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| ???org.dspace.app.webui.jsptag.ItemTag.dcfield??? | Value | Language |
|---|---|---|
| dc.contributor.advisor | 梁文傑(Man-Kit Leung) | |
| dc.contributor.author | Pei-Ling Ding | en |
| dc.contributor.author | 丁沛翎 | zh_TW |
| dc.date.accessioned | 2021-06-16T02:36:47Z | - |
| dc.date.available | 2020-08-01 | |
| dc.date.copyright | 2015-07-29 | |
| dc.date.issued | 2015 | |
| dc.date.submitted | 2015-07-26 | |
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The Journal of Organic Chemistry 2009, 74 (8), 3152-3155. 44. Portmann, C.; Prestinari, C.; Myers, T.; Scharte, J.; Gademann, K., Directed Biosynthesis of Phytotoxic Alkaloids in the Cyanobacterium Nostoc 78–12A. ChemBioChem 2009, 10 (5), 889-895. 45. Sako, K.; Aoyama, H.; Sato, S.; Hashimoto, Y.; Baba, M., γ-Carboline derivatives with anti-bovine viral diarrhea virus (BVDV) activity. Bioorganic Medicinal Chemistry 2008, 16 (7), 3780-3790. 46. Janiak, C., A critical account on [small pi]-[small pi] stacking in metal complexes with aromatic nitrogen-containing ligands. Journal of the Chemical Society, Dalton Transactions 2000, (21), 3885-3896. 47. Y. J. Cho; K. S. Yook; J. Y. Lee, A Universal Host Material for High External Quantum Effi ciency Close to 25% and Long Lifetime in Green Fluorescent and Phosphorescent OLEDsAdvanced Materials 2014, 26, 4050-4055. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/54019 | - |
| dc.description.abstract | In this thesis, we focus on the effect on device performance by varying positions of nitrogen in carboline compounds—the host materials for blue phosphorescent organic light emitting diodes. The triplet energy level of carboline compounds is higher than carbazole in common use, meaning that different positions of nitrogen can lead to different resonance structures. Ergo, the steric effect would change crystal packing, which, consequently, leads to different electronic behaviours. Focusing on the electrochemical and photochemical properties of the compounds, we characterise the compounds into high triplet energy host materials in PhOLED. The device with the host of compound 9 and the guest of FIrpic exhibited the turn on voltage at 20.6 mA/cm2 of 10.10 V, luminance of 4644 cd/m2, max. current efficiency of 49.31 cd/A at 4.5 V, power efficiency of 37.55 lm/W at 4 V and the external quantum efficiency of 22.03 %. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T02:36:47Z (GMT). No. of bitstreams: 1 ntu-104-R02223181-1.pdf: 6051419 bytes, checksum: 16ef483da6ad866c88898576231be9b2 (MD5) Previous issue date: 2015 | en |
| dc.description.tableofcontents | 目錄 I 中文摘要 III Abstract IV 圖目錄 V 表目錄 VII 流程目錄 VIII 化合物1H共振光譜及13C核磁共振光譜 IX 第一章 緒論 1 1.1前言 1 1.2有機發光二極體 (OLED) 研究發展歷史 2 1.3有機發光二極體 (OLED) 工作原理 3 1.3.1發光機制 3 1.3.2 有機發光二極體 (OLED) 元件結構 4 1.3.3 有機發光二極體 (OLED) 元件工作機制 6 1.4 主客發光體系統 7 1.5 有機發光二極體 (OLED) 各層材料 9 1.5.1 陽極材料 9 1.5.2 陰極材料 9 1.5.3 電洞注入材料 9 1.5.4 電洞傳輸材料 10 1.5.5 電子注入材料 11 1.5.6 電子傳輸材料 12 1.5.7 發光材料 14 第二章 結果與討論 15 2.1研究動機與分子設計 15 2.2 合成策略及方法 18 2.3 X-ray晶體結構分析 24 2.4 熱性質分析 29 2.5 光物理性質分析 31 2.6 能量轉移實驗 36 2.7電化學性質分析 38 2.8 有機電激發光材料之元件性質探討 44 第三章 結論 52 第四章 實驗內容 53 4.1 實驗儀器與試劑 53 4.1.1 儀器部分 53 4.1.2試劑與溶劑 54 第五章 參考文獻 66 附錄一 化合物TGA及DSC圖 72 附錄二 化合物X-ray晶體參數表、鍵長與鍵角數據 74 附錄三 化合物氫核磁共振光譜及碳核磁共振光譜 89 | |
| dc.language.iso | zh-TW | |
| dc.subject | 雙偶極 | zh_TW |
| dc.subject | 有機發光二極體 | zh_TW |
| dc.subject | 主發光體材料 | zh_TW |
| dc.subject | ?淋 | zh_TW |
| dc.subject | 噁二唑 | zh_TW |
| dc.subject | 有機發光二極體 | zh_TW |
| dc.subject | 主發光體材料 | zh_TW |
| dc.subject | 雙偶極 | zh_TW |
| dc.subject | ?淋 | zh_TW |
| dc.subject | 噁二唑 | zh_TW |
| dc.subject | oxadiazole | en |
| dc.subject | host | en |
| dc.subject | oxadiazole | en |
| dc.subject | carboline | en |
| dc.subject | bipolar | en |
| dc.subject | host | en |
| dc.subject | OLED | en |
| dc.subject | bipolar | en |
| dc.subject | carboline | en |
| dc.subject | OLED | en |
| dc.title | 三種噁二唑咔U+5549化合物之合成、性質探討及其在藍色磷光有機發光二極體之應用 | zh_TW |
| dc.title | Synthesis and Characterization of Three Carboline Compounds and Their Application in Blue Phosphorescent Organic Light Emitting Diodes | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 103-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 徐秀福(Hsiu-Fu Hsu),邱天隆(Tien-Lung Chiu) | |
| dc.subject.keyword | 有機發光二極體,主發光體材料,雙偶極,?淋,噁二唑, | zh_TW |
| dc.subject.keyword | OLED,host,oxadiazole,carboline,bipolar, | en |
| dc.relation.page | 110 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2015-07-27 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| Appears in Collections: | 化學系 | |
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| File | Size | Format | |
|---|---|---|---|
| ntu-104-1.pdf Restricted Access | 5.91 MB | Adobe PDF |
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