請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/52856
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 錢義隆(I-Lung Chien) | |
dc.contributor.author | Yi-Chun Chen | en |
dc.contributor.author | 陳怡均 | zh_TW |
dc.date.accessioned | 2021-06-15T16:30:51Z | - |
dc.date.available | 2018-11-30 | |
dc.date.copyright | 2015-11-30 | |
dc.date.issued | 2015 | |
dc.date.submitted | 2015-08-13 | |
dc.identifier.citation | [1] Tyreus, B. D., Distillation–Energy Conservation and Process Control, a 35 Year Perspective, AIChE Annual Meeting, October 16-21, 2011, Minneapolis MN, U.S.A.
[2] Julka, V.; Chiplunkar, M.; O’Young, L., Selecting Entrainers for Azeotropic Distillation, Chem. Eng. Prog., 2009, 105, 3, 47. [3] Luyben, W. L.; Chien, I. L., Design and Control of Distillation Systems for Separating Azeotropes, Wiley: Hoboken, New Jersey, 2010. [4] Ayoub, M.; Abdullah, A. Z. Critical review on the current scenario and significance of crude glycerol resulting from biodiesel industry towards more sustainable renewable energy industry., Renew. Sust. Energ. Rev., 2012, 16, 2671-2686. [5] Rahmat, N.; Abdullah, A. Z.; Mohamed, A. R., Recent Progress on Innovative and Potential Technologies for Glycerol Transformation into Fuel Additives: A Critical Review., Renew. Sust. Energ. Rev., 2010, 14, 987-1000. [6] Posada, J. A.; Rincón, L. E.; Cardona, C. A., Design and Analysis of Biorefineries Based on Raw Glycerol: Addressing the Glycerol Problem., Bioresour. Tehcnol., 2012, 111, 282-293. [7] Torres, A.; Roy, D.; Subramaniam, B.; Chaudhari, R. V., Kinetic Modeling of Aqueous-phase Glycerol Hydrogenolysis in a Batch Slurry Reactor., Ind. Eng. Chem. Res., 2010, 49, 10826-10835. [8] Wasylkiewicz, S. K.; Kobylka, L. C.; Castillo, F. J. L., Optimal Design of Complex Azeotropic Distillation Columns., Chem. Eng. J., 2000, 79, 219-227. [9] Chien, I. L.; Zeng, K. L.; Chao, H. Y.; Liu, J. H., Design and Control of Acetic Acid Dehydration System via Heterogeneous Azeotropic Distillation., Chem. Eng. Sci., 2004, 59, 4547-4567. [10] Chien, I. L.; Kuo, C. L., Investigating the Need of a Pre-concentrator Column for Acetic Acid Dyhydration System via Heterogeneous Azeotropic Distillation, Chem. Eng. Sci., 2006, 61, 569-585. [11] Chien, I. L.; Huang, H. P.; Gau, T. K.; Wang, C. H., Influence of Feed Impurity on the Design and Operation of an Industrial Acetic Acid Dehydration Column., Ind. Eng. Chem. Res., 2005, 44, 3510-3521. [12] Huang, H. P.; Lee, H. Y.; Gau, T. K.; Chien, I. L. Design and Control of Acetic Acid Dehydration Column with p-Xylene or m-Xylene Feed Impurity. 1. Importance of Feed Tray Location on the Process Design., Ind. Eng. Chem. Res., 2007, 46, 505-517. [13] Wang, S. J.; Huang, K., Design and Control of Acetic Acid Dehydration System via Heterogeneous Azeotropic Distillation Using p-Xylene as an Entrainer, Chem. Eng. Proc., 2012, 60, 65-76. [14] Huang, X.; Zhong, W.; Du, W.; Qian, F., Thermodynamic Analysis and Process Simulation of an Industrial Acetic Acid Dehydration System via Heterogeneous Azeotropic Distillation., Ind. Eng. Chem. Res., 2013, 52, 2944-2957. [15] Jongmans, M. T. G.; Schuur, B.; de Haan, A. B., Ionic Liquid Screening for Ethylbenzene/styrene Separation by Extractive Distillation., Ind. Eng. Chem. Res., 2011, 50, 10800-10810. [16] Jongmans, M. T. G.; Hermens, E.; Raijmakers, M.; Maassen J. I. W.; Schuur, B.; de Haan, A. B., Conceptual Process Design of Extractive Distillation Processes for Ethylbenzene/styrene Separation., Chem. Eng. Res. Des., 2012, 90, 2086-2100. [17] Lek-utaiwan, P.; Suphanit, B.; Douglas, P. L.; Mongkolsiri, N., Design of Extractive Distillation for the Separation of Close-boiling Mixtures: Solvent Selection and Column Optimization., Comput. Chem. Engng., 2011, 35, 1088-1100. [18] Long, N. V. D.; Lee, M., Optimal Retrofit Design of Extractive Distillation to Energy Efficient Thermally Coupled Distillation Scheme., AIChE J., 2013, 59, 1175-1182. [19] Shiau, L. D.; Wen, C. C.; Lin, B. S., Separation and Purification of p-Xylene from the Mixture of m-Xylene and p-Xylene by Distillative Freezing., Ind. Eng. Chem. Res., 2005, 44, 2258-2265. [20] Shiau, L. D.; Liu, K. F.; Jang, S. M.; Wu, S. C., Separation of Diethylbenzene Isomers by Distillative Freezing., J. Chin. Inst. Chem. Eng., 2008, 39, 59-65. [21] Shiau, L. D.; Lai, M. H.; Liu, K. F., Purification of C9 Arenes by Stripping Crystallization., Chem. Eng. Tech., 2011, 34, 1335-1340. [22] Micovic, J.; Beierling, T.; Lutze, P.; Sadowski, G.; Górak, A., Design of Hybrid Distillation/melt Crystallization Processes for Separation of Close Boiling Mixtures., Chem. Eng. Proc., 2013, 67, 16-24. [23] Doherty, M. F.; Malone, M. F., Conceptual Design of Distillation Systems; McGraw-Hill: New York, NY, 2001. [24] Berg, L., Separation of Propylene Glycol from Ethylene Glycol by Azeotropic distillation, U. S. Patent 5,425,851, 1995. [25] Dhale, A. D.; Myrant, L. K.; Chopade, S. P.; Jackson, J. E.; Miller, D. J., Propylene Glycol and Ethylene Glycol Recovery from Aqueous Solution via Reactive Distillation., Chem. Eng. Sci., 2004, 59, 2881-2890. [26] Oh, B. K.; Lee, Y. M., Effects of Functional Group and Operating Temperature on the Separation of Pyridine-Water mixture by Pervaporation., J. Membrane Sci., 1996, 113, 183. [27] Lv, J.; Xiao, G., Ultrasound Assisted Pervaporation Separation of Pyridine/Water Mixtures Using Poly(vinyl alcohol)/Polyacrylonitrile Blend Membrains., Chem. Eng. Technol., 2010, 33, 2051. [28] Pommier, S.; Massebeuf, S.; Kotai, B.; Lang, P.; Baudouin, O.; Floquet, P.; Gerbaud, V., Heterogeneous Batch Distillation Processes: Real System Optimisation., Chem. Eng. Proc., 2008, 47, 408. [29] Wu, Y. C.; Chien, I. L., Design and Control of Heterogeneous Azeotropic Column System for the Separation of Pyridine and Water., Ind. Eng. Chem. Res., 2009, 48, 10564. [30] Wu, Y. C.; Lee, H. Y.; Huang, H. P.; Chien, I. L., Energy-Saving Dividing-Wall Column Design and Control for Heterogeneous Azeotropic Distillation Systems., Ind. Eng. Chem. Res., 2014, 53, 1537. [31] McCabe, W. L.; Smith, J. C.; Harriott, P., Unit Operations of Chemical Engineering; 7th ed., McGraw Hill: New York, 2005. [32] Kürüm, S.; Fonyo, Z.; Kut, Ö, M., Design Strategy for Acetic Acid Recovery., Chem. Eng. Comm., 1995, 136, 161. [33] Martínez, A. A.; Saucedo-Luna, J.; Segovia-Hernandez, J. G.; Hernandez, S.; Gomez-Castro, F. I.; Castro-Montoya, A. J., Dehydration of Bioethanol by Hybrid Process Liquid-Liquid Extraction/Extractive Distillation., Ind. Eng. Chem. Res., 2012, 51, 5847. [34] Pereiro, A. B.; Rodríquez, A., Effective Extraction in Packed Column for Ethanol from the Azeotropic Mixture Ethanol + Hexane with an Ionic Liquid as Solvent., Chem. Eng. J., 2009, 153, 85. [35] Pereiro, A. B.; Rodríquez, A., Azeotrope-breaking Using [BMIM][MeSO4] Ionic Liquid in an Extraction Column., Sep. Pur. Tech., 2008, 62, 733. [36] Pereiro, A. B.; Rodríquez, A., Separation of Ethanol-Heptane Azeotropic Mixtures by Solvent Extraction with an Ionic Liquid., Ind. Eng. Chem. Res., 2009, 48, 1579. [37] Pereiro, A. B.; Araújo, J. M. M.; Esperanca, J. M. S. S.; Marrucho, I. M.; Rebelo, L. P. N., Ionic Liquids in Separations of Azeotropic Systems – A Review., J. Chem. Thermodynamics, 2012, 46, 2. [38] Garcia-Chavez, L. Y.; Schuur, B.; de Haan, A. B., Conceptual Process Design and Economic Analysis of a Process Based on Liquid-Liquid Extraction for the Recovery of Glycols from Aqueous Streams., Ind. Eng. Chem. Res., 2013, 52, 4902. [39]吳義章(2009), “各類非均勻相共沸蒸餾系統之設計與控制” , 國立台灣科技大學化學工程研究所碩士論文 [40]許仲志(2010), “各類共沸蒸餾系統之程序設計與控制” , 國立台灣科技大學化學工程研究所碩士論文 [41] Qin, J.; Ye, Q.; Xiong, X.; Li, N.; Control of Benzene−Cyclohexane Separation System via Extractive Distillation Using Sulfolane as Entrainer., Ind. Eng. Chem. Res., 2013, 52, 10754-10766 [42] 魏民忠(2008), “各類批次蒸餾系統採中槽配置的操作與控制” , 國立台灣科技大學化學工程研究所碩士論文 [43] Doherty, M. F.; Malone, M. F., Distillation, Azeotropic, and Extractive in Kirk-Othmer Encyclopedia of Chemical Technology, 5th ed., Vol. 8; Wiley: Hoboken, New Jersey, 2007. [44] Gmehling, J.; Möllmann, C., Synthesis of distillation processes using thermodynamic models and the Dortmund data bank., Ind. Eng. Chem. Res., 1998, 37, 3112-3123 [45] Dharmendira Kumar, M.; Rajendran, M. J., Effect of Dissolved Salts on the Vapor-Liquid Equilibrium Relationships of Three Miscible Binary Systems at the Pressure of 101.3 kPa, Chem. Eng. Jpn., 1998, 31(5), 749-757 [46] Hsu, K. Y.; Hsiao, Y. C.; Chien, I. L., Design and Control of a Dimethyl Carbonate-Methanol Separation via Extractive Distillation in the Dimethyl Carbonate Reactive-Distillation Process., Ind. Eng. Chem. Res., 2010, 49, 735. [47] Chen, Y. C.; Hung, S. K.; Lee, H. Y.; Chien, I. L., Energy-Saving Designs for Separation of a Close-Boiling 1,2-Propanediol and Ethylene Glycol Mixture., Ind. Eng. Chem. Res., 2015, 54, 3828. [48] Kürüm, S.; Fonyo, Z.; Kut, Ö, M., Design Strategy for Acetic Acid Recovery., Chem. Eng. Comm., 1995, 136, 161. [49] Katsumi, T.; Hideyrki, T.; Yoshinnori, S.; Yosyto, K., Isobaric Vapor-liquid Equilibria Water + Propylene Glycol Monomethyl Ether (PGME), Water + Propylene Glycol Monomethyl Ether Acetate (PGMEA), and PGME + PGMEA at Reduced Pressures, Fluid Phase Equilib., 2007, 260, 65-69. [50] Cui, Z.; Li, Z.; Gao, Z.; Li, J., Vapor-liquid Equilibria of n-Methylpyrrolidone(1)-Water(2) Binary System by an Ebulliometer, Chin. J. Chem. Eng., 1994, V2(2): 119-124. [51] Yu, Y. X.; Liu, J. G.; Gao, G. H., Isobaric Vapor-liquid Equilibria and Excess Volumes for the Binary Mixtures Water + Sulfolane, Water + Tetraethylene Glycol, and Benzene + Tetraethylene Glycol, J. Chem. Eng. Data, 2000, 45, 570-574. [52] Gmehling, J.; Mollmann, C.; Synthesis of Distillation Process Using Thermodynamic Models and the Dortmund Data Bank, Ind. End. Chem. Res., 1998, 37, 3112-3123. [53] Luyben, W. L., Comparison of Extractive Distillation and Pressure-swing Distillation for Acetone/chloroform Separation., Comput. Chem. Engng., 2013, 50, 1-7. [54] Seider, W. D.; Seader, J. D.; Lewin, D. R.; Widagdo, S., Product and Process Design Principles, 3rd ed., Wiley: Hoboken, New Jersey, 2009. [55] Chiang, T. P.; Luyben, W. L., Comparison of Energy Consumption in Five Heat-integrated Distillation Configurations., Ind. Eng. Chem. Process Des. Dev., 1983, 22, 175-179. [56] Chiang, T. P.; Luyben, W. L., Comparison of the Dynamic Performances of Three Heat-integrated Distillation Configurations., Ind. Eng. Chem. Res., 1988, 27, 99-104. [57] Douglas, J. M., Conceptual Design of Chemical Processes, McGraw-Hill, New York, 1988. [58] Knight, J. R; Doherty, M.F., Optimal Design and Synthesis of Homogeneous Azeotropic Distillation Sequences, Ind. Eng. Chem. Res., 28, 564-72. [59] Luyben, W. L., Principles and Case Studies of Simultaneous Design, Wiley: Hoboken, New Jersey, 2011. [60] Tyreus, B. D.; Luyben, W. L., Tuning PI Controllers for Integrator/Deadtime Processes., Ind. Eng. Chem. Res., 1992, 31, 2625. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/52856 | - |
dc.description.abstract | 本文探討各類近沸或共沸混合物分離之節能設計流程。首先討論近沸物質1,2-丙二醇和乙二醇之各種分離設計流程,包括單一蒸餾塔、多效熱整合、非勻相共沸蒸餾與萃取蒸餾系統,並透過熱整合或熱耦合 (thermally-couple) 的方式節能。若採用多效熱整合蒸餾系統,仍需要高蒸餾板數才能獲得高純度之產品,且為了避免低壓時存在之切線狹點,低壓塔設定為一大氣壓,反而會造成高壓塔再沸器不適合使用高壓蒸汽。若採用非勻相共沸蒸餾系統,由於進料組成中1,2-丙二醇成分較高,因此能預期非勻相共沸蒸餾塔內部流循環率將會很高。最後發現以三甘醇作為萃取劑之萃取蒸餾系統,並進行熱整合以將萃取劑回收流與進料流進行熱交換之設計流程最具經濟效益。
本文亦針對Pyridine與水的分離系統,討論萃取/蒸餾複合系統 (hybrid extraction/distillation system) 之程序設計與動態控制策略。探討n-propyl formate (NPF) 與diisopropyl ether (DIPE) 作為溶劑之萃取/蒸餾複合系統,並進行最適化分析。由於液-液相萃取塔不需要蒸汽,因此與非勻相共沸蒸餾系統或是隔牆塔設計相比,能大幅節省操作費用。若考量萃取塔各板與液-液分相槽中兩液相之密度差,將發現液-液相分離以DIPE作為溶劑實際上較可行。本文也討論萃取/蒸餾複合系統之動態模擬,並得知最適化流程與動態控制能力之間有經濟損益關係。最後進行閉環干擾排除測試,以確認儘管進料組成或是流率干擾,本文提出之控制策略仍能正確地維持高純度之產品規格。 本文也針對丙二醇甲醚與水的分離系統,討論改良之萃取蒸餾系統,以改善高沸點環丁碸作為萃取劑造成萃取劑回收塔塔底溫度過高的問題。結果發現以較低沸點但提升水對丙二醇甲醚之相對揮發度能力較差的N-Methyl-2-pyrrolidone (NMP) 作為萃取劑並無經濟效益。若繼續以環丁碸為萃取劑,但將萃取劑回收塔改為低壓塔,雖然設備成本增加,減少的蒸汽費用卻更加顯著,使得此低壓塔系統能夠大幅減少年度總成本。本文最後亦說明若欲以萃取/蒸餾複合系統進行丙二醇甲醚去水流程,必須找尋到合適的溶劑方能進行。 藉由討論上述之三個近沸或共沸物之節能設計流程,能發現儘管對於特定的混合物系統可以用不只一種方式來完成分離,但若是能夠選擇使用最適合之分離方式則可以大幅節省蒸汽費用與年度總成本。 | zh_TW |
dc.description.abstract | In this thesis, energy-saving design and control for the separation of close-boiling or azeotropic mixtures will be discussed. For the separation of close-boiling mixtures, 1,2-propanediol and ethylene glycol, several alternative designs, including multi-effect distillation, heterogeneous azeotropic distillation, and extractive distillation, are investigated in order to save steam cost and total annual cost. Extractive distillation system using triethylene glycol as entrainer with a feed-effluent heat exchanger is considered to be the most economic design.
For the separation of pyridine and water, hybrid extraction/distillation system using n-propyl format (NPF) or diisopropyl ether (DIPE) as solvent is proposed. Since the main extraction column does not require steam, this design flowsheet can significantly save operating cost as compared to the previous designs based on heterogeneous azeotropic distillation. Considering the density differences in each stage of extraction column and in decanter, DIPE is a more practically favorable solvent for reaching liquid-liquid equilibrium in each stage. Dynamic control of this proposed system is also investigated. It is found that a trade-off between optimal steady-state design and dynamic controllability needs to be made in order to properly reject feed flow rate and feed composition disturbances. For the separation of propylene glycol monomethyl ether (PM) and water, two modifications have been made in extractive distiilation system in order to overcome the drawback of high bottom temperature in entrainer recovery column due to using high-boiling sulfolane as entrainer. With relatively low-boiling n-methyl-2-pyrrolidone (NMP) as entrainer, steam cost reduces, but overall result does not show any encomic benefit due to NMP’s low enhancement of relative volatility of water over PM. Instead, decreasing the pressure of entrainer recovery column, significant reduction in steam cost and total annual cost can be obtained. For the same separation task, hybrid extraction/distillation system is also considered. However, a suitable solvent is important for effective extraction process but none of any has been found in open literature. In summary, for a particular close-boiling or azeotropic mixture, there are more than one ways to achieve the separation task. However, significant savings on the steam cost and total annual cost can be achieved if the most suitable separation method can be selected. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T16:30:51Z (GMT). No. of bitstreams: 1 ntu-104-R02524035-1.pdf: 7120920 bytes, checksum: 35c69fa58900a2f2baae3b347a70f971 (MD5) Previous issue date: 2015 | en |
dc.description.tableofcontents | 目錄
誌謝 I 摘要 II Abstract IV 目錄 VI 圖目錄 VIII 表目錄 XI 1. 緒論 1 1.1 前言 1 1.2 文獻回顧 3 1.2.1 1,2-丙二醇與乙二醇之分離系統 3 1.2.2 Pyridine去水系統 5 1.2.3 丙二醇甲醚去水系統 10 2. 熱力學模式 14 2.1 引言 14 2.2 1,2-丙二醇與乙二醇之分離系統 15 2.3 Pyridine去水系統 22 2.4 丙二醇甲醚去水系統 29 3. 穩態模擬與最適化分析 37 3.1 引言 37 3.2 1,2-丙二醇與乙二醇之分離系統 38 3.2.1 單一蒸餾塔 39 3.2.2 多效熱整合蒸餾系統 44 3.2.3 非勻相共沸蒸餾系統 50 3.2.4 萃取蒸餾系統 53 3.2.5 小結 64 3.3 Pyridine去水系統 66 3.3.1 萃取/蒸餾複合系統 66 3.4 丙二醇甲醚去水系統 78 3.4.1 萃取蒸餾系統 78 3.4.2 萃取/蒸餾複合程序 90 4. 動態模擬 92 4.1 引言 92 4.2 Pyridine去水系統 93 4.2.1 干擾排除能力分析 93 4.2.2 控制架構與策略 96 5. 結論及未來工作 103 6. 參考文獻 107 附錄 分項年度總成本計算公式 113 | |
dc.language.iso | zh-TW | |
dc.title | 各類近沸或共沸混合物分離之節能設計與控制 | zh_TW |
dc.title | Energy-saving Design and Control for the Separation of Close-boiling or Azeotropic Mixtures | en |
dc.type | Thesis | |
dc.date.schoolyear | 103-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 陳誠亮(Cheng-Liang Chen),李豪業(Hao-Yeh Lee),王國彬,陳逸航 | |
dc.subject.keyword | 近沸,共沸,多效熱整合,非勻相共沸蒸餾,萃取蒸餾,萃取/蒸餾複合系統,程序設計,程序控制, | zh_TW |
dc.subject.keyword | Close-boiling,azeotropes,multi-effect distillation,heterogeneous azeotropic distillation,extractive distillation,hybrid extraction/distillation system,process design,process control, | en |
dc.relation.page | 115 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2015-08-13 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-104-1.pdf 目前未授權公開取用 | 6.95 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。