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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 張豐丞 | |
| dc.contributor.author | Chia-Yuan Chang | en |
| dc.contributor.author | 張家源 | zh_TW |
| dc.date.accessioned | 2021-06-16T02:25:21Z | - |
| dc.date.available | 2018-08-31 | |
| dc.date.copyright | 2015-08-31 | |
| dc.date.issued | 2015 | |
| dc.date.submitted | 2015-08-06 | |
| dc.identifier.citation | 行政院環境保護署 (2014) 環境保護統計年報。行政院環境保護署。
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/53521 | - |
| dc.description.abstract | 木質素是一生物性材料，大量存在於植物體當中且為製漿過程之副產物，具有成本低、生物可分解等優點，本研究利用靜電紡絲技術將木質素製成奈米等級之纖維，並應用於空氣過濾方面。經實驗發現許多參數皆會影響纖維成型與否，不良的靜電紡絲條件會產生串珠結構、纖維表面不均勻等缺點，嚴重者甚至無法產生纖維結構，因此本研究以電子顯微鏡針對不同變因所形成之纖維進行照相，並以纖維直徑、形態等為主要分析目標。分析結果指出溶液濃度、針徑、電壓和流速等因子會顯著影響纖維直徑，且不同參數之間存在交互作用，將不同參數對纖維直徑之影響以統計分析所得迴歸式具有高度相關性。另外將木質素纖維所形成之薄膜進行空氣過濾試驗，結果顯示單獨使用木質素纖維並無法得到良好的過濾效果，此乃因其機械性質較弱等因素所造成。若將木質素和PEO結合市售口罩進行靜電紡絲作業後，所得複合式濾材具有良好的空氣過濾效果，達到N95標準，可作為未來改良、發展的目標。 | zh_TW |
| dc.description.abstract | Lignin is believed to be an important biomaterial, since a vast quantity of lignin would be byproduced during the pulping process. If reprocessing properly, we can not only achieve waste recovery but also reduce the cost of raw material. By introducing electrospinning technology, a layered-web structure of lignin fibers can be formed, which may have a great potential in filtration application. Therefore, the focus of this research was mainly on developing lignin fibers as filter media using electrospinning technique. The electrospinning process was operated and fibers were produced and analyzed, and various factors such as solution concentration, needle gauge, applied voltage and flow rate of solution were statistically significant on fiber diameters. Since different factors were correlated, multiple regression analysis was conducted. The regression model showed that fiber diameter was highly correlated with different factors and interaction terms. Furthermore, in order to evaluate the filtration efficiency of lignin-based filter, a series of tests were conducted. Preliminary results showed that the lignin-based filter had relatively insufficient efficiency due to its unfavorable mechanical properties. However, laminating with PEO fibers and surgical masks to form a lignin-based composite filter, according to the testing results, its filtration efficiency was comparable to N95 level. Therefore, the lignin-based composite filter was assumed to have a great potential on air filtration applications. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T02:25:21Z (GMT). No. of bitstreams: 1 ntu-104-R02625033-1.pdf: 5298018 bytes, checksum: 20db6eb2468b6ae63c34737395ed5686 (MD5) Previous issue date: 2015 | en |
| dc.description.tableofcontents | 摘 要 I
Abstract II 目 錄 III 圖 目 錄 V 表 目 錄 X 壹、前言 1 貳、研究目標 3 參、文獻回顧 5 一、木質素 5 (一) 木質素磺酸鹽Lignosulfonates 6 (二) Kraft 木質素 8 (三) 溶劑型木質素 9 二、靜電紡絲技術 10 (一) 歷史發展 10 (二) 應用領域 11 (三) 操作參數 15 三、簡介過濾相關背景 20 (一) 濾材的種類 20 (二) 濾材的過濾機制 21 (三) 氣體過濾理論 24 (四) 過濾效率分類 26 (五) 靜電紡絲應用於過濾之實例 30 (六) 木質素應用於過濾之實例 31 肆、材料設備與方法 32 一、木質素纖維 32 (一) 試驗材料 32 (二) 試驗方法 34 二、木質素濾材 35 (一) 試驗材料 35 (二) 試驗方法 36 伍、結果與討論 39 一、木質素纖維 39 (一) Lignosulfonates靜電紡絲操作參數 39 (二) 針徑對纖維直徑大小之影響 45 (三) 濃度、黏度對纖維直徑的影響 45 (四) 電壓、流速對纖維直徑的影響 51 (五) 多元迴歸分析 52 (六) 官能基分析 54 二、木質素濾材 55 (一) 純木質素濾材 55 (二) 木質素複合濾材 72 陸、結論與未來研究 79 柒、參考文獻 81 | |
| dc.language.iso | zh-TW | |
| dc.subject | 空氣過濾 | zh_TW |
| dc.subject | 木質素 | zh_TW |
| dc.subject | 纖維 | zh_TW |
| dc.subject | 靜電紡絲 | zh_TW |
| dc.subject | fiber | en |
| dc.subject | air filtration | en |
| dc.subject | Electrospinning | en |
| dc.subject | Lignin | en |
| dc.title | 應用靜電紡絲技術生產木質素纖維過濾材料 | zh_TW |
| dc.title | Developing Lignin-based Electrospun Fibrous Materials for Filtration | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 103-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳文章,胡明銓,林法勤 | |
| dc.subject.keyword | 木質素,纖維,靜電紡絲,空氣過濾, | zh_TW |
| dc.subject.keyword | Lignin,fiber,Electrospinning,air filtration, | en |
| dc.relation.page | 91 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2015-08-06 | |
| dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
| dc.contributor.author-dept | 森林環境暨資源學研究所 | zh_TW |
| 顯示於系所單位： | 森林環境暨資源學系 | |
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