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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 楊吉水(Jye-Shane Yang) | |
dc.contributor.author | Sheng-Fang Tseng | en |
dc.contributor.author | 曾聖方 | zh_TW |
dc.date.accessioned | 2021-06-16T02:32:48Z | - |
dc.date.available | 2020-08-03 | |
dc.date.copyright | 2015-08-03 | |
dc.date.issued | 2015 | |
dc.date.submitted | 2015-07-29 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/53898 | - |
dc.description.abstract | 超級電容相較於電池具備較好的功率密度和穩定性,並且比起電容具有更高的能量密度,因此成為新一代的能源儲存元件。以聚苯胺作為電極材料,因為具有環境汙染較少、導電機制易於控制、具良好加工性及價格低在之優點,但其循環穩定度不夠高,乃因為薄膜體積膨脹的問題所造成。在本研究中,我們將聚苯胺的骨架引入具有三維立體結構的五苯荑分子,利用其本身特殊的立體結構將聚苯胺高分子鏈隔開,設計並合成出線性的APPANI及星狀的TAPPANI兩種高分子,探討其應用於超電容器電極材料的潛力。
結果顯示,由於五苯荑分子的引入,在苯胺成核的時期會作為模板參與聚合反應,並且得到不同於聚苯胺的表面形貌。TAPPANI和APPANI隨著摻入的比例不同而產生不同大小的球形聚集,相較於聚苯胺形成較紊亂的顆粒狀堆積,五苯荑分子的引入其特殊的孔洞讓聚苯胺長鏈之間可以有很好的分散效果。並且藉由電化學測量其循環穩定度,可以發現在經過1000次循環穩定度測試後,聚苯胺衰退了40 %,但是線性的APPANI和星狀的TAPPANI分子因為五苯荑的摻入使得衰退僅僅只有13 %及7 %,穩定度有明顯的提升。 透過APPANI及TAPPANI兩系列聚合物,我們也可以進而推論聚苯胺的膨脹效應受到空間排列的影響相當密切。藉由五苯荑分子的引入幫助我們了解有關其在超電容器材料之中的反應情形,有助於之後有關超電容器材料上的改良之研究。 | zh_TW |
dc.description.abstract | Supercapacitors have superior power density and stability as compared with batteries and higher energy density than conventional capacitors, making them attractive for energy storage applications. Polyaniline has been considered as promising supercapacitor electrode materials due to its high environmental stability, controllable electrical conductivity, easy processability and low cost. However, serious mechanical decay during the cycling test occurs for polyaniline devices. We have introduced the rigid and nonplanar pentiptycene scaffold to polyaniline, linear APPANI and star-shaped TAPPANI, to overcome this problem.
The results indicate that pentiptycene-containing starting materials act as a reaction template and replace the nucleation step in the chemical polymerization. Both APPANI and TAPPANI display sphere morphology of different size depending on the ratio of pentiptycene anilines versus anilines, which might account for the increased stability on the basis of the electrochemical analysis of cyclic voltammetry. After 1000 cycles, the pristine polyaniline film retains about 63 % of capacity whereas APPANI and TAPPANI retain 87 and 93% , respectively. This work allows one to understand the reaction associated with charging/discharging, and we believe that the stability of polyaniline is intimately related to the morphology. Our results may be helpful for future modification and application of model polyanilines as the electrode materials of supercapacitors. | en |
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dc.description.tableofcontents | 目錄
目錄 iii 圖目錄 vi 表目錄 x 附圖目錄 xi 1-1能源儲存 1 1-2超電容器簡介 3 1-2-1 超電容器原理 3 1-2-2超電容器分類 4 1-2-3 電極材料特性分析 7 1-3聚苯胺 9 1-3-1 聚苯胺導電原理簡介 9 1-3-2聚苯胺生成的反應機制 11 1-3-3 聚苯胺的奈米結構 14 1-3-4 聚苯胺的合成方式 16 1-3-5 寡聚物添加對聚苯胺奈米結構之影響 19 1-4 聚苯胺在超電容器應用 20 1-4-1聚苯胺應用於超電容器的限制 20 1-4-2聚苯胺超電容器的改善方針 22 1-4-3共軛導電高分子的奈米結構和表面性質改善 23 1-4-4聚苯胺高分子鏈的本質的改變 25 1-4-5製備成混合式超電容器 27 1-5 電化學電容器的介面化學分析 29 1-5-1 介面化學分析 29 1-5-2 掃描式電子顯微鏡 29 1-5-3 穿透式電子顯微鏡 30 1-5-4 BET比表面積及孔徑分析儀 31 1-6 超電容器的電化學分析 33 1-6-1 電化學分析簡介 33 1-6-2 循環伏安法 34 1-5-3恆電流充放電法 35 1-6-4 電化學阻抗光譜 36 1-7苯荑之化學 38 1-7-1苯荑分子應用於高分子之研究背景 38 1-7-2苯荑分子之結構與性質 38 1-7-3苯荑分子之合成 39 1-7-4 五苯荑醌之官能化 41 1-7-5苯荑分子於共軛高分子之應用 43 1-8 研究動機 46 2-1 單體之合成及電化學特性分析 49 2-1-1 含五苯荑分子之苯胺衍生物之合成策略分析 49 2-1-2 含五苯荑分子之苯胺衍生物之合成 50 2-1-3含胺基五苯荑單體分子之電化學性質 52 2-2 含五苯荑之聚苯胺之聚合及鑑定與性質 54 2-2-1含五苯荑之聚苯胺之聚合 54 2-2-2含五苯荑之聚苯胺之鑑定 57 2-2-3 聚苯胺及含五苯荑之聚苯胺之性質量測 62 2-3含五苯荑之聚苯胺高分子奈米結構和表面形態 65 2-3-1含五苯荑之聚苯胺高分子之SEM影像圖 65 2-3-2含五苯荑之聚苯胺高分子之TEM影像圖 71 2-3-3 聚苯胺及含五苯荑之聚苯胺高分子奈米結構形態分析 72 2-4 聚苯胺及含五苯荑之聚苯胺之表面分析 74 2-4-1聚苯胺及含五苯荑之聚苯胺之氮氣吸脫附等溫曲線 74 2-5聚苯胺與含五苯荑之聚苯胺作為超電容器電及材料之電化學分析 76 2-5-1聚苯胺與含五苯荑之聚苯胺作為超電容器電極之掃描速率分析 76 2-5-2聚苯胺與含五苯荑之聚苯胺作為電極之循環伏安法分析 79 2-5-3聚苯胺與含五苯荑之聚苯胺作為電極之恆電流充放電法分析 80 2-5-4聚苯胺與含五苯荑之聚苯胺作為電極之電化學阻抗光譜分析 82 2-5-5聚苯胺與含五苯荑之聚苯胺作為電極之循環穩定度分析 86 2-5-6聚苯胺與含五苯荑之聚苯胺進行循環穩定度前後之SEM影像 88 4-1 實驗的藥品與溶劑 92 4-2 實驗儀器 96 4-2-1化合物結構之鑑定 96 4-2-2純化系統 97 4-2-3化合物表面化學性質之量測 98 4-2-4化合物熱穩定、光物理與電化學性質之量測 98 4-2-5聚苯胺高分子超電容器電極之電化學性質之量測 99 4-3實驗步驟 100 參考資料 111 附圖 117 | |
dc.language.iso | zh-TW | |
dc.title | 含五苯荑骨架之聚苯胺之合成與作為超電容器電極材料之研究 | zh_TW |
dc.title | Synthesis of Pentiptycene-incorporated Polyanilines for Application as the Electrode Materials of Supercapacitors | en |
dc.type | Thesis | |
dc.date.schoolyear | 103-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 鄭淑芬(Soo-fin Cheng),張哲政(Che-Chen Chang) | |
dc.subject.keyword | 超電容器,五苯荑,穩定度,表面化學, | zh_TW |
dc.subject.keyword | supercapacitors,pentiptycene,stability, | en |
dc.relation.page | 165 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2015-07-29 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 化學研究所 | zh_TW |
顯示於系所單位: | 化學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
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ntu-104-1.pdf 目前未授權公開取用 | 24.12 MB | Adobe PDF |
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