymer Photocatalysts. Angewandte Chemie International Edition 2016, 55 (5), 1792-1796. 25. Dai, C.; Xu, S.; Liu, W.; Gong, X.; Panahandeh-Fard, M.; Liu, Z.; Zhang, D.; Xue, C.; Loh, K. P.; Liu, B., Dibenzothiophene-S,S-Dioxide-Based Conjugated Polymers: Highly Efficient Photocatalyts for Hydrogen Production from Water under Visible Light. Small 2018, 14 (34), 1801839. 26. Sachs, M.; Sprick, R. S.; Pearce, D.; Hillman, S. A. J.; Monti, A.; Guilbert, A. A. Y.; Brownbill, N. J.; Dimitrov, S.; Shi, X.; Blanc, F.; Zwijnenburg, M. A.; Nelson, J.; Durrant, J. R.; Cooper, A. I., Understanding structure-activity relationships in linear polymer photocatalysts for hydrogen evolution. Nature Communications 2018, 9 (1), 4968. 27. Aitchison, Catherine M.; Sprick, R. S.; Cooper, A. I., Emulsion polymerization derived organic photocatalysts for improved light-driven hydrogen evolution. Journal of Materials Chemistry A 2019, 7 (6), 2490-2496. 28. Pecher, J.; Mecking, S., Nanoparticles of Conjugated Polymers. Chemical Reviews 2010, 110 (10), 6260-6279. 29. Li, K.; Liu, B., Polymer encapsulated conjugated polymer nanoparticles for fluorescence bioimaging. Journal of Materials Chemistry 2012, 22 (4), 1257-1264. 30. Kundu, S.; Patra, A., Nanoscale Strategies for Light Harvesting. Chemical Reviews 2017, 117 (2), 712-757. 31. Wang, L.; Fernández-Terán, R.; Zhang, L.; Fernandes, D. L. A.; Tian, L.; Chen, H.; Tian, H., Organic Polymer Dots as Photocatalysts for Visible Light-Driven Hydrogen Generation. Angewandte Chemie International Edition 2016, 55 (40), 12306-12310. 32. Tseng, P.-J.; Chang, C.-L.; Chan, Y.-H.; Ting, L.-Y.; Chen, P.-Y.; Liao, C.-H.; Tsai, M.-L.; Chou, H.-H., Design and Synthesis of Cycloplatinated Polymer Dots as Photocatalysts for Visible-Light-Driven Hydrogen Evolution. ACS Catalysis 2018, 8 (9), 7766-7772. 33. Hoven, C. V.; Garcia, A.; Bazan, G. C.; Nguyen, T.-Q., Recent Applications of Conjugated Polyelectrolytes in Optoelectronic Devices. Advanced Materials 2008, 20 (20), 3793-3810. 34. Jiang, H.; Taranekar, P.; Reynolds, J. R.; Schanze, K. S., Conjugated Polyelectrolytes: Synthesis, Photophysics, and Applications. Angewandte Chemie International Edition 2009, 48 (24), 4300-4316. 35. Duarte, A.; Pu, K.-Y.; Liu, B.; Bazan, G. C., Recent Advances in Conjugated Polyelectrolytes for Emerging Optoelectronic Applications. Chemistry of Materials 2011, 23 (3), 501-515. 36. Cui, Q.; Bazan, G. C., Narrow Band Gap Conjugated Polyelectrolytes. Accounts of Chemical Research 2018, 51 (1), 202-211. 37. Dai, C.; Panahandeh-Fard, M.; Gong, X.; Xue, C.; Liu, B., Water-Dispersed Conjugated Polyelectrolyte for Visible-Light Hydrogen Production. Solar RRL 2019, 3 (3), 1800255. 38. Hu, Z.; Wang, Z.; Zhang, X.; Tang, H.; Liu, X.; Huang, F.; Cao, Y., Conjugated Polymers with Oligoethylene Glycol Side Chains for Improved Photocatalytic Hydrogen Evolution. iScience 2019, 13, 33-42. 39. Sprick, R. S.; Wilbraham, L.; Bai, Y.; Guiglion, P.; Monti, A.; Clowes, R.; Cooper, A. I.; Zwijnenburg, M. A., Nitrogen Containing Linear Poly(phenylene) Derivatives for Photo-catalytic Hydrogen Evolution from Water. Chemistry of Materials 2018, 30 (16), 5733-5742. 40. 黃郁翔. 視紫紅質用於ITO表面修飾及與共軛高分子間的能量轉移研究. 國立臺灣大學, 2019. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/54561 | - |
dc.description.abstract | 於此篇論文中,我們將產氫反應後之溶液以電噴灑離子式質譜進行分析並結合密度泛函理論計算探討三乙胺做為犧牲試劑時,於整個產氫系統中所扮演的角色並同時發現其可能具有抑制雙氧水的功用,並且我們也於共軛高分子聚對亞苯 (PPP)的側鏈上引入親疏水基團分別為PHOB以及PPESO3探討親水性質對於產氫的影響,並發現引入親油基團的PHOB會失去產氫的活性,且親水性很好但主鏈上接有三鍵的PPESO3也會失去產氫活性,除了親水性質以外,我們也合成了4個不同分子量的高分子PFBT,並發現聚合度最高也就是分子量最大的PFBT同時也具有最高的產氫效率,並針對這個發現透過一系列的儀器分析來探討其原因。 | zh_TW |
dc.description.abstract | In this thesis, a solution containing water, triethylamine, methanol, and poly(p-phenylene subsequent to photo-induced hydrogen evolution reaction was examined by electrospray ionization mass spectrometry. Products resulted from triethylamine were detected. Density functional theory calculations were then employed to account for the role of triethylamine in the reaction. The results suggest that triethylamine could not only reduce the activation energy for photo-induced hydrogen evolution reactions but also quench hydrogen peroxide, a side product from the reactions. Hydrophilic and hydrophobic groups are used as the side chains to give conjugated polymers PPESO3 and PHOB, respectively. Impact of hydrophilic properties on hydrogen evolution reactions was discussed. We found that PHOB equipped with hydrophobic group lost the hydrogen evolution activity and PPESO3 with good hydrophilicity was also inactive. The poor catalytic performance of PHOB and PPESO3 might be associated with the strong charge recombination. Moreover, PFBT was synthesized with 4 different molecular weights. It was found that the polymer with the highest molecular weight exhibited the best hydrogen evolution rate. Numerous techniques were utilized to account for the observed efficiency. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T03:04:27Z (GMT). No. of bitstreams: 1 U0001-0308202011031300.pdf: 4525980 bytes, checksum: 3b5f6761d864772505411c746f7c24cd (MD5) Previous issue date: 2020 | en |
dc.description.tableofcontents | 口試委員會審定書 I 致謝 II 摘要 III Abstract IV 目錄 V 圖目錄 VII 表目錄 XI 第1章 緒論 1 1-1光催化產氫 1 1-1-1光催化產氫之背景 1 1-1-2光催化氫氣之條件 3 1-1-3 光觸媒於光催化產氫的基本原理 3 1-1-4 光催化產氣之系統 5 1-2 有機高分子材料於產氫之應用 6 1-2-1 氮化碳(CxNy) 6 1-2-2 共價有機框架(Covalent Organic Framework,COF) 8 1-2-3 線性共軛高分子 11 1-3 研究動機 18 第2章 結果與討論 19 2-1 以密度泛函理論結合電噴灑離子式質譜儀探討犧牲試劑之反應機制 19 2-2 氫氣之定量 25 2-3 PPP衍生物與PFBT之合成 25 2-4 PPP衍生物之吸收光譜、能階與產氫效率比較 29 2-5 PFBT的吸收光譜、能階以及產氫效率的比較 33 第3章 結論 39 第4章 實驗 40 4-1 試藥 40 4-2 實驗儀器 40 4-2-1 氣相層析儀(Gas Chromatography,GC) 40 4-2-2 紫外光與可見光光譜儀(UV-Vis Spectroscopy,UV) 40 4-2-3 電子順磁共振光譜儀(Electron Paramagnetic Resonance,EPR) 40 4-2-4 電噴霧離子式質譜儀(Electrospray Ionization Mass Spectroscopy ,ESI-MS) 41 4-2-5 核磁共振光譜儀(Nuclear Magnetic Resonance,NMR) 41 4-2-6 凝膠滲透層析(Gel Permeation Chromatograph,GPC) 41 4-2-7 電化學阻抗頻譜(Electrochemical Impedance Spectroscopy,EIS) 41 4-2-8 粒徑/介面電位分析儀(Particle Sizing and Zeta Potential) 42 4-2-9 Atmospheric Photoelectron Spectroscopy(PES) 42 4-3 光催化產氫實驗 42 4-4 合成 43 第5章 參考文獻 49 第6章 附錄 54 | |
dc.language.iso | zh-TW | |
dc.title | 共軛高分子的分子量及親水性質對光催化產氫反應之影響 | zh_TW |
dc.title | Effect of molecular weight and hydrophilicity of conjugated polymers on photo-induced hydrogen evolution reaction | en |
dc.type | Thesis | |
dc.date.schoolyear | 108-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 吳紀聖(Chi-Sheng Wu),鍾博文(Po-Wen Chung) | |
dc.subject.keyword | 共軛高分子,電噴灑離子式質譜,密度泛函理論,三乙胺,產氫,分子量,親水性, | zh_TW |
dc.subject.keyword | conjugated polymers,electrospray ionization mass spectrometry,density function theory,triethylamine,hydrogen evolution,hydrophilicity,molecular weight, | en |
dc.relation.page | 81 | |
dc.identifier.doi | 10.6342/NTU202002252 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2020-08-05 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
U0001-0308202011031300.pdf 目前未授權公開取用 | 4.42 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。